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1. 发明授权

US06495641B1 Catalysts based on vanadium, their preparation and use in the (CO) polymerization of &agr;-olefins 有权
标题翻译：基于钒的催化剂，它们的制备和在α-烯烃（CO））聚合中的应用
公开(公告)号：US06495641B1
公开(公告)日：2002-12-17
申请号：US09442647
申请日：1999-11-18
申请人： Francesco Masi , Liliana Gila , Roberto Santi , Antonio Proto , Evelina Ballato , Anna Maria Romano
发明人： Francesco Masi , Liliana Gila , Roberto Santi , Antonio Proto , Evelina Ballato , Anna Maria Romano
IPC分类号： C08F468
CPC分类号： C07F9/005 , C08F10/00 , C08F210/16 , C08F210/18 , C08F4/68 , C08F210/06 , C08F2500/03 , C08F2500/25
摘要： Vanadium complex having general formula (I) (RCOO)nVXpLm (I) wherein R is a monofunctional hydrocarbon radical having from 1 to 20 carbon atoms and from 1 to 6 halogen atoms, selected from chlorine and bromine, preferably chlorine; X is chlorine or bromine, preferably chlorine; L is an electron donor; p+n=3, 4 or 5, preferably=3; n is greater than or equal to 1; m is between 0 and 3. The preparation of the above complex is also described together with its use in the (co)polymerization of &agr;-olefins.
摘要翻译：具有通式（I）的钒络合物，其中R是具有1至20个碳原子和1至6个选自氯和溴，优选氯的卤素原子的单官能烃基; X是氯或溴，优选氯; L是电子给体; p + n = 3,4或5，优选= 3; n大于或等于1; m在0和3之间。上述络合物的制备也与其在α-烯烃的（共）聚合中的应用一起被描述。

2. 发明授权

US5861352A Supported metallocene catalyst for olefins (co)polymerization 失效
标题翻译：用于烯烃（共）聚合的负载金属茂催化剂
公开(公告)号：US5861352A
公开(公告)日：1999-01-19
申请号：US593523
申请日：1996-01-30
申请人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
发明人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
IPC分类号： C08F4/642 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： A solid catalyst component for the polymerization and copolymerization of ethylene and alpha- olefins, containing a metallocene supported on an inorganic solid carrier constituted by a porous silicon oxide, the supported metallocene having the formula (I): ##STR1## wherein M is a group of metal, R' and R" are dialkylamide groups, R'" has the same definition as R' or is a cyclopentadienyl consisting ligand, and A is an anion containing an .eta..sup.5 -cyclopentadienyl ring coordinated to metal M, and wherein a carbon atom of the .eta..sup.5 -cyclopentadienyl ring of anion A is covalently bonded to the surface of the porous inorganic solid carrier.
摘要翻译：一种用于乙烯和α-烯烃的聚合和共聚的固体催化剂组分，其包含负载在由多孔氧化硅构成的无机固体载体上的金属茂，所述支化金属茂具有式（I）：其中M 是一组金属，R'和R“是二烷基酰胺基团，R”具有与R'相同的定义，或是作为环戊二烯基的配体，A是含有与金属M配位的η5环戊二烯基环的阴离子并且其中阴离子A的η5 5-环戊二烯基环的碳原子共价键合到多孔无机固体载体的表面。

3. 发明授权

US5846895A Supported metallocene complex and process for its preparation 失效
标题翻译：负载金属茂络合物及其制备方法
公开(公告)号：US5846895A
公开(公告)日：1998-12-08
申请号：US837898
申请日：1997-04-22
申请人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
发明人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
IPC分类号： C07F17/00 , C08F4/02 , C08F4/656 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/941
摘要： A supported metallocene complex of a metal M selected from Ti, Zr or Hf, is prepared by a process comprising, in a first step, the reaction of an inorganic carrier containing hydroxyl groups with a compound (II) containing a cyclopentadienyl group and at least one alkoxysilane group reactive with said hydroxyl groups so as to chemically bind said cyclopentadienyl group to said carrier; and in a second step the reaction with a complex of said metal M capable of reacting with said supported cyclopentadienyl group without carrying out any intermediate metallation of the latter. This process is simple and convenient, and enables high concentrations of metal stably bound to the carrier, to be reached. The complex thus obtained can be used as solid component of a catalyst active in the polymerization of .alpha.-olefins, in the presence of a suitable co-catalyst, preferably consisting of an organo-oxygenated derivative of aluminum.
摘要翻译：选自Ti，Zr或Hf的金属M的负载茂金属络合物通过以下方法制备，所述方法包括：在第一步中，将含有羟基的无机载体与含有环戊二烯基的化合物（II）一个烷氧基硅烷基团与所述羟基反应，以便将所述环戊二烯基化学结合到所述载体上; 并且在第二步中与能够与所述负载的环戊二烯基反应的所述金属M的络合物进行反应而不进行后者的任何中间金属化。该方法简单方便，可达到稳定结合载体的高浓度金属。由此获得的络合物可以在合适的助催化剂，优选由铝的有机 - 氧化衍生物组成的情况下用作在α-烯烃的聚合中有活性的催化剂的固体组分。

4. 发明授权

US06833465B2 Stabilized metallocene compounds of transition metals of group 4 and process for their preparation 有权
标题翻译：第4组过渡金属的稳定金属茂化合物及其制备方法
公开(公告)号：US06833465B2
公开(公告)日：2004-12-21
申请号：US10670348
申请日：2003-09-26
申请人： Francesco Masi , Anna Sommazzi , Giampietro Borsotti , Evelina Ballato , Roberto Santi
发明人： Francesco Masi , Anna Sommazzi , Giampietro Borsotti , Evelina Ballato , Roberto Santi
IPC分类号： C07F1700
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F8/04 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65925 , C08F4/65927 , C08F4/6592 , C08F2500/03 , C08F210/14
摘要： A metallocene compound of a metal M of group 4 in the table of elements, comprising a cyclopentadienyl group and at least one oligomeric group R′ bonded to M, having the following formula (II): -(AxDyUz)RI (II) wherein: A represents any monomeric unit deriving from a vinylaromatic group polymerizable by means of anionic polymerization, having from 6 to 20 carbon atoms; D represents any monomeric unit deriving from a conjugated diolefin polymerizable by means of anionic polymerization, having from 4 to 20 carbon atoms; U represents any generic optional monomeric unit deriving from an unsaturated compound copolymerizable with any of the above conjugated diolefins D or vinylaromatic compounds A; RI represents hydrogen or a hydrocarbyl group having from 1 to 20 carbon atoms, each index “x” and “y” can be independently zero or an integer, provided the sum (x+y) is equal to or higher than 2, preferably between 2 and 50, more preferably between 2 and 25; “z” can be zero or an integer ranging from 1 to 20. Said complex can be used for the formation of catalytic systems, in particular for the (co)polymerization of olefins, with enhanced stability and a high activity, so as to enable transportation and storage for prolonged periods of time.
摘要翻译：元素表中第4族金属M的茂金属化合物，其包含环戊二烯基和至少一个与M键合的低级基团R'，具有下式（II）：其中：A表示衍生自通过阴离子聚合可聚合的乙烯基芳族基团，具有6至20个碳原子; D表示衍生自具有4至20个碳原子的通过阴离子聚合可共聚的共轭二烯烃的任何单体单元; U表示任何通用的任选单体单元衍生物可以与任何上述共轭二烯烃D或乙烯基芳族化合物A共聚的不饱和化合物; R 1表示氢或具有1至20个碳原子的烃基，每个指数“x”和“y”可以独立地为零或（x + y）等于或高于2，优选在2和50之间，更优选在2和25之间;“z”可以是0或1至20的整数。 lex可以用于形成催化体系，特别是用于烯烃的（共）聚合，具有增强的稳定性和高活性，从而使得运输和储存更长时间。

5. 发明授权

US5529966A Catalyst and process for (co)polymerizing alpha-olefins 失效
标题翻译：用于（共）聚合α-烯烃的催化剂和方法
公开(公告)号：US5529966A
公开(公告)日：1996-06-25
申请号：US138980
申请日：1993-10-21
申请人： Luciano Luciani , Federico Milani , Liliana Gila , Evelina Ballato
发明人： Luciano Luciani , Federico Milani , Liliana Gila , Evelina Ballato
IPC分类号： B01J31/38 , C08F4/60 , C08F4/642 , C08F4/651 , C08F4/654 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , B01J31/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925
摘要： A catalyst active in the polymerization of alpha-olefins is formed by:(a) a bis(cyclopentadienyl) bis(amide) derivative of an element of Group IVB of the Periodic Table of the Elements, to be defined by means of the formula: ##STR1## wherein M represents a metal of Group IVB, each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, and Cp have the same meaning as reported in the disclosure, and(b) an aluminoxane co-catalyst.This catalyst finds use in the processes of ethylene and other alpha-olefins polymerization and copolymerization.
摘要翻译：通过以下方式形成在α-烯烃聚合中有效的催化剂：（a）元素周期表第IVB族元素的双（环戊二烯基）双（酰胺）衍生物，其通过下式定义：（I）其中M表示IVB族金属，R 1，R 2，R 3和R 4以及Cp各自具有与本公开中所报道的相同的含义，和（b）铝氧烷助催化剂。该催化剂用于乙烯和其他α-烯烃聚合和共聚过程中。

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