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1. 发明授权

US4722975A Crosslinkable copolymer composition and a method for the preparation thereof 失效
标题翻译：可交联共聚物组合物及其制备方法
公开(公告)号：US4722975A
公开(公告)日：1988-02-02
申请号：US800433
申请日：1985-11-21
申请人： Kunio Itoh , Yasuo Tarumi , Tsutomu Nakamura , Hiroyuki Ohata , Tsutomu Matsuo , Harukazu Okuda
发明人： Kunio Itoh , Yasuo Tarumi , Tsutomu Nakamura , Hiroyuki Ohata , Tsutomu Matsuo , Harukazu Okuda
IPC分类号： C08F8/42
CPC分类号： C08F8/42
摘要： The inventive copolymer composition is satisfactorily curable or vulcanizable into, for example, a rubbery elastomer even by an organic peroxide contained therein as a crosslinking agent. The crosslinkable copolymer comprised therein is a polymer having, in a molecule, at least two monomeric units each having a vinyl-containing organosilicon pendant group represented by the general formula (Vi.sub.m R.sup.1.sub.n SiO).sub.a Vi.sub.b R.sup.2.sub.c Si--, in which Vi is a vinyl group, R.sup.1 is a hydrogen atom or a group selected from the class consisting of monovalent hydrocarbon groups free from aliphatic unsaturation, hydroxy group and hydrolyzable groups excepting halogen atoms, R.sup.2 is a hydrogen atom or a monovalent hydrocarbon group, m is 1, 2 or 3, n is zero, 1 or 2, a is 1, 2 or 3, b is zero, 1 or 2 and c is zero, 1 or 2 with the proviso that a+b=1, 2 or 3 and a+b+c=3. Such a copolymer can be prepared by the copolymerization of a first ordinary ethylenically unsaturated monomer and a second monomer having, simultaneously in a molecule, an ethylenically unsaturated linkage copolymerizable with the first monomer and the vinyl-containing organosilicon group of the above given formula.
摘要翻译：本发明的共聚物组合物甚至可以通过其中含有的有机过氧化物作为交联剂令人满意地固化或硫化成例如橡胶弹性体。包含在其中的可交联共聚物是分子中具有至少两个单体单元的聚合物，每个单体单元具有由通式（VimR1nSiO）aVibR2cSi-表示的含乙烯基的有机硅侧基，其中Vi是乙烯基，R1是氢原子或选自不含脂肪族不饱和键的一价烃基，羟基和除卤素原子外的可水解基团的基团，R 2为氢原子或一价烃基，m为1,2或3，n为0 ，1或2，a为1,2或3，b为0,1或2，c为0,1或2，条件是a + b = 1,2或3，a + b + c = 3。这种共聚物可以通过共聚第一普通烯键式不饱和单体和第二单体来制备，该单体在分子中同时具有可与上述给定式的第一单体和含乙烯基的有机硅基团共聚的烯属不饱和键。

2. 发明授权

US5164442A Rubber composition 失效
公开(公告)号：US5164442A
公开(公告)日：1992-11-17
申请号：US504364
申请日：1990-04-04
申请人： Kunio Itoh , Motoo Fukushima , Tsutomu Nakamura , Hiroyuki Ohata , Harukazu Okuda
发明人： Kunio Itoh , Motoo Fukushima , Tsutomu Nakamura , Hiroyuki Ohata , Harukazu Okuda
IPC分类号： C08F283/12 , C08K3/00 , C08K5/00 , C08K13/02 , C08L51/08 , C08L83/10
CPC分类号： C08L83/10 , C08F283/122 , C08K13/02 , C08L51/085
摘要： The polymeric ingredient of the inventive rubber composition is an acrylic polymer modified with a mercapto-containing organopolysiloxane as prepared by the emulsion polymerization of an acrylic monomer in an aqueous emulsion of the organopolysiloxane. Characteristically, the acrylic monomer is copolymerized with another monomer having an active halogen atom or an epoxy group. By virtue of this unique formulation of the rubbery polymer, the inventive rubber composition prepared by compounding the rubbery polymer with a reinforcing filler and a specified curing or crosslinking agent can be vulcanized to give a vulcanizate having excellent mechanical properties, heat resistance, oil resistance and cold resistance as a combination of the features of silicone rubbers and acrylic rubbers.

3. 发明授权

US5232997A Method for the preparation of an acrylic polymer modified with an organopolysiloxane 失效
标题翻译：制备用有机硅氧烷改性的丙烯酸聚合物的方法
公开(公告)号：US5232997A
公开(公告)日：1993-08-03
申请号：US670276
申请日：1991-03-15
申请人： Kunio Itoh , Motoo Fukushima , Toshio Ohba , Hiroyuki Ohata , Harukazu Okuda
发明人： Kunio Itoh , Motoo Fukushima , Toshio Ohba , Hiroyuki Ohata , Harukazu Okuda
IPC分类号： C08F230/08 , C08F290/06
CPC分类号： C08F230/08 , C08F290/068
摘要： An acrylic rubbery polymer having remarkably improved cold resistance can be prepared by modification with an organopolysiloxane by the emulsion copolymerization of a monomeric mixture of two acrylic monomers, of which one is, for example, an alkyl acrylate and the other is an acrylic compound having, in a molecule, at least one ethylenically unsaturated group other than acrylic group in an aqueous emulsion of an organopolysiloxane having a substantial amount of mercapto-substituted monovalent hydrocarbon groups bonded to the silicon atoms.
摘要翻译：具有显着改善的耐寒性的丙烯酸类橡胶状聚合物可以通过用两种丙烯酸类单体的单体混合物的乳液共聚物进行改性来制备，其中一种是例如丙烯酸烷基酯，另一种是丙烯酸类化合物，在具有大量巯基取代的单价烃基键合到硅原子的有机聚硅氧烷的水性乳液中，在分子中至少有一个除丙烯酸以外的烯属不饱和基团。

4. 发明授权

US4910278A Monomeric composition and polymer therefrom 失效
标题翻译：单体组成和聚合物
公开(公告)号：US4910278A
公开(公告)日：1990-03-20
申请号：US368513
申请日：1989-06-20
申请人： Kunio Itoh , Motoo Fukushima , Harukazu Okuda , Hiroyuki Ohata
发明人： Kunio Itoh , Motoo Fukushima , Harukazu Okuda , Hiroyuki Ohata
IPC分类号： C08F30/08 , C08F18/02 , C08F18/20 , C08F20/32 , C08F220/10 , C08F220/18 , C08F220/32 , C08F230/08 , C08F290/00 , C08F299/08 , C08G59/00 , C08G59/40 , C08L63/00
CPC分类号： C08F230/08
摘要： Rubber vulcanizates having excellent oil resistance, heat resistance and cold resistance can be obtained from a rubbery copolymer which is a polymerization product of an acrylic monomer mixture of which the essential components are an organosiloxy-containing acrylate compound such as acryloxymethyl pentamethyl disiloxane and 3-acryloxypropyl pentamethyl disiloxane and an epoxy group- or halogen-containing monomer such as allyl glycidyl ether, glycidyl methacrylate and vinyl chloroacetate, optionally, with addition of an acrylate ester monomer such as ethyl acrylate, n-butyl acrylate and 2-methoxyethyl acrylate.

5. 发明授权

US4977200A Ethylene-propylene organopolysiloxane rubber composition 失效
标题翻译：乙烯 - 丙烯有机聚硅氧烷橡胶组合物
公开(公告)号：US4977200A
公开(公告)日：1990-12-11
申请号：US330576
申请日：1989-03-30
申请人： Kunio Itoh , Takeshi Fukuda , Tsutomu Nakamura
发明人： Kunio Itoh , Takeshi Fukuda , Tsutomu Nakamura
IPC分类号： A45D33/34 , C08J9/04 , C08J9/06 , C08K3/34 , C08K3/36 , C08K5/01 , C08K7/00 , C08K13/04 , C08L23/16 , C08L83/04 , C08L83/07 , C08L87/00
CPC分类号： C08J9/06 , C08K3/36 , C08L23/16 , C08J2323/16 , C08L2312/00
摘要： A rubber composition, which forms a vulcanizate having excellent surface properties such as pleasant feeling of touch and slipperiness or lubricity, comprises, in addition to conventional ingredients such as an ethylene-propylene copolymer, organopolysiloxane, reinforcing silica filler, process oil and curing agent, a powder of spherical particles, such as a poly(methyl silsesquioxane) powder, in the form having a particle diameter of 0.1 .mu.m to 50 .mu.m in a limited amount. The rubber composition forms a spongy rubber vulcanizate when vulcanized in the presence of a blowing agent which, by virtue of excellent surface properties, is useful as powder puffs for make-up.
摘要翻译：形成具有良好的触感，滑溜感或润滑性等优异表面性能的橡胶组合物除了常规成分如乙烯 - 丙烯共聚物，有机聚硅氧烷，增强二氧化硅填料，加工油和固化剂之外，有限量的粒径为0.1μm〜50μm的球状颗粒粉末，例如聚（甲基倍半硅氧烷）粉末。在发泡剂存在下硫化时，橡胶组合物形成海绵状橡胶硫化橡胶，由于具有优异的表面性能，可用作化妆粉末泡沫。

6. 发明授权

US4876344A Novel organosilicon compounds 失效
标题翻译：新型有机硅化合物
公开(公告)号：US4876344A
公开(公告)日：1989-10-24
申请号：US277632
申请日：1988-11-29
申请人： Kunio Itoh , Motoo Fukushima , Tsutomu Nakamura
发明人： Kunio Itoh , Motoo Fukushima , Tsutomu Nakamura
IPC分类号： C07D251/38 , C07F7/18 , C08G59/40 , C08K5/548
CPC分类号： C07F7/1816 , C07D251/38 , C08K5/548
摘要： Organosilicon compounds of the following formula, or hydrolyzates thereof, ##STR1## ps in which Rhu 1 l and Rhu 2 l are independently a hydrogen atom or an alkyl group having from 1 to 8 carbon atoms, m is an integer of from 1 to 8, and n is an integer of from 1 to 3. The compound is useful as a vulcanizing agent particularly for vulcanizable elastomer compositions comprising inorganic fillers.
摘要翻译：下式的有机硅化合物或其水解产物，其中R 1和L 2独立地为氢原子或具有1至8个碳原子的烷基，m为1至8的整数，n为1〜3的整数。该化合物特别用于含有无机填料的可硫化弹性体组合物，可用作硫化剂。

7. 发明授权

US4761452A Oil-resistant rubber composition 失效
标题翻译：耐油橡胶组合物
公开(公告)号：US4761452A
公开(公告)日：1988-08-02
申请号：US883535
申请日：1986-07-09
申请人： Kunio Itoh , Motoo Fukushima , Tsutomu Nakamura
发明人： Kunio Itoh , Motoo Fukushima , Tsutomu Nakamura
IPC分类号： C08L23/00 , C08K3/00 , C08L23/16 , C08L33/00 , C08L33/04 , C08L33/08 , C08L43/04
CPC分类号： C08L43/04 , C08L23/16 , C08L2312/08
摘要： A rubber composition capable of giving a highly oil-resistant vulcanizate with an organic peroxide as the vulcanizing agent is proposed. The composition is a blend of an EPM or EPDM rubber and an acrylic rubber loaded with a reinforcing filler, of which the latter rubber is a copolymer having at least two vinylsilyl groups in a molecule as the pendant groups introduced by the copolymerization of one or more acrylic monomers with a vinylsilyl-containing organosilicon compound having an aliphatically unsaturated group copolymerizable with the acrylic monomers in a molecule, such as CH.sub.2 .dbd.CH--CO--O--CH.sub.2 CH.sub.2 CH.sub.2 --Si-- and CH.sub.2 .dbd.CH--C.sub.6 H.sub.4 --Si--. The covulcanizate has the high mechanical strengths of the EPM or EPDM rubber and the high oil resistance of the acrylic rubber in combination.
摘要翻译：提出了能够以有机过氧化物作为硫化剂赋予高耐油硫化橡胶的橡胶组合物。该组合物是EPM或EPDM橡胶和装载有增强填料的丙烯酸橡胶的共混物，其中后者橡胶是在分子中具有至少两个乙烯基甲硅烷基的共聚物，作为通过一个或多个丙烯酸类单体与具有乙烯基甲硅烷基的有机硅化合物在分子中具有可与丙烯酸单体共聚的脂族不饱和基团，例如CH 2 = CH-CO-O-CH 2 CH 2 CH 2 -Si-和CH 2 = CH-C 6 H 4 -Si。共硫化橡胶具有EPM或EPDM橡胶的高机械强度和丙烯酸橡胶的高耐油性组合。

8. 发明授权

US4533687A Flame-retardant rubber composition 失效
标题翻译：阻燃橡胶组合物
公开(公告)号：US4533687A
公开(公告)日：1985-08-06
申请号：US575504
申请日：1984-01-31
申请人： Kunio Itoh , Toshimichi Oshima , Tsutomu Nakamura
发明人： Kunio Itoh , Toshimichi Oshima , Tsutomu Nakamura
IPC分类号： C08L23/00 , C08K3/00 , C08K3/02 , C08K3/04 , C08K3/22 , C08L7/00 , C08L21/00 , C08L23/02 , C08L33/00 , C08L33/02 , C08L87/00 , C08L101/00 , H01B3/44
CPC分类号： C08K3/02 , C08K3/22 , C08L23/02 , C08L23/16
摘要： The invention provides a highly flame-retardant polyolefin-based rubber composition free from the problem of the formation of toxic or corrosive gases and a large volume of smoke by burning of conventional flame-retardant rubber compositions impregnated with a large amount of a halogen-containing flame retardant agent. The inventive rubber composition comprises (a) a synthetic rubber of polyolefin type, (b) an organopolysiloxane resin which is preferably formed of monofunctional siloxane units and tetrafunctional siloxane units in a molar ratio of 0.6/1.0 to 2.0/1.0, (c) red phosphorus and (d) aluminum hydroxide or magnesium hydroxide in a specified proportion.
摘要翻译：本发明提供了一种高阻燃聚烯烃基橡胶组合物，其不含有形成有毒或腐蚀性气体和大量烟雾的问题，通过燃烧常规的含有大量含卤素的阻燃橡胶组合物阻燃剂。本发明的橡胶组合物包含（a）聚烯烃类合成橡胶，（b）优选由摩尔比为0.6 / 1.0至2.0 / 1.0的单官能硅氧烷单元和四官能硅氧烷单元形成的有机聚硅氧烷树脂，（c）红色磷和（d）氢氧化铝或氢氧化镁以规定的比例。

9. 发明授权

US4731406A Flame-retardant low-smoking rubber composition 失效
标题翻译：阻燃低烟胶组合物
公开(公告)号：US4731406A
公开(公告)日：1988-03-15
申请号：US942388
申请日：1986-12-16
申请人： Kunio Itoh , Tsutomu Nakamura , Ken-ichi Takita
发明人： Kunio Itoh , Tsutomu Nakamura , Ken-ichi Takita
IPC分类号： C08K3/22 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/16 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/08 , C08L51/00 , C08L51/02 , C08L83/04 , C08L101/00
CPC分类号： C08L23/16 , C08K3/22 , C08L2201/02 , C08L2312/00
摘要： Vulcanizates of so-called EPM and EPDM rubber compositions can be imparted with greatly improved flame retardancy and emit a greatly decreased volume of smoke in burning when the rubber composition is compounded with a conventional flame retardant agent of aluminum or magnesium hydroxide together with a polymer of an acrylic acid ester and an organopolysiloxane in combination or a copolymer composed of the moieties of these two kinds of monomeric units in a limited weight proportion.
摘要翻译：所谓的EPM和EPDM橡胶组合物的硫化橡胶可以赋予极大改善的阻燃性，并且当将橡胶组合物与常规的铝或氢氧化镁的阻燃剂以及组合的丙烯酸酯和有机聚硅氧烷或由这两种单体单元的部分以有限重量比组成的共聚物。

10. 发明授权

US4560719A Flame retardant polyolefin-based rubber composition 失效
标题翻译：阻燃聚烯烃基橡胶组合物
公开(公告)号：US4560719A
公开(公告)日：1985-12-24
申请号：US705564
申请日：1985-02-26
申请人： Tsutomu Nakamura , Kunio Itoh
发明人： Tsutomu Nakamura , Kunio Itoh
IPC分类号： C08K3/00 , C08K3/02 , C08K3/04 , C08K3/22 , C08K3/26 , C08K5/02 , C08K5/03 , C08K13/02 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/02 , C08L23/16 , C08L23/18 , C08L31/04 , C08L33/00 , C08L33/02 , C08L83/04 , C08L87/00 , C08L99/00 , C08L101/00
CPC分类号： C08K3/26 , C08K3/02 , C08K3/22 , C08K5/02 , C08L23/16 , C08L2201/02 , C08L83/04
摘要： The invention provides a polyolefin-based rubber composition capable of giving a vulcanizate having excellent flame retardancy along with high mechanical strengths. The composition comprises: (A) 100 parts by weight of a polyolefin-based synthetic rubber, e.g. EPDM rubber; (B) 1 to 100 parts by weight of an organopolysiloxane; (C) 1 to 100 parts by weight of a bromine-containing flame retardant agent and/or red phosphorus; (D) 5 to 200 parts by weight of aluminum hydroxide and/or magnesium hydroxide; and (E) 0.5 to 20 parts by weight of zinc carbonate and/or manganese carbonate.
摘要翻译：本发明提供一种聚烯烃类橡胶组合物，其能够提供具有优异的阻燃性以及高机械强度的硫化橡胶。该组合物包含：（A）100重量份的聚烯烃基合成橡胶，例如，三元乙丙橡胶; （B）1〜100重量份的有机聚硅氧烷; （C）1〜100重量份的含溴阻燃剂和/或红磷; （D）5〜200重量份的氢氧化铝和/或氢氧化镁; 和（E）0.5〜20重量份的碳酸锌和/或碳酸锰。

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