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    • 1. 发明专利
    • SPUTTERING TARGET FOR Sn ALLOY FILM DEPOSITION ON OPTICAL INFORMATION RECORDING MEDIUM
    • 用于锡合金薄膜沉积的光学信息记录介质的溅射目标
    • JP2008240115A
    • 2008-10-09
    • JP2007085313
    • 2007-03-28
    • Kobe Steel LtdKobelco Kaken:Kk株式会社コベルコ科研株式会社神戸製鋼所
    • FUJII HIDEOMATSUZAKI HITOSHI
    • C22C13/00G11B7/26
    • PROBLEM TO BE SOLVED: To suppress warpage in a sputtering target for Sn alloy film deposition occurring when an Sn alloy film on an optical information recording medium is continuously deposited by sputtering. SOLUTION: A melted sputtering target ingot is forged at a low forging rate to obtain the sputtering target with objective structure composed of an Sn alloy comprising Ni and Co and having acicular and bar-shaped intermetallic compounds of Ni, Co and Sn intermingled into an Sn matrix. In the intermetallic compounds, little black breaks and hole parts are present and the intermetallic compounds are not finely broken, and the Vickers hardness of the target is controlled to ≥20 MPa and its 0.2% proof stress is controlled to ≥20 MPa. In this way, the occurrence of the warpage in an Sn alloy sputtering target upon the continuous deposition of an Sn alloy film by sputtering is suppressed. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了抑制当通过溅射连续沉积光学信息记录介质上的Sn合金膜时发生的Sn合金膜沉积的溅射靶的翘曲。 解决方案:以低的锻造速度锻造熔融的溅射靶锭,以获得由包含Ni和Co的Sn合金构成的目标结构的溅射靶,并且具有混合的Ni,Co和Sn的针状和棒状的金属间化合物 成为Sn基体。 在金属间化合物中,存在小的黑色断裂和孔部分,并且金属间化合物没有细碎,目标的维氏硬度控制在≥20MPa,其0.2%的屈服应力控制在≥20MPa。 以这种方式,抑制了通过溅射连续沉积Sn合金膜时Sn合金溅射靶中翘曲的发生。 版权所有(C)2009,JPO&INPIT
    • 3. 发明专利
    • Ag BASED SPUTTERING TARGET AND ITS PRODUCTION METHOD
    • 基于Ag的溅射目标及其生产方法
    • JP2005036291A
    • 2005-02-10
    • JP2003275621
    • 2003-07-16
    • Kobe Steel LtdKobelco Kaken:Kk株式会社コベルコ科研株式会社神戸製鋼所
    • TAKAGI KATSUHISANAKAI JUNICHITAUCHI HIRONORIMATSUZAKI HITOSHIFUJII HIDEO
    • C22F1/14C22C5/06C22F1/00C23C14/34
    • C22C5/06C22F1/14C23C14/3414
    • PROBLEM TO BE SOLVED: To provide an Ag based sputtering target capable of stably and continuously depositing a thin film having excellent uniformity of a film thickness and a componential composition in the film face direction without interruption from the start of its use to the completion.
      SOLUTION: In the Ag based sputtering target, cutting is performed at the faces parallel to the sputtering face to expose a plurality of sputtering faces, a plurality of parts are selected for each exposed sputtering face, the following values A and B are calculated on the basis of the crystal grain sizes in all the selected parts, and, provided that the higher one in the values A and B is defined as the three-dimensional variation of the crystal grain sizes, the three-dimensional variation of the crystal grain sizes is ≤18%: value A=(D
      max -D
      ave )/D
      ave ×100(%), and value B=(D
      ave -D
      min )/D
      ave ×100(%)(wherein, D
      max denotes the maximum one of the crystal grain sizes in all the selected parts, D
      min denotes the minimum one, and D
      ave denotes the average value).
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决的问题:提供一种能够稳定且连续地沉积薄膜厚度均匀性和膜面方向上的组成成分的薄膜的Ag系溅射靶,而不会从使用开始到中断地沉积 完成。 解决方案:在Ag基溅射靶中,在与溅射面平行的面上进行切割以暴露多个溅射面,为每个暴露的溅射面选择多个部分,以下值A和B为 基于所有选择的部分中的晶粒尺寸计算,并且如果将值A和B中较高的值定义为晶粒尺寸的三维变化,则晶体的三维变化 晶粒尺寸≤18%:值A =(D max -D ave )/ D ave ×100(%),值B =(D ave -D min )/ D ave ×100(%)(其中,D max 所有选定部分的最大晶粒尺寸D min 表示最小值,D ave 表示平均值。 版权所有(C)2005,JPO&NCIPI
    • 6. 发明专利
    • Ag-BASED SPUTTERING TARGET
    • 基于Ag的飞溅目标
    • JP2009132962A
    • 2009-06-18
    • JP2007309248
    • 2007-11-29
    • Kobelco Kaken:Kk株式会社コベルコ科研
    • MATSUZAKI HITOSHI
    • C23C14/34B22F9/08C22C5/06C22F1/00C22F1/14C23C14/14
    • C23C14/3414C22C5/06C22F1/14
    • PROBLEM TO BE SOLVED: To provide an Ag-based sputtering target useful for depositing an Ag-based thin film having very excellent in-plane uniformity.
      SOLUTION: The mean crystal grain size d
      ave of the sputtering face of the Ag-based sputtering target is ≤10 μm when the mean crystal grain size d
      ave is measured according to the procedures (1)-(3). (Procedure 1) A plurality of locations in the sputtering face are optionally selected and a micrograph of each selected location ( magnification : 40-2,000 times) is taken. (Procedure 2) Four or more straight lines are drawn in a grid pattern or radially on each micrograph, the number n of grain boundaries existing on the straight lines is investigated, and a crystal grain size d is calculated for each straight on the basis of the following equation d=L/n/m, wherein L denotes the length of the straight line, n denotes the number of grain boundaries existing on the straight lines, and m denotes the magnification of the micrograph. (Procedure 3) The mean value of the crystal grain sizes d of all selected locations is defined as the mean crystal grain size d
      ave of the sputtering face.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供用于沉积具有非常优异的面内均匀性的Ag基薄膜的Ag基溅射靶。 解决方案:当平均晶粒尺寸d ave 时,Ag系溅射靶的溅射面的平均晶粒尺寸d ave 为≤10μm 根据程序(1) - (3)测量。 (步骤1)可选地选择溅射面中的多个位置,并且取出每个所选择的位置(倍率:40-2,000次)的显微照片。 (步骤2)四个或更多条直线以网格图案或每个显微照片上的径向绘制,研究存在于直线上的晶界数n,并且基于每个直线计算晶粒尺寸d 以下等式d = L / n / m,其中L表示直线的长度,n表示直线上存在的晶界数,m表示显微照片的放大率。 (步骤3)将所有选择的位置的晶粒尺寸d的平均值定义为溅射面的平均晶粒尺寸d ave 。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Ag-BASED SPUTTERING TARGET
    • 基于Ag的飞溅目标
    • JP2012007237A
    • 2012-01-12
    • JP2011123536
    • 2011-06-01
    • Kobelco Kaken:Kk株式会社コベルコ科研
    • MATSUZAKI HITOSHI
    • C23C14/34B22F3/115B22F9/08C22C5/06C23C14/14G11B7/258G11B7/26
    • PROBLEM TO BE SOLVED: To provide an Ag-based sputtering target useful for depositing an Ag-based thin film having extremely excellent in-plane uniformity.SOLUTION: The average crystal grain size dof the sputtering face of the Ag-based sputtering target is not larger than 10 μm when the average crystal grain size dis measured according to procedures (1)-(3). (Procedure 1): A plurality of locations in the sputtering face are optionally selected and a micrograph of each selected location (magnification: 40-2,000 times) is taken. (Procedure 2): Four or more straight lines are drawn in a grid pattern or radially on each micrograph, the number n of grain boundaries present on the straight lines is investigated, and a crystal grain size d is calculated for each straight line on the basis of the following equation d=L/n/m where L denotes the length of the straight line, n denotes the number of grain boundaries present on the straight lines, and m denotes the magnification of the micrograph. (Procedure 3): The average value of the crystal grain sizes d of all selected locations is defined as the average crystal grain size dof the sputtering face.
    • 要解决的问题:提供一种用于沉积具有非常优异的面内均匀性的Ag基薄膜的Ag基溅射靶。 解决方案:当Ag基溅射靶的溅射面的平均晶粒尺寸d ave 不大于10μm,当平均晶粒尺寸d ave 。 (步骤1):任选地选择溅射面中的多个位置,并且取出每个选定位置(倍率:40-2,000次)的显微照片。 (步骤2):四个或更多条直线以网格图案或每个显微照片上的径向绘制,研究直线上存在的晶界数n,并对每条直线上的晶粒尺寸d进行计算 下式的基数d = L / n / m其中L表示直线的长度,n表示直线上存在的晶界数,m表示显微照片的放大倍数。 (步骤3)将所有选择的位置的晶粒尺寸d的平均值定义为溅射面的平均晶粒尺寸d ave 。 版权所有(C)2012,JPO&INPIT
    • 10. 发明专利
    • Ag ALLOY SPUTTERING TARGET, AND ITS MANUFACTURING METHOD
    • Ag合金喷射目标及其制造方法
    • JP2009057580A
    • 2009-03-19
    • JP2007223152
    • 2007-08-29
    • Kobelco Kaken:Kk株式会社コベルコ科研
    • TAKAGI KATSUHISAMORIMOTO EIICHIMATSUZAKI HITOSHITAUCHI HIRONORI
    • C23C14/34B22F3/15C22C5/06C23C14/06G11B7/26
    • C23C14/3414B22F3/15C22C5/06G11B7/259
    • PROBLEM TO BE SOLVED: To provide an Ag-Ta-Cu alloy sputtering target, wherein a thin film excellent in uniformity of a component in a film surface direction (within a film plane), is stably formed.
      SOLUTION: The sputtering target consists of Ag alloy containing, by atom, 0.6-10.5% Ta and 2-13% Cu. The image analysis of a sputtering surface of the sputtering target results in that (1) the total area of Ta grains of the circle-equivalent diameter of 10-50 μm to the total area of Ta grains is ≥60 area%, and the average distance between centers of gravity of Ta grains is 10-50 μm, and (2) the total area of Cu grains of the circle-equivalent diameter of 10-50 μm to the total area of Cu grains is ≥70 area%, and the average distance between centers of gravity of Cu grains is 60-120 μm.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供Ag-Ta-Cu合金溅射靶,其中稳定地形成膜表面方向(在膜平面内)的成分的均匀性优异的薄膜。 解决方案:溅射靶由含有0.6-10.5%Ta和2-13%Cu的原子的Ag合金组成。 溅射靶的溅射表面的图像分析结果是(1)圆当量直径为10-50μm的Ta晶粒与Ta晶粒的总面积的总面积为≥60面积%,平均 Ta颗粒重心之间的距离为10〜50μm,(2)圆当量直径为10〜50μm的Cu颗粒的总面积与Cu颗粒的总面积为≥70面积%, Cu颗粒重心之间的平均距离为60-120μm。 版权所有(C)2009,JPO&INPIT