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1. 发明授权

US06727318B1 Method for producing aqueous polymer dispersions containing colorants 失效
标题翻译：含有着色剂的聚合物水分散体的制备方法
公开(公告)号：US06727318B1
公开(公告)日：2004-04-27
申请号：US09600868
申请日：2000-08-09
申请人： Klemens Mathauer , Arno Böhm , Walter Mächtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Müllen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schlösser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Rüdiger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
发明人： Klemens Mathauer , Arno Böhm , Walter Mächtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Müllen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schlösser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Rüdiger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
IPC分类号： C08K300
CPC分类号： C08F2/32 , C08F2/44 , C08K3/00 , C09B69/102
摘要： The present invention relates to a process for preparing dye-comprising aqueous polymer dispersions by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of free-radical initiators, in which at least some of the monomers are employed in the form of an oil-in-water emulsion E1 whose disperse phase comprises at least one oil-soluble dye, wherein the disperse phase of E1 is formed essentially of dye-comprising monomer droplets having a diameter
摘要翻译：本发明涉及一种在自由基引发剂存在下通过烯键式不饱和单体的自由基水乳液聚合制备含染料的聚合物水分散体的方法，其中至少一些单体以水包油乳液E1，其分散相包含至少一种油溶性染料，其中E1的分散相基本上由具有直径<500nm的含染料的单体液滴形成。本发明还涉及如权利要求35所述的式III的苝染料。本发明除了含有染料的制剂外，还包括本发明的含染料的聚合物和着色剂，其包含本发明包括荧光增白剂。

2. 发明申请

US20050075453A1 Method for producing aqueous polymer dispersions containing colorants 失效
标题翻译：含有着色剂的聚合物水分散体的制备方法
公开(公告)号：US20050075453A1
公开(公告)日：2005-04-07
申请号：US10629552
申请日：2003-07-30
申请人： Klemens Mathauer , Arno Bohm , Walter Machtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Mullen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schlosser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Rudiger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
发明人： Klemens Mathauer , Arno Bohm , Walter Machtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Mullen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schlosser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Rudiger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
IPC分类号： C07D221/18 , C07C69/54 , C07C271/12 , C07D213/85 , C08F2/22 , C08F2/32 , C08F2/44 , C09B69/10 , C09D5/02 , C09D5/03 , C09D11/00 , D21H19/00
CPC分类号： C08F2/32 , C08F2/44 , C08K3/00 , C09B69/102
摘要： The present invention relates to a process for preparing dye-comprising aqueous polymer dispersions by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of free-radical initiators, in which at least some of the monomers are employed in the form of an oil-in-water emulsion E1 whose disperse phase comprises at least one oil-soluble dye, wherein the disperse phase of E1 is formed essentially of dye-comprising monomer droplets having a diameter
摘要翻译：本发明涉及一种在自由基引发剂存在下通过烯键式不饱和单体的自由基水乳液聚合制备含染料的聚合物水分散体的方法，其中至少一些单体以水包油乳液E1，其分散相包含至少一种油溶性染料，其中E1的分散相基本上由具有直径<500nm的含染料的单体液滴形成。本发明还涉及如权利要求35所述的式III的苝染料。本发明除了含有染料的制剂外，还包括本发明的含染料的聚合物和着色剂，其包含本发明包括荧光增白剂。

3. 发明授权

US07176255B2 Method for producing aqueous polymer dispersions containing colorants 失效
标题翻译：含有着色剂的聚合物水分散体的制备方法
公开(公告)号：US07176255B2
公开(公告)日：2007-02-13
申请号：US10629552
申请日：2003-07-30
申请人： Klemens Mathauer , Arno Boehm , Walter Maechtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Muellen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schloesser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Ruediger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
发明人： Klemens Mathauer , Arno Boehm , Walter Maechtle , Peter Rossmanith , Sabine Kielhorn-Bayer , Klaus Muellen , Ulrike Rohr , Friedrich-Wilhelm Raulfs , Ulrike Schloesser , Wolfgang Schrof , Harutyun Hanciogullari , Karl Siemensmeyer , Paul Delavier , Ruediger Sens , Torsten Freund , Takahiro Ikeda , Takanori Wakebe
IPC分类号： C08F2/32
CPC分类号： C08F2/32 , C08F2/44 , C08K3/00 , C09B69/102
摘要： The present invention relates to a process for preparing dye-comprising aqueous polymer dispersions by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of free-radical initiators, in which at least some of the monomers are employed in the form of an oil-in-water emulsion E1 whose disperse phase comprises at least one oil-soluble dye, wherein the disperse phase of E1 is formed essentially of dye-comprising monomer droplets having a diameter
摘要翻译：本发明涉及一种在自由基引发剂存在下通过烯键式不饱和单体的自由基水乳液聚合制备含染料的聚合物水分散体的方法，其中至少一些单体以水包油乳液E1，其分散相包含至少一种油溶性染料，其中E1的分散相基本上由具有直径<500nm的含染料的单体液滴形成。本发明涉及包含本发明的含染料的聚合物的含染料制剂以及包含本发明聚合物的着色制剂，其包含荧光增白剂。

4. 发明授权

US06218468B1 Preparation of an aqueous polymer dispersion by the free radical aqueous emulsion polymerization method 失效
标题翻译：通过自由基水乳液聚合方法制备聚合物水分散体
公开(公告)号：US06218468B1
公开(公告)日：2001-04-17
申请号：US09101778
申请日：1998-07-22
申请人： Klemens Mathauer , Walter Mächtle , Wolfgang Schrof , Horst Schuch , Timo Rager , Wolfgang Meyer , Gerhard Wegner
发明人： Klemens Mathauer , Walter Mächtle , Wolfgang Schrof , Horst Schuch , Timo Rager , Wolfgang Meyer , Gerhard Wegner
IPC分类号： C08L5302
CPC分类号： C08F2/22 , C08F297/026 , C08J3/03
摘要： In a process for the preparation of an aqueous polymer dispersion by the free radical aqueous emulsion polymerization method, the polymerization is carried out in the presence of frozen micelles of amphiphilic substances.
摘要翻译：在通过自由基水乳液聚合方法制备聚合物水分散体的方法中，聚合在两亲性物质的冷冻胶束的存在下进行。

5. 发明授权

US06278518B1 Centrifuging process for sample characterization 失效
标题翻译：样品表征的离心过程
公开(公告)号：US06278518B1
公开(公告)日：2001-08-21
申请号：US09109765
申请日：1998-07-06
申请人： Wolfgang Schrof , Peter Rossmanith , Walter Mächtle
发明人： Wolfgang Schrof , Peter Rossmanith , Walter Mächtle
IPC分类号： G01N2151
CPC分类号： G01N15/04 , G01N1/4077
摘要： A process for characterizing at least one sample comprising at least one substance (Si), in which at least one substance (Si) in the sample is identified and in which at least one quantity (Gji) which characterizes a substance (Si) in the sample is determined, at least the following process steps being carried out successively or simultaneously in an analytical centrifuging device: a) centrifuging the sample in an analytical centrifuge, b) exposing the sample to monochromatic light, preferably laser light, c) detecting light scattered by the sample, d) identifying at least one substance (Si) by a spectral evaluation of the inelastically scattered fraction of the scattered light which was detected in step c), e.g. by means of Raman scattering, and e) determining at least one quantity (Gji) for a substance (Si) by evaluating the state of the sample which it has entered as a consequence of the centrifuging in step a).
摘要翻译：用于表征至少一种包含至少一种物质（Si）的样品的方法，其中鉴定出样品中的至少一种物质（Si），并且其中至少一种表征物质（Si）的量（Gji）在确定样品，至少在分析离心设备中连续或同时进行以下处理步骤：a）在分析离心机中离心样品，b）将样品暴露于单色光，优选为激光，c）检测光散射通过样品，d）通过在步骤c）中检测到的散射光的非弹性散射分数的光谱评估来鉴定至少一种物质（Si），例如通过拉曼散射，和）通过在步骤a）中评估其作为离心的结果进入的样品的状态来确定物质（Si）的至少一个量（Gji）。

6. 发明授权

US06624219B1 Surface active random radical (co)polymer and dispersion method for using the same 失效
标题翻译：表面活性无规自由基（共）聚合物及其分散方法
公开(公告)号：US06624219B1
公开(公告)日：2003-09-23
申请号：US09640093
申请日：2000-08-17
申请人： Robert Heger , Wolfgang Schrof , Michael Seufert , Helmut Auweter , Walter Mächtle , Rüdiger Iden , Dieter Horn , Ralph Nielsen , Eric Carlson , Chang Han-Ting , Sigrid Kuebler , Petro Miroslav
发明人： Robert Heger , Wolfgang Schrof , Michael Seufert , Helmut Auweter , Walter Mächtle , Rüdiger Iden , Dieter Horn , Ralph Nielsen , Eric Carlson , Chang Han-Ting , Sigrid Kuebler , Petro Miroslav
IPC分类号： C08K541
CPC分类号： B82Y30/00 , C08F212/04 , C08F220/34 , C09B67/0085 , C09D11/106 , C09D11/30 , C09D133/14 , C09D135/06 , C09D139/08
摘要： The present invention relates to a set of (co)polymers, dispersion formulations, solid solutions and formulation conditions able to disperse a dye selected from the group of a monoazo dye, quinophthalone dye and an anthraquinone dye in a stable nanoparticular form in an aqueous medium.
摘要翻译：本发明涉及一种（共）聚合物，分散体配制剂，固溶体和配制条件，其能够将稳定的纳米颗粒形式的选自单偶氮染料，喹酞酮染料和蒽醌染料的染料分散在水性介质中。

7. 发明授权

US08277935B2 Cleaning implement comprising a modified open-cell foam 有权
标题翻译：包括改性开孔泡沫的清洁工具
公开(公告)号：US08277935B2
公开(公告)日：2012-10-02
申请号：US11641353
申请日：2006-12-19
申请人： Denis Alfred Gonzales , Iris Bogaerts , Karl Häberle , Wolfgang Schrof , Volker Schwendemann , Stefan Frenzel
发明人： Denis Alfred Gonzales , Iris Bogaerts , Karl Häberle , Wolfgang Schrof , Volker Schwendemann , Stefan Frenzel
IPC分类号： B32B5/28
CPC分类号： C08J9/405 , A47L13/16 , C08J9/42 , C08J2361/02 , C08J2421/00 , C08J2425/00 , C08J2429/00 , C08J2433/00 , Y10T428/249953 , Y10T428/249981 , Y10T428/249986 , Y10T428/249991 , Y10T428/249992
摘要： A cleaning implement comprises a modified open-cell foam with a density in the range from about 5 to about 1,000 kg/m3 and with an average pore diameter in the range from about 1 μm to about 1 mm, comprising an amount in the range from about 1 to about 2,500% by weight, based on the weight of the unmodified open-cell foam, of at least about one water-insoluble polymer (b), selected from polystyrene, styrene copolymers, polybutadiene, butadiene copolymers, polyvinylesters, polyvinylethers, copolymers from (meth)acrylic acid with at least one (meth)acrylate, and polyurethanes, with the proviso that styrene-acrylonitrile-C1-C10-alkyl (meth)acrylate terpolymers, styrene-butadiene-n-butyl acrylate terpolymers, and styrene-maleic anhydride copolymers are excluded.
摘要翻译：清洁工具包括密度在约5至约1,000kg / m 3范围内且平均孔径在约1μm至约1mm范围内的改性开孔泡沫，其含量范围为至少约一种水不溶性聚合物（b），其选自聚苯乙烯，苯乙烯共聚物，聚丁二烯，丁二烯共聚物，聚乙烯基酯，聚乙烯醚，聚乙烯基醚，（甲基）丙烯酸与至少一种（甲基）丙烯酸酯和聚氨酯的共聚物，条件是苯乙烯 - 丙烯腈 - （C 1 -C 10） - （甲基）丙烯酸烷基酯三元共聚物，苯乙烯 - 丁二烯 - 丙烯酸正丁酯三元共聚物和苯乙烯 - 马来酸酐共聚物被排除。

8. 发明授权

US08129531B2 Process of producing bleach boosters 有权
标题翻译：漂白助剂生产工艺
公开(公告)号：US08129531B2
公开(公告)日：2012-03-06
申请号：US11917217
申请日：2006-06-14
申请人： Ludwig Voelkel , Christian Bittner , Ingo Muenster , Frank Dietsche , Wolfgang Schrof
发明人： Ludwig Voelkel , Christian Bittner , Ingo Muenster , Frank Dietsche , Wolfgang Schrof
IPC分类号： C07D217/04 , C07D491/02
CPC分类号： C07D217/10 , C07D217/04 , C07D498/04
摘要： This invention relates to a process of producing compounds, which are useful as bleach boosters, as well as to the compounds, which are obtainable using said process, and to their use.
摘要翻译：本发明涉及生产可用作漂白助剂的化合物的方法，以及可使用所述方法获得的化合物及其用途。

9. 发明申请

US20100328676A1 METHOD FOR DETECTING IMPURITIES ON A SURFACE 有权
标题翻译：检测表面污染的方法
公开(公告)号：US20100328676A1
公开(公告)日：2010-12-30
申请号：US12444750
申请日：2007-09-11
申请人： Eva Wagner , Thomas Brinz , Thomas Geiger , Jane Lewis , Markus Tiefenbacher , Tobias Burk , Sebastian Koltzenburg , Wolfgang Schrof
发明人： Eva Wagner , Thomas Brinz , Thomas Geiger , Jane Lewis , Markus Tiefenbacher , Tobias Burk , Sebastian Koltzenburg , Wolfgang Schrof
IPC分类号： G01B11/30
CPC分类号： G01N1/04 , G01N21/94 , G01N2001/028 , G01N2001/2833
摘要： A method is provided for detecting not fully set coatings and liquid or smearing impurities on a surface, in which in a first step a film is pressed onto a surface of a coating using a predefined press-on pressure, the film having a relative motion with respect to the surface of the coating, thereafter the film is pulled off the surface of the coating and finally it is determined whether impurities are adhering to the film. A device is also provided for performing the method, including at least one film, which may be pressed against a surface to be tested, at least one press-on roller having a surface by which the film is pressed against the coating, and at least one device for determining whether there are impurities adhering to the film.
摘要翻译：提供了一种用于检测表面上未完全固化的涂层和液体或污迹杂质的方法，其中在第一步骤中，使用预定的压力压力将膜压在涂层的表面上，所述膜具有相对运动相对于涂层的表面，然后将膜从涂层的表面拉出，最后确定杂质是否粘附在膜上。还提供了一种用于执行该方法的装置，包括至少一个可压在被测试表面上的膜，至少一个压膜辊，其具有将膜压在涂层上的表面，至少一种用于确定是否存在粘附于薄膜上的杂质的装置。

10. 发明申请

US20080318785A1 Preparation Comprising at Least One Conazole Fungicide 有权
标题翻译：包括最少一种针唑杀真菌剂的制备
公开(公告)号：US20080318785A1
公开(公告)日：2008-12-25
申请号：US11918522
申请日：2006-04-13
申请人： Sebastian Koltzenburg , Peter Dombo , Gunter Oetter , Christian Kruger , Wolfgang Schrof , Matthias Bratz
发明人： Sebastian Koltzenburg , Peter Dombo , Gunter Oetter , Christian Kruger , Wolfgang Schrof , Matthias Bratz
IPC分类号： A01N43/653 , C08F228/02 , A01P3/00 , C08F26/06
CPC分类号： C08F220/60 , A01N25/10 , A01N25/14 , A01N43/653 , C08F220/18 , C08F220/38 , A01N2300/00
摘要： The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l, c) at least one type of copolymer CP consisting of M monomers comprising α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and β) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, β1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20° C. is less than 30 g/l and β2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20° C. is greater than 50 g/l.
摘要翻译：本发明涉及制剂，特别是含有至少两种不同的活性植物保护物质的混合物的植物保护制剂，其中a）至少一种活性物质选自唑类（活性物质1）和b）另一种在20℃温度下的水溶性小于20g / l的活性植物保护物质（活性物质2），c）由M单体组成的至少一种共聚物CP，包括α）至少一种类型的包含至少一个磺酸基团的单烯属不饱和单体M1和β）至少一种中性单烯属不饱和单体M2，其中活性物质1与另一种活性植物保护物质2的定量比范围为1:10至10 ：1。所述发明还涉及新型共聚物CP，其以由至少三种不同单烯属不饱和单体M组成的聚合物的形式体现并且以聚合形式包含α）至少一种类型的单烯属不饱和单体M1，其包含在至少一种磺酸基团，β1）至少一种类型的中和单烯属不饱和单体M2b，其在20℃温度下的水溶性小于30g / l和β2）至少一种中性单烯属不饱和单体M2b，其中在20℃的温度下的水溶解度大于50g / l。

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