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    • 1. 发明授权
    • Star polymers having statistical poly(isobutylene-co-styrene) copolymer arms
    • 具有统计聚(异丁烯 - 共 - 苯乙烯)共聚物臂的星形聚合物
    • US06512056B1
    • 2003-01-28
    • US09802338
    • 2001-03-09
    • Joseph A. KennedyDiana L. Hull
    • Joseph A. KennedyDiana L. Hull
    • C08L5302
    • C08F297/00C08L53/02C08L2666/02
    • The synthesis and characterization of star copolymers by living carbocationic copolymerization of statistical polymers comprising monomers of isobutylene (IB) and another monomer selected from the group consisting of styrene, isoprene and living carbocationically copolymerizable derivatives thereof is described. The poly(isobutylene-co-styrene) arms emanate from a calix[n]arene core where n preferably equals 8, forming an multi(octa)-arm star. The arms are advantageously fitted with crosslinkable termini such as allyl or hydroxyl end groups. The hydroxyl-terminated arm star copolymers are particularly suitable for use in coatings when reacted with crosslinking agents such as isocyanates.
    • 描述了由包含异丁烯(IB)单体和选自苯乙烯,异戊二烯和其活性碳阳离子可共聚合衍生物的另一单体的统计聚合物的活性碳阳离子共聚合成和表征星形共聚物。 聚(异丁烯 - 共 - 苯乙烯)臂从杯[n]芳烃芯发出,其中n优选等于8,形成多(八) - 星星。 臂有利地装配有可交联的末端,例如烯丙基或羟基端基。 羟基封端的臂状星形共聚物特别适用于与交联剂如异氰酸酯反应时的涂层。
    • 5. 发明授权
    • Hot melt construction adhesives for disposable articles
    • 一次性物品的热熔粘结剂
    • US06184285B2
    • 2001-02-06
    • US09185965
    • 1998-11-05
    • Stephen F. HatfieldAlejandro MatassaRobert Goodman
    • Stephen F. HatfieldAlejandro MatassaRobert Goodman
    • C08L5302
    • C09J153/02C08L2666/02C08L2666/04C08L2666/24
    • Novel hot melt construction adhesives for disposable articles, such as diapers, sanitary napkins, medical gowns, surgical drapes, and the like, are described which offer superior properties versus currently available hot melt adhesives. These hot melt construction adhesive compositions comprise a blend of styrene-isoprene block copolymer containing at least about 25 weight percent styrene and styrene-butadiene block copolymer containing at least about 25 weight percent styrene, at least one compatible tackifying resin and at least one plasticizer. The hot melt construction adhesive possesses a viscosity no greater than about 25,000 mPa·s at about 140° C., a shear adhesion failure temperature of at least about 60° C., and a static shear time to failure of no less than about 25 hours at about 23°.
    • 描述了与目前可获得的热熔粘合剂相比具有优异性能的用于一次性制品的新型热熔结构粘合剂,例如尿布,卫生巾,医用长袍,外科用手术织带等。 这些热熔结构粘合剂组合物包含含有至少约25重量%苯乙烯的苯乙烯 - 异戊二烯嵌段共聚物和含有至少约25重量%苯乙烯,至少一种相容的增粘树脂和至少一种增塑剂的苯乙烯 - 丁二烯嵌段共聚物的共混物。 热熔结构粘合剂在约140℃下的粘度不大于约25,000mPa.s,剪切粘附破坏温度为至少约60℃,静态剪切时间为不低于约25℃ 小时在23度左右。
    • 6. 发明授权
    • Block copolymer and composition containing the copolymer
    • 含共聚物的嵌段共聚物和组合物
    • US06833413B2
    • 2004-12-21
    • US10030246
    • 2002-01-09
    • Masahiro SasagawaShigeki TakayamaShigeo Nakajima
    • Masahiro SasagawaShigeki TakayamaShigeo Nakajima
    • C08L5302
    • C09J123/02C08F8/04C08F297/04C08L23/02C08L23/06C08L23/10C08L53/02C08L53/025C08L2666/04C08L2666/24C09J153/025
    • An object of the present invention is to provide a block copolymer having the excellent improving characteristics. Specifically, the block copolymer is a hydrogenated block copolymer capable of obtaining a molded product, as a polyolefin based resin composition, having excellent physical property balance between impact resistance, in particular, low temperature impact resistance and rigidity, and molding processability, and further, capable of providing, as a viscous adhesive composition, a composition having an excellent balance between adhesion characteristics such as adhesive power and retentivity, and having excellent melt viscosity stability under heating at a high temperature. The block copolymer is a hydrogenation product of a block copolymer having at least one polymer block mainly comprising a vinyl aromatic hydrocarbon and at least one polymer block mainly comprising a conjugate diene compound, and having a vinyl bonding amount V (%) based on the conjugate diene compound of from not less than 37% to less than 70%, wherein (a) the total hydrogenation ratio H (%) of the unsaturated double bond based on the conjugate diene compound satisfies the following relational formulae: V
    • 本发明的目的是提供具有优异改进特性的嵌段共聚物。 具体而言,嵌段共聚物是能够得到耐冲击性,特别是低温耐冲击性,刚性与成型加工性的物性平衡优异的作为聚烯烃类树脂组合物的成型体的氢化嵌段共聚物, 能够提供作为粘性粘合剂组合物的粘合力和保持力等粘合特性之间具有优异平衡的组合物,并且在高温加热下具有优异的熔体粘度稳定性。嵌段共聚物是嵌段共聚物的氢化产物 具有至少一个主要包含乙烯基芳烃的聚合物嵌段和至少一个主要包含共轭二烯化合物的聚合物嵌段,并且具有基于共轭二烯化合物的乙烯基键合量V(%)不小于37% 70%以下,(a)不饱和双键的总氢化率H(%) d基于共轭二烯化合物满足以下关系式:其中(b)乙烯基键的氢化率为82%以上。
    • 8. 发明授权
    • Soft, flexible composition and method for making same
    • 柔软,柔软的组合和制作方法
    • US06756434B1
    • 2004-06-29
    • US09648883
    • 2000-08-25
    • Karla E. WilliamsPaul D. Zwick
    • Karla E. WilliamsPaul D. Zwick
    • C08L5302
    • A61F13/26C08L53/02C08L2666/04
    • There is provided a composition comprising a unique polymeric compound that provides a soft, flexible product. There is also provided a unique polymeric tampon applicator that is soft and flexible. When used as a tampon applicator barrel, the barrel is more comfortable and has improved ease of insertion. The polymeric compound primarily comprises a thermoplastic resin and a block copolymer that exhibit unique load, energy and modulus of elasticity properties. The polymeric compound should also include a plasticizer and a compatibilizer/flow modifier, and may include a slip/mold release agent, an antioxidant, and even a pigment. There is also provided a method for making the polymeric compound that will be formed into a product, such as an applicator or applicator barrel in which all of the above ingredients, except for the thermoplastic resin, are combined and formed into soft pellets. The soft resin pellets are then dry blended with pellets of the thermoplastic resin. The mixture of the thermoplastic resin pellets and the soft resin pellets are then melted and injection molded into the desired shape. There is thus provided a method of making a soft, polymeric tampon applicator or tampon applicator barrel.
    • 提供了包含提供柔软,柔性产品的独特聚合物的组合物。 还提供了一种柔软而灵活的独特的聚合物棉条敷料器。 当用作棉塞施用器筒时,筒更舒适并且改善了插入的容易性。 聚合物主要包括热塑性树脂和显示独特的负载,能量和弹性模量的嵌段共聚物。 聚合物还应包括增塑剂和增容剂/流动改性剂,并且可以包括滑脱/脱模剂,抗氧化剂,甚至颜料。 还提供了一种制备将被制成产品的高分子化合物的方法,例如施用器或涂抹器筒,其中除了热塑性树脂之外的所有上述成分都组合并形成软颗粒。 然后将软树脂颗粒与热塑性树脂的颗粒干混。 然后将热塑性树脂颗粒和软质树脂颗粒的混合物熔融并注塑成所需的形状。 因此,提供了一种制造柔软的聚合物棉塞施用器或棉塞施用器筒的方法。
    • 9. 发明授权
    • Amphiphilic networks, implantable immunoisolatory devices, and methods of preparation
    • 两亲网络,可植入免疫隔离装置及其制备方法
    • US06727322B2
    • 2004-04-27
    • US10114647
    • 2002-04-01
    • Joseph P. KennedyIrada S. Isayeva
    • Joseph P. KennedyIrada S. Isayeva
    • C08L5302
    • C08F290/042Y10S514/866
    • The present invention provides high mechanical strength amphiphilic polymeric networks and implantable biological devices made therefrom that are capable of encasing and, thus, immunoisolating biological material from an immunological response of a host individual. The present invention also provides methods for making the amphiphilic networks and implantable biological devices. The present invention also provides a method for the treatment of type I diabetes mellitus comprising the steps of encasing a sufficient amount of islet of Langerhans cells within said biological device, wherein said biological device is capable of immunoisolating said encased islet cells upon implantation into an individual; implanting said biological device into a diabetic host individual; allowing said implanted biological device to remain implanted in said diabetic individual for a time sufficient to normalize the blood glucose level in said diabetic individual.
    • 本发明提供高机械强度两亲性聚合物网络和由其制备的可植入生物装置,其能够包裹并因此免疫分离生物材料免受宿主个体的免疫应答。 本发明还提供了制造两亲网络和可植入生物装置的方法。 本发明还提供了一种治疗I型糖尿病的方法,包括以下步骤:在所述生物装置内​​包含足够量的朗格汉斯细胞胰岛,其中所述生物装置能够在植入个体时对所述包封的胰岛细胞进行免疫隔离 ; 将所述生物学装置植入糖尿病宿主个体中; 允许所述植入的生物装置保持植入所述糖尿病个体中足以使所述糖尿病个体中的血糖水平归一化的时间。