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    • 3. 发明授权
    • Ion trap mass spectrometer
    • 离子阱质谱仪
    • US6121610A
    • 2000-09-19
    • US167892
    • 1998-10-07
    • Kiyomi YoshinariYoichi OseYoshiaki Kato
    • Kiyomi YoshinariYoichi OseYoshiaki Kato
    • G01N27/62H01J49/42
    • H01J49/424H01J49/4295
    • By preventing the trapping efficiency of ions from largely depending on the mass-to-charge ratio, an ion trap mass spectrometer suitable for obtaining a high sensitive mass spectrum is provided. Ions of a specimen to be mass analyzed generated at an external ion source pass through an ion transportation portion and then injected into a space (ion trap volume) between the ring electrode and the end cap electrodes. An RF trap voltage power source applies an RF frequency V.multidot.cos .OMEGA.t between the ring electrode and the end cap electrodes to form a radio frequency electric field in the ion trap volume. The RF trap voltage is changed so that the optimum trap frequency is in inverse proportion to 1/2 power of a mass-to-charge ratio while the ions are being trapped in the radio frequency electric field formed in the ion trap volume.
    • 通过防止离子在很大程度上取决于质荷比的捕获效率,提供了适于获得高灵敏质谱的离子阱质谱仪。 在外部离子源处产生的待质量分析的样品的离子通过离子输送部分,然后注入到环形电极和端盖电极之间的空间(离子阱体积)中。 RF陷波电压电源在环形电极和端盖电极之间施加RF频率VxCOS OMEGA t,以在离子阱体积中形成射频电场。 改变RF陷波电压,使得最佳陷波频率与质荷比的1/2功率成反比,同时离子被捕获在形成于离子阱体积中的射频电场中。
    • 4. 发明授权
    • Mass spectrometer ring-shaped electrode having high ion selection
efficiency and mass spectrometry method thereby
    • 因此,具有高离子选择效率和质谱法的质谱仪环形电极
    • US5623144A
    • 1997-04-22
    • US598890
    • 1996-02-09
    • Kiyomi YoshinariYoichi OseYoshiaki Kato
    • Kiyomi YoshinariYoichi OseYoshiaki Kato
    • H01J49/42
    • H01J49/424H01J49/427
    • A mass spectrometer and a mass spectrometry method having a high ion selection efficiency are provided. The mass spectrometer comprises an ion trap, a sample introducing device, an electron gun, a detector, a power supply for applying voltage to the ion trap, a control device for controlling the power supply and the electron gun, a mass analyzing device for performing mass spectrometry based on a detected signal of the detector. Using an auxiliary power supply, direction of an auxiliary electric field generated between end cap electrodes is made to point only toward the detector. In this occasion, by setting the cycle of the auxiliary voltage near the oscillation cycle of interest ion species in the axial direction, the interest ion species are synchronized with the auxiliary electric field to be certainly unstabilized in the detector side.
    • 提供了具有高离子选择效率的质谱仪和质谱法。 质谱仪包括离子阱,样品引入装置,电子枪,检测器,用于向离子阱施加电压的电源,用于控制电源和电子枪的控制装置,用于执行的质量分析装置 基于检测器的检测信号的质谱。 使用辅助电源,使端帽电极之间产生的辅助电场的方向仅指向检测器。 在这种情况下,通过将辅助电压的周期设定在轴向的兴趣离子种类的振荡周期附近,兴趣离子种类与辅助电场同步,在检测器侧肯定不稳定。