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1. 发明授权

US4125454A Process for suppression of catalyst deactivation and C.sub.5 + liquid yield loss in a cyclic reforming unit 失效
标题翻译：抑制催化剂失活的方法和C（HD 5 {B {30}在循环重整单元中的液体产率损失
公开(公告)号：US4125454A
公开(公告)日：1978-11-14
申请号：US851060
申请日：1977-11-14
申请人： Kenneth R. Clem , George A. Swan , Louis Dauber
发明人： Kenneth R. Clem , George A. Swan , Louis Dauber
IPC分类号： C10G59/02 , C10G35/04 , C10G35/08
CPC分类号： C10G35/04
摘要： A process for reforming with hydrogen, or hydroforming, a naphtha in a cyclic reforming unit which contains a plurality of catalyst-containing on stream reactors in series, and a catalyst-containing swing reactor manifolded therewith which can be periodically placed in series and substituted for an on stream reactor while the latter is removed from series for regeneration and reactivation of the catalyst contained therein. In the process, a reactor which is next scheduled for regeneration and reactivation of its near deactivated catalyst is located immediately downstream next in series with a reactor which contains freshly regenerated, reactivated catalyst at the time the latter is initially put on stream so that sulfur released by the freshly regenerated, reactivated catalyst which occurs a short time after the upstream reactor has been returned to service, is adsorbed by the near deactivated catalyst of the reactor next requiring removal from the series for catalyst regeneration and reactivation. Subsequent to this time, and prior to any desorption and release of major concentrations of sulfur from the deactivated catalyst, the reactor used for scavenging the sulfur is then swung out of series for regeneration and reactivation of the sulfided catalyst, and replaced in the series by the swing reactor.
摘要翻译：在含有多个含有串联反应器的含催化剂的反应器的循环重整单元中用氢气或液压成型重整石脑油的方法，以及含有其的含催化剂的挥发反应器，其可以周期性地串联并代替一种在线反应器，而后者则从串联中除去，用于再生和再活化其中所含的催化剂。在此过程中，接下来计划用于其近钝化催化剂的再生和再活化的反应器紧邻下游与包含新鲜再生的再活化催化剂的反应器在下游串联，在反应器最初置于流动时，使得硫释放通过在上游反应器返回使用后短时间内发生的新鲜再生的再活化催化剂被反应器的近钝化催化剂吸附，需要从该系列中除去催化剂再生和再活化。在此之后，在从失活的催化剂中解吸和释放主要浓度的硫之前，然后将用于清除硫的反应器串联排出以再生和重新活化硫化催化剂，并以串联方式替换摆动反应堆。

2. 发明授权

US4166024A Process for suppression of hydrogenolysis and C.sub.5.sup.+ liquid yield loss in a cyclic reforming unit 失效
标题翻译：用于抑制氢解的方法和C（HD 5 {HU {30在循环重整单元中的液体产率损失）
公开(公告)号：US4166024A
公开(公告)日：1979-08-28
申请号：US923192
申请日：1978-07-10
申请人： George A. Swan
发明人： George A. Swan
IPC分类号： C10G35/04 , C10G35/08
CPC分类号： C10G35/04
摘要： A process for reforming naphtha, with hydrogen, in a cyclic reforming unit which contains a plurality of catalyst-containing on-stream reactors in series, and a catalyst-containing swing reactor manifolded therewith which can be periodically placed in series and substituted for an on-stream reactor while the latter is removed from series for regeneration and reactivation of the catalyst contained therein. In the process, the ability of a catalyst to operate in a hydrogenolysis mode and effect sulfur release can be effectively suppressed after the freshly prepared catalyst has been regenerated, and reactivated several times, generally about five times or more, by the addition thereto of sufficient sulfur to maintain an equilibrium amount of sulfur on the catalyst, preferably a maximum of about 0.01 weight percent sulfur. Preferably, a modified catalyst presulfiding regimen is imposed wherein the amount of sulfur added to a fresh catalyst is progressively, and preferably proportionately reduced from one regeneration, reactivation sequence to the next such that, on and after about the fifth regeneration, and reactivation of the catalyst a maximum of about 0.01 weight percent sulfur is added to the catalyst. In a preferred mode of operation, the catalyst of the lead reactors of the series is not directly sulfided, but indirectly sulfided by sulfur added to, and released by the tail reactor, or reactors. An on-stream water wave displaces sulfur from the sulfided catalyst of the tail reactor, or reactors, as it is returned to service, and a water wave from the catalyst of each reactor redistributes sulfur to undersulfided catalysts of other reactors in the form of hydrogen sulfide released to and carried by the recycle gas.
摘要翻译：在包含多个含有催化剂的串联反应器的循环重整单元中，用氢气重整石脑油的方法，以及与其串联的含催化剂的回转反应器，其可以周期性地串联置换并代替流反应器，而后者从串联中除去，用于再生和再活化其中所含的催化剂。在此过程中，新鲜制备的催化剂再生后，催化剂以氢解方式运行并实现硫释放的能力可以得到有效的抑制，并通过加入足量的催化剂重新活化数次，通常约为五次或更多次硫以保持催化剂上的硫的平衡量，优选最大约0.01重量％的硫。优选地，进行改性的催化剂预硫化方案，其中添加到新鲜催化剂中的硫的量是逐渐地，并且优选从一个再生，再活化顺序到下一个的再次活化顺序逐个减少，使得在第五次再生之后和之后，重新激活向催化剂中加入最多约0.01重量％的硫的催化剂。在优选的操作模式中，该系列的牵引反应器的催化剂不是直接硫化，而是通过加到尾气反应器或反应器中的硫而间接硫化。一个在线水波从尾气反应器或反应器的硫化催化剂中排出硫，当其返回使用时，来自每个反应器的催化剂的水波将硫分解成其它反应器的硫化催化剂，形式为氢释放到循环气体中并由循环气携带的硫化物。

3. 发明授权

US5868922A Analyzer system for strippable hydrocarbon on FCC catalyst 失效
标题翻译： FCC催化剂上可剥离烃分析仪系统
公开(公告)号：US5868922A
公开(公告)日：1999-02-09
申请号：US771074
申请日：1996-12-20
申请人： James P. Glass, Jr. , George A. Swan
发明人： James P. Glass, Jr. , George A. Swan
IPC分类号： C10G11/18
CPC分类号： C10G11/187 , Y10S208/01 , Y10S585/905 , Y10S585/906
摘要： A FCC process in which spent catalyst is stripped of hydrocarbon in a stripping zone prior to entering the regenerator. In order to maximize the amount of strippable hydrocarbon removed in the stripping zone with minimal use of stripping gas, a sample of spent catalyst is removed prior to entering the regenerator. The spent catalyst is analyzed for strippable hydrocarbon by conducting the sample to a heated catalyst collection vessel, evacuating the catalyst, collecting the gases from the collection vessel and analyzing the gases for amount of strippable hydrocarbon on the spent catalyst.
摘要翻译： FCC方法，其中在进入再生器之前在汽提区中将废催化剂汽提出烃。为了最大限度地利用汽提气体在汽提区中除去的可汽提碳氢化合物的量，在进入再生器之前，将废催化剂样品除去。通过将样品导入加热的催化剂收集容器，抽空催化剂，从收集容器中收集气体并分析废气中的可消除烃的量，对废催化剂进行分析。

4. 发明授权

US6106697A Two stage fluid catalytic cracking process for selectively producing b. C.su2 to C.sub.4 olefins 失效
标题翻译：用于选择性生产C2至C4烯烃的两阶段流化催化裂解方法
公开(公告)号：US6106697A
公开(公告)日：2000-08-22
申请号：US073084
申请日：1998-05-05
申请人： George A. Swan , Michael W. Bedell , Paul K. Ladwig , John E. Asplin , Gordon F. Stuntz , William A. Wachter , Brian Erik Henry
发明人： George A. Swan , Michael W. Bedell , Paul K. Ladwig , John E. Asplin , Gordon F. Stuntz , William A. Wachter , Brian Erik Henry
IPC分类号： C10G11/05 , C10G51/02 , C10G57/00 , C10G57/02
CPC分类号： C10G57/02 , C10G2400/20
摘要： C.sub.2 to C.sub.4 olefins are selectively produced from a gas oil or resid in a two stage process. The gas oil or resid is reacted in a first stage comprised of a fluid catalytic cracking unit wherein it is converted in the presence of conventional large pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage comprised of a process unit containing a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone.
摘要翻译： C 2 -C 4烯烃可以从瓦斯油中选择性地制备，或者在两段工艺中残留。瓦斯油或渣油在由流化催化裂化装置组成的第一阶段中反应，其中在常规大孔沸石催化剂存在下将其转化为包括石脑油沸程的反应产物。将石脑油沸程流引入包含含有反应区，汽提区，催化剂再生区和分馏区的处理单元的第二阶段。石脑油原料流在反应区中与含有约10至50wt。％的平均孔径小于约0.7纳米的结晶沸石在包括约500至650℃的温度和约10至40psia的烃分压的反应条件下进行。蒸气产物被顶部收集，催化剂颗粒在通向催化剂再生区的途中通过汽提区。挥发物在汽提区中用蒸汽汽提，并将催化剂颗粒送入催化剂再生区，其中焦炭从催化剂燃烧，然后再循环到反应区。

5. 发明授权

US4634515A Nickel adsorbent for sulfur removal from hydrocarbon feeds 失效
标题翻译：用于从烃进料中除硫的镍吸附剂
公开(公告)号：US4634515A
公开(公告)日：1987-01-06
申请号：US791532
申请日：1985-10-25
申请人： George W. Bailey , George A. Swan
发明人： George W. Bailey , George A. Swan
IPC分类号： C10G25/00 , C10G61/06 , C10G69/08 , C10G45/00 , C10G67/06
CPC分类号： C10G69/08 , C10G25/003 , C10G61/06
摘要： An improved sulfur trap for the sulfur level reduction of a reformer feed leaving a hydrofiner to render it suitable for use in a reforming unit employing a sulfur-sensitive reforming catalyst. The nickel catalyst contained in said sulfur trap is one wherein the average crystallite size of the nickel is at least about 75.ANG., and at greater than 50 percent of the nickel is in reduced state, based on the total weight of the supported component.
摘要翻译：改进的硫捕集器用于重整器进料的硫含量降低，离开氢化还原剂使其适用于采用硫敏感重整催化剂的重整单元。所述硫捕集器中所含的镍催化剂是镍的平均微晶尺寸至少为约75，并且大于镍的50％处于还原状态，基于所支撑的组分的总重量。

6. 发明授权

US4613423A Catalytic reforming process 失效
标题翻译：催化重整过程
公开(公告)号：US4613423A
公开(公告)日：1986-09-23
申请号：US729816
申请日：1985-05-02
申请人： George A. Swan , William C. Baird, Jr. , Robert G. Corry
发明人： George A. Swan , William C. Baird, Jr. , Robert G. Corry
IPC分类号： C10G35/06 , C10G59/02
CPC分类号： C10G59/02
摘要： A process wherein, in a series of reforming zones, or reactors, each of which contains a bed, or beds of catalyst, the catalyst in the leading reforming zone, or zones, is constituted of supported platinum or supported platinum and rhenium, and the catalyst in the rearward reforming zone, or zones of the series, is constituted of platinum, rhenium, and iridium. The amount of (rhenium+iridium) relative to the platinum in the last reforming zone, or zones is present in weight ratio of at least about 1.5:1 and more preferably ranges from about 1.5:1 to about 10:1. The beds of catalyst are contacted with a hydrocarbon or naphtha feed, and hydrogen, at reforming conditions to produce a hydrocarbon, or naphtha product of improved octane, and the product is withdrawn.
摘要翻译：一种方法，其中在一系列重整区或反应器中，每个重整区或反应器各自含有床或催化剂床，前导重整区或区域中的催化剂由负载的铂或负载的铂和铼构成，并且在后向重整区域或该系列的区域中的催化剂由铂，铼和铱构成。在最后的重整区域中，相对于铂的铼+铱的含量以至少约1.5:1的重量比存在，更优选在约1.5:1至约10:1的范围内。催化剂床与碳氢化合物或石脑油进料和氢气在重整条件下接触以产生烃或改进的辛烷的石脑油产物，并且产物被排出。

7. 发明授权

US4436612A Catalytic reforming process 失效
标题翻译：催化重整过程
公开(公告)号：US4436612A
公开(公告)日：1984-03-13
申请号：US482515
申请日：1983-04-06
申请人： Soni O. Oyekan , George A. Swan
发明人： Soni O. Oyekan , George A. Swan
IPC分类号： B01J23/656 , C10G35/09 , C10G35/06
CPC分类号： B01J23/6567 , C10G35/09
摘要： A process wherein, in a series of reforming zones, or reactors, each of which contains a bed, or beds of catalyst, the catalyst in the leading reforming zones is constituted of supported platinum and a relatively low concentration of rhenium, and the catalyst in the last reforming zone, or reactor of the series, is constituted of platinum and a relatively high concentration of rhenium. The amount of rhenium relative to the platinum in the last reforming zone, or reactor is present in an atomic or weight ratio of rhenium:platinum of at least about 1.5:1; preferably at least about 2:1, and more preferably ranges from about 2:1 to about 3:1. The beds of catalyst are contacted with a hydrocarbon or naphtha feed, and hydrogen, at reforming conditions to produce a hydrocarbon, or naphtha product of improved octane, and the product is withdrawn.
摘要翻译：一种方法，其中在一系列重整区或反应器中，每个重整区或反应器各自含有床或催化剂床，前导重整区中的催化剂由负载的铂和相对低浓度的铼构成，催化剂在该系列的最后一个重整区或反应器由铂和较高浓度的铼组成。在最后的重整区或反应器中相对于铂的铼的量以至少约1.5:1的铼：铂的原子或重量比存在; 优选至少约2:1，更优选约2:1至约3:1。催化剂床与碳氢化合物或石脑油进料和氢气在重整条件下接触以产生烃或改进的辛烷的石脑油产物，并且产物被排出。

8. 发明授权

US06352639B2 Superheating atomizing steam with hot FCC feed oil 失效
标题翻译：用热FCC原料油过热雾化蒸汽
公开(公告)号：US06352639B2
公开(公告)日：2002-03-05
申请号：US09735779
申请日：2000-12-13
申请人： Jackson I. Ito , Leonard Schoenman , Dean C. Draemel , Teh C. Ho , George A. Swan
发明人： Jackson I. Ito , Leonard Schoenman , Dean C. Draemel , Teh C. Ho , George A. Swan
IPC分类号： C10G1100
CPC分类号： F28F7/02 , B01J8/1827 , B01J19/26 , B01J2219/00092 , B01J2219/00094 , B01J2219/00119 , B01J2219/00123 , B01J2219/00159 , B05B7/0433 , B05B7/0483 , C10G11/18 , F28C3/06 , F28F13/08
摘要： An atomizing gas, such as steam, and a hot fluid comprising a hot liquid to be atomized, are passed under pressure, through separate fluid conduits in a heat exchange means, in which the hot liquid heats the steam to a superheat temperature, by indirect heat exchange. The superheated steam is then injected into the hot fluid, which comprises a two-phase fluid comprising steam and the hot liquid, subsequent to the superheated steam injection. The two-phase fluid is passed through an atomizing means, such as an orifice, into a lower pressure atomizing zone, which causes the steam to expand and atomize the liquid into a spray of liquid droplets. The two-phase fluid is formed before or as a consequence of the superheated steam injection and is preferably steam-continuous when passed through the atomizing means. This process is useful for atomizing a hot feed oil for a fluid cat cracking (FCC) process.
摘要翻译：雾化气体，例如蒸汽，以及包含待雾化的热液体的热流体在压力下通过热交换装置中的分开的流体导管通过，其中热液体将蒸汽加热至过热温度，间接热交换。然后将过热蒸汽注入到热流体中，该热流体包括在过热蒸汽注入之后包括蒸汽和热液体的两相流体。两相流体通过诸如孔口的雾化装置进入较低压力的雾化区，这使得蒸汽膨胀并将液体雾化成液滴喷雾。两相流体在过热蒸汽注入之前或之后形成，并且优选在通过雾化装置时是蒸汽连续的。该方法可用于雾化用于流动性猫裂解（FCC）方法的热进料油。

9. 发明授权

US5125834A Apparatus, and method, for simultaneous flossing and subgingival injection with antibacterial liquid solution to prevent plaque buildup on teeth 失效
标题翻译：用于同时进行牙线和龈下注射抗菌液体溶液以防止牙齿积累的装置和方法
公开(公告)号：US5125834A
公开(公告)日：1992-06-30
申请号：US734288
申请日：1991-07-15
申请人： George A. Swan
发明人： George A. Swan
IPC分类号： A61C15/04
CPC分类号： A61C15/041
摘要： Apparatus, and method, for flossing the teeth, and simultaneously applying an antibacterial liquid solution to the teeth being flossed. The apparatus is constituted generally of a flexible hollow fiber with porous walls of diameter sufficiently small for fitting between and flossing the teeth, and a positive displacement device for supplying an antibacterial liquid to the interior volume, or bore, of the flexible hollow fiber for transport through the porous walls to the teeth. Flossing with the flexible hollow fiber, to which the antibacterial liquid solution is applied during flossing, bathes the teeth with the liquid solution during the flossing and provides a significant reduction in plaque accumulation.
摘要翻译：用于牙线牙线的装置和方法，同时将抗菌液体溶液施用于被牙线的牙齿。该装置通常由柔性中空纤维构成，其多孔壁的直径足够小以用于在牙齿之间进行牙齿和牙线之间的啮合;以及用于将柔性中空纤维的内部容积或孔中的抗菌液体供给到正位移装置通过多孔壁到牙齿。用柔性中空纤维进行梳理，其中在牙线期间施用抗菌液体溶液，在牙线期间用液体溶液洗涤牙齿，并且显着减少斑块积聚。

10. 发明授权

US4427533A Catalytic reforming process 失效
标题翻译：催化重整过程
公开(公告)号：US4427533A
公开(公告)日：1984-01-24
申请号：US482508
申请日：1983-04-06
申请人： George A. Swan
发明人： George A. Swan
IPC分类号： B01J23/656 , C10G35/09 , C10G35/06
CPC分类号： C10G35/09 , B01J23/6567
摘要： A process wherein, in a series of reforming zones, or reactors, each of which contains a bed, or beds of catalyst, the catalyst in the leading reforming zones is constituted of supported platinum and a relatively low concentration of rhenium, and the catalyst in the last reforming zone, or reactor of the series, is constituted of platinum and a relatively high concentration of rhenium. The amount of rhenium relative to the platinum in the last reforming zone, or reactor is present in an atomic or weight ratio of rhenium:platinum of at least 1.5:1; preferably at least about 2:1, and more preferably ranges from about 2:1 to about 3:1. The beds of catalyst are contacted with a hydrocarbon or naphtha feed, and hydrogen, at reforming conditions to produce a hydrocarbon, or naphtha product of improved octane, and the product is withdrawn.
摘要翻译：一种方法，其中在一系列重整区或反应器中，每个重整区或反应器各自含有床或催化剂床，前导重整区中的催化剂由负载的铂和相对低浓度的铼构成，催化剂在该系列的最后一个重整区或反应器由铂和较高浓度的铼组成。在最后的重整区或反应器中相对于铂的铼的量以至少1.5:1的铼：铂的原子或重量比存在; 优选至少约2:1，更优选约2:1至约3:1。催化剂床与碳氢化合物或石脑油进料和氢气在重整条件下接触以产生烃或改进的辛烷的石脑油产物，并且产物被排出。

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