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    • 2. 发明授权
    • Two stage fluid catalytic cracking process for selectively producing C2 to C4 olefins
    • 用于选择性生产C2至C4烯烃的两阶段流化催化裂解方法
    • US07323099B2
    • 2008-01-29
    • US10993036
    • 2004-11-19
    • Brian Erik Henry
    • Brian Erik Henry
    • C10G51/02C07C4/06
    • C10G51/02C07C4/06C07C11/02C07C11/06
    • A process for selectively producing C2 to C4 olefins from feedstock such as a gas oil or resid. The feedstock is reacted in a first stage comprising a fluid catalytic cracking unit wherein it is converted in the presence of a mixture of conventional large pore zeolitic catalyst and a medium pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage where it is contacted with a catalyst containing from about 10 to about 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to about 650° C. and a hydrocarbon partial pressure from about 10 to about 40 psia (about 70 to about 280 kPa).
    • 从原料如瓦斯油或渣油中选择性地向C 4 O 3烯烃中选择性地生产C 2 O 3的方法。 原料在包括流化催化裂化装置的第一阶段中反应,其中在常规大孔沸石催化剂和中孔沸石催化剂的混合物存在下将其转化成包括石脑油沸程的反应产物。 将石脑油沸程流引入第二阶段,其中与含有约10至约50wt。 在包括约500至约650℃的温度和约10至约40psia(约70至约280kPa)的烃分压的反应条件下,平均孔径小于约0.7纳米的结晶沸石的% )。