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1. 发明授权

US4454750A Apparatus for generating a knock signal for use with an internal combustion engine 失效
标题翻译：用于产生用于内燃机的爆震信号的装置
公开(公告)号：US4454750A
公开(公告)日：1984-06-19
申请号：US367922
申请日：1982-04-13
申请人： Kenichi Yoshida , Masaharu Asano , Kenji Yoneda
发明人： Kenichi Yoshida , Masaharu Asano , Kenji Yoneda
IPC分类号： F02P5/152 , F02P5/153 , G01H17/00 , G01L23/22 , G01M15/00 , G01R19/00 , G01R19/165
CPC分类号： G01L23/225 , F02P5/152 , Y02T10/46
摘要： An output signal of a vibration sensor mounted on an internal combustion engine is compared with a background noise reference signal to produce a knock signal which can accurately represent the intensity of knocking. The background noise level signal is produced by averaging a component of the vibration sensor output signal which represents the vibration of the engine other than knock-induced vibration. In order to produce a feedback signal for inhibiting the knock induced component of the sensor output signal, a first comparator compares the sensor output signal with a first reference signal having a sufficiently low level. Knock signal is produced by a second comparator which receives a second reference signal, which is proportional to the first reference signal but having sufficiently higher level, thereby enabling a precise determination of knock intensity.
摘要翻译：安装在内燃机上的振动传感器的输出信号与背景噪声参考信号进行比较，以产生可以准确地表示爆震强度的爆震信号。背景噪声电平信号是通过对表示发生器的振动以外的振动传感器输出信号的分量进行平均而产生的，而不是敲击引起的振动。为了产生用于抑制传感器输出信号的敲击感应分量的反馈信号，第一比较器将传感器输出信号与具有足够低电平的第一参考信号进行比较。敲击信号由第二比较器产生，第二比较器接收与第一参考信号成比例但具有足够高的电平的第二参考信号，由此能够精确地确定爆震强度。

2. 发明授权

US08329766B2 Functional membrane and production method thereof, and electrolyte membrane for use in fuel cell and production method thereof 失效
标题翻译：功能膜及其制造方法以及燃料电池用电解质膜及其制造方法
公开(公告)号：US08329766B2
公开(公告)日：2012-12-11
申请号：US11884786
申请日：2006-02-23
申请人： Shigeharu Takagi , Toshiya Saito , Misaki Kobayashi , Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano
发明人： Shigeharu Takagi , Toshiya Saito , Misaki Kobayashi , Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano
IPC分类号： C08J5/20 , C08J7/18 , B01J47/00 , B01J47/12 , B01J41/00
CPC分类号： H01M8/1088 , B01D67/0032 , B01D67/0093 , B01D2323/34 , B01D2323/385 , C08J5/2293 , C08J7/123 , C08J7/18 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M2300/0082 , H01M2300/0088 , Y02P70/56 , Y10T428/249992
摘要： A functional membrane and a production method thereof including: an ion irradiation step in which a polymer film substrate is irradiated with high energy heavy ions at 104 to 1014 ions/cm2, to generate active species in the film substrate; and a graft polymerization step in which after the ion irradiation step, the film substrate is added with one or more monomers selected from a group A consisting of monomers each having a functional group and 1 to 80 mol % of a monomer including a group B consisting of a crosslinking agent(s) for the group A monomer(s), and the film substrate and the monomer(s) are graft-polymerized. There is obtained a functional membrane having high functionality in conjunction with the gas barrier property intrinsically possessed by a polymer film substrate, in particular, a polymer electrolyte membrane optimal as a polymer electrolyte membrane for use in fuel cells, high in proton conductivity and excellent in gas barrier property.
摘要翻译：一种功能膜及其制造方法，其特征在于，包括：离子照射工序，其中以104〜1014个离子/ cm 2的高能重离子照射聚合物膜基材，以在所述膜基材中生成活性物质; 以及接枝聚合步骤，其中在离子照射步骤之后，向基材添加一种或多种选自由各自具有官能团的单体组成的单体A和1至80mol％的包含B组的单体，的用于A族单体的交联剂，并且膜基材和单体被接枝聚合。结合聚合物膜基材本身具有的气体阻隔性能，特别是优选作为燃料电池用高分子电解质膜的高分子电解质膜，具有高官能度的功能膜，质子传导性高，优异的阻气性。

3. 发明授权

US08283088B2 Silane crosslinked structure-introduced fuel-cell polymer electrolyte membrane and fuel-cell electrode assembly having the same 失效
标题翻译：硅烷交联结构引入的燃料电池聚合物电解质膜和具有该电解质膜的燃料电池电极组件
公开(公告)号：US08283088B2
公开(公告)日：2012-10-09
申请号：US12311570
申请日：2007-09-05
申请人： Masaru Yoshida , Masaharu Asano , Jinhua Chen , Yasunari Maekawa , Toshimitsu Tachibana , Yozo Nagai , Soji Nishiyama
发明人： Masaru Yoshida , Masaharu Asano , Jinhua Chen , Yasunari Maekawa , Toshimitsu Tachibana , Yozo Nagai , Soji Nishiyama
IPC分类号： H01M8/10
CPC分类号： C08F255/00 , C08F8/00 , C08F8/12 , C08F8/36 , C08F259/08 , C08J5/2293 , C08J7/18 , C08J2323/06 , C08J2327/18 , H01B1/122 , H01M8/1027 , H01M8/1037 , H01M8/1039 , H01M8/1044 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56 , C08F230/08
摘要： An object is to provide an electrolyte membrane that maintains excellent cell characteristics for a long time under high temperature and low water retention, as this is the most important point in fuel cells.A process for producing a polymer electrolyte membrane for fuel cells is provided, which process comprises in sequence: forming graft molecular chains by graft-polymerization of a vinyl silane coupling agent on a polymer film substrate that has phenyl groups capable of holding sulfonic acid groups; introducing sulfonic acid groups into phenyl groups contained in the graft molecular chains; and hydrolyzing and condensing alkoxy groups contained in the graft molecular chains so that a silane crosslinked structure is introduced between the graft molecular chains. A polymer electrolyte membrane produced by the process is also provided.
摘要翻译：目的是提供一种电解质膜，其在高温和低保水性下长时间保持优异的电池特性，因为这是燃料电池中最重要的一点。本发明提供一种燃料电池用高分子电解质膜的制造方法，该方法依次包括：在具有能够保持磺酸基的苯基的聚合物膜基材上接枝聚合乙烯基硅烷偶联剂而形成接枝分子链; 将磺酸基团引入到接枝分子链中所含的苯基中; 并且使包含在接枝分子链中的烷氧基水解和缩合，使得在接枝分子链之间引入硅烷交联结构。还提供了通过该方法制备的聚合物电解质膜。

4. 发明授权

US07919537B2 Methods for producing a polymer electrolyte membrane having improved oxidation resistance 失效
标题翻译：具有改善的抗氧化性的聚合物电解质膜的制造方法
公开(公告)号：US07919537B2
公开(公告)日：2011-04-05
申请号：US11267160
申请日：2005-11-07
申请人： Yozo Nagai , Toshimitsu Tachibana , Soji Nishiyama , Tetsuya Yamaki , Masaharu Asano , Masaru Yoshida
发明人： Yozo Nagai , Toshimitsu Tachibana , Soji Nishiyama , Tetsuya Yamaki , Masaharu Asano , Masaru Yoshida
IPC分类号： C08J5/22 , H01M8/10
CPC分类号： C08J5/2243 , C08J2325/00 , H01M8/1004 , H01M8/1023 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： A method for producing a polymer electrolyte membrane for electrolyte fuel cells includes: irradiating gamma rays onto a polymer substrate to obtain a crosslinked polytetrafluoroetylene substrate, grafting a styrenic monomer and bis(vinylphenyl)ethane as monomers to the crosslinked polymer substrate, and introducing sulfonic acid groups into graft side chains formed by grafting. Fluoro polymer substrates such as polytetrafluoroethylene and ethylene tetrafluoroethylene copolymer may be used.
摘要翻译：一种电解质燃料电池用聚合物电解质膜的制造方法，其特征在于，将γ射线照射在聚合物基材上，得到交联聚四氟乙烯基材，将苯乙烯类单体和双（乙烯基苯基）乙烷作为单体接枝到交联聚合物基材上，通过接枝形成接枝侧链。可以使用氟聚合物基材如聚四氟乙烯和乙烯四氟乙烯共聚物。

5. 发明申请

US20100040927A1 Silane crosslinked structure-introduced fuel-cell polymer electrolyte membrane and fuel-cell electrode assembly having the same 失效
标题翻译：硅烷交联结构引入的燃料电池聚合物电解质膜和具有该电解质膜的燃料电池电极组件
公开(公告)号：US20100040927A1
公开(公告)日：2010-02-18
申请号：US12311570
申请日：2007-09-05
申请人： Masaru Yoshida , Masaharu Asano , Jinhua Chen , Yasunari Maekawa , Toshimitsu Tachibana , Yozo Nagai , Soji Nishiyama
发明人： Masaru Yoshida , Masaharu Asano , Jinhua Chen , Yasunari Maekawa , Toshimitsu Tachibana , Yozo Nagai , Soji Nishiyama
IPC分类号： H01M8/10 , C08J9/00
CPC分类号： C08F255/00 , C08F8/00 , C08F8/12 , C08F8/36 , C08F259/08 , C08J5/2293 , C08J7/18 , C08J2323/06 , C08J2327/18 , H01B1/122 , H01M8/1027 , H01M8/1037 , H01M8/1039 , H01M8/1044 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56 , C08F230/08
摘要： An object is to provide an electrolyte membrane that maintains excellent cell characteristics for a long time under high temperature and low water retention, as this is the most important point in fuel cells.A process for producing a polymer electrolyte membrane for fuel cells is provided, which process comprises in sequence: forming graft molecular chains by graft-polymerization of a vinyl silane coupling agent on a polymer film substrate that has phenyl groups capable of holding sulfonic acid groups; introducing sulfonic acid groups into phenyl groups contained in the graft molecular chains; and hydrolyzing and condensing alkoxy groups contained in the graft molecular chains so that a silane crosslinked structure is introduced between the graft molecular chains. A polymer electrolyte membrane produced by the process is also provided.
摘要翻译：目的是提供一种电解质膜，其在高温和低保水性下长时间保持优异的电池特性，因为这是燃料电池中最重要的一点。本发明提供一种燃料电池用高分子电解质膜的制造方法，该方法依次包括：在具有能够保持磺酸基的苯基的聚合物膜基材上接枝聚合乙烯基硅烷偶联剂而形成接枝分子链; 将磺酸基团引入到接枝分子链中所含的苯基中; 并且使包含在接枝分子链中的烷氧基水解和缩合，使得在接枝分子链之间引入硅烷交联结构。还提供了通过该方法制备的聚合物电解质膜。

6. 发明申请

US20080171251A1 Functional Membrane and Production Method Thereof, and Electrolyte Membrane for Use in Fuel Cell and Production Method Thereof 失效
标题翻译：功能膜及其制备方法以及用于燃料电池的电解质膜及其制备方法
公开(公告)号：US20080171251A1
公开(公告)日：2008-07-17
申请号：US11884786
申请日：2006-02-23
申请人： Shigeharu Takagi , Toshiya Saito , Misaki Kobayashi , Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano
发明人： Shigeharu Takagi , Toshiya Saito , Misaki Kobayashi , Masaru Yoshida , Tetsuya Yamaki , Masaharu Asano
IPC分类号： H01M8/10 , C08J5/22
CPC分类号： H01M8/1088 , B01D67/0032 , B01D67/0093 , B01D2323/34 , B01D2323/385 , C08J5/2293 , C08J7/123 , C08J7/18 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M2300/0082 , H01M2300/0088 , Y02P70/56 , Y10T428/249992
摘要： A functional membrane and a production method thereof including: an ion irradiation step in which a polymer film substrate is irradiated with high energy heavy ions at 10 4 to 10 14 ions/cm2, to generate active species in the film substrate; and a graft polymerization step in which after the ion irradiation step, the film substrate is added with one or more monomers selected from a group A consisting of monomers each having a functional group and 1 to 80 mol % of a monomer including a group B consisting of a crosslinking agent(s) for the group A monomer(s), and the film substrate and the monomer(s) are graft-polymerized. There is obtained a functional membrane having high functionality in conjunction with the gas barrier property intrinsically possessed by a polymer film substrate, in particular, a polymer electrolyte membrane optimal as a polymer electrolyte membrane for use in fuel cells, high in proton conductivity and excellent in gas barrier property.
摘要翻译：一种功能膜及其制造方法，其特征在于，包括：以10 4〜10 14个/ cm 2以高能重离子照射高分子膜基板的离子照射工序，生成活性物质薄膜基材; 以及接枝聚合步骤，其中在离子照射步骤之后，向基材添加一种或多种选自由各自具有官能团的单体组成的单体A和1至80mol％的包含B组的单体，的用于A族单体的交联剂，并且膜基材和单体被接枝聚合。结合聚合物膜基材本身具有的气体阻隔性能，特别是优选作为燃料电池用高分子电解质膜的高分子电解质膜，具有高官能度的功能膜，质子传导性高，优异的阻气性。

7. 发明授权

US5420126A 3,4-dihydro-2H-1,4-benzoxazine derivatives and pharmaceutical compositions containing the same 失效
标题翻译： 3,4-二氢-2H-1,4-苯并恶嗪衍生物和含有它们的药物组合物
公开(公告)号：US5420126A
公开(公告)日：1995-05-30
申请号：US982034
申请日：1992-11-24
申请人： Yuzo Matsumoto , Ryuji Tsuzuki , Akira Matsuhisa , Kazuhisa Takayama , Wataru Uchida , Masaharu Asano , Isao Yanagisawa , Toru Yoden
发明人： Yuzo Matsumoto , Ryuji Tsuzuki , Akira Matsuhisa , Kazuhisa Takayama , Wataru Uchida , Masaharu Asano , Isao Yanagisawa , Toru Yoden
IPC分类号： C07D265/36 , C07D413/04 , C07D413/06 , C07D273/01 , C07D413/02
CPC分类号： C07D413/04 , C07D265/36 , C07D413/06
摘要： Novel benzoxazine derivatives of the formula (I): ##STR1## are provided as well as their pharmaceutically acceptable salts and a method for their use as potassium channel activating agents 2-(3,4-Dihydro-2, 2-dimethyl-6-phenylsulfonyl-2H-1,4-benzoxazin-4-yl)pyridine N-oxide is illustrative of a benzoxazine derivative of formula (I). Also provided are intermediate compounds such as those of formula (II): ##STR2##
摘要翻译：提供了式（I）：新颖的（I）的苯并恶嗪衍生物：其中药学上可接受的盐及其作为钾通道活化剂的方法2-（3,4-二氢-2,2-二甲基 -6-苯基磺酰基-2H-1,4-苯并恶嗪-4-基）吡啶N-氧化物是式（I）的苯并恶嗪衍生物的说明。还提供了中间体化合物，例如式（II）的那些：（II）

8. 发明授权

US5110820A Dihydropyridine compounds which process both calcium (2+)-antagonistic and beta receptor blocking activities 失效
标题翻译：二钙二氢化合物（2 +） - 拮抗剂和受体阻断活性
公开(公告)号：US5110820A
公开(公告)日：1992-05-05
申请号：US611340
申请日：1990-11-13
申请人： Takashi Fujikura , Noriki Ito , Yuzo Matsumoto , Masaharu Asano , Toichi Takenaka
发明人： Takashi Fujikura , Noriki Ito , Yuzo Matsumoto , Masaharu Asano , Toichi Takenaka
IPC分类号： A61K31/4427 , A61K31/455 , A61P3/00 , A61P3/14 , A61P9/08 , A61P9/10 , A61P9/12 , A61P25/02 , C07D211/90 , C07D401/12
CPC分类号： C07D401/12 , C07D211/90
摘要： Dihydropyridine compounds and salts thereof are provided which exhibit both Ca.sup.2+ -antagonistic and adrenergic beta-receptor blocking activities and therefore are useful for the treatment of ischemic heart diseases and hypertension. The compounds have the formula ##STR1## wherein A represents a straight or branched carbon chain alkylene group having 1 to 10 carbon atoms which may be interrupted by an oxygen atom(s); R.sup.1 and R.sup.4, which may be the same or different, each represents a lower alkyl group; R.sup.2 represents an amino group, ##STR2## R.sup.3 represents a straight or branched carbon chain alkyl group having 1 to 10 carbon atoms which may be interrupted by an oxygen atom(s), or ##STR3## R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, a nitro group, a halogen atom, a trifluoromethyl group, a cyano group, a lower alkyl group, a lower alkoxy group or a lower alkenyloxy group; R.sup.7 represents a hydrogen atom, a cyano group, a halogen atom, a lower alkoxy group or a lower alkanoyl group; R.sup.8 and R.sup.9, which may be the same or different, each represents a lower alkyl group or an aralkyl group; and n represents an integer of 1 to 2: these symbols, hereafter, have the same significances.
摘要翻译：提供二氢吡啶化合物及其盐，其表现出Ca 2+ +拮抗性和肾上腺素能β受体阻断活性，因此可用于治疗缺血性心脏病和高血压。化合物具有式（I）的化合物，其中A表示可被氧原子间隔的具有1-10个碳原子的直链或支链碳链亚烷基; R 1和R 4可以相同或不同，各自表示低级烷基; R 2表示氨基，R 3表示可被氧原子间隔的具有1〜10个碳原子的直链或支链碳链烷基，或者R 5和R 6 可以相同或不同，分别表示氢原子，硝基，卤素原子，三氟甲基，氰基，低级烷基，低级烷氧基或低级链烯氧基。 R7表示氢原子，氰基，卤素原子，低级烷氧基或低级烷酰基; R 8和R 9可以相同或不同，各自表示低级烷基或芳烷基; n表示1〜2的整数，以下，符号相同。

9. 发明授权

US4672566A Device for measuring variable with automatic compensation for offset 失效
标题翻译：用于测量变量的装置，具有自动补偿补偿
公开(公告)号：US4672566A
公开(公告)日：1987-06-09
申请号：US442291
申请日：1982-11-17
申请人： Masaharu Asano , Yoshihisa Kawamura , Koyo Nakamura
发明人： Masaharu Asano , Yoshihisa Kawamura , Koyo Nakamura
IPC分类号： G01D3/02 , G01K3/08 , G01K19/00
CPC分类号： G01D3/022 , G01K3/08
摘要： A measurement device for measuring a physical property such as temperature difference, displacement, pressure, fluid flow rate, etc. comprises: (a) an amplifying means which receives and amplifies a voltage signal corresponding to a detected physical property; (b) a reference voltage generator which generates and applies a reference voltage to the amplifying means at a predetermined time; (c) a memory which stores the output voltage signal from the amplifying means when the reference voltage generator applies the reference voltage to the amplifying means; and (d) a calculating means which outputs at least one command signal to the reference voltage generator to apply the reference voltage to the amplifying means and to the memory to store the output voltage of the amplifying means into a specified memory location thereof at the predetermined time and calculates the value of the desired physical property from the current output voltage of the amplifying means with reference to the stored voltage value in the memory, whereby an accurate physical property measurement can be made by compensating for individual differences and deterioration of the characteristics of the measurement device.
摘要翻译：用于测量诸如温度差，位移，压力，流体流速等的物理性质的测量装置包括：（a）放大装置，其接收和放大对应于检测到的物理性质的电压信号; （b）参考电压发生器，其在预定时间产生并施加参考电压到所述放大装置; （c）当基准电压发生器将参考电压施加到放大装置时存储来自放大装置的输出电压信号的存储器; 以及（d）计算装置，其将至少一个命令信号输出到参考电压发生器以将参考电压施加到放大装置和存储器，以将放大装置的输出电压存储在预定的存储位置中时间，并根据存储器中存储的电压值从放大装置的当前输出电压计算所需物理量的值，从而可以通过补偿个体差异和特性劣化来进行精确的物理性质测量测量装置。

10. 发明授权

US4359992A Method of controlling fuel supply to internal combustion engine 失效
标题翻译：控制内燃机燃料供应的方法
公开(公告)号：US4359992A
公开(公告)日：1982-11-23
申请号：US148937
申请日：1980-05-12
申请人： Masaharu Asano , Hideyuki Tamura , Shoji Furuhashi
发明人： Masaharu Asano , Hideyuki Tamura , Shoji Furuhashi
IPC分类号： F02D41/04 , F02D41/26 , F02D41/34 , G05B15/02 , F02B3/00 , F02D21/04 , G06F15/20
CPC分类号： F02D41/345 , F02D41/26 , Y02T10/44
摘要： The calculation of an adjustment value, which is determined by the concentration of oxygen in the exhaust gas, the opening of a throttle valve provided in an intake air passage to the engine, the engine temperature, etc., is started every time a predetermined number of repeatedly produced start signals, the repetition rate of which corresponds to the rotational speed of the crankshaft, occur. A basic value for fuel supply, T.sub.p =k Q/N, is calculated from the engine operating parameters; the amount of flow of intake air into the engine, Q the rotational speed of the crankshaft, N, and a constant k, and adjusted according to the adjustment value to obtain a control output signal, in the vicinity of the next start signal after said predetermined number.
摘要翻译：由排气中的氧气浓度确定的调节值的计算，设置在发动机的进气通道中的节气门的打开，发动机的温度等的计算，每当预定数量发生重复产生的启动信号，其重复率对应于曲轴的转速。燃油供应的基本值，Tp = k Q / N，根据发动机运行参数计算; 进入发动机的进气量Q，曲轴的转速N和常数k，并根据调节值进行调整，以获得控制输出信号，在所述第一启动信号之后的所述预定数量。

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