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1. 发明申请

US20100227963A1 RESIN COMPOSITION, MOLDED ARTICLE, AND PRODUCTION METHODS THEREOF 审中-公开
标题翻译：树脂组合物，成型品及其生产方法
公开(公告)号：US20100227963A1
公开(公告)日：2010-09-09
申请号：US12161295
申请日：2007-01-17
申请人： Katsuhiko Hironaka , Fumitaka Kondo , Keiichiro Ino , Yuichi Matsuno , Kiyotsuna Toyohara , Hirotaka Suzuki
发明人： Katsuhiko Hironaka , Fumitaka Kondo , Keiichiro Ino , Yuichi Matsuno , Kiyotsuna Toyohara , Hirotaka Suzuki
IPC分类号： C08L69/00 , C08L73/00 , C08K3/34 , B29C45/00 , B29C49/00
CPC分类号： C08L69/00 , C08K3/013 , C08K3/34 , C08K5/51 , C08L23/02 , C08L25/04 , C08L67/02 , C08L67/04 , C08L2666/18
摘要： There are provided a resin composition comprising a polylactic acid which (i) comprises a poly-L-lactic acid (component B-1) and a poly-D-lactic acid (component B-4), (ii) has a weight ratio of the component B-1 to the component B-4 (component B-1/component B-4) of 10/90 to 90/10, and (iii) shows a proportion of melt peaks at 195° C. or higher to all melt peaks in a temperature rising process in measurement by a differential scanning calorimeter (DSC) of at least 20%; a molded article of the resin composition; and methods for producing the resin composition and the molded article.
摘要翻译：提供了包含聚乳酸的树脂组合物，（i）包含聚-L-乳酸（组分B-1）和聚-D-乳酸（组分B-4），（ii）具有重量比的组分B-1与组分B-4（组分B-1 /组分B-4）的比例为10/90至90/10，和（iii）显示195℃或更高至通过差示扫描量热计（DSC）测量的升温过程中所有熔体峰值至少为20％; 树脂组合物的模塑制品; 以及树脂组合物和成型体的制造方法。

2. 发明申请

US20110160364A1 RESIN COMPOSITION, MANUFACTURING METHOD THEREOF, AND MOLDED ARTICLE 审中-公开
标题翻译：树脂组合物，其制造方法和成型品
公开(公告)号：US20110160364A1
公开(公告)日：2011-06-30
申请号：US12375347
申请日：2007-07-26
申请人： Kiyotsuna Toyohara , Takaaki Matsuda , Keiichiro Ino , Yuichi Matsuno , Fumitaka Kondo , Jitsuo Oda
发明人： Kiyotsuna Toyohara , Takaaki Matsuda , Keiichiro Ino , Yuichi Matsuno , Fumitaka Kondo , Jitsuo Oda
IPC分类号： C08L67/04 , C08K5/52 , C08K3/26
CPC分类号： C08L67/02 , C08K3/013 , C08K5/523 , C08K5/527 , C08L67/025 , C08L67/04 , C08L2666/18
摘要： To provide a resin composition having high heat resistance with a high melting point and excellent melt stability and hydrolysis resistance, a molded article of the resin composition and a method of manufacturing the resin composition; the resin composition comprises an aromatic polyester (component A) having a butylene terephthalate skeleton as the main constituent unit and polylactic acid (component B) having a melting point of 190° C. or higher.
摘要翻译：为了提供具有高熔点的高耐热性和优异的熔体稳定性和耐水解性的树脂组合物，该树脂组合物的模塑制品和该树脂组合物的制造方法; 树脂组合物包含具有对苯二甲酸丁二醇酯骨架作为主要构成单元的芳族聚酯（组分A）和熔点为190℃或更高的聚乳酸（组分B）。

3. 发明申请

US20100222486A1 AROMATIC POLYCARBONATE RESIN COMPOSITION 审中-公开
标题翻译：芳香聚碳酸酯树脂组合物
公开(公告)号：US20100222486A1
公开(公告)日：2010-09-02
申请号：US12734196
申请日：2008-10-15
申请人： Yuichi Matsuno , Fumitaka Kondo , Kiyotsuna Toyohara
发明人： Yuichi Matsuno , Fumitaka Kondo , Kiyotsuna Toyohara
IPC分类号： C08K3/34 , C08L69/00
CPC分类号： C08L67/04 , C08K3/34 , C08K5/29 , C08K5/521 , C08L69/00
摘要： The object of this invention is to provide a resin composition that contains a polymer obtained from biomass resources and constitutes molded articles excellent in heat resistance, mechanical properties and durable stability, this invention including a resin composition comprising (i) a resin component containing 95 to 5% by weight of an aromatic polycarbonate (component A) and 5 to 95% by weight of polylactic acid (component B), (ii) 0.001 to 10 parts by weight, per 100 parts by weight of the resin component, of a phosphoric ester metal salt (component C), and (iii) 0.01 to 5 parts by weight, per 100 parts by weight of the polylactic acid (component B), of a terminal blocker (component F), the stereo-complex crystal content (X) of the following expression (I) being 80% or more, X (%)={ΔHb/(ΔHa+ΔHb)}×100 (I) wherein ΔHa and ΔHb are a melting enthalpy (ΔHa) of a crystal melting point that appears at lower than 190° C. and a melting enthalpy (ΔHb) of a crystal melting point that appears at 190° C. or higher but less than 250° C., respectively, in a temperature-elevation process by a differential scanning calorimeter (DSC), and molded articles thereof.
摘要翻译：本发明的目的是提供一种含有由生物质资源获得的聚合物的树脂组合物，并且构成耐热性，机械性能和耐久稳定性优异的成型体，本发明包括树脂组合物，其包含（i）含有95〜 5重量％的芳族聚碳酸酯（组分A）和5至95重量％的聚乳酸（组分B），（ii）每100重量份树脂组分0.001至10重量份的磷酸酯组分C）和（iii）每100重量份聚乳酸（组分B），末端阻断剂（组分F），立体络合物结晶含量（X）为0.01〜5重量份（I）为80％以上，X（％）= {＆Dgr; Hb /（＆Dgr; Ha +＆Dgr; Hb）}×100（I）其中＆Dgr; Ha和＆Dgr; Hb为熔融焓（＆Dgr; Ha）的晶体熔点低于190℃，熔融焓（＆Dgr; Hb）为通过差示扫描量热计（DSC）在升温过程中分别出现在190℃以上但小于250℃的晶体熔点，以及其成型体。

4. 发明申请

US20110092623A1 FLAME RETARDANT RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 审中-公开
标题翻译：阻燃树脂组合物及其制品
公开(公告)号：US20110092623A1
公开(公告)日：2011-04-21
申请号：US12994791
申请日：2009-05-26
申请人： Katsuhiro Yamanaka , Fumitaka Kondo , Kiyotsuna Toyohara
发明人： Katsuhiro Yamanaka , Fumitaka Kondo , Kiyotsuna Toyohara
IPC分类号： C08K5/5357
CPC分类号： C08K5/5357 , C07F9/657181 , C08L67/04
摘要： A flame retardant resin composition which has high flame retardancy and excellent physical properties and comprises a resin obtained from a plant-derived raw material and a molded article thereof.The flame retardant resin composition comprises: (A) 100 parts by weight of a resin component (component A) which contains at least 50 wt % of a resin (component A-1) obtained from a plant-derived raw material; and (B) 1 to 100 parts by weight of an organic phosphorus compound (component B) represented by the following formula (1). (in the above formula, X1 and X2 are the same or different and each an aromatic substituted alkyl group represented by the following formula (2): ALAr)n (2) in the above formula, AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar is a phenyl group which may have a substituent, naphthyl group which may have a substituent or anthryl group which may have a substituent, n is an integer of 1 to 3, and Ar may be bonded to any carbon atom contained in AL.)
摘要翻译：阻燃性树脂组合物，其具有高阻燃性和优异的物理性质，并且含有由植物来源的原料得到的树脂及其成型体。阻燃树脂组合物包含：（A）100重量份含有至少50重量％由植物来源的原料得到的树脂（A-1成分）的树脂成分（A成分）和（B）1〜100重量份由下式（1）表示的有机磷化合物（B成分）。（在上式中，X1和X2相同或不同，并且每个由下式（2）表示的芳族取代的烷基：上式中的n（2）中，AL是支链或具有1至5个碳原子的直链脂族烃基，Ar是可以具有取代基的苯基，可以具有取代基的萘基或可以具有取代基的蒽基，n是1〜3的整数，Ar可以结合到AL中包含的任何碳原子上。）

5. 发明申请

US20110263762A1 POLYLACTIC ACID COMPOSITION AND MOLDED ARTICLE THEREOF 审中-公开
标题翻译：聚乳酸组合物及其成型品
公开(公告)号：US20110263762A1
公开(公告)日：2011-10-27
申请号：US13127661
申请日：2009-11-02
申请人： Yuichi Matsuno , Masaki Mitsunaga , Jitsuo Oda , Mitsuru Doteguchi , Yoshitaka Shibata , Kiyotsuna Toyohara , Masahiro Iwai , Takuro Kitamura
发明人： Yuichi Matsuno , Masaki Mitsunaga , Jitsuo Oda , Mitsuru Doteguchi , Yoshitaka Shibata , Kiyotsuna Toyohara , Masahiro Iwai , Takuro Kitamura
IPC分类号： C08K5/5317 , C08K5/35 , C08K5/1515
CPC分类号： C08L67/04 , C08K5/0091 , C08K5/13 , C08K5/372 , C08K5/524 , C08K5/527 , C08K5/5333 , C08K5/5393 , C08K5/5399 , C08L2666/02
摘要： A composition comprising polylactic acid and having excellent heat stability, especially moist heat stability, and a molded article thereof.The composition comprises 100 parts by weight of a resin component (component A) which is composed of 5 to 100 wt % of polylactic acid (component A-α) and 95 to 0 wt % of a thermoplastic resin (component A-β), 0.001 to 5 parts by weight of a phosphono-fatty acid ester (component B), 0.01 to 5 parts by weight of a phosphate metal salt (component C), 0.001 to 2 parts by weight of at least one antioxidant (component D) selected from the group consisting of a phosphite-based compound, a phosphonite-based compound, a hindered phenol-based compound and a thioether-based compound, and 0.001 to 10 parts by weight of an end-sealing agent (component E).
摘要翻译：包含聚乳酸并且具有优异的热稳定性，特别是湿热稳定性的组合物及其模塑制品。该组合物包含100重量份由5〜100重量％的聚乳酸（A-α成分）和95〜0重量％的热塑性树脂（成分A-＆bgr）组成的树脂成分（A成分），0.001〜5重量份膦酰基脂肪酸酯（B成分），0.01〜5重量份磷酸盐金属盐（C成分），0.001〜2重量份的至少一种抗氧化剂（D成分）选自亚磷酸酯类化合物，亚膦酸酯系化合物，受阻酚系化合物和硫醚系化合物，0.001〜10重量份的端部密封剂（E成分）。

6. 发明授权

US08575302B2 Polylactide composition 失效
标题翻译：聚丙交酯组合物
公开(公告)号：US08575302B2
公开(公告)日：2013-11-05
申请号：US12089322
申请日：2006-10-04
申请人： Hirotaka Suzuki , Kiyotsuna Toyohara , Shin To
发明人： Hirotaka Suzuki , Kiyotsuna Toyohara , Shin To
IPC分类号： C08G63/08 , C08G63/82 , C08L67/04 , C08L101/16 , C08K3/32
CPC分类号： C08L67/04 , C08K3/30 , C08K5/098 , C08L2205/02 , C08L2666/18
摘要： A composition which comprises polylactide and has excellent heat stability, color and hydrolytic resistance. The composition comprises (i) polylactide, (ii) a metal catalyst and (iii) a hypophosphorous acid-based deactivator or a metaphosphoric acid-based deactivator.
摘要翻译：包含聚丙交酯并具有优异的热稳定性，颜色和耐水解性的组合物。组合物包含（i）聚丙交酯，（ii）金属催化剂和（iii）次磷酸基失活剂或基于偏磷酸的失活剂。

7. 发明申请

US20100160597A1 MANUFACTURING APPARATUS OF POLYLACTIC ACID AND MANUFACTURING METHOD OF POLYLACTIC ACID 审中-公开
标题翻译：聚酸酸的制备装置及其制备方法
公开(公告)号：US20100160597A1
公开(公告)日：2010-06-24
申请号：US12161098
申请日：2007-01-15
申请人： Hideshi Kurihara , Takeshi Katsuda , Kiyotsuna Toyohara , Ryuji Nonokawa , Hirotaka Suzuki , Kenji Ohashi
发明人： Hideshi Kurihara , Takeshi Katsuda , Kiyotsuna Toyohara , Ryuji Nonokawa , Hirotaka Suzuki , Kenji Ohashi
IPC分类号： C08G63/06 , B01J19/18 , C08G63/08
CPC分类号： C08G63/08 , B01J19/006 , B01J19/0066 , B01J19/1887 , B01J19/20 , B01J2219/00085 , B01J2219/00094 , B01J2219/00135 , B01J2219/00779 , B01J2219/182 , B01J2219/1943 , C08G63/785
摘要： A manufacturing apparatus of polylactic acid having at least an inlet and an outlet of a substance to be reacted and an exhaust port provided in a horizontal reaction vessel not having continuous rotating shafts in a direction of center line of a rotating shaft of a stirring blade provided in the reaction vessel and a manufacture method. By removing low molecular weight substance in the polylactic acid, high-quality polylactic acid can be stably manufactured.
摘要翻译：具有至少具有待反应物质的入口和出口的聚乳酸的制造装置和设置在不具有连续的旋转轴的水平反应容器中的排气口，该搅拌叶片设置在搅拌叶片的旋转轴的中心线方向上在反应容器中和制造方法。通过除去聚乳酸中的低分子量物质，可以稳定地制造高品质的聚乳酸。

8. 发明授权

US08263690B2 Polylactic acid composition 有权
标题翻译：聚乳酸组成
公开(公告)号：US08263690B2
公开(公告)日：2012-09-11
申请号：US12294549
申请日：2007-03-28
申请人： Hirotaka Suzuki , Kiyotsuna Toyohara , Yuka Komazawa
发明人： Hirotaka Suzuki , Kiyotsuna Toyohara , Yuka Komazawa
IPC分类号： C07F9/40
CPC分类号： C08K5/0091 , C08J3/005 , C08J2367/04 , C08K5/5333 , C08L67/04 , C08L2205/02 , C08L2666/18
摘要： It is an object of the present invention to provide a composition which contains polylactic acid and has excellent heat stability, mechanical strength and color. The composition contains 0.001 to 0.1 part by weight of a metal catalyst and 0.001 to 0.5 part by weight of a phosphono-fatty acid ester based on 100 parts by weight of polylactic acid.
摘要翻译：本发明的目的是提供含有聚乳酸并且具有优异的热稳定性，机械强度和颜色的组合物。基于100重量份的聚乳酸，该组合物含有0.001〜0.1重量份的金属催化剂和0.001〜0.5重量份的膦酰基脂肪酸酯。

9. 发明申请

US20090062437A1 POLYLACTIC ACID COMPOSITION 有权
标题翻译：聚乳酸组合物
公开(公告)号：US20090062437A1
公开(公告)日：2009-03-05
申请号：US12294549
申请日：2007-03-28
申请人： Hirotaka Suzuki , Kiyotsuna Toyohara , Yuka Komazawa
发明人： Hirotaka Suzuki , Kiyotsuna Toyohara , Yuka Komazawa
IPC分类号： C08K5/5333
CPC分类号： C08K5/0091 , C08J3/005 , C08J2367/04 , C08K5/5333 , C08L67/04 , C08L2205/02 , C08L2666/18
摘要： It is an object of the present invention to provide a composition which contains polylactic acid and has excellent heat stability, mechanical strength and color.The composition contains 0.001 to 0.1 part by weight of a metal catalyst and 0.001 to 0.5 part by weight of a phosphono-fatty acid ester based on 100 parts by weight of polylactic acid.
摘要翻译：本发明的目的是提供含有聚乳酸并且具有优异的热稳定性，机械强度和颜色的组合物。基于100重量份的聚乳酸，该组合物含有0.001〜0.1重量份的金属催化剂和0.001〜0.5重量份的膦酰基脂肪酸酯。

10. 发明申请

US20090234094A1 POLYLACTIDE COMPOSITION 失效
标题翻译：聚酯组合物
公开(公告)号：US20090234094A1
公开(公告)日：2009-09-17
申请号：US12089322
申请日：2006-10-04
申请人： Hirotaka Suzuki , Kiyotsuna Toyohara , Shin To
发明人： Hirotaka Suzuki , Kiyotsuna Toyohara , Shin To
IPC分类号： C08G63/08
CPC分类号： C08L67/04 , C08K3/30 , C08K5/098 , C08L2205/02 , C08L2666/18
摘要： A composition which comprises polylactide and has excellent heat stability, color and hydrolytic resistance. The composition comprises (i) polylactide, (ii) a metal catalyst and (iii) a hypophosphorous acid-based deactivator or a metaphosphoric acid-based deactivator.
摘要翻译：包含聚丙交酯并具有优异的热稳定性，颜色和耐水解性的组合物。组合物包含（i）聚丙交酯，（ii）金属催化剂和（iii）次磷酸基失活剂或基于偏磷酸的失活剂。

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