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    • 2. 发明专利
    • Method for producing co absorbing/desorbing agent
    • 生产吸收/脱硫剂的方法
    • JP2010269264A
    • 2010-12-02
    • JP2009124049
    • 2009-05-22
    • Kansai Coke & Chem Co LtdKobe Steel Ltd株式会社神戸製鋼所関西熱化学株式会社
    • NAKANISHI ATSUHIKOYASUMARU JUNICHITAKEUCHI MASAMIMIURA SHINICHIYAMASHITA TAKESHI
    • B01J20/02C01B32/40
    • PROBLEM TO BE SOLVED: To provide an absorbing/desorbing agent having excellent CO absorbing/desorbing performance which can efficiently separate/recover high purity CO from a mixed gas containing CO.
      SOLUTION: In a method for producing the CO absorbing/desorbing agent in which, after a porous carrier and a solution or a dispersion in which a copper (II) compound and a reducing agent are dissolved or dispersed in a solvent are brought into contact, the solvent is removed, a treatment to make the porous carrier be impregnated with an inorganic acid is carried out, and next, contact with the solution or the dispersion in which the copper (II) compound and the reducing agent are dissolved or dispersed in the solvent is carried out, or after the inorganic acid is made contained in the solvent or the dispersion, the carrier is contacted with the solution or the dispersion.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种具有优异的CO吸收/解吸性能的吸收/解吸剂,其能够从含有CO的混合气体中有效地分离/回收高纯度CO。解决方案:在生产CO的方法中 在将多孔载体和其中溶解或分散有铜(II)化合物和还原剂的溶液或分散体溶解或分散在溶剂中的吸附/解吸剂接触后,除去溶剂,进行处理 进行无机酸浸渍的多孔载体,然后与溶解或溶解或分散有铜(II)化合物和还原剂的溶液或分散体进行接触,或者在无机酸 将酸包含在溶剂或分散体中,使载体与溶液或分散体接触。 版权所有(C)2011,JPO&INPIT
    • 6. 发明专利
    • 水素製造装置の停止方法及び水素製造装置
    • 氢生产装置​​停止方法和氢生产装置
    • JP2014234322A
    • 2014-12-15
    • JP2013115731
    • 2013-05-31
    • 株式会社神戸製鋼所Kobe Steel Ltd
    • TANIGUCHI YUKINOBUFUJISAWA AKITOSHITOMEKAWA SHUHEIMIURA SHINICHI
    • C01B3/38C01B3/02C01B3/48C01B3/56
    • 【課題】改質器内の触媒の劣化を防止しつつ、装置が完全に停止するまでの時間を短縮化でき、かつ装置を小型化できる水素製造装置の停止方法及び水素製造装置を提供することを目的とする。【解決手段】本発明は、炭化水素含有原料ガスの水蒸気改質により水素及び一酸化炭素を含む改質ガスを生成する改質部と、この改質ガスのCO変成により水素リッチな変成ガスを排出する変成部とを有する改質器を備える水素製造装置の停止方法であって、上記水素製造装置が水電解装置をさらに備え、改質器への原料ガス及び水蒸気の供給を停止すると共に、水電解装置で発生した水素ガスにより上記改質器内をパージすることを特徴とする。また、別の本発明は、水素リッチな変成ガスを排出する改質器と、水電解装置と、改質器への原料ガス及び水蒸気の供給を停止すると共に、水電解装置で発生した水素ガスにより改質器内をパージする制御手段とを備える水素製造装置である。【選択図】図1
    • 要解决的问题:提供一种氢气制备装置停止方法和氢气制备装置,其可以缩短完全停止装置所需的时间,同时防止重整器中催化剂的劣化,并且可以减小尺寸的装置。 本发明提供一种氢气制备装置的停止方法,该制氢装置包括:重整器,具有通过含烃进料气体的蒸汽改性产生含有氢和一氧化碳的改性气体的改性部分,以及用于排出富氢转化气体的转化部分 通过改性气体的CO转化,其特征在于,氢气制造装置还包括水电解单元,并且停止向改性剂供应进料气体和蒸汽,并且改性剂的内部被氢气 在水电解单元中产生。 本发明还提供了一种氢气制备装置,其包括用于排出富氢转化气体的改性剂,水电解单元,以及用于停止供给气体和蒸汽供给至修饰剂以及用于清洗改性剂内部的控制装置 在水电解单元中产生的氢气。
    • 7. 发明专利
    • Hydrogen storage/release apparatus
    • 氢储存/释放装置
    • JP2014080329A
    • 2014-05-08
    • JP2012229336
    • 2012-10-16
    • Kobe Steel Ltd株式会社神戸製鋼所
    • FUJISAWA AKITOSHIMIURA SHINICHITOMEKAWA SHUHEITANIGUCHI YUKINOBU
    • C01B3/00C01B3/56F17C11/00H01M8/04H01M8/10
    • Y02P90/45
    • PROBLEM TO BE SOLVED: To provide a hydrogen storage/release apparatus capable of mitigating the compaction and consolidation of a hydrogen storage alloy due to the expansion/contraction thereof, of simultaneously extending flow channels of a hydrogen-containing gas within a hydrogen storage alloy-filled layer while inhibiting short-circuited paths of the hydrogen-containing gas, of accelerating the conduction of heat to the filler, and, as a result, of significantly improving hydrogen storage/purification efficiencies.SOLUTION: A hydrogen storage/release apparatus 1 includes: a cylindrical tank 2 having, on one terminal side thereof, a hydrogen-containing gas supply port 6 and, on the other terminal side thereof, an off-gas discharge port 7; a filler 5 filled into this tank 2 and including a hydrogen storage alloy; and temperature control means 4 for heating and cooling the filler 5; and possesses fins 3 configured to abut from the inner plane of the tank 2 so as to regulate the gas in a zigzag or spiral circulatory pattern in relation to the axial direction thereof.
    • 要解决的问题:提供一种能够减轻由于其膨胀/收缩而导致的储氢合金的压实和固结的氢存储/释放装置,同时延长储氢合金中的含氢气体的流动通道, 同时抑制含氢气体的短路路径,加速向填料的热传递,结果显着提高储氢/净化效率。解决方案:氢储存/释放装置1包括 :一个圆筒形容器2,其一个端部侧具有含氢气体供给口6,另一个端子侧具有排气口7; 填充到该罐2中并包含储氢合金的填料5; 以及用于加热和冷却填料5的温度控制装置4; 并且具有构造成从罐2的内平面邻接的翅片3,以相对于其轴向以曲折或螺旋形循环图案调节气体。
    • 8. 发明专利
    • Activation method of autothermal reformer and autothermal reforming system
    • 自动翻新机和自动翻新系统的激活方法
    • JP2014040364A
    • 2014-03-06
    • JP2013152120
    • 2013-07-22
    • Kobe Steel Ltd株式会社神戸製鋼所
    • TANIGUCHI YUKINOBUFUJISAWA AKITOSHITOMEKAWA SHUHEIMIURA SHINICHI
    • C01B3/38C25B1/04
    • Y02E60/366
    • PROBLEM TO BE SOLVED: To provide an activation method of an autothermal reformer and an autothermal reforming system in which, even when a capacity of an oxidation reforming part is large, efficient temperature rising can be performed and start time can be shorten.SOLUTION: Provided is an activation method of an autothermal reformer that includes an oxidation reforming part including an oxidation and reforming catalyst. In the oxidation reforming part, a part of a hydrocarbon included in a mixed gas of the hydrocarbon and moisture vapor is burned, and moisture vapor reforming reaction of the hydrocarbon is performed by the burning heat. The activation method includes (A) process in which a hydrogen inclusion gas and an oxygen inclusion gas are supplied into the oxidation reforming part so as to burn the hydrogen. The activation method further includes (B) process in which the hydrogen inclusion gas is generated using an autothermal reformer for activation that has a smaller size than that of the autothermal reformer, or (C) process in which the hydrogen inclusion gas is generated using a water electrolytic apparatus. The hydrogen inclusion gas generated in the (C) process is preferably used as the hydrogen inclusion gas for the (A) process.
    • 要解决的问题:为了提供自热重整器和自热重整系统的激活方法,其中即使氧化重整部分的容量大,可以实现有效的升温,并且可以缩短开始时间。解决方案:提供 是一种自热重整器的活化方法,其包括包含氧化和重整催化剂的氧化重整部分。 在氧化重整部分中,燃烧包含在烃和水蒸气的混合气体中的烃的一部分,并且通过燃烧热进行烃的水蒸气重整反应。 活化方法包括(A)将氢气夹杂物和氧气夹杂物气体供给至氧化重整部分以使其燃烧的工序。 活化方法还包括(B)使用具有比自热重整器的尺寸小的激活的自热重整器产生氢气夹杂气体的方法,或者(C)使用 水电解设备。 在(C)工序中产生的氢气夹杂气优选用作(A)工艺的氢气夹杂气体。
    • 10. 发明专利
    • High purity hydrogen production apparatus
    • 高纯度氢生产设备
    • JP2010143778A
    • 2010-07-01
    • JP2008321248
    • 2008-12-17
    • Kobe Steel Ltd株式会社神戸製鋼所
    • NAKAO NOBORUMIURA SHINICHIFUJISAWA AKITOSHIYAMASHITA TAKESHI
    • C01B3/38C01B3/56
    • PROBLEM TO BE SOLVED: To provide a high purity hydrogen production apparatus capable of collecting high purity hydrogen gas at a higher recovery rate from a reformed gas which is produced by a reforming process such as the autothermal reforming method and contains CO, CH
      4 , H
      2 O and CO
      2 as impurity components, and contributing to miniaturize the equipment more, i.e. to reduce the equipment cost.
      SOLUTION: In the high purity hydrogen production apparatus equipped with an autothermal type reformer 1 which produces a reformed gas B by reforming a raw material for reformation A and a PSA (Pressure Swing Adsorption) apparatus (composed of adsorption towers 2a, 2b, 2c of 3 towers) which produces high purity hydrogen C by refining the reformed gas B by adsorbing and removing unnecessary gases from it, hydrogen gas D produced by a water electrolysis apparatus 4 is used as hydrogen gas used for the washing process and/or the pressure rising process of the PSA apparatus. Moreover, oxygen gas E coproduced by the water electrolysis apparatus 4 may be used as oxygen gas for reforming of the reformer 1.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种能够从通过自热重整法等重整工序制造的重整气体以更高的回收率收集高纯度氢气的高纯度氢气生产装置,并且含有CO,CH 4 ,H 2 O和CO 2 作为杂质成分,有助于使设备小型化,即降低设备成本。 解决方案:在具有自热型重整器1的高纯度氢气制备装置中,其通过重整用于改造原料A的原料和PSA(压力摆动吸附)装置(由吸附塔2a,2b组成)产生重整气体B ,3塔3),其通过从其中吸附除去不需要的气体来精炼重整气体B而产生高纯度氢气,由水电解装置4产生的氢气D用作用于洗涤过程的氢气和/或 PSA装置的升压过程。 此外,由水电解装置4共同生成的氧气E可以用作重整器1的重整用氧气。版权所有(C)2010,JPO&INPIT