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    • 2. 发明申请
    • LITHOGRAPHIC METHOD
    • 光刻方法
    • WO2007029177A1
    • 2007-03-15
    • PCT/IB2006/053117
    • 2006-09-05
    • KONINKLIJKE PHILIPS ELECTRONICS N.V.ZANDBERGEN, PeterLAMMERS, Jeroen, H.VAN STEENWINCKEL, David
    • ZANDBERGEN, PeterLAMMERS, Jeroen, H.VAN STEENWINCKEL, David
    • G03F7/039G03F7/038
    • G03F7/0392G03F7/0382
    • The present invention provides a method of lithographic patterning. The method comprisese: applying to a surface to be patterned a photoresist (18) comprising a polymer resin, a photocatalyst generator which generates a catalyst on exposure to actinic radiation, and a quencher; exposing the photoresist (18) to actinic radiation through a mask pattern (12); carrying out a post-exposure bake; and then developing the photoresist (18) with a developer to remove a portion of the photoresist which has been rendered soluble in the developer. Either the polymer resin is substantially insoluble in the developer prior to exposure to actinic radiation and rendered soluble in the developer by the action of the catalyst, and by the action of the quencher during the bake, or the polymer resin is soluble in the developer prior to exposure to actinic radiation and rendered substantially insoluble in the developer by the action of the catalyst, and by the action of the quencher during the bake.
    • 本发明提供一种平版印刷图案化方法。 该方法包括:施加到待图案化的表面上,包含聚合物树脂的光致抗蚀剂(18),在曝光于光化辐射下产生催化剂的光催化剂产生剂和淬灭剂; 通过掩模图案(12)将光致抗蚀剂(18)暴露于光化辐射; 进行曝光后烘烤; 然后用显影剂显影光致抗蚀剂(18)以除去已经溶解在显影剂中的一部分光致抗蚀剂。 聚合物树脂在暴露于光化辐射之前基本上不溶于显影剂,并且通过催化剂的作用以及在烘烤期间通过猝灭剂的作用使其溶解在显影剂中,或者聚合物树脂可溶于显影剂前 暴露于光化辐射并且通过催化剂的作用基本上不溶于显影剂,并且通过在烘烤期间猝灭剂的作用。
    • 3. 发明申请
    • LITHOGRAPHIC METHOD
    • 光刻方法
    • WO2007029176A1
    • 2007-03-15
    • PCT/IB2006/053116
    • 2006-09-05
    • KONINKLIJKE PHILIPS ELECTRONICS N.V.ZANDBERGEN, PeterLAMMERS, Jeroen, H.VAN STEENWINCKEL, David
    • ZANDBERGEN, PeterLAMMERS, Jeroen, H.VAN STEENWINCKEL, David
    • G03F7/039
    • G03F7/0392
    • The present invention provides a method of lithographic patterning in order to the strength of the patterned photoresist. The method comprises: applying to a surface to be patterned a photoresist (18) comprising a polymer resin, a photocatalyst generator which generates a catalyst on exposure to actinic radiation, and a quencher; and exposing the photoresist (18) to actinic radiation through a mask pattern (12). This is followed, in either order, by carrying out a post-exposure bake; and developing the photoresist (18) with a developer to remove a portion of the photoresist which has been exposed to the actinic radiation. The polymer resin is substantially insoluble in the developer prior to exposure to actinic radiation and rendered soluble in the developer by the action of the catalyst, and wherein the polymer resin is crosslinked by the action of the quencher during the bake.
    • 本发明提供了一种平版印刷图案化方法,以便图案化光致抗蚀剂的强度。 该方法包括:向待图案化的表面施加包含聚合物树脂的光致抗蚀剂(18),在曝光于光化辐射时产生催化剂的光催化剂产生剂和猝灭剂; 以及通过掩模图案(12)将光致抗蚀剂(18)暴露于光化辐射。 接下来,按照任何顺序,通过进行曝光后烘烤; 以及用显影剂显影所述光致抗蚀剂(18)以去除已经暴露于所述光化辐射的光致抗蚀剂的一部分。 聚合物树脂在暴露于光化辐射之前基本上不溶于显影剂,并通过催化剂的作用使其溶解在显影剂中,并且其中聚合物树脂在烘烤期间通过猝灭剂的作用而交联。
    • 4. 发明申请
    • LITHOGRAPHIC METHOD
    • 光刻方法
    • WO2006056905A2
    • 2006-06-01
    • PCT/IB2005/053700
    • 2005-11-10
    • KONINKLIJKE PHILIPS ELECTRONICS N.V.VAN STEENWINCKEL, DavidZANDBERGEN, Peter
    • VAN STEENWINCKEL, DavidZANDBERGEN, Peter
    • G03F7/30G03F7/095G03F7/32
    • A method of achieving frequency doubled lithographic patterning is described. An optical pattern (16) having a first period (p 1 ) is used to expose conventional acid-catalysed photoresist (18) on substrate (20), leaving regions of high exposure (24), regions of low exposure (26) and intermediate regions (22). Processing proceeds leaving regions (24) which received high exposure very polar, i.e. hydrophilic, regions (26) of low exposure very apolar, i.e. hydrophobic, and the intermediate regions having intermediate polarity. A developer of intermediate polarity such as propylene glycol methyl ether acetate is then used to dissolve only the intermediate regions (22) leaving photoresist patterned to have a pitch (p 2 ) half that of the optical period (p 1 ). Alternatively, the photoresist is removed from the apolar and polar regions leaving only the intermediate regions (22) again with the same pitch (p 2 ) half that of the optical period (p 1 ).
    • 描述了实现倍频光刻图案的方法。 使用具有第一周期(p <1> 1)的光学图案(16)来曝光基底(20)上的常规酸催化的光致抗蚀剂(18),留下高曝光区域(24) 低曝光(26)和中间区域(22)。 处理进行离开区域(24),其接收高暴露非常极性,即亲水性低暴露非极性(即疏水性)的区域(26),并且具有中等极性的中间区域。 然后使用中等极性的显影剂如丙二醇甲基醚乙酸酯仅溶解中间区域(22),留下光刻胶图案化以具有光学周期(p)的一半的间距(p <2> 2) 1 )。 或者,光致抗蚀剂从非极性区域和极性区域移除,仅再次以中间区域(22)的光学周期(p 1 )。
    • 8. 发明公开
    • REMOVABLE PELLICLE FOR IMMERSION LITHOGRAPHY
    • BESTRAHLUNGSVERFAHREN
    • EP1700164A2
    • 2006-09-13
    • EP04806612.0
    • 2004-12-22
    • Koninklijke Philips Electronics N.V.
    • DIRKSEN, PeterMORTON, Robert, D.ZANDBERGEN, PeterVAN STEENWINCKEL, DavidAKSENOV, YuriLAMMERS, Jeroen, H.VAN WINGERDEN, JohannesMARINIER, Laurent
    • G03F7/20
    • G03F7/70341G03F7/70983
    • A method of irradiating to pattern a photosensitive layer such as a resist (L2) immersed in a fluid (L3), involves applying a removable transparent layer (L4, L5), projecting the radiation onto the resist through the immersion fluid and through the transparent layer, such that imperfections in the fluid are out of focus as projected on the surface, and subsequently removing the transparent layer. The transparent layer can help distance such imperfections from the focus of the radiation on the surface and so can reduce or eliminate shadowing. Hence the irradiation can be more complete, and defects reduced. It can be particularly effective for imperfections in the form of small bubbles or particles in the immersion fluid especially at the fluid/surface interface for example. The radiation can be for any purpose including inspection, processing, patterning and so on. The removal of the transparent layer can be combined with a step of developing the resist layer.
    • 一种照射方法来照射浸入流体(L3)中的抗蚀剂(L2)的感光层,包括施加可去除的透明层(L4,L5),通过浸没流体将辐射投射到抗蚀剂上,并通过透明 使得流体中的缺陷如投射在表面上而失焦,然后移除透明层。 透明层可以帮助将这种缺陷与辐射在表面上的焦点相距离,因此可以减少或消除阴影。 因此,照射可以更完整,并且缺陷减少。 特别是在浸液中的小气泡或颗粒形式的缺陷,特别是在流体/表面界面处的缺陷可能特别有效。 辐射可以用于任何目的,包括检查,加工,图案化等。 可以将透明层的去除与显影抗蚀剂层的步骤组合。