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    • 3. 发明专利
    • AUTOMATIC PRODUCTION OF OXIDE CRYSTAL AND DEVICE THEREFOR
    • JPH101389A
    • 1998-01-06
    • JP15703096
    • 1996-06-18
    • KOKUSAI CHODENDO SANGYO GIJUTSISHIKAWAJIMA HARIMA HEAVY IND
    • EGAMI MASAHIROSHIOBARA TORU
    • C30B15/02C30B29/22C30B35/00
    • PROBLEM TO BE SOLVED: To provide the production method for performing a pulling-up production process of an oxide crystal or oxide superconductor crystal with automatic control and also to provide the device for the production. SOLUTION: In this production, at the time of performing the crystal growth of an oxide crystal, the composition for replenishing a liquid phase 3 with constituent elements of the oxide crystal includes the composition of a solid phase 2 that is located apart from the position where the oxide crystal is to be grown and has a different composition from that of the oxide crystal, and at least consists of the oxide crystal constituent elements and also, the liquid phase 2 having a different composition from that of the oxide crystal is used and accordingly, the oxide crystal having a composition different from those of the solid phase 2 and liquid phase 3 is grown. That is, this production comprises: using as the composition for replenishing a liquid phase 3 with constituent elements of an oxide crystal, a composition that includes the composition of a solid phase 2 which is located apart from the position where the oxide crystal is to be grown and has a composition different from that of the oxide crystal, and at least consists of the oxide crystal constituent elements; using the liquid phase 3 having a composition different from that of the oxide crystal; automatically controlling each of a seed crystal 5, the rotational speed and rotational direction of the seed crystal and the atmosphere inside a furnace; and growing the oxide crystal having a composition different from those of the solid phase 2 and liquid phase 3.
    • 4. 发明专利
    • PREPARATION OF OXIDE CRYSTAL
    • JPH09100193A
    • 1997-04-15
    • JP26047195
    • 1995-10-06
    • SUMITOMO ELECTRIC INDUSTRIESKOKUSAI CHODENDO SANGYO GIJUTSISHIKAWAJIMA HARIMA HEAVY IND
    • YAO SHINNAMIKAWA YASUOEGAMI MASAHIROSHIOBARA TORU
    • C01G1/00C01G3/00C30B15/00C30B29/22
    • PROBLEM TO BE SOLVED: To increase the crystal growth rate and prepare a large-sized oxide crystal of good quality in relation to a method for preparing the crystal for an oxide superconductor of a Y-based or a lanthanoid-based element by keeping the atmosphere for growing the oxide crystal under a higher pressure than oxygen partial pressure in the atmospheric air. SOLUTION: The atmosphere for growing an oxide crystal having a structure of R1+x Ba2-x Cu3 O7-z [R is Y or a lanthanoid-based element; 0 =0.8atm partial oxygen pressure. A crystal of Y123 (YBa2 Cu3 O7-x ) is prepared by using an apparatus in the figure. Y2 BaCuO5 is placed in the lower part of a crucible 6 made of a sintered compact of Y2 O3 . Barium carbonate is mixed with copper oxide so as to afford 3:5 molar ratio of Ba to Cu and the resultant mixture is then calcined to provide a substance, which is placed in the upper part of the crucible and used as a raw material for a melt 4. Supporting columns 7 made of an MgO single crystal are stood in a dish 8 made of Al2 O3 and Ag 9 is placed therein. The crucible 6 is then placed on the dish 8. Oxygen is introduced from an introduction port 14 is regulate the oxygen concentration at >=95%. The interior of an airtight chamber 13 is heated at >=1020 deg.C with a heater 11 to carry out the crystal growth while rotating the seed crystal 2.