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    • 3. 发明授权
    • High-strength beryllium-free moulded body made from zirconium alloys which may be plastically deformed at room temperature
    • 由锆合金制成的高强度无铍成型体,其可在室温下塑性变形
    • US07300529B2
    • 2007-11-27
    • US10487383
    • 2002-08-12
    • Uta KuehnJuergen EckertLudwig Schultz
    • Uta KuehnJuergen EckertLudwig Schultz
    • C22C45/10
    • C22C45/10
    • High-strength, beryllium-free moulded bodies made from zirconium alloys which may be plastically deformed comprise a material essentially corresponding to the following formula in composition: Zra(E1)b(E2)c(E3)d(E4)e, where E1=one or several of Nb, Ta, Mo, Cr, W, Ti, V, Hf and Y, E2=one or several of Cu, Au, Ag, Pd and Pt, E3=one or several of Ni, Co, Fe, Zn and Mn, E4=one or several of AI, Ga, Si, P, C, B, Sn, Pb and Sb, a=100−(b+c+d+e), b=5 to 15, c=5 to 15, d=0 to 15 and e=5 to 15 (a, b, c, d, e in atom %). The moulded body essentially comprises a homogeneous, microstructural structure which is a glass-like or nano-crystalline matrix with a ductile, dendritic, cubic body-centered phase embedded therein.
    • 由塑性变形的锆合金制成的高强度,不含铍的成型体包括基本上对应于组成中的下列公式的材料:Zr a(E1)b < (E2)C(E3)D(E4)e,其中E1 = Nb,Ta,Mo,Cr,W中的一种或几种 ,Ti,V,Hf和Y,E2 = Cu,Au,Ag,Pd和Pt中的一种或几种,E3 = Ni,Co,Fe,Zn和Mn中的一种或几种,E4 = Al,Ga中的一种或几种 ,Si,P,C,B,Sn,Pb和Sb,a = 100-(b + c + d + e),b = 5〜15,c = 5〜15,d = 0〜15,e = 5 至15(a,b,c,d,e原子%)。 成型体基本上包括均匀的微结构结构,其是嵌入其中的延展性,树枝状,立体体中心相的玻璃状或纳米晶体基体。
    • 4. 发明授权
    • Process for the Production of low TC superconductor molded bodies
    • 低温超导体成型体的生产工艺
    • US6066270A
    • 2000-05-23
    • US234040
    • 1999-01-19
    • Juergen EckertKathrin JostOliver De HaasMichael SeidelLudwig Schultz
    • Juergen EckertKathrin JostOliver De HaasMichael SeidelLudwig Schultz
    • C04B35/563C01G1/00C01G3/00C04B35/45C04B35/56C04B35/58C04B35/583H01L39/12H01L39/24H01B1/02
    • C04B35/583C04B35/56C04B35/563C04B35/645C04B35/6455H01L39/125H01L39/24Y10S420/901Y10S505/805
    • The production of compact molded bodies of rare-earth transition-metal boron carbide and boron nitride compounds configured so as to avoid a selective evaporation of individual components in the production process and enable an exact adjustment of the desired stoichiometry. The process is characterized in thata) a powder mixture with particles sizes from 1 to 250 .mu.m is produced, containingaa) at least one element from the group comprising Y, La, Ho, Dy, Er, Tm, Lu, Sc,ab) at least one element from the group comprising Ni, Cu, Co, Fe, Pd, Pt,ac) B and C or borides and carbides or nitrides and carbides or B and carbides or nitrides and carbon or mixtures of boron and carbon-containing solid solutions or mixtures of boron- and N-containing solid solutions;b) converting the powder mixture by mechanical alloying or intensive grinding under an atmosphere containing argon, nitrogen or carbon, into a secondary powder with an amorphous, glass-like structure, a completely nanocrystalline structure, or a mixture of an amorphous and nanocrystalline structure;c) heat-treating the secondary powder to form superconducting phases at formation temperatures below 1600.degree. C.; andd) compacting the secondary powder by pressure to form superconductor molded bodies at temperatures below the crystallization temperature of the amorphous phase or below the temperature where the superconducting phase transforms into a non-superconducting phase.
    • 生产稀土过渡金属碳化硼的紧凑型成型体和氮化硼化合物,其被配置为避免在生产过程中选择性地蒸发各个组分,并能精确调整所需的化学计量。 该方法的特征在于a)产生粒度为1至250μm的粉末混合物,其含有aa至少一种元素,所述元素包括Y,La,Ho,Dy,Er,Tm,Lu,Sc, ab)来自包含Ni,Cu,Co,Fe,Pd,Pt,ac,Fe,Pd,Pt,ac)B和C或硼化物的至少一种元素,碳化物或氮化物和碳化物或B和碳化物或氮化物以及碳或硼和碳 - 含有固体溶液或含硼和N的固溶体的混合物; b)在含有氩,氮或碳的气氛下通过机械合金化或强力研磨将粉末混合物转化成具有无定形,玻璃状结构,完全纳米晶体结构或非晶和纳米晶体结构的混合物的二次粉末; c)在低于1600℃的地层温度下对二次粉末进行热处理以形成超导相。 和d)通过压力压制二次粉末,以在低于非晶相的结晶温度或低于超导相转变为非超导相的温度的温度下形成超导体模制体。
    • 5. 发明申请
    • High-tensile, malleable molded bodies of titanium alloys
    • 高强度,有韧性的钛合金成型体
    • US20060054250A1
    • 2006-03-16
    • US10995207
    • 2004-11-24
    • Guo HeWolfgang LoeserJuergen EckertUta Kuehn
    • Guo HeWolfgang LoeserJuergen EckertUta Kuehn
    • C22C14/00
    • C22C14/00C22C45/10
    • The object of the invention is to create high-tensile molded bodies that are made of titanium alloys and are malleable at room temperature and that, compared with the metallic glasses, have macroscopic plasticity and work hardening, without other properties, such as breaking resistance, elastic elongation or corrosion behavior being thus greatly impaired. The molded bodies according to the invention are characterized in that they are made of a material that in its composition conforms to the formula Tia E1b E2c E3d E4e, where E1 comprises one or more elements of the group containing the elements Ta, Nb, Mo, Cr, W, Zr, V, Hf and Y, E2 comprises one or more elements of the group containing the elements Cu, Au, Ag, Pd and Pt, E3 comprises one or more elements of the group containing the elements Ni, Co, Fe, Zn, Mn and E4 comprises one or more elements of the group containing the elements Sn, Al, Ga, Si, P, C, B, Pb and Sb, where a=100−(b+c+d+e), b=0 to 20, c=5 to 30, d=5 to 30, e=1 to 15 (a, b, c, d, e in atomic %). The molded bodies have a homogenous microstructure, mainly comprising a glassy or nanocrystalline matrix with ductile dendritic body-centered cubic phase embedded therein. A third phase with low volumetric proportion can be present. Such molded bodies can be used as high-stress components, e.g., in the aircraft industry, space aviation and the automobile industry, but also for medical technical equipment and implants in the medical field.
    • 本发明的目的是制造由钛合金制成并且在室温下具有延展性的高强度成型体,并且与金属玻璃相比,具有宏观可塑性和加工硬化,而没有其它性能如耐断裂性, 因此弹性伸长或腐蚀行为受到极大的损害。 根据本发明的成型体的特征在于它们由其组成符合下列公式的材料制成:其中,C 1,B 2,C 2,C 2, 其中E1包括含有元素Ta,Nb,Mo,Cr,W,Zr,V,Hf的元素的一种或多种元素,和/ Y,E 2包含含有元素Cu,Au,Ag,Pd和Pt的一个或多个元素,E3包括含有元素Ni,Co,Fe,Zn,Mn和E4的一个或多个元素包括一个或多个 其中a = 100-(b + c + d + e),b = 0〜20,c = 5的元素更多为元素Sn,Al,Ga,Si,P,C,B,Pb和Sb 至30,d = 5〜30,e = 1〜15(a,b,c,d,e,原子%)。 成型体具有均匀的微观结构,主要包括嵌入其中的具有延性树枝状体心立方相的玻璃状或纳米晶体基质。 可以存在体积比低的第三相。 这样的成型体可以用作高应力成分,例如飞机工业,航空航空和汽车工业,也可用于医疗技术设备和医疗领域的植入物。
    • 6. 发明申请
    • Method For Improving The Plastic Ductility Of High-Strength Molded Bodies From Bulk Metallic Glasses And Molded Bodies So Produced
    • 提高散装金属玻璃和成型体高强度成型体塑性延性的方法
    • US20070256760A1
    • 2007-11-08
    • US10561288
    • 2004-07-09
    • Juergen EckertAnnett GebertUthandi Mudali
    • Juergen EckertAnnett GebertUthandi Mudali
    • C22C45/00
    • C01B3/0031C22C45/10C22F1/02C22F1/18C22F1/183C22F1/186Y02E60/327
    • Disclosed is a method for improving the plastic ductility of high-strength molded bodies from bulk metallic glasses from Zr, Ti and Hf base alloys and molded bodies so produced. An object is to find ways to substantially increase the plasticity and toughness of bulk metallic glasses produced on the basis of early transition metals (Zr, Ti, Hf) which is comparatively low as compared to their very high strength, thereby further increasing their potential applicability as materials for airplane structures. Hydrogen in defined ranges of concentration is introduced into the molded bodies in a concentration below the brittle hydride formation concentration. The molded bodies produced comprise hydrogen in a homogenous distribution in the amorphous short-range order structure and/or in the form of hydrogen-induced local enrichment of ductile alloy components and/or in the form of hydrogen-induced precipitations of ductile nanocrystalline phases while excluding brittle hydrides.
    • 本发明公开了一种从Zr,Ti和Hf基合金以及如此制造的成型体的本体金属玻璃中提高高强度成形体的塑性延展性的方法。 一个目的是找到基本上提高基于与其非常高的强度相比较低的早期过渡金属(Zr,Ti,Hf)生产的散装金属玻璃的可塑性和韧性的方法,从而进一步提高其潜在适用性 作为飞机结构的材料。 在规定浓度范围内的氢气以低于脆性氢化物形成浓度的浓度引入成型体。 所制造的成型体包括在非晶态短程有序结构中和/或氢诱导局部富集延性合金组分和/或以氢诱导的延性纳米晶相沉淀形式的均匀分布中的氢,而 不包括脆性氢化物。