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1. 发明授权

US5594066A Low-viscosity, stable, agglomerate-free polymer polyols, a process for their preparation and their use in producing polyurethane plastics 失效
标题翻译：低粘度，稳定，无附聚物的聚合物多元醇，其制备方法及其在制备聚氨酯塑料中的应用
公开(公告)号：US5594066A
公开(公告)日：1997-01-14
申请号：US518370
申请日：1995-08-23
申请人： Torsten Heinemann , Manfred Dietrich , Gundolf Jacobs , Mark Kratz , Josef Sanders , Uwe Scholz , Helmut Woynar
发明人： Torsten Heinemann , Manfred Dietrich , Gundolf Jacobs , Mark Kratz , Josef Sanders , Uwe Scholz , Helmut Woynar
IPC分类号： C08F2/38 , C08F290/06 , C08G18/63 , C08G18/81 , C08G18/48
CPC分类号： C08G18/635 , C08F290/062 , C08G18/8175
摘要： Stable, agglomerate-free, low-viscosity graft copolymer dispersions are prepared by the radical polymerization of 25 to 65% by weight of ethylenically unsaturated monomers in the presence of a base polyol, a macromer, a low-molecular weight regulator and, optionally, an organic solvent. The dispersions of this process are suitable as a polyol component for the production of polyurethane plastics by the isocyanate addition process.
摘要翻译：通过在碱性多元醇，大分子单体，低分子量调节剂和任选地，式（I））存在下，通过25至65重量％的烯属不饱和单体的自由基聚合制备稳定的无附聚物，低粘度的接枝共聚物分散体，有机溶剂。该方法的分散体适用于通过异氰酸酯加成方法生产聚氨酯塑料的多元醇组分。

2. 发明授权

US5554662A Low viscosity polymer polyols a process for their production as well as the manufacture of polyurethane from materials 失效
标题翻译：低粘度聚合物多元醇是其生产方法以及聚氨酯泡沫材料的制造
公开(公告)号：US5554662A
公开(公告)日：1996-09-10
申请号：US470695
申请日：1995-06-06
申请人： Josef Sanders , Mark Kratz , Manfred Dietrich , Torsten Heinemann , Helmut Woynar , Gundolf Jacobs , Uwe Scholz
发明人： Josef Sanders , Mark Kratz , Manfred Dietrich , Torsten Heinemann , Helmut Woynar , Gundolf Jacobs , Uwe Scholz
IPC分类号： C08F283/00 , C08G18/63 , C08G63/91 , C08G65/32 , C08K5/09 , C08L75/00
CPC分类号： C08F283/00 , C08G18/63 , C08K5/09 , C08L75/00 , C08G63/91 , C08G65/32
摘要： A process for the production of stable, agglomerate-free, low viscosity graft copolymer dispersions through radical polymerization of ethylenically unsaturated monomers in the presence of a base polyol, a macromer, an enol ether of a specific formula, and optionally, an organic solvent. These enol ethers correspond to the general formula:A=CH--O--Rwherein:A represents a di-valent residue of the formula ##STR1## R represents an aliphatic hydrocarbon radical having 1 to 18 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 10 carbon atoms, or a substituted or unsubstituted benzyl radical;andR' represents a hydrogen atom or an aliphatic hydrocarbon radical having 1 to 8 carbon atoms.
摘要翻译：在碱性多元醇，大分子单体，特定式的烯醇醚和任选的有机溶剂的存在下，通过烯属不饱和单体的自由基聚合制备稳定的无附聚物，低粘度接枝共聚物分散体的方法。这些烯醇醚对应于以下通式：A = CH-O-R其中：A表示下式的二价残基：R表示具有1至18个碳原子的脂族烃基，脂环族烃基具有5至 10个碳原子，或取代或未取代的苄基; R'表示氢原子或碳原子数1〜8的脂肪族烃基。

3. 发明授权

US5854358A Polymerizing monomers in presence of polyol and castor oil-polyol product 失效
标题翻译：在多元醇和蓖麻油 - 多元醇产物存在下聚合单体
公开(公告)号：US5854358A
公开(公告)日：1998-12-29
申请号：US682063
申请日：1996-07-16
申请人： Torsten Heinemann , Hans-Joachim Scholl , Manfred Dietrich , Gundolf Jacobs , Mark Kratz , Josef Sanders , Helmut Woynar
发明人： Torsten Heinemann , Hans-Joachim Scholl , Manfred Dietrich , Gundolf Jacobs , Mark Kratz , Josef Sanders , Helmut Woynar
IPC分类号： C08F283/06 , C08G18/63 , C08G18/65 , C08G18/04 , C08G63/06 , C08G65/48
CPC分类号： C08G18/6547 , C08F283/06 , C08G18/632 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： A process is described for the preparation of stable, agglomerate-free, low-viscosity graft copolymer dispersions by the free-radical polymerization of olefinic monomers, such as styrene and/or acrylonitrile, with polyol compounds in the presence of a hydroxyl compound modified with castor oil. The use of these graft copolymer dispersions in the manufacture of polyurethane plastics, particularly flexible foams, by the isocyanate polyaddition process is also described.
摘要翻译：描述了一种通过烯烃单体如苯乙烯和/或丙烯腈与多元醇化合物在羟基化合物的存在下通过自由基聚合制备稳定的无团聚的低粘度接枝共聚物分散体的方法，所述羟基化合物在蓖麻油。还描述了通过异氰酸酯加聚方法在制备聚氨酯塑料，特别是柔性泡沫体中使用这些接枝共聚物分散体。

4. 发明授权

US5814699A Continuous process for the preparation of highly stable, finely divided, low viscosity polymer polyols of small average particle size 失效
标题翻译：用于制备平均粒度小的高度稳定，细分，低粘度的聚合物多元醇的连续方法
公开(公告)号：US5814699A
公开(公告)日：1998-09-29
申请号：US723659
申请日：1996-10-03
申请人： Mark R. Kratz , Manfred Dietrich , Torsten Heinemann , Gundolf Jacobs , Josef Sanders , Helmut Woynar
发明人： Mark R. Kratz , Manfred Dietrich , Torsten Heinemann , Gundolf Jacobs , Josef Sanders , Helmut Woynar
IPC分类号： C08F212/10 , C08F220/42 , C08F220/44 , C08F283/06 , C08F285/00 , C08F290/02 , C08G18/63 , C08F283/02
CPC分类号： C08G18/635 , C08F290/02 , C08G2101/0008 , C08G2101/0016
摘要： A continuous process for the preparation of highly stable, finely divided, low viscosity polymer polyols of small average particle size wherein in the first step an intermediate is prepared by reacting (1) a mixture of at least two ethylenically unsaturated monomers, preferably styrene and acrylonitrile, in a mixture comprising (2) a base polyol and (3) a macromer in the presence of (4) a free radical initiator, (5) a solvent having moderate chain transfer activity, and, optionally, (6) a reaction moderator at a temperature of at least 100.degree. C., such that the intermediate contains at least about 12% by weight of macromer, based on the weight of the base polyol and macromer, and a solids content of at least about 15% by weight and less than about 30% by weight, based on the weight of the base polyol, macromer and ethylenically unsaturated monomers. The intermediate, which functions as a seed for further polymerization, is then further reacted, in one or more stirred-tank reactors in series, in a mixture of at least two ethylenically unsaturated monomers, preferably styrene and acrylonitrile, in a base polyol and, optionally, a macromer, in the presence of solvent, initiator and a reaction moderator which are distributed among the remaining reactors.
摘要翻译：一种用于制备平均粒度小的高度稳定，细分，低粘度的聚合物多元醇的连续方法，其中在第一步中，通过使（1）至少两种烯属不饱和单体，优选苯乙烯和丙烯腈的混合物在（4）自由基引发剂，（5）具有中等链转移活性的溶剂的存在下，（2）基础多元醇和（3）大分子单体的混合物中，和（6）反应调节剂在至少100℃的温度下，使得中间体含有至少约12重量％的大分子单体，基于基础多元醇和大分子单体的重量，固体含量至少约15重量％，和小于约30重量％，基于基础多元醇，大分子单体和烯属不饱和单体的重量。作为进一步聚合的种子的中间体在一个或多个串联的搅拌釜反应器中在基础多元醇中进一步在至少两种烯属不饱和单体，优选苯乙烯和丙烯腈的混合物中反应，任选地，大分子单体在溶剂，引发剂和反应缓和剂的存在下分布在剩余的反应器中。

5. 发明授权

US4837359A Process for the production of polyisocyanates with biuret structures 失效
标题翻译：用缩二脲结构生产多异氰酸酯的方法
公开(公告)号：US4837359A
公开(公告)日：1989-06-06
申请号：US139495
申请日：1987-12-30
申请人： Helmut Woynar , Klaus Konig , Josef Pedain , William E. Slack
发明人： Helmut Woynar , Klaus Konig , Josef Pedain , William E. Slack
IPC分类号： C07C263/16 , C07C67/00 , C07C241/00 , C07C265/00 , C07C273/18 , C07C275/62 , C08G18/02 , C08G18/78
CPC分类号： C07C273/1827 , C08G18/7831
摘要： Polyisocyanates with biuret structures are produced at temperatures above 250.degree. C. More specifically, an excess of a diisocyanate having aliphatically and/or cycloaliphatically bound isocyanate groups is reacted with a diamine containing aliphatically and/or cycloaliphatically bound amino groups at temperatures above 250.degree. C. for relatively brief periods of time. Water and/or polyvalent alcohols may optionally be included in the reaction mixture. The polyisocyanates with biuret structures produced by this process are characterized by good color, good dilutability with covalent solvents and comparatively low viscosity.
摘要翻译：具有缩二脲结构的聚异氰酸酯在高于250℃的温度下生产。更具体地说，过量的具有脂族和/或环烯键合的异氰酸酯基团的二异氰酸酯在高于250℃的温度下与含有脂族和/或环状结合氨基的二胺反应在相对较短的时间内。水和/或多元醇可以任选地包括在反应混合物中。通过该方法制备的具有缩二脲结构的多异氰酸酯的特征在于良好的颜色，与共价溶剂的良好稀释性和较低的粘度。

6. 发明授权

US4810251A Fatliquoring solution dispersion or emulsion and a process for treating leather therewith 失效
标题翻译：加脂溶液分散体或乳液及其处理方法
公开(公告)号：US4810251A
公开(公告)日：1989-03-07
申请号：US858160
申请日：1986-05-01
申请人： Harro Traubel , Helmut Woynar , Hans-Werner Muller , Hans J. Focks
发明人： Harro Traubel , Helmut Woynar , Hans-Werner Muller , Hans J. Focks
IPC分类号： C14C9/02 , D06N3/14
CPC分类号： D06N3/14 , C14C9/02
摘要： Aqueous fatliquoring solutions, dispersions or emulsions are made with (a) polyethers having at least two hydroxyl groups and a molecular weight of from 200 to 20,000 and/or (b) polyester containing at least two hydroxyl groups and a molecular weight of from 200 to 20,000 and/or (c) polycarbonates containing at least two hydroxyl groups and a molecular weight of from 200 to 20,000 and/or mixtures thereof. These fatliquoring agents are used to treat tanned leathers until from 0.1 to 20 wt % has been taken up. The thus-treated leather is particularly useful in the production of leather-polyurethane compositions such as shoes without the use of an adhesive.
摘要翻译：水性加脂溶液，分散体或乳液用（a）具有至少两个羟基，分子量为200至20,000的聚醚和/或（b）含有至少两个羟基的聚酯和分子量为200至200 20,000和/或（c）含有至少两个羟基并且分子量为200至20,000的聚碳酸酯和/或其混合物。这些加脂剂用于处理鞣制皮革，直到已经吸收了0.1至20重量％。如此处理的皮革特别可用于生产皮革 - 聚氨酯组合物如鞋，而不使用粘合剂。

7. 发明授权

US4625052A Process for the production of polyisocyanates which have a biuret structure 失效
标题翻译：制备具有缩二脲结构的聚异氰酸酯的方法
公开(公告)号：US4625052A
公开(公告)日：1986-11-25
申请号：US695144
申请日：1985-01-25
申请人： Klaus Konig , Josef Pedain , Helmut Woynar
发明人： Klaus Konig , Josef Pedain , Helmut Woynar
IPC分类号： C08G18/00 , C07C273/18 , C07C275/62 , C08G18/30 , C08G18/78 , C07C127/24
CPC分类号： C07C273/1863 , C07C273/1872 , C08G18/7831
摘要： The present invention is directed to a process for the production of polyisocyanates which have a biuret structure by reacting aliphatic diisocyanates with water at elevated temperature, characterized in that the reaction is carried out in the presence of:(a) .alpha., .alpha., .alpha.-tri-substituted acetic acids, which do not have any further isocyanate-reactive group other than the carboxyl group,and/or(b) anhydrides of acids of the type mentioned in (a)wherein up to 0.39 mols of component (a) are used per mol of water, up to about 2 mols of component (b) are used per mol of water, and the total quantity of components (a) and (b) is at least 0.02 to about 2 mols per mol of water.
摘要翻译：本发明涉及通过在高温下使脂族二异氰酸酯与水反应而具有缩二脲结构的多异氰酸酯的方法，其特征在于反应在以下存在下进行：（a）α，α，α- （a）中提到的类型的酸类的酸酐，其中至多0.39摩尔的组分（a）是酸酐，其中不含羧基以外的任何其它异氰酸酯反应性基团的三取代的乙酸，和/ 每摩尔水使用多达约2摩尔组分（b），组分（a）和（b）的总量为每摩尔水至少0.02至约2摩尔。

8. 发明授权

US4613686A Process for the preparation of polyisocyanates with biuret structure 失效
标题翻译：用缩二脲结构制备多异氰酸酯的方法
公开(公告)号：US4613686A
公开(公告)日：1986-09-23
申请号：US695138
申请日：1985-01-25
申请人： Klaus Konig , Josef Pedain , Helmut Woynar
发明人： Klaus Konig , Josef Pedain , Helmut Woynar
IPC分类号： C08G18/00 , C07C67/00 , C07C239/00 , C07C273/18 , C07C275/62 , C08G18/30 , C08G18/78 , C07C127/24
CPC分类号： C07C273/1809 , C08G18/7831
摘要： The present invention relates to a process for the preparation of polyisocyanates which have a biuret structure of reacting excess quantities of aliphatic diisocyanates with biuretizing agents at elevated temperature, characterized in that the biuretizing agent contains(a) .alpha.,.alpha.,.alpha.-trisubstituted acetic acids which do not contain isocyanate-reactive groups apart from the carboxyl group, and optionally(b) water,wherein the molar ratio of biuretizing components (a) to (b) is within the range of from 1:0 to 1:2.5.
摘要翻译：本发明涉及一种制备多异氰酸酯的方法，其具有在过高温度下使过量的脂族二异氰酸酯与缩合反应剂反应的缩二脲结构，其特征在于，缩二脲化合物含有（a）α，α，α-三取代的乙酸其不包含除羧基以外的异氰酸酯反应性基团，和任选地（b）水，其中缩二脲化成分（a）至（b）的摩尔比在1:0至1:2.5的范围内。

9. 发明授权

US5994491A Process for the production of polyisocyanates having a biuret structure 失效
标题翻译：制备具有缩二脲结构的多异氰酸酯的方法
公开(公告)号：US5994491A
公开(公告)日：1999-11-30
申请号：US22792
申请日：1998-02-13
申请人： Helmut Woynar , Manfred Schmidt , Jurgen Gronen
发明人： Helmut Woynar , Manfred Schmidt , Jurgen Gronen
IPC分类号： C07C273/18 , C07C275/62 , C08G18/02 , C08G18/78 , C08G18/32
CPC分类号： C07C273/1854 , C08G18/7831
摘要： A process for the production of polyisocyanates having a biuret structure, comprising continuously combining organic diisocyanates having aromatically attached isocyanate groups in a mixing chamber with organic diamines having aromatically attached amino groups in a molar ratio of at least 8:1 to form a reaction mixture; and reacting said reaction mixture at a temperature of above 180.degree. C., wherein a residence time of said reaction mixture in the mixing chamber from when said organic diisocyanates and said organic diamines are combined is at most 60 seconds.
摘要翻译：一种制备具有缩二脲结构的多异氰酸酯的方法，包括在混合室中将具有芳香连接的异氰酸酯基团的有机二异氰酸酯与摩尔比为至少8:1的芳族连接的氨基的有机二胺连续地混合以形成反应混合物; 并使所述反应混合物在高于180℃的温度下反应，其中所述反应混合物在所述有机二异氰酸酯和所述有机二胺的混合室中的停留时间为至多60秒。

10. 发明授权

US4831075A Leather treatment agent 失效
标题翻译：皮革处理剂
公开(公告)号：US4831075A
公开(公告)日：1989-05-16
申请号：US40915
申请日：1987-04-21
申请人： Harro Traubel , Helmut Woynar , Hans-Werner Muller
发明人： Harro Traubel , Helmut Woynar , Hans-Werner Muller
IPC分类号： C14C11/00 , D06P1/613 , D06P1/649 , D06P1/651 , D06P3/32 , D06P5/00
CPC分类号： D06P1/65125 , D06P1/6131 , D06P1/6495 , D06P3/32
摘要： Leather treatment agents contain a mixture of(a) 2-98% by weight of an adduct with a molecular weight of 500-50,000 of an alkylene oxide onto an aliphatic or aromatic compound containing one or more hydroxyl groups and(b) 98-2% by weight of a reaction product, containing carboxyl groups or salts thereof, with a molecular weight of 170-20,000 of an aliphatic, cycloaliphatic or aromatic compound containing at least two carboxyl groups or anhydrides thereof and an aliphatic or cycloaliphatic compound containing at least two hydroxyl and/or primary or secondary amino groups and, if appropiate, ether or tertiary amino groups.
摘要翻译：皮革处理剂含有（a）2-98重量％的分子量为500-50,000的烯化氧的加合物与含有一个或多个羟基的脂族或芳族化合物的混合物，和（b）98-2 含有羧基或其盐的反应产物的重量％，分子量为170-20,000的含有至少两个羧基或酸酐的脂族，脂环族或芳族化合物和含有至少两个羧酸或脂环族化合物的脂族或脂环族化合物羟基和/或伯或仲氨基，如果适当的是醚或叔氨基。

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