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    • 4. 发明授权
    • Tanning with carboxylic acid carrying ester, urethane and/or amide group
    • 用羧酸进行鞣制,酯,氨基甲酸酯和/或酰胺基
    • US4126413A
    • 1978-11-21
    • US802101
    • 1977-05-31
    • Harro TraubelHelga Heinze
    • Harro TraubelHelga Heinze
    • C14C3/06C14C3/08
    • C14C3/06C14C3/08
    • In the tanning or re-tanning of a hide with a tanning composition comprising a tanning-active substance and at least one of a Cr(III) salt, a dicarboxylic acid, a dicarboxylic acid salt, an emulsifier and an acid-binding agent, the improvement which comprises employing as said tanning-active substance a carboxylic acid carrying at least one of an ester, urethane or amide group. Advantageously the agent has at least two carboxyl groups per molecule and a molecular weight of about 170 to 30,000, preferably 310 to 10,000. The products are softer and better through-tanned and there is maximum utilization of chromium, thereby minimizing the waste disposal problem.
    • 在用鞣制活性物质和Cr(III)盐,二羧酸,二羧酸盐,乳化剂和酸结合剂中的至少一种的鞣制组合物的皮革的鞣制或再鞣制中, 包括使用携带至少一种酯,氨基甲酸酯或酰胺基团的羧酸作为所述鞣制活性物质的改进。 有利的是,该试剂每分子具有至少两个羧基,分子量为约170至30,000,优选310至10,000。 产品更柔软,更好地通过鞣制,最大限度地利用铬,从而最大限度地减少废物处理的问题。
    • 9. 发明授权
    • Use of polyaspartic acid amides as leather auxiliary products
    • 使用聚天冬氨酸酰胺作为皮革辅助产品
    • US5885474A
    • 1999-03-23
    • US11241
    • 1998-01-28
    • Jurgen ReinersManfred SchneeTorsten GrothWinfried JoentgenGerd SchmitzHarro TraubelNikolaus Muller
    • Jurgen ReinersManfred SchneeTorsten GrothWinfried JoentgenGerd SchmitzHarro TraubelNikolaus Muller
    • C08G73/10C14C9/00
    • C08G73/1092C14C9/00Y10T428/4935
    • Leather can be pretreated to obtain good body, soft feel, and excellent grain smoothness and solidity with products having a molecular weight of 700 to 30,000 and which are obtainable by reaction ofA. polysuccinimide having a molecular weight, determined as the number-average, of 500 to 10,000, withB. 5 to 90 mol % based on the succinimide units of polysuccinimide A, and/or secondary amine, the nitrogen substituents of which contain 1 to 60 carbon atoms and which can be unsubstituted or substituted, at least 2.5 mol % of the nitrogen substituents of the amine containing at least 12 carbon atoms,C. optionally, (i) derivatives of C.sub.1 -C.sub.18 -monocarboxylic acids, C.sub.2 -C.sub.10 -dicarboxylic acids, and/or (ii) monoisocyanates, diisocyanates epichlorohydrin (for reaction of amino and/or hydroxyl groups on the nitrogen substituents of the reaction product of A and B), andD. 95 to 10 mol % of ring-opening base in the presence of water.
    • PCT No.PCT / EP96 / 03241 Sec。 371日期1998年1月28日 102(e)1998年1月28日PCT PCT 1996年7月23日PCT公布。 公开号WO97 / 06279 日期1997年2月20日可以预处理具有分子量为700〜30,000的产品的良好的身体,柔软的手感和良好的颗粒光滑度和稳定性,并且可以通过将分子量为A的聚琥珀酰亚胺 数均分子量为500〜10000,B为5〜90摩尔%,基于琥珀酰亚胺单元的聚琥珀酰亚胺A,和/或仲胺,其氮取代基含有1〜60个碳原子,可以是未取代的或 至少2.5mol%含有至少12个碳原子的胺的氮取代基,C.任选地,(i)C 1 -C 18 - 一元羧酸的衍生物,C 2 -C 10 - 二羧酸和/或(ii) 单异氰酸酯,二异氰酸酯表氯醇(用于在A和B的反应产物的氮取代基上的氨基和/或羟基的反应)和D.95至10摩尔%的开环碱在水的存在下反应。