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1. 发明授权

US5854358A Polymerizing monomers in presence of polyol and castor oil-polyol product 失效
标题翻译：在多元醇和蓖麻油 - 多元醇产物存在下聚合单体
公开(公告)号：US5854358A
公开(公告)日：1998-12-29
申请号：US682063
申请日：1996-07-16
申请人： Torsten Heinemann , Hans-Joachim Scholl , Manfred Dietrich , Gundolf Jacobs , Mark Kratz , Josef Sanders , Helmut Woynar
发明人： Torsten Heinemann , Hans-Joachim Scholl , Manfred Dietrich , Gundolf Jacobs , Mark Kratz , Josef Sanders , Helmut Woynar
IPC分类号： C08F283/06 , C08G18/63 , C08G18/65 , C08G18/04 , C08G63/06 , C08G65/48
CPC分类号： C08G18/6547 , C08F283/06 , C08G18/632 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： A process is described for the preparation of stable, agglomerate-free, low-viscosity graft copolymer dispersions by the free-radical polymerization of olefinic monomers, such as styrene and/or acrylonitrile, with polyol compounds in the presence of a hydroxyl compound modified with castor oil. The use of these graft copolymer dispersions in the manufacture of polyurethane plastics, particularly flexible foams, by the isocyanate polyaddition process is also described.
摘要翻译：描述了一种通过烯烃单体如苯乙烯和/或丙烯腈与多元醇化合物在羟基化合物的存在下通过自由基聚合制备稳定的无团聚的低粘度接枝共聚物分散体的方法，所述羟基化合物在蓖麻油。还描述了通过异氰酸酯加聚方法在制备聚氨酯塑料，特别是柔性泡沫体中使用这些接枝共聚物分散体。

2. 发明授权

US5260481A Process for the conditioning and/or purification of organic isocyanates 失效
标题翻译：有机异氰酸酯的调理和/或纯化方法
公开(公告)号：US5260481A
公开(公告)日：1993-11-09
申请号：US860621
申请日：1992-03-30
申请人： Hans-Joachim Scholl
发明人： Hans-Joachim Scholl
IPC分类号： C07C263/18 , C07C263/20 , C07C265/14 , C07C263/10
CPC分类号： C07C263/18 , C07C263/20
摘要： The present invention relates to a process for the conditioning and/or purification of organic isocyanates bya) mixing organic isocyanates at 20.degree. to 150.degree. C. with 0.001 to 1 mole %, based on the isocyanate, of a silylated acid corresponding to the formulaX-[Si(CH.sub.3).sub.3 ].sub.n whereinX represents the neutral acid residue obtained by removing the acidic hydrogen atoms from an n-basic acid having a pKa value of at most 3, with the exception of hydrohalic acids andn is an integer from 1 to 3, andb) optionally working up the resulting mixture by distillation after a residence time of at least 5 minutes.
摘要翻译：本发明涉及一种通过以下步骤来调节和/或净化有机异氰酸酯的方法：a）在20-150℃下将有机异氰酸酯与基于异氰酸酯的0.001至1摩尔％的对应于式X- [Si（CH 3）3] n其中，X表示通过从pKa值为3以下的正碱性酸除去酸性氢原子得到的中性酸残基，除了氢卤酸，n是 1至3的整数，和b）任选地在至少5分钟的停留时间后通过蒸馏处理所得混合物。

3. 发明授权

US5202358A Process for the preparation of liquid storable organic isocyanates containing carbodiimide and/or uretone imine groups and their use for the preparation of polyurethane plastics 失效
标题翻译：制备含有碳二亚胺和/或尿素酮组的液体有机异氰酸酯的方法及其制备聚氨酯塑料的用途
公开(公告)号：US5202358A
公开(公告)日：1993-04-13
申请号：US884143
申请日：1992-05-18
申请人： Hans-Joachim Scholl , Rainer Welte
发明人： Hans-Joachim Scholl , Rainer Welte
IPC分类号： C07C263/18 , C07C265/14 , C07C267/00 , C07D229/00 , C08G18/79
CPC分类号： C08G18/797 , C07C267/00 , C08G2101/0025
摘要： The present invention relates to liquid storable organic isocyanates containing carbodiimide and/or uretone imine groups prepared by(a) partially carbodiimidizing isocyanate groups of an organic isocyanate with catalysts of the phospholine type, and(b) terminating the carbodiimidization reaction by the addition of a silylated acid corresponding to the formulaX--[Si(CH.sub.3).sub.3 ].sub.n in whichX represents the neutral acid residue obtained by removal of the acidic hydrogen atoms from an n-basic acid having a pK.sub.a value of at most 3, other than a hydrohalic acid, andn is an integer of 1 to 3.The invention further relates to the use of the liquid polyisocyanate mixtures according to the invention for the preparation of polyurethane plastics, preferably polyurethane foams, having improved burning behavior.
摘要翻译：本发明涉及通过以下步骤制备的含有碳二亚胺和/或脲酮亚胺基团的液体存储有机异氰酸酯：（a）将有机异氰酸酯的异氰酸酯基团部分碳化亚胺化，用磷酸酯型催化剂制备，和（b）通过加入碳酸二亚胺化反应终止碳二亚胺化反应对应于式X- [Si（CH 3）3] n的甲硅烷基化的酸，其中X表示通过从pKa值至多为3的n-碱性酸除去酸性氢原子而获得的中性酸残基，氢卤酸，n为1至3的整数。本发明还涉及根据本发明的液体多异氰酸酯混合物用于制备具有改进的燃烧行为的聚氨酯塑料，优选聚氨酯泡沫塑料的用途。

4. 发明授权

US4267353A Preparation of aromatic urethanes 失效
标题翻译：芳香族聚氨酯的制备
公开(公告)号：US4267353A
公开(公告)日：1981-05-12
申请号：US69020
申请日：1979-08-22
申请人： Hans-Joachim Scholl , Armin Zenner
发明人： Hans-Joachim Scholl , Armin Zenner
IPC分类号： B01J31/02 , B01J31/00 , C07B61/00 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/06 , C07C125/063 , C07C125/065 , C07C125/07 , C07C125/073
CPC分类号： C07C271/06
摘要： This invention relates to an improved process for the preparation of urethanes by the reaction of aromatic nitro compounds with alcohols and carbon monoxides in the presence of catalyst systems containing sulphur and/or selenium and/or compounds of these elements.
摘要翻译：本发明涉及通过在含有硫和/或硒和/或这些元素的化合物的催化剂体系存在下，通过芳族硝基化合物与醇和一氧化碳的反应制备聚氨酯的改进方法。

5. 发明授权

US4230876A Process for the preparation of urethanes 失效
标题翻译：制备聚氨酯的方法
公开(公告)号：US4230876A
公开(公告)日：1980-10-28
申请号：US13638
申请日：1979-02-21
申请人： Hans-Joachim Scholl , Armin Zenner
发明人： Hans-Joachim Scholl , Armin Zenner
IPC分类号： C07B61/00 , B01J27/02 , B01J27/24 , B01J31/00 , B01J31/02 , C07C67/00 , C07C239/00 , C07C269/00 , C07C125/07
CPC分类号： C07C269/00
摘要： The instant invention relates to an improved process for the preparation of urethanes by the reaction of aromatic nitro compounds with alcohols and carbon monoxide in the presence of catalyst systems which contain selenium.
摘要翻译：本发明涉及通过在含有硒的催化剂体系的存在下芳族硝基化合物与醇和一氧化碳的反应来制备氨基甲酸酯的改进方法。

6. 发明授权

US5837796A Polyisocyanates containing isocyanurate groups and prepared by trimerizing alkyl-substituted cycloaliphatic diisocyanates 失效
标题翻译：含有异氰脲酸酯基并通过三烷基取代的环脂族二异氰酸酯制备的多异氰酸酯
公开(公告)号：US5837796A
公开(公告)日：1998-11-17
申请号：US883477
申请日：1997-06-25
申请人： Hans-Joachim Scholl , Bernhard Jansen , Rolf-Volker Meyer
发明人： Hans-Joachim Scholl , Bernhard Jansen , Rolf-Volker Meyer
IPC分类号： C07D251/34 , C08G18/02 , C08G18/18 , C08G18/70 , C08G18/79 , C08G18/82
CPC分类号： C07D251/34 , C08G18/706 , C08G18/792
摘要： The present invention relates to a process for preparing polyisocyanates containing isocyanurate groups by trimerizing a portion of the isocyanate groups of an organic polyisocyanate component containing a) one or more diisocyanates corresponding to formula (1) ##STR1## wherein R represents a saturated, straight-chain, aliphatic hydrocarbon group having 8 to 15 carbon atoms and optionally b) up to 95 NCO equivalent-%, based on the total equivalents a) and b), of one or more organic polyisocyanates other than a), in the presence of trimerization catalysts and terminating the trimerization reaction at any desired degree of trimerization. The invention also relates to the polyisocyanates containing isocyanurate groups obtained by this process and to their use, optionally in excess starting polyisocyanates and optionally blocked with blocking agents for isocyanate groups, as an isocyanate component for preparing polyisocyanate addition products.
摘要翻译：本发明涉及通过将有机多异氰酸酯组分的一部分异氰酸酯基团三聚而制备含有异氰脲酸酯基的多异氰酸酯的方法，该有机多异氰酸酯组分含有a）一种或多种对应于式（1）的二异氰酸酯，其中R表示饱和，具有8至15个碳原子的直链脂族烃基和任选的b）基于a）和b）的总当量a）和b）至多95NCO当量，一种或多种除a）之外的有机多异氰酸酯，在存在三聚催化剂并以任何所需的三聚程度终止三聚反应。本发明还涉及通过该方法获得的含有异氰脲酸酯基团的多异氰酸酯基团，以及它们的用途，任选地过量起始多异氰酸酯，并任选地用异氰酸酯基团的封端剂封端，作为用于制备多异氰酸酯加成产物的异氰酸酯组分。

7. 发明授权

US5070115A Substantially closed-cell rigid foams containing urethane, urea and biuret groups and a process for their production 失效
标题翻译：含有氨基甲酸酯，尿素和缩二脲基团的基本上封闭的刚性泡沫及其生产方法
公开(公告)号：US5070115A
公开(公告)日：1991-12-03
申请号：US663221
申请日：1991-03-01
申请人： Rainer Welte , Hans-Joachim Scholl
发明人： Rainer Welte , Hans-Joachim Scholl
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/78 , C08G101/00 , C08J9/02
CPC分类号： C08G18/78 , C08G18/10 , C08G18/4018 , C08G18/4244 , C08G18/425 , C08G18/4812 , C08G2101/0025 , C08G2101/0041 , C08G2101/0083
摘要： Rigid substantially closed cell foams are made by reacting an organic isocyanate with a mixture of high molecular weight polyols in the presence of water, a catalyst and other optional materials such as chain extenders, crosslinking agents and flameproofing agents. The reactants are used in quantities such that the isocyanate to hydroxyl group index is from about 90 to about 150. The mixture of high molecular weight polyols is composed of (1) a polyester having at least two hydroxyl groups and an OH number greater than 150 and/or a polyether having at least two hydroxyl groups and an OH number greater than 200 and (2) a polyether having at least two hydroxyl groups and an OH number below 100. The foams produced in accordance with this process are useful as insulating materials and as structural reinforcing materials.
摘要翻译：通过在水，催化剂和其它任选材料如扩链剂，交联剂和防火剂的存在下使有机异氰酸酯与高分子量多元醇的混合物反应制备刚性基本上闭合的泡孔。反应物的用量使得异氰酸酯与羟基指数为约90至约150.高分子量多元醇的混合物由（1）具有至少两个羟基并且OH数大于150的聚酯组成和/或具有至少两个羟基并且OH数大于200的聚醚和（2）具有至少两个羟基并且OH数低于100的聚醚。根据该方法生产的泡沫可用作绝缘材料并作为结构增强材料。

8. 发明授权

US5013838A Polyisocyanates containing isocyanurate groups and a process for their production 失效
标题翻译：含异氰脲酸酯基的聚异氰酸酯及其制备方法
公开(公告)号：US5013838A
公开(公告)日：1991-05-07
申请号：US467822
申请日：1990-01-19
申请人： Hans-Joachim Scholl
发明人： Hans-Joachim Scholl
IPC分类号： B01J31/00 , B01J31/02 , C07D251/34 , C07D273/04 , C08G18/02 , C08G18/78 , C08G18/79 , C09D175/04
CPC分类号： C08G18/792 , C07D251/34 , C07D273/04 , C08G18/022 , C08G18/7887
摘要： The present invention relates to a process for the production of an isocyanurate group-containing polyisocyanate by(a) partially reacting the isocyanate groups of an organic diisocyanate containing aliphatically and/or cycloaliphatically bound isocyanate groups in the presence of an ammonium or phosphonium fluoride trimerization catalyst,(b) introducing carbon dioxide into the reaction mixture at least periodically during the reaction and(c) terminating the reaction at the desired degree of conversion.The present invention also relates to the isocyanurate group-containing polyisocyanates obtained in accordance with this process.
摘要翻译：本发明涉及通过以下方法制备含异氰脲酸酯基的多异氰酸酯的方法：（a）在铵或氟化鏻三聚催化剂存在下，使含有脂族和/或环状结合的异氰酸酯基团的有机二异氰酸酯的异氰酸酯基团部分反应，（b）在反应期间至少周期性地向反应混合物中引入二氧化碳，和（c）以期望的转化程度终止反应。本发明还涉及根据该方法获得的含异氰脲酸酯基的多异氰酸酯。

9. 发明授权

US4935534A 1-(N-formylamino)-2,4-dicyanobutane and a process for its production 失效
标题翻译： 1-（N-甲酰氨基）-2,4-二氰基丁烷及其制备方法
公开(公告)号：US4935534A
公开(公告)日：1990-06-19
申请号：US327079
申请日：1989-03-22
申请人： Hans-Joachim Scholl
发明人： Hans-Joachim Scholl
IPC分类号： C07C253/30 , C07C255/24 , C07C255/27
CPC分类号： C07C255/00
摘要： This invention relates to the novel compound 1-(N-formylamino)-2,4-dicyanobutane, which is useful as an intermediate, for example, in the preparation of -aminomethyl glutamic acid. This invention further relates to a process for the production of 1-(N-formylamino)-2,4-dicyanobutane by the reaction of 2,4-dicyano-1-butene and formamide in the presence of 4-aminopyridine derivative.
摘要翻译：本发明涉及新化合物1-（N-甲酰氨基）-2,4-二氰基丁烷，其可用作例如氨基甲基谷氨酸的制备中的中间体。本发明还涉及通过2,4-二氰基-1-丁烯和甲酰胺在4-氨基吡啶衍生物的存在下反应制备1-（N-甲酰氨基）-2,4-二氰基丁烷的方法。

10. 发明授权

US4918235A 1,5-Diaminoheptanol-1,6, 失效
标题翻译： 1,5-二氨基庚醇-1,6，
公开(公告)号：US4918235A
公开(公告)日：1990-04-17
申请号：US227224
申请日：1988-08-02
申请人： Hans-Joachim Scholl , Josef Pedain
发明人： Hans-Joachim Scholl , Josef Pedain
IPC分类号： C07C213/02 , C07B61/00 , C07C67/00 , C07C213/00 , C07C215/18 , C08G18/10 , C08G18/65
CPC分类号： C08G18/10
摘要： The present invention is directed to a new chemical compound, 1,5-diaminoheptanol-6, which corresponds to the formula ##STR1## The present invention is additionally directed to a process for the preparation of 1,5-diaminoheptanol-6 by reacting L-lysine in its free form and/or in the form of its HCl salt, with acetic acid anhydride in the presence of a tertiary organic amino base and with the addition of a 4-aminopyridine derivative, hydrogenating the resulting 1,5-bisacetaminohepthanone-6 to 1,5-bisacetaminoheptanol-6, forming a salt of 1,5-diaminoheptanol-6 by treating 1,5-bisacetaminoheptanone-6 with a mineral acid and isolating the free amine by treating the 1,5-diaminoheptanol-6 salt of a mineral acid with a strong base.Finally, the present invention is directed to the use of 1,5-diaminoheptanol-6 as at least a portion of the chain lengthening agent for the preparation of polyurethane plastics by the isocyanate polyaddition process.
摘要翻译：本发明涉及对应于式（I）的新化合物1,5-二氨基庚醇-6本发明另外涉及一种制备1,5-二氨基庚醇-6 通过使其游离形式的L-赖氨酸和/或其盐酸盐的形式与乙酸酐在叔有机氨基的存在下反应，并加入4-氨基吡啶衍生物，将所得的1,5 - 双乙酰氨基庚酮-6至1,5-双乙酰氨基庚醇-6，通过用无机酸处理1,5-双氨基庚酮-6，形成1,5-二氨基庚醇-6的盐，并通过处理1,5-二氨基庚醇 -6盐的无机酸与强碱。最后，本发明涉及1,5-二氨基庚醇-6作为链增长剂的至少一部分用于通过异氰酸酯加聚方法制备聚氨酯塑料的用途。

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