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    • 4. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US5260177A
    • 1993-11-09
    • US884897
    • 1992-05-18
    • Kozo AokiMichio OnoKatsuyoshi YamakawaShigeru YamazakiKei SakanoueHidetoshi Kobayashi
    • Kozo AokiMichio OnoKatsuyoshi YamakawaShigeru YamazakiKei SakanoueHidetoshi Kobayashi
    • C07D213/75C07D213/76C07D471/04G03C7/38G03C7/388
    • C07D213/75C07D213/76C07D471/04G03C7/3815
    • A silver halide color photographic light-sensitive material comprises a novel cyan dye-forming coupler or a combination of a specific cyan dye-forming coupler with an .alpha.-pivaloylacetoanilide type yellow dye-forming coupler or a pyrazoloazole type magenta dye-forming coupler, the specific cyan dye-forming coupler being contained in the silver halide emulsion layer in the form of an emulsion of lipophilic fine particles obtained by mixing the coupler with at least one water-insoluble and organic solvent-soluble homo- or co-polymer to form a dispersion. The silver halide color photographic light-sensitive material is excellent in the reproduction of yellow, magenta and cyan colors and has low fog of cyan. Thus, the light-sensitive material can provide color images excellent in the fastness of the cyan color images.The cyan dye-forming coupler is represented by general formula (II): ##STR1## wherein R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group; R.sub.2 represents a group or atom which can be bonded with the heterocyclic ring; X represents a hydrogen atom or a group which can be eliminated; Y represents a divalent bonding group having at least one amido bond and/or ester bond; Z represents a dissociative group; A, B, C, D and E each represents a nitrogen atom or a carbon atom a which hydrogen atom is bonded, provided that one or two of them represent a nitrogen atom; and n represents 0, 1 or 2.
    • 卤化银彩色照相感光材料包括新型的青色染料形成成色剂或特定的形成青色染料的成色剂与α-对甲酰基乙酰苯胺型黄色染料形成成色剂或吡唑并唑型品红色染料形成成色剂的组合, 通过将成色剂与至少一种水不溶性和有机溶剂可溶性均聚物或共聚物混合而形成的亲脂性细颗粒乳液形式的卤化银乳剂层中所含有特定的青色成色剂, 分散。 卤化银彩色摄影感光材料在黄色,品红色和青色的再现方面是优异的,并且具有低的青色雾。 因此,感光材料可以提供在青色图像的牢度方面优异的彩色图像。 青色染料成色剂由通式(II)表示:其中R 1表示脂族基团,芳族基团或杂环基团; R2表示可以与杂环结合的基团或原子; X表示氢原子或可被除去的基团; Y表示具有至少一个酰胺键和/或酯键的二价键合基​​团; Z表示离解基团; A,B,C,D和E各自表示氮原子或氢原子键合的碳原子a,条件是它们中的一个或两个表示氮原子; n表示0,1或2。
    • 5. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US5300419A
    • 1994-04-05
    • US888858
    • 1992-05-27
    • Nobuo SetoHiroyuki YoneyamaMasakazu MorigakiHidekazu SakaiHidetoshi KobayashiShigeru Yamazaki
    • Nobuo SetoHiroyuki YoneyamaMasakazu MorigakiHidekazu SakaiHidetoshi KobayashiShigeru Yamazaki
    • G03C7/36G03C7/30G03C7/392G03C7/34
    • G03C7/3006
    • Disclosed is a silver halide color photographic material containing at least one cyan dye forming coupler of the following general formula (C-1) and at least one compound of the following general formula (I) in the same layer of the material: ##STR1## where R.sub.0 represents an alkyl group, an alkenyl group, an aryl group, or a heterocyclic group;X represents a hydrogen atom, or a group capable of being split off by a coupling reaction with the oxidation product of an aromatic primary amine color developing agent; andAr represents an aromatic group; ##STR2## where R.sub.1, R.sub.2 and R.sub.3 each represent an aliphatic group, an aryl group, or a heterocyclic group;R.sub.4 represents a hydrogen atom, an aliphatic group, an aryl group, or a heterocyclic group;R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4 may be bonded to each other to form a 5-membered to 8-membered ring along with the nitrogen atom in the formula;the compound of formula (I) may form a dimer or a higher polymer at the position of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 ;provided that R.sub.1 and R.sub.3, or R.sub.2 and R.sub.4 are not bonded to each other to form a ring, and that the sum of the carbon atoms of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 6 or more.
    • 公开了在同一层材料中含有至少一种以下通式(C-1)的青色染料形成成色剂和至少一种以下通式(I)的化合物的卤化银彩色照相材料:(* CHEMICAL 结构*)(C-1)其中R 0表示烷基,烯基,芳基或杂环基; X表示氢原子或能够通过与芳族伯胺显色剂的氧化产物的偶联反应而分裂的基团; Ar表示芳香族基团。 (*化学结构*)(I)其中R 1,R 2和R 3各自表示脂族基,芳基或杂环基; R4表示氢原子,脂族基,芳基或杂环基; R 1和R 2,或者R 3和R 4可以彼此键合以与式中的氮原子一起形成5元至8元环; 式(I)化合物可以在R 1,R 2,R 3或R 4的位置上形成二聚体或更高级的聚合物; 条件是R1和R3或R2和R4彼此不结合形成环,并且R 1,R 2,R 3和R 4的碳原子之和为6以上。
    • 6. 发明授权
    • Silver halide photographic lightsensitive material
    • 卤化银照相感光材料
    • US06280918B1
    • 2001-08-28
    • US09396944
    • 1999-09-15
    • Hisashi MikoshibaHidetoshi Kobayashi
    • Hisashi MikoshibaHidetoshi Kobayashi
    • G03C110
    • G03C1/10G03C1/34G03C7/3022G03C7/3885G03C7/39288G03C2007/3027
    • A silver halide photographic lightsensitive material comprises at least one silver halide emulsion layer on a support and contains at least one noncolor-forming compound represented by the following general formula (1) wherein each of R1, R2 and R3 independently represents an alkyl group, an aryl group, a halogen atom, a heterocyclic group, a cyano group, a hydroxy group, a nitro group, a carboxyl group, a sulfo group, an amino group, an alkoxy group, an aryloxy group, an acylamino group, an alkylamino group, an anilino group, an ureido group, an alkylthio group, an arylthio group, an alkoxycarbonylamino group, a sulfonamido group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, an alkoxycarbonyl group, a heterocyclic oxy group, an azo group, an acyloxy group, a carbamoyloxy group, a silyloxy group, an aryloxycarbonylamino group, an imido group, a sulfinyl group, an aryloxycarbonyl group or an acyl group, each of k and n independently represents an integer of 0 to 5, and m represents an integer of 0 to 4.
    • 卤化银照相感光材料在载体上包含至少一个卤化银乳剂层,并含有至少一种由以下通式(1)表示的不成色化合物,其中R1,R2和R3各自独立地表示烷基, 芳基,卤素原子,杂环基,氰基,羟基,硝基,羧基,磺基,氨基,烷氧基,芳氧基,酰氨基,烷基氨基 苯胺基,脲基,烷硫基,芳硫基,烷氧基羰基氨基,亚磺酰氨基,氨基甲酰基,氨磺酰基,磺酰基,烷氧基羰基,杂环氧基,偶氮基, 酰氧基,氨基甲酰氧基,甲硅烷氧基,芳氧基羰基氨基,亚氨基,亚磺酰基,芳氧基羰基或酰基,k和n分别独立地表示0〜5的整数,m表示 表示0到4的整数。
    • 9. 发明授权
    • Silver halide color photographic materials
    • 卤化银彩色照相材料
    • US5273868A
    • 1993-12-28
    • US793008
    • 1991-11-15
    • Mamoru SakurazawaHidetoshi Kobayashi
    • Mamoru SakurazawaHidetoshi Kobayashi
    • G03C7/36G03C7/32G03C7/38
    • G03C7/3225
    • A silver halide color photographic material comprising a support having thereon at least one blue sensitive silver halide emulsion layer, at least one green sensitive silver halide emulsion layer and at least one red sensitive silver halide emulsion layer, wherein at least one type of acylacetamide type yellow coupler in which the acyl group represented by formula [I] indicated below is included in said blue sensitive silver halide emulsion layer and at least one type of magenta coupler represented by formula [M] indicated below is included in said green sensitive silver halide emulsion layer, ##STR1## wherein R.sub.1 represents a univalent group, Q represents a group of non-metal atoms which, together with C, is required to form a three to five membered hydrocarbon ring or a three to five membered heterocyclic ring which has within the ring at least one hetero atom selected from the group consisting of N, O, S and P, with the proviso with R.sub.1 is not a hydrogen atom and is not linked to Q and does not form a ring, ##STR2## wherein R.sub.20 represents a hydrogen atom or a substituent group, Z represents a group of non-metal atoms which is required to form a five membered azole ring which contains 2 to 4 nitrogen atoms, said azole rings may have substituent groups including condensed rings, and X represents a hydrogen atom or a coupling-off group.