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    • 1. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US5260177A
    • 1993-11-09
    • US884897
    • 1992-05-18
    • Kozo AokiMichio OnoKatsuyoshi YamakawaShigeru YamazakiKei SakanoueHidetoshi Kobayashi
    • Kozo AokiMichio OnoKatsuyoshi YamakawaShigeru YamazakiKei SakanoueHidetoshi Kobayashi
    • C07D213/75C07D213/76C07D471/04G03C7/38G03C7/388
    • C07D213/75C07D213/76C07D471/04G03C7/3815
    • A silver halide color photographic light-sensitive material comprises a novel cyan dye-forming coupler or a combination of a specific cyan dye-forming coupler with an .alpha.-pivaloylacetoanilide type yellow dye-forming coupler or a pyrazoloazole type magenta dye-forming coupler, the specific cyan dye-forming coupler being contained in the silver halide emulsion layer in the form of an emulsion of lipophilic fine particles obtained by mixing the coupler with at least one water-insoluble and organic solvent-soluble homo- or co-polymer to form a dispersion. The silver halide color photographic light-sensitive material is excellent in the reproduction of yellow, magenta and cyan colors and has low fog of cyan. Thus, the light-sensitive material can provide color images excellent in the fastness of the cyan color images.The cyan dye-forming coupler is represented by general formula (II): ##STR1## wherein R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group; R.sub.2 represents a group or atom which can be bonded with the heterocyclic ring; X represents a hydrogen atom or a group which can be eliminated; Y represents a divalent bonding group having at least one amido bond and/or ester bond; Z represents a dissociative group; A, B, C, D and E each represents a nitrogen atom or a carbon atom a which hydrogen atom is bonded, provided that one or two of them represent a nitrogen atom; and n represents 0, 1 or 2.
    • 卤化银彩色照相感光材料包括新型的青色染料形成成色剂或特定的形成青色染料的成色剂与α-对甲酰基乙酰苯胺型黄色染料形成成色剂或吡唑并唑型品红色染料形成成色剂的组合, 通过将成色剂与至少一种水不溶性和有机溶剂可溶性均聚物或共聚物混合而形成的亲脂性细颗粒乳液形式的卤化银乳剂层中所含有特定的青色成色剂, 分散。 卤化银彩色摄影感光材料在黄色,品红色和青色的再现方面是优异的,并且具有低的青色雾。 因此,感光材料可以提供在青色图像的牢度方面优异的彩色图像。 青色染料成色剂由通式(II)表示:其中R 1表示脂族基团,芳族基团或杂环基团; R2表示可以与杂环结合的基团或原子; X表示氢原子或可被除去的基团; Y表示具有至少一个酰胺键和/或酯键的二价键合基​​团; Z表示离解基团; A,B,C,D和E各自表示氮原子或氢原子键合的碳原子a,条件是它们中的一个或两个表示氮原子; n表示0,1或2。
    • 3. 发明授权
    • Silver halide color photographic material
    • 银色彩色摄影材料
    • US5210012A
    • 1993-05-11
    • US648894
    • 1991-01-31
    • Michio OnoKouichi HanakiKei SakanoueShigeo HiranoMitsuru Yamamoto
    • Michio OnoKouichi HanakiKei SakanoueShigeo HiranoMitsuru Yamamoto
    • G03C7/305
    • G03C7/30511Y10S430/156Y10S430/158
    • A silver halide color photographic material is provided comprising on a support at least one silver halide emulsion layer containing at least one of the compounds represented by formulae (I) to (III): ##STR1## wherein R.sub.11 represents ##STR2## in which R.sub.13 represents an alkyl, aryl or heterocyclic group, and R.sub.14 and R.sub.15 each represents hydrogen, alkyl group or aryl group; R.sub.12 represents a substituent having a Hammett's substituent constant .sigma.p of 0.3 or less; n represents an integer 0 to 2, and when n is 2, the two R.sub.12 's may be the same or different; B represents a group which releases PUG after being separated from a hydroquinone nucleus; PUG represents a development inhibitor; l represents an integer; and A and A' each represents hydrogen or a group capable of being removed by an alkali; R.sub.11 and R.sub.12, R.sub.11 and A or A', R.sub.12 and A or A', and two R.sub.12 's may together form a ring; ##STR3## wherein Q.sup.1 represents an atomic group containing at least one hetero atom and is required for the formation of a heterocyclic group containing 5 or more members together with carbon atoms connected thereto; R.sup.21 represents a group capable of substituting on the hydroquinone nucleus; and B, PUG, l, A and A' are as defined above; ##STR4## wherein R.sub.31 represents an alkyl group containing two or more carbon atoms in which the carbon atom adjacent to the carbonyl group is not substituted by a hetero atom, a cycloalkyl group, an aryl group or a heterocyclic group; R.sub.32 and R.sub.33 each represents hydrogen or a substituent having a Hammett's substituent constant .sigma.p of 0.3 or less; and B, PUG, l, A and A' are as defined above.
    • 6. 发明授权
    • Color-forming aminopyrimidine couplers and silver halide color
photographic light-sensitive materials containing the coupler
    • 含有偶合剂的成色氨基嘧啶成色剂和卤化银彩色照相感光材料
    • US5017466A
    • 1991-05-21
    • US527376
    • 1990-05-23
    • Hidetoshi KobayashiReiichi OhiKei Sakanoue
    • Hidetoshi KobayashiReiichi OhiKei Sakanoue
    • G03C7/32G03C7/38
    • G03C7/3815
    • A color-forming aminopyrimidine coupler represented by formula (I): ##STR1## where R.sub.1, R.sub.2, and R.sub.3 independently represent a hydrogen atom, a halogen atom, an alkoxy group, an aryloxy group, a heterocyclic-oxy group, an alkylthio group, an arylthio group, a heterocyclic-thio group, a substituted or unsubstitued amino group, a heterocyclic group bonding to the pyrimidine ring via a nitrogen atom thereof, an alkyl group or an aryl group; provided that at least one of R.sub.1, R.sub.2 and R.sub.3 is an unsubstituted or substituted amino group, and that when any one of R.sub.1, R.sub.2 or R.sub.3 contains a sulfonic acid group or a salt thereof, R.sub.1 , R.sub.2 or R.sub.3 contains at least one linear or branched alkyl group and that the total carbon atoms in the alkyl group(s) are to be more than 8; and R.sub.4 represents a hydrogen atom, a halogen atom, an alkoxy group, an aryloxy group, a heterocyclic-oxy group, an alkylthio group, an arylthio group, a heterocyclic-thio group, a substituted or unsubstituted amino group, or a heterocyclic group bonding to the pyrimidine ring via a nitrogen atom thereof.At least one coupler of formula (I) is incorporated into the photographic constitutive layer of a color silver halide photographic material, which gives a color image with high heat-fastness.
    • 由式(I)表示的形成颜色的氨基嘧啶成色剂:其中R 1,R 2和R 3独立地表示氢原子,卤素原子,烷氧基,芳氧基,杂环氧基, 烷硫基,芳硫基,杂环硫基,取代或未取代的氨基,通过氮原子与嘧啶环键合的杂环基,烷基或芳基; 条件是R 1,R 2和R 3中的至少一个是未取代或取代的氨基,当R 1,R 2或R 3中的任何一个含有磺酸基或其盐时,R 1,R 2或R 3含有至少一个直链 或支链烷基,并且烷基中的总碳原子数大于8; R 4表示氢原子,卤素原子,烷氧基,芳氧基,杂环氧基,烷硫基,芳硫基,杂环硫基,取代或未取代的氨基或杂环基 通过其氮原子与嘧啶环结合。 将至少一种式(I)的成色剂并入到彩色卤化银照相材料的照相组成层中,其产生具有高耐热性的彩色图像。
    • 10. 发明授权
    • Silver halide color photographic material containing a bleach
accelerator releasing compound
    • 含有漂白促进剂释放化合物的卤化银彩色照相材料
    • US4865959A
    • 1989-09-12
    • US210942
    • 1988-06-24
    • Kei SakanoueHidetoshi Kobayashi
    • Kei SakanoueHidetoshi Kobayashi
    • G03C7/34G03C7/26G03C7/305G03C7/32
    • G03C7/32G03C7/3225Y10S430/156
    • A silver halide color photographic material having on a support at least one silver halide emulsion layer, wherein the color photographic material contains at least one compound releasing a bleach accelerator upon reaction with the oxidation product of an aromatic primary amine color developing agent and at least one cyan dye-forming coupler represented by formula (A); ##STR1## wherein R.sub.1 represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group; or a substituted or unsubstituted heterocyclic group; X represents a hydrogen atom or a group capable of releasing upon a coupling reaction with the oxidation product of an aromatic primary amine color developing agent; and Ar represents an aromatic group having at least one substituent, wherein the sum of the .sigma..sub.m and .sigma..sub.p values of the substituent is at least 0.67.
    • 一种卤化银彩色照相材料,其在载体上具有至少一个卤化银乳剂层,其中彩色照相材料含有至少一种化合物,该化合物与芳族伯胺彩色显影剂的氧化产物和至少一种 由式(A)表示的青色染料成色剂; (A)其中R1表示取代或未取代的脂族基团,取代或未取代的芳族基团; 或取代或未取代的杂环基; X表示氢原子或与芳族伯胺显色剂的氧化产物偶联反应时能够释放的基团; 并且Ar表示具有至少一个取代基的芳族基团,其中取代基的σm和σp值之和至少为0.67。