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    • 5. 发明授权
    • Metal oxide coatings
    • 金属氧化物涂层
    • US08404877B2
    • 2013-03-26
    • US11930991
    • 2007-10-31
    • Sergei KniajanskiAharon Yakimov
    • Sergei KniajanskiAharon Yakimov
    • C08G77/06
    • G02B1/10C07F7/0836C07F7/0874C07F7/0889C07F9/005C09D1/00C09D5/24G02B1/105G02B27/0006Y10T428/31663
    • Compounds of formula I may be hydrolyzed to produce metal oxides wherein M is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu; X is O1/2 or OR; R is alkyl; R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14, and R15 are independently C1-C10 alkyl or phenyl; n is equal to the value of the oxidation state of M minus q; m and p are independently 0 or an integer from 1 to 5; and q is 0, 1, 2, or 4; with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu. Articles comprising at least one metal oxide are fabricated by coating a substrate with at least one compounds of formula I before hydrolyzing, and/or heating the compound at a temperature ranging from about 50° C. to about 450° C.
    • 式I化合物可以水解生成金属氧化物,其中M是Mg,Al,Ca,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Ga,Ge,As,Y, Nb,Mo,Tc,Ru,Rh,Pd,Cd,In,Sn,Sb,La,Hf,Ta,W,Re,Os,Ir,Pt,Hg,Tl,Pb,Bi,Ce,Pr, Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Th,U或Pu; X为O1 / 2或OR; R是烷基; R1,R2,R3,R4,R5,R6和R7独立地为H,烷氧基,C1-C10烷基,苯基或R10,R11,R12,R13,R14和R15独立地为C1-C10烷基或苯基; n等于M的氧化态减去q; m和p独立地为0或1至5的整数; q为0,1,2或4; 条件是当q为1时,X为OR; 当q为2时,X为O1 / 2,M为V,Cr,Mn,Fe,As,Nb,Mo,Tc,Ru,Sb,Ta,W,Re,Os,Ir,Pt,Bi,Th ,U或Pu; 当q为4时,X为O1 / 2,M为Cr,Mo,W,Ru,Re,Os,U或Pu。 包含至少一种金属氧化物的制品通过在至少一种式I化合物之前涂覆底物,然后在约50℃至约450℃的温度下水解和/或加热该化合物来制备。
    • 8. 发明授权
    • Metal oxide coatings
    • 金属氧化物涂层
    • US07652157B2
    • 2010-01-26
    • US11931039
    • 2007-10-31
    • Sergei KniajanskiAharon Yakimov
    • Sergei KniajanskiAharon Yakimov
    • C07F7/26
    • C07F7/0836C07F9/005
    • Compounds of formula I may be hydrolyzed to produce metal oxides wherein M is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu; X is O1/2 or OR; R is alkyl; R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14 and R15 are independently C1-C10 alkyl or phenyl; n is equal to the the value of the oxidation state of M minus q; m and p are independently 0 or an integer from 1 to 5; and q is 0, 1, 2, or 4; with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu. Articles comprising at least one metal oxide are fabricated by coating a substrate with at least one compounds of formula I before hydrolyzing, and/or heating the compound at a temperature ranging from about 50° C. to about 450° C.
    • 式I化合物可以水解生成金属氧化物,其中M是Mg,Al,Ca,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Ga,Ge,As,Y, Nb,Mo,Tc,Ru,Rh,Pd,Cd,In,Sn,Sb,La,Hf,Ta,W,Re,Os,Ir,Pt,Hg,Tl,Pb,Bi,Ce,Pr, Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Th,U或Pu; X为O1 / 2或OR; R是烷基; R1,R2,R3,R4,R5,R6和R7独立地为H,烷氧基,C1-C10烷基,苯基或R10,R11,R12,R13,R14和R15独立地为C1-C10烷基或苯基; n等于M的氧化态减去q值; m和p独立地为0或1至5的整数; q为0,1,2或4; 条件是当q为1时,X为OR; 当q为2时,X为O1 / 2,M为V,Cr,Mn,Fe,As,Nb,Mo,Tc,Ru,Sb,Ta,W,Re,Os,Ir,Pt,Bi,Th ,U或Pu; 当q为4时,X为O1 / 2,M为Cr,Mo,W,Ru,Re,Os,U或Pu。 包含至少一种金属氧化物的制品通过在至少一种式I化合物之前涂覆底物,然后在约50℃至约450℃的温度下水解和/或加热该化合物来制备。
    • 10. 发明申请
    • METAL OXIDE COATINGS
    • 金属氧化物涂层
    • US20080319212A1
    • 2008-12-25
    • US11931039
    • 2007-10-31
    • Sergei KniajanskiAharon Yakimov
    • Sergei KniajanskiAharon Yakimov
    • C07F7/02
    • C07F7/0836C07F9/005
    • Compounds of formula I may be hydrolyzed to produce metal oxides whereinM is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu;X is O1/2 or OR;R is alkyl;R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14 and R15 are independently C1-C10 alkyl or phenyl;n is equal to the the value of the oxidation state of M minus q;m and p are independently 0 or an integer from 1 to 5; andq is 0, 1, 2, or 4;with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu. Articles comprising at least one metal oxide are fabricated by coating a substrate with at least one compounds of formula I before hydrolyzing, and/or heating the compound at a temperature ranging from about 50° C. to about 450° C.
    • 式I化合物可以水解生成金属氧化物,其中M是Mg,Al,Ca,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Ga,Ge,As,Y, Nb,Mo,Tc,Ru,Rh,Pd,Cd,In,Sn,Sb,La,Hf,Ta,W,Re,Os,Ir,Pt,Hg,Tl,Pb,Bi,Ce,Pr, Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Th,U或Pu; X为O1 / 2或OR; R是烷基; R1,R2,R3,R4,R5,R6和R7独立地为H,烷氧基,C1-C10烷基,苯基或R10,R11,R12,R13,R14和R15独立地为C1-C10烷基或苯基; n等于M的氧化态减去q值; m和p独立地为0或1至5的整数; q为0,1,2或4; 条件是当q为1时,X为OR; 当q为2时,X为O1 / 2,M为V,Cr,Mn,Fe,As,Nb,Mo,Tc,Ru,Sb,Ta,W,Re,Os,Ir,Pt,Bi,Th ,U或Pu; 当q为4时,X为O1 / 2,M为Cr,Mo,W,Ru,Re,Os,U或Pu。 包含至少一种金属氧化物的制品通过在至少一种式I化合物之前涂覆底物,然后在约50℃至约450℃的温度下水解和/或加热该化合物来制备。