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1. 发明授权

US08476350B2 Triglyceride plasticizer and process of making 有权
标题翻译：甘油三酯增塑剂及其制备方法
公开(公告)号：US08476350B2
公开(公告)日：2013-07-02
申请号：US12653744
申请日：2009-12-17
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08L91/00 , C07C51/16
CPC分类号： C08L91/00 , C08K5/103 , Y10T428/139 , Y10T442/20 , C08L27/06 , C08L67/00 , C08L75/04 , C08L31/04 , C08L33/00
摘要： Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C10 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供组合物，制备方法和使用甘油三酯作为增塑剂的方法。甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 10醛，用氧和/或空气氧化成酸，回收所得酸，并用甘油进行酯化来制备，其中三酯的总碳数对于大于或等于45重量％的增塑剂，基团为20至25。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

2. 发明申请

US20100159177A1 Triglyceride plasticizer and process of making 有权
标题翻译：甘油三酯增塑剂及其制备方法
公开(公告)号：US20100159177A1
公开(公告)日：2010-06-24
申请号：US12653744
申请日：2009-12-17
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08L91/00 , C07C51/16 , C07C57/00 , B32B1/08 , B32B27/04 , A61M1/00
CPC分类号： C08L91/00 , C08K5/103 , Y10T428/139 , Y10T442/20 , C08L27/06 , C08L67/00 , C08L75/04 , C08L31/04 , C08L33/00
摘要： Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C10 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供组合物，制备方法和使用甘油三酯作为增塑剂的方法。甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 10醛，用氧和/或空气氧化成酸，回收所得酸，并用甘油进行酯化来制备，其中三酯的总碳数对于大于或等于45重量％的增塑剂，基团为20至25。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

3. 发明申请

US20090062475A1 Production of elastomeric functionalized olefin polymers 有权
标题翻译：弹性体官能化烯烃聚合物的生产
公开(公告)号：US20090062475A1
公开(公告)日：2009-03-05
申请号：US12231384
申请日：2008-09-02
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
IPC分类号： C08C19/02 , C08F232/00 , C08F22/30 , C08F4/42
CPC分类号： C08C19/02 , C08F4/80 , C08F232/00 , C08G61/08
摘要： In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.
摘要翻译：在制备官能化的聚链烯聚合物的方法中，至少一种包含具有至少一个与其键合的侧链烷基的单环烯烃的单体，其中所述侧基烷基具有至少两个碳原子并且被极性部分取代，所述极性部分被至少一个来自单环烯烃的碳原子在有效地实现单环烯烃的开环聚合的条件下与聚合催化剂接触并产生官能化的聚链烷醇。

4. 发明授权

US07285609B2 Olefin polymerization catalyst system useful for polar monomers 有权
标题翻译：烯烃聚合催化剂体系可用于极性单体
公开(公告)号：US07285609B2
公开(公告)日：2007-10-23
申请号：US10844683
申请日：2004-05-13
申请人： Lisa Saunders Baugh , Enock Berluche , Paul Veinbergs Hinkle , Francis Charles Rix , Donald Norman Schulz
发明人： Lisa Saunders Baugh , Enock Berluche , Paul Veinbergs Hinkle , Francis Charles Rix , Donald Norman Schulz
IPC分类号： C08F4/44 , B01J31/38
CPC分类号： C07F15/04 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , C08F232/08 , C08F2500/03 , C08F2500/09 , C08F2500/10 , C08F4/80 , C08F232/00 , C08F216/04 , C08F210/14 , C08F2500/05 , C08F4/7031 , C08F4/7022
摘要： This invention relates to a polymerization method comprising contacting at least one olefin monomer, at least one polar monomer, an optional activator, and a catalyst compound represented by the formula: wherein M is selected from groups 3-11 of the periodic table; L1 represents a formal anionic ligand, L2 represents a formal neutral ligand, a is an integer greater than or equal to 1; b is greater than or equal to 0; c is greater than or equal to 1, E is nitrogen or phosphorus, Ar0 is arene, R1-R4 are, each independently, selected from hydrogen, hydrocarbyl, substituted hydrocarbyl or functional group, provided however that R3 and R4 do not form a naphthyl ring, N is nitrogen and O is oxygen.
摘要翻译：本发明涉及聚合方法，其包括使至少一种烯烃单体，至少一种极性单体，任选的活化剂和由下式表示的催化剂化合物：其中M选自周期表的第3-11组; L 1表示正式的阴离子配体，L 2表示正式的中性配体，a是大于或等于1的整数; b大于或等于0; c大于或等于1，E是氮或磷，Ar 0是芳烃，R 1 -R 4是各自独立地其中R 3选自氢，烃基，取代的烃基或官能团，但是R 3和R 4不形成萘环，N为氮，O为氧。

5. 发明授权

US08519056B2 Blends of co-precipitated hydrogenated ethylene-dicyclpentadiene and elastomeric polymers to provide impact modified structural polyolefins 有权
标题翻译：共沉淀的氢化乙烯 - 二环戊二烯和弹性体聚合物的共混物以提供冲击改性的结构聚烯烃
公开(公告)号：US08519056B2
公开(公告)日：2013-08-27
申请号：US11809573
申请日：2007-06-01
申请人： Lisa Saunders Baugh , Enock Berluche
发明人： Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08L45/00 , C08L9/00 , C08F8/00
CPC分类号： C08F236/20 , C08F8/04 , C08L23/0823 , C08L23/16 , C08L23/26 , C08L2205/02 , C08F210/02 , C08L2666/06 , C08L2666/04
摘要： Disclosed is the preparation of compositions which are blends of certain types of hydrogenated ethylene-dicyclopentadiene (E/DCPD) copolymers in combination with elastomeric polymers. An E/DCPD copolymer and an elastomeric polymer are co-dissolved in a common liquid reaction medium which is then subjected to hydrogenation conditions. These hydrogenation conditions serve to hydrogenate in-situ at least a portion of the residual double bonds of the E/DCPD copolymer component and possibly also eliminate any residual unsaturation which might be present in the elastomeric polymers. This combination of materials which has been hydrogenated in-situ can then be co-precipitated to form a polymer composition which can be molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.
摘要翻译：公开了组合物的制备，其是某些类型的氢化乙烯 - 二环戊二烯（E / DCPD）共聚物与弹性体聚合物的组合的共混物。将E / DCPD共聚物和弹性体聚合物共溶于通常的液体反应介质中，然后将其进行氢化条件。这些氢化条件用于原位氢化E / DCPD共聚物组分的残余双键的至少一部分，并且还可以消除可能存在于弹性体聚合物中的任何残余不饱和度。然后可将这种原位氢化的材料的组合共沉淀形成聚合物组合物，该聚合物组合物可以模塑成具有改善的结构，热和机械性能并具有期望的耐冲击性的聚烯烃材料。

6. 发明授权

US08455598B2 Production of elastomeric functionalized olefin polymers 有权
公开(公告)号：US08455598B2
公开(公告)日：2013-06-04
申请号：US13596567
申请日：2012-08-28
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
IPC分类号： C08G61/08 , C08F8/04 , C08F4/80 , C07C255/31
CPC分类号： C08C19/02 , C08F4/80 , C08F232/00 , C08G61/08
摘要： In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.

7. 发明授权

US08263712B2 Production of elastomeric functionalized olefin polymers 有权
标题翻译：弹性体官能化烯烃聚合物的生产
公开(公告)号：US08263712B2
公开(公告)日：2012-09-11
申请号：US12231384
申请日：2008-09-02
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle
IPC分类号： C08F8/04 , C08G61/08 , C08F4/80 , C07C255/31
CPC分类号： C08C19/02 , C08F4/80 , C08F232/00 , C08G61/08
摘要： In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.
摘要翻译：在制备官能化的聚链烯聚合物的方法中，至少一种包含具有至少一个与其键合的侧链烷基的单环烯烃的单体，其中所述侧基烷基具有至少两个碳原子并且被极性部分取代，所述极性部分被至少一个来自单环烯烃的碳原子在有效地实现单环烯烃的开环聚合的条件下与聚合催化剂接触并产生官能化的聚链烷醇。

8. 发明申请

US20120071605A1 POLYMER COMPOSITIONS COMPRISING CYCLIC OLEFIN POLYMERS, POLYOLEFIN MODIFIERS AND NON-FUNCTIONALIZED PLASTICIZERS 有权
标题翻译：包含环烯烃聚合物，聚氧乙烯改性剂和非官能化塑料的聚合物组合物
公开(公告)号：US20120071605A1
公开(公告)日：2012-03-22
申请号：US12012380
申请日：2008-02-01
申请人： Lisa Saunders Baugh , Bryan R. Chapman , Enock Berluche
发明人： Lisa Saunders Baugh , Bryan R. Chapman , Enock Berluche
IPC分类号： C08L45/00 , C08L51/06 , C08L47/00
CPC分类号： C08L23/0823 , C08L23/16 , C08L53/00 , C08L2314/06 , C08L2666/24 , C08L2666/06
摘要： This invention relates to a polymer composition comprising a blend comprising: (a) greater than 30 wt (based upon the weight of the composition) of a cyclic olefin polymer having a Tg greater than 60° C. and having a Tm heat of fusion (ΔHf) of 40 J/g or less selected from the group consisting of: i) copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; ii) partially or completely hydrogenated copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; iii) metathesis copolymers comprising two or more cyclic olefins; iv) partially or completely hydrogenated metathesis copolymers comprising two or more cyclic olefins; v) metathesis homopolymers comprising cyclic olefins; vi) partially or completely hydrogenated metathesis homopolymers comprising cyclic olefins; and vii) mixtures thereof; (b) from 1 to 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier having a glass transition temperature of less than 0° C.; (c) from 0.1 to 50 wt % (based upon the weight of the composition) of a non-functionalized plasticizer having a kinematic viscosity at 100° C. of 3 to 3000 cSt, a viscosity index of 120 or more, a pour point of 0° C. or less and a flash point of 200° C. or more.
摘要翻译：本发明涉及一种包含共混物的聚合物组合物，其包含：（a）大于30重量％（基于组合物的重量）的Tg大于60℃并具有Tm熔化热的环状烯烃聚合物 40J / g或更低，选自：i）包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃的共聚物; ii）部分或完全氢化的共聚物，其包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃; iii）包含两个或更多个环烯烃的复分解共聚物; iv）包含两种或多种环烯烃的部分或完全氢化的复分解共聚物; v）包含环烯烃的复分解均聚物; vi）包含环状烯烃的部分或完全氢化的复分解均聚物; 和vii）其混合物; （b）1至50重量％（基于组合物的重量）的玻璃化转变温度低于0℃的无环烯烃聚合物改性剂; （c）0.1至50重量％（基于组合物的重量）的在100℃下的运动粘度为3至3000cSt，粘度指数为120或更大的非官能化增塑剂，倾点为0℃以下，闪点为200℃以上。

9. 发明授权

US07247687B2 Late transition metal catalysts for olefin polymerization and oligomerization 有权
标题翻译：用于烯烃聚合和低聚的后期过渡金属催化剂
公开(公告)号：US07247687B2
公开(公告)日：2007-07-24
申请号：US10517104
申请日：2003-07-17
申请人： Vladimir Kuzunich Cherkasov , Michael Paviovich Bubnov , Nikolay Olegovich Druzhkov , Valentina Nikolavena Glushakova , Irina Alexandrovna Teplova , Nina Aleksandrovna Skorodumova , Gleb Arsent′evich Abakumov , Cynthia A. Ballinger , Kevin R. Squire , Jo Ann Marie Canich , Enock Berluche , Lisa Saunders Baugh , Donald Norman Schulz , Baiyi Zhao
发明人： Vladimir Kuzunich Cherkasov , Michael Paviovich Bubnov , Nikolay Olegovich Druzhkov , Valentina Nikolavena Glushakova , Irina Alexandrovna Teplova , Nina Aleksandrovna Skorodumova , Gleb Arsent′evich Abakumov , Cynthia A. Ballinger , Kevin R. Squire , Jo Ann Marie Canich , Enock Berluche , Lisa Saunders Baugh , Donald Norman Schulz , Baiyi Zhao
IPC分类号： C07F15/00 , C08F4/70
CPC分类号： B01J31/0214 , B01J31/1805 , B01J31/1815 , B01J2231/12 , B01J2531/845 , B01J2531/847 , C07F15/0066 , C07F15/045 , C07F15/065 , C08F10/00 , C08F210/16 , C08F2410/03 , C08F4/025 , C08F210/06 , C08F2500/03 , C08F210/14 , C08F4/7037 , C08F4/7027 , C08F4/7006 , C08F4/52 , C08F4/7042 , C08F4/7004
摘要： This invention relates to a transition metal compound represented by the formula LMX wherein M is a Group 3 to 11 metal L is a bulky bidentate or tridentate neutral ligand that is bonded to M by two or three heteroatoms and at least one heteroatom is nitrogen; X is a substituted or unsubstituted catecholate ligand provided that the substituted catecholate ligand does not contain a 1,2-diketone functionality.
摘要翻译：本发明涉及由式LMX表示的过渡金属化合物，其中M为第3至11族金属，L为通过两个或三个杂原子与至少一个杂原子与氮键合至M的体积大的二齿或三齿中性配体; X是取代或未取代的儿茶酚酸酯配体，条件是取代的儿茶酚酸配体不含有1,2-二酮官能团。

10. 发明授权

US08815992B2 Tetracarboxylic ester plasticizers 有权
标题翻译：四羧酸酯增塑剂
公开(公告)号：US08815992B2
公开(公告)日：2014-08-26
申请号：US13085905
申请日：2011-04-13
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
IPC分类号： A61L15/62 , C08K5/12 , C07C69/34 , C07C69/74 , C08K5/11
CPC分类号： C07C69/34 , C07C69/74 , C07C2601/08 , C08K5/11 , C08K5/12
摘要： Tetraesters of a C4-C5 aliphatic tetracarboxylic acid and OXO-alcohols and plasticized compositions containing said tetraesters are provided.
摘要翻译：提供C4-C5脂族四羧酸和OXO-醇的四酯和含有所述四酯的增塑组合物。

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