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1. 发明申请

US20100249299A1 Process for making triglyceride plasticizer from crude glycerol 有权
标题翻译：从粗甘油制备甘油三酯增塑剂的方法
公开(公告)号：US20100249299A1
公开(公告)日：2010-09-30
申请号：US12661362
申请日：2010-03-16
申请人： Jihad Mohammed Dakka , Edmund J. Mozeleski , Lisa Saunders Baugh
发明人： Jihad Mohammed Dakka , Edmund J. Mozeleski , Lisa Saunders Baugh
IPC分类号： C08K5/11 , C07C67/48 , C07C69/52 , C08K5/12
CPC分类号： C08K5/0016 , C07C67/08 , C11C3/02 , C07C69/30
摘要： Provided are processes for making, and processes for using triglycerides as plasticizers. Mixed triglyceride plasticizers can be produced by recovery of linear or branched C4 to C13 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with a crude glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. The product selectivity obtained from esterifying with crude glycerol is comparable to that of esterifying with pure glycerol. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供了制备方法和使用甘油三酯作为增塑剂的方法。混合甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 13醛，用氧气和/或空气氧化成酸，回收所得酸，并用粗甘油进行酯化来制备，其中总碳数的三聚物组合物的增塑剂的含量为大于或等于45wt％的20至25。用粗甘油酯化获得的产物选择性与用纯甘油酯化的产物选择性相当。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

2. 发明授权

US08299281B2 Process for making triglyceride plasticizer from crude glycerol 有权
标题翻译：从粗甘油制备甘油三酯增塑剂的方法
公开(公告)号：US08299281B2
公开(公告)日：2012-10-30
申请号：US12661362
申请日：2010-03-16
申请人： Jihad Mohammed Dakka , Edmund J Mozeleski , Lisa Saunders Baugh
发明人： Jihad Mohammed Dakka , Edmund J Mozeleski , Lisa Saunders Baugh
IPC分类号： C09F7/02 , C07C51/16 , C07C51/235 , C07C67/48
CPC分类号： C08K5/0016 , C07C67/08 , C11C3/02 , C07C69/30
摘要： Provided are processes for making, and processes for using triglycerides as plasticizers. Mixed triglyceride plasticizers can be produced by recovery of linear or branched C4 to C13 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with a crude glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. The product selectivity obtained from esterifying with crude glycerol is comparable to that of esterifying with pure glycerol. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供了制备方法和使用甘油三酯作为增塑剂的方法。混合甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 13醛，用氧气和/或空气氧化成酸，回收所得酸，并用粗甘油进行酯化来制备，其中总碳数的三聚物组合物的增塑剂的含量为大于或等于45wt％的20至25。用粗甘油酯化获得的产物选择性与用纯甘油酯化的产物选择性相当。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

3. 发明申请

US20110184105A1 Phenylene Oxo-Diester Plasticizers and Methods of Making 审中-公开
标题翻译：苯氧基二酯增塑剂及其制备方法
公开(公告)号：US20110184105A1
公开(公告)日：2011-07-28
申请号：US12892680
申请日：2010-09-28
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Francisco Manuel Benitez , Catherine Anne Faler , Allen David Godwin , Jörg Friedrich Wilhelm Weber , Diana S. Smirnova
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Francisco Manuel Benitez , Catherine Anne Faler , Allen David Godwin , Jörg Friedrich Wilhelm Weber , Diana S. Smirnova
IPC分类号： C08K5/12 , C07C69/73 , C07C67/08 , C09K3/00
CPC分类号： C07C69/612 , C07C69/76
摘要： A process for making non-phthalate, 1,2-phenylene oxo-diester plasticizers for polymer compositions, by selectively hydrogenating naphthalene to form a partially hydrogenated naphthalene, oxygenating said partially hydrogenated naphthalene to form phenylene diacids, and esterifying said phenylene diacids with oxo-alcohols to form 1,2-phenylene oxo-diesters. Also a process for making phenylene oxo-diester plasticizers by selectively brominating xylenes to form bisbromomethylbenzene, catalytic carboalkoxylation of the bromo-compound to form phenylene diacetate, followed by transesterification to form the phenylene oxo-diester.
摘要翻译：通过选择性氢化萘以形成部分氢化的萘来制备用于聚合物组合物的非邻苯二甲酸酯，1,2-亚苯基氧代二酯增塑剂的方法，将所述部分氢化的萘氧化以形成亚苯基二酸，并用所述亚苯基二酸酯化所述亚苯基二酸，醇形成1,2-亚苯基氧代二酯。也是通过选择性溴化二甲苯以形成双溴甲苯制备亚苯基二氧代二酯增塑剂的方法，溴化合物的催化羰基烷氧基化形成亚苯基二乙酸酯，然后酯交换以形成亚苯基氧代二酯。

4. 发明申请

US20110165355A1 Process For Making Polyol Neoalkylester Plasticizers From Neo Acids 有权
标题翻译：从新酸制备多元醇新烷基酯增塑剂的方法
公开(公告)号：US20110165355A1
公开(公告)日：2011-07-07
申请号：US12880586
申请日：2010-09-13
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
IPC分类号： B32B1/08 , C08K5/04 , C08K5/10 , C07C55/22 , B32B5/02 , C07C51/10
CPC分类号： C07C67/38 , C08K5/103 , Y10T428/139 , Y10T442/20 , C07C69/30
摘要： Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供了组合物，制备方法和使用新烷基多元醇酯和甘油三酸酯作为增塑剂的方法。在一种形式中，新烷基酯甘油三酯增塑剂可以通过（i）干燥多元醇进料流来制备; （ii）在有效温度，压力和时间下在干燥的多元醇原料流中与干燥的多元醇原料流接触以形成新的烷基酯增塑剂流出物流，和（iii）纯化新烷基酯增塑剂流出物流以除去未反应的多元醇和未反应的新酸，形成新烷基酯增塑剂。这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。

5. 发明申请

US20110009548A1 OIL BASED POLYOLS OR DIACIDS ESTERIFIED WITH OXO-ACIDS OR OXO-ALCOHOLS FOR PRODUCING PLASTICIZERS 有权
标题翻译：用于生产聚合物的含氧基或异丙醇的基于油的多元醇或多元醇
公开(公告)号：US20110009548A1
公开(公告)日：2011-01-13
申请号：US12830606
申请日：2010-07-06
申请人： Jihad Mohammed DAKKA , Edmund Joseph Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
发明人： Jihad Mohammed DAKKA , Edmund Joseph Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
IPC分类号： C07C69/74 , C08K5/12 , C07C67/00
CPC分类号： C07C67/08 , C07C5/32 , C07C29/147 , C07C45/50 , C07C51/16 , C07C67/26 , C07C69/28 , C07C69/75 , C07C2601/14 , C07C2603/68 , C08K5/10 , C07C35/08 , C07C47/32 , C07C61/08
摘要： Oxo-diesters of cyclic olefins, methods of making them and their use as plasticizers in polymer compositions are disclosed.
摘要翻译：公开了环烯烃的氧代二酯，其制备方法及其作为增塑剂在聚合物组合物中的用途。

6. 发明授权

US08604114B2 Aromatic acylation with cyclic anhydride for plasticizer production 有权
标题翻译：用环状酸酐进行芳香族酰化，用于增塑剂生产
公开(公告)号：US08604114B2
公开(公告)日：2013-12-10
申请号：US12840715
申请日：2010-07-21
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Karla Schall Colle , Allen David Godwin , Diana S. Smirnova , Jörg Friedrich Wilhelm Weber , Stephen Zushma
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Karla Schall Colle , Allen David Godwin , Diana S. Smirnova , Jörg Friedrich Wilhelm Weber , Stephen Zushma
IPC分类号： C08G73/10 , C08K5/00 , C07C69/76
CPC分类号： C08K5/12 , C07C51/31 , C07C67/08 , C07C67/31 , C07C69/73 , C07C69/732 , C07C69/738 , C07C2602/10 , C08K5/10 , C07C59/84 , C07C59/86
摘要： Provided is a process for making non-phthalate plasticizers, by acylating an aromatic compound with a succinic anhydride to form a keto-acid, and then esterifying the keto-acid with C4-C13 OXO-alcohols to form a plasticizer compound. The aromatic rings of the aromatic compound may also be optionally hydrogenated.
摘要翻译：提供了制备非邻苯二甲酸酯增塑剂的方法，通过用琥珀酸酐酰化芳族化合物以形成酮酸，然后用C4-C13OXO-醇酯化酮酸以形成增塑剂化合物。芳族化合物的芳环也可以任选氢化。

7. 发明申请

US20110160371A1 AROMATIC ACYLATION WITH CYCLIC ANHYDRIDE FOR PLASTICIZER PRODUCTION 有权
标题翻译：用于增塑剂生产的环状非离子表面活性剂
公开(公告)号：US20110160371A1
公开(公告)日：2011-06-30
申请号：US12840715
申请日：2010-07-21
申请人： Jihad Mohammed DAKKA , Edmund John Mozeleski , Lisa Saunders Baugh , Karla Schall Colle , Allen David Godwin , Diana S. Smimova , Jorg Friedrich Wilhelm Weber , Stephen Zushma
发明人： Jihad Mohammed DAKKA , Edmund John Mozeleski , Lisa Saunders Baugh , Karla Schall Colle , Allen David Godwin , Diana S. Smimova , Jorg Friedrich Wilhelm Weber , Stephen Zushma
IPC分类号： C08K5/07 , C07C69/616 , C07C69/612
CPC分类号： C08K5/12 , C07C51/31 , C07C67/08 , C07C67/31 , C07C69/73 , C07C69/732 , C07C69/738 , C07C2602/10 , C08K5/10 , C07C59/84 , C07C59/86
摘要： Provided is a process for making non-phthalate plasticizers, by acylating an aromatic compound with a succinic anhydride to form a keto-acid, and then esterifying the keto-acid with C4-C13 OXO-alcohols to form a plasticizer compound. The aromatic rings of the aromatic compound may also be optionally hydrogenated.
摘要翻译：提供了制备非邻苯二甲酸酯增塑剂的方法，通过用琥珀酸酐酰化芳族化合物以形成酮酸，然后用C4-C13OXO-醇酯化酮酸以形成增塑剂化合物。芳族化合物的芳环也可以任选氢化。

8. 发明授权

US08476350B2 Triglyceride plasticizer and process of making 有权
标题翻译：甘油三酯增塑剂及其制备方法
公开(公告)号：US08476350B2
公开(公告)日：2013-07-02
申请号：US12653744
申请日：2009-12-17
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08L91/00 , C07C51/16
CPC分类号： C08L91/00 , C08K5/103 , Y10T428/139 , Y10T442/20 , C08L27/06 , C08L67/00 , C08L75/04 , C08L31/04 , C08L33/00
摘要： Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C10 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供组合物，制备方法和使用甘油三酯作为增塑剂的方法。甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 10醛，用氧和/或空气氧化成酸，回收所得酸，并用甘油进行酯化来制备，其中三酯的总碳数对于大于或等于45重量％的增塑剂，基团为20至25。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

9. 发明授权

US08329795B2 Oil based polyols or diacids esterified with oxo-acids or oxo-alcohols for producing plasticizers 有权
标题翻译：用含氧酸或羰基醇酯化的油基多元醇或二酸用于生产增塑剂
公开(公告)号：US08329795B2
公开(公告)日：2012-12-11
申请号：US12830606
申请日：2010-07-06
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
IPC分类号： C08K5/00
CPC分类号： C07C67/08 , C07C5/32 , C07C29/147 , C07C45/50 , C07C51/16 , C07C67/26 , C07C69/28 , C07C69/75 , C07C2601/14 , C07C2603/68 , C08K5/10 , C07C35/08 , C07C47/32 , C07C61/08
摘要： Oxo-diesters of cyclic olefins, methods of making them and their use as plasticizers in polymer compositions are disclosed.
摘要翻译：公开了环烯烃的氧代二酯，其制备方法及其作为增塑剂在聚合物组合物中的用途。

10. 发明申请

US20120035308A1 METHODS OF MAKING 6-HYDROXYHEXANOPHENONE AND 5-BENZOYLPENTANOIC ACID AND MONO OR DIESTERS THEREOF 审中-公开
标题翻译：制备6-羟基六氢呋喃酮和5-苯甲酰基戊酸及其单体或二氧化钛的方法
公开(公告)号：US20120035308A1
公开(公告)日：2012-02-09
申请号：US13197253
申请日：2011-08-03
申请人： Kun Wang , Jihad Mohammed Dakka , Edmund John Mozeleski , Francisco Manuel Benitez , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova , Stephen Zushma
发明人： Kun Wang , Jihad Mohammed Dakka , Edmund John Mozeleski , Francisco Manuel Benitez , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova , Stephen Zushma
IPC分类号： C08K5/12 , C07C45/28 , C08K5/101 , C07C67/40 , C07C67/08 , C07C69/612 , C07C69/716
CPC分类号： C07C45/53 , C07C51/235 , C07C67/08 , C07C67/29 , C07C67/31 , C07C69/24 , C07C69/738 , C07C407/00 , C07C2601/14 , C08K5/10 , C07C49/82 , C07C409/14 , C07C59/84 , C07C69/732 , C07C69/73 , C07C69/28
摘要： Mono- or diester plasticizers of the formula: wherein A is either —OC(O)R′ or ═O, and X is either —COC(O)R or —C(O)OR, and R and R′ are C3 to C13 alkyl, which are the same or different, formed from cyclohexylbenzene and processes of making them.
摘要翻译：单或二酯增塑剂，其通式为：其中A为-OC（O）R'或= O，X为-COC（O）R或-C（O）OR，R和R'为C 3〜 C13烷基，它们是相同或不同的，由环己基苯形成及其制备方法。

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