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1. 发明授权

US5504256A Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates (LAW229) 失效
标题翻译：通过多核过渡金属聚集体催化生产芳基烷基氢过氧化物（LAW229）
公开(公告)号：US5504256A
公开(公告)日：1996-04-02
申请号：US402077
申请日：1995-03-10
申请人： Jeffrey E. Bond , Sergiu M. Gorun , George W. Schriver , Robert T. Stibrany , Thomas H. Vanderspurt
发明人： Jeffrey E. Bond , Sergiu M. Gorun , George W. Schriver , Robert T. Stibrany , Thomas H. Vanderspurt
IPC分类号： B01J31/04 , B01J31/16 , B01J31/18 , B01J31/22 , C07C39/04 , C07C45/53 , C07C409/08 , C07C409/10 , C07C409/14
CPC分类号： C07C409/14 , B01J31/1805 , B01J31/2239 , C07C39/04 , C07C407/00 , C07C409/08 , C07C409/10 , C07C45/53 , B01J2231/70 , B01J2531/0216 , B01J2531/0258 , B01J2531/16 , B01J2531/26 , B01J2531/32 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2101/14 , C07C2101/16 , Y02P20/52 , Y02P20/582
摘要： A method is provided for preparing organic hydroperoxides by oxidizing aryl alkyl hydrocarbons having a benzylic hydrogen with an oxygen containing gas using as a catalyst an oxo (hydroxo) bridged tetranuclear metal complex having a mixed metal core, one metal of the core being a divalent metal selected from Zn, Cu Fe, Co, Ni, Mn or mixtures thereof and another metal being a trivalent metal selected from In, Fe, Mn, Ga, and Al.
摘要翻译：提供了通过用具有含氧气体的芳基烷基烃与含氧气体氧化的方法来制备有机氢过氧化物的方法，所述方法使用具有混合金属核的氧代（羟基）桥连四核金属络合物作为催化剂，所述芯的一种金属是二价金属选自Zn，CuFe，Co，Ni，Mn或其混合物，另一种金属是选自In，Fe，Mn，Ga和Al的三价金属。

2. 发明授权

US5183945A Catalytic production of aryl alkyl hydroperoxides by manganese complexes 失效
标题翻译：通过锰络合物催化生产芳基烷基氢过氧化物
公开(公告)号：US5183945A
公开(公告)日：1993-02-02
申请号：US794096
申请日：1991-11-18
申请人： Robert T. Stibrany , Sergiu M. Gorun
发明人： Robert T. Stibrany , Sergiu M. Gorun
IPC分类号： B01J31/12 , C07B61/00 , C07C407/00 , C07C409/08 , C07C409/10
CPC分类号： C07C409/10 , C07C407/00 , C07C409/08 , Y02P20/582
摘要： This invention relates to a process for preparing organic hydroperoxides by selectively oxidizing aryl alkyl hydrocarbons to their corresponding organic hydroperoxides using a catalyst certain tetranuclear manganese complexes. The process is carried out without appreciable decomposition by the catalyst of the resulting organic hydroperoxides, and without oxidation by the catalyst of other hydrocarbons present in the starting mixture.The process of the present invention is useful for producing organic hydroperoxides, which themselves are useful as starting materials for a number of commercial reactions, for example, phenol and acetone production.

3. 发明授权

US5041575A Manganese oligomer containing main group elements 失效
标题翻译：含有主要元素的锰低聚物
公开(公告)号：US5041575A
公开(公告)日：1991-08-20
申请号：US580413
申请日：1990-09-10
申请人： Sergiu M. Gorun , Robert T. Stibrany
发明人： Sergiu M. Gorun , Robert T. Stibrany
IPC分类号： C07F13/00
CPC分类号： C07F13/005
摘要： The present invention is based on the discovery that the previously disclosed tetranuclear manganese compounds are converted into a hexadeca manganese aggregate and a core of 4 barium, 2 sodium and 1 chloride ion. Stated differently, one embodiment of the present invention comprises a composition of matter having the formula:[Mn.sub.16 Ba.sub.8 Na.sub.2 ClO.sub.4 (OH).sub.4 (CO.sub.3).sub.4 (H.sub.2 O).sub.22 L.sub.8 ].multidot.xH.sub.2 Owherein x is an integer ranging from 0 to about 32 and L is a ligand having the formula: ##STR1## Another embodiment of the present invention comprises a method of preparing the novel compounds of the present invention, which method comprises preparing an aqueous solution containing sodium chloride, a source of carbonate ion selected from sodium carbonate, sodium bicarbonate and mixtures thereof and a compound having the formula:Ba.sub.2 [Mn.sub.4 (O)(OH)(O.sub.2 CR).sub.2 L.sub.2 ]wherein R is hydrogen or a hydrocarbyl group and L is a ligand having formula I set forth above, and thereafter allowing the reaction mixture to stand for a time sufficient for a compound having the formula:[Mn.sub.16 Ba.sub.8 Na.sub.2 ClO.sub.4 (OH).sub.4 (CO.sub.3).sub.4 (H.sub.2 O).sub.22 L.sub.8 ].multidot.xH.sub.2 Oto form.

4. 发明授权

US5099045A Manganese oligomer containing main group elements 失效
标题翻译：含有主要组分元素的马来西亚低分子
公开(公告)号：US5099045A
公开(公告)日：1992-03-24
申请号：US698046
申请日：1990-05-10
申请人： Sergiu M. Gorun , Robert T. Stibrany
发明人： Sergiu M. Gorun , Robert T. Stibrany
IPC分类号： C07F13/00
CPC分类号： C07F13/005
摘要： One embodiment of the present invention is based on the discovery of another hexadecanuclear manganese aggregate having a core of 6 barium ions surrounding a carbonate ion. Stated differently, one embodiment of the present invention comprises a composition of matter having the formula:[Mn.sub.16 Ba.sub.10 O.sub.4 (OH).sub.4 (CO.sub.3).sub.5 L.sub.8 ].xH.sub.2 Owherein x is an integer ranging from about 0 to about 120 and L is a ligand.Another embodiment of the present invention comprises a method of preparing the novel compounds of the present invention, which method comprises preparing a chloride free aqueous solution containing a source of carbonate ion selected from sodium carbonate, CO.sub.2 and mixtures thereof and a compound having the formula:Ba.sub.2 [Mn.sub.4 (O)(OH)(O.sub.2 CR).sub.2 L.sub.2 ].xH.sub.2 Owherein R is hydrogen or a hydrocarbyl group, x is an integer ranging from 0 to about 30, and L is a ligand having formula I set forth above, and thereafter allowing the reaction mixture to stand for a time sufficient for a compound having the formula:[Mn.sub.16 Ba.sub.10 O.sub.4 (OH).sub.4 (CO.sub.3).sub.5 L.sub.8 ].xH.sub.2 Oto form.The compounds of the present invention have magnetic properties rendering them particularly suitable for use in magnetic thermometry and magnetic fluids.
摘要翻译：本发明的一个实施方案是基于碳酸根离子周围具有6个钡离子核心的另一个十六碳核锰骨料的发现。换句话说，本发明的一个实施方案包括具有下式的物质组合物：[Mn16Ba10O4（OH）4（CO3）5L8]·xH2O其中x为约0至约120的整数，L为配体。本发明的另一个实施方案包括制备本发明的新化合物的方法，该方法包括制备含有选自碳酸钠，CO 2及其混合物的碳酸根离子源的无氯化物水溶液和具有下式的化合物： Ba2 [Mn4（O）（OH）（O2CR）2L2]·xH2O其中R为氢或烃基，x为0至约30的整数，L为上述式I的配体，使反应混合物放置足够的时间，使其具有下式的化合物：[Mn16Ba10O4（OH）4（CO3）5L8]·xH2O形成。本发明的化合物具有磁性，使得它们特别适用于磁测温和磁性流体。

5. 发明授权

US5627164A Pyrazolyl borates complexes-(LAW294) 失效
标题翻译：吡唑基硼酸盐络合物 - （LAW294）
公开(公告)号：US5627164A
公开(公告)日：1997-05-06
申请号：US489860
申请日：1995-06-13
申请人： Sergiu M. Gorun , Robert T. Stibrany
发明人： Sergiu M. Gorun , Robert T. Stibrany
IPC分类号： C07F5/02 , C07F13/00 , C07F15/06 , A61K31/41
CPC分类号： C07F5/022 , C07F13/005 , C07F15/065
摘要： Briefly stated, the present invention comprises a composition of matter having the formula M.sub.x L.sub.y P.sub.z.nQ where M is a metal, P is a counterion, x, y, and z are integers, Q is a solvent, n is a numerical value of from 0 to about 12, and L is either a tris or a bis substituted pyrazolyl borate anion having the structural formula: ##STR1##
摘要翻译：简言之，本发明包括具有式MxLyPz.nQ的物质组合物，其中M是金属，P是抗衡离子，x，y和z是整数，Q是溶剂，n是0的数值至约12，L是具有以下结构式的三取代或双取代的吡唑基硼酸根阴离子：

6. 发明授权

US5025101A Novel tetranuclear manganese complexes 失效
标题翻译：新型四核锰络合物
公开(公告)号：US5025101A
公开(公告)日：1991-06-18
申请号：US541699
申请日：1990-06-21
申请人： Sergiu M. Gorun , Robert T. Stibrany
发明人： Sergiu M. Gorun , Robert T. Stibrany
IPC分类号： C07F13/00 , C11D7/54
CPC分类号： C07F13/005
摘要： Briefly stated, the present invention comprises a composition of matter having the formula:M.sub.2 [Mn.sub.4 (O) (OH) (O.sub.2 CR).sub.2 L.sub.2 ]wherein M is an alkali earth metal selected from magnesium, calcium, strontium, barium or mixtures thereof, R is hydrogen or a hydrocarbyl group, and L is a ligand having the formula: ##STR1## The present invention also encompasses methods for preparing these novel compounds.
摘要翻译：简言之，本发明包括具有下式的物质组成：M2 [Mn4（O）（OH）（O2CR）2L2]其中M是选自镁，钙，锶，钡或其混合物的碱土金属，R 是氢或烃基，L是具有下式的配体：本发明还包括制备这些新化合物的方法。

7. 发明授权

US06642327B2 Late transition metal complexes, their use as catalysts and polymers therefrom 失效
公开(公告)号：US06642327B2
公开(公告)日：2003-11-04
申请号：US10245101
申请日：2002-09-17
申请人： Robert T. Stibrany , Smita Kacker
发明人： Robert T. Stibrany , Smita Kacker
IPC分类号： C08F426
CPC分类号： C08F10/00 , B01J23/72 , B01J31/143 , B01J31/1805 , B01J31/1825 , B01J2531/16 , B01J2531/17 , B01J2531/18 , C07F1/005 , C07F1/08 , C08F10/02 , C08F110/02 , C08F210/02 , C08F220/10 , C08F4/54 , C08F4/44 , C08F4/50 , C08F220/12
摘要： The invention provides a novel metal complex which, when used with an activating cocatalyst, provides a novel catalyst composition. The invention also provides a polymerization method which utilizes the catalyst composition to produce polymers and copolymers containing polar monomer groups. More specifically, the invention comprises a composition comprising the formula LMXZn wherein X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert. M is selected from the group consisting of Cu, Ag, and Au. L is a nitrogen-containing bidentate ligand having more than two nitrogen atoms. Z is a neutral coordinating ligand and n equals 0, 1, or 2.

8. 发明授权

US06506859B1 Polymerization using late transition metal catalyst complexes formed in situ 失效
标题翻译：使用晚期形成的过渡金属催化剂复合物进行聚合
公开(公告)号：US06506859B1
公开(公告)日：2003-01-14
申请号：US09642487
申请日：2000-08-18
申请人： Abhimanyu O. Patil , Robert T. Stibrany , Stephen Zushma , Enock Berluche , Donald N. Schulz
发明人： Abhimanyu O. Patil , Robert T. Stibrany , Stephen Zushma , Enock Berluche , Donald N. Schulz
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F110/02 , C08F210/02 , C08F4/54 , C08F2500/03 , C08F220/12
摘要： The invention is directed towards the formation of polymers and copolymers using late transition metal polymerization catalyst complexes which are formed in situ. In the first process step of the instant invention, a composition having the formula MXZn is simultaneously contacted with a ligand and an activating cocatalyst. Referring to the formula, M is selected from the group consisting of Cu, Ag, and Au; X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; Z is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, a neutral coordinating ligand, and any other moiety into which a monomer can insert; n equals 0, 1 or 2. In the second process step of the instant invention, olefinic monomers are contacted with the activated catalyst composition under polymerization conditions.
摘要翻译：本发明涉及使用在原位形成的后过渡金属聚合催化剂络合物形成聚合物和共聚物。在本发明的第一工艺步骤中，具有式MXZn的组合物与配体和活化助催化剂同时接触。参考式，M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃和单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃，中性配位配体和单体可插入的任何其它部分; n等于0,1或2.在本发明的第二工艺步骤中，烯烃单体在聚合条件下与活化的催化剂组合物接触。

9. 发明授权

US6037297A Catalyst complexes and polymers therefrom 失效
标题翻译：催化剂络合物和聚合物
公开(公告)号：US6037297A
公开(公告)日：2000-03-14
申请号：US212035
申请日：1998-12-15
申请人： Robert T. Stibrany , Donald N. Schulz , Smita Kacker , Abhimanyu O. Patil
发明人： Robert T. Stibrany , Donald N. Schulz , Smita Kacker , Abhimanyu O. Patil
IPC分类号： B01J31/14 , B01J31/18 , C07F1/08 , C08F4/44 , C08F4/52 , C08F4/54 , C08F4/602 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , B01J31/00
CPC分类号： C08F210/02 , B01J31/143 , B01J31/1815 , B01J31/183 , C07F1/08 , C08F10/00 , C08F220/18 , C08F4/52 , C08F4/54 , B01J2231/122 , B01J2231/20 , B01J2531/16 , B01J2531/17 , B01J2531/18 , C08F110/02 , C08F210/16
摘要： The invention is directed towards a metal complex having the formula LMX.sub.1 X.sub.2. L is a bidentate nitrogen-containing ligand with more than two nitrogen atoms. M is copper, silver, or gold. X.sub.1 and X.sub.2 are independently selected from the group consisting of halogens, C.sub.1 through C.sub.12 straight chain, branched, or cycloalkyl or aryl, C.sub.1 through C.sub.12 straight chain, branched, or cycloalkoxy, hydride, triflate, trifluoroacetate, trisperfluorotetraphenylborate, and tetrafluoroborate. Such metal complexes have a tetrahedral or pseudo-tetrahedral structure. The invention relates to a catalyst composition of the reaction product of the metal complex and an activating cocatalyst. The invention is also directed towards a method for forming polymers and copolymers using such catalyst compositions, especially copolymers having segments formed from olefinic monomers and monomers having at least one hydrocarbyl polar functional group.
摘要翻译：本发明涉及具有式LMX1X2的金属络合物。 L是具有两个以上氮原子的双齿含氮配体。 M是铜，银或金。 X1和X2独立地选自卤素，C1至C12直链，支链或环烷基或芳基，C1至C12直链，支链或环烷氧基，氢化物，三氟甲磺酸酯，三氟乙酸酯，三全氟四硼酸盐和四氟硼酸盐。这种金属络合物具有四面体或假四面体结构。本发明涉及金属络合物和活化助催化剂的反应产物的催化剂组合物。本发明还涉及使用这种催化剂组合物形成聚合物和共聚物的方法，特别是具有由烯属单体形成的链段和具有至少一个烃基极性官能团的单体的共聚物。

10. 发明授权

US07498287B2 Chromium complexes and their use in olefin polymerization 失效
标题翻译：铬络合物及其在烯烃聚合中的应用
公开(公告)号：US07498287B2
公开(公告)日：2009-03-03
申请号：US11904056
申请日：2007-09-25
申请人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
发明人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
IPC分类号： C08F4/69
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful polymerizing olefinic monomers.
摘要翻译：具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数，Y 是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。当与活化助催化剂组合时，有用的是使烯烃单体聚合。

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