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1. 发明授权

US08039660B2 Method of producing nitrile compounds 失效
标题翻译：腈化合物的制备方法
公开(公告)号：US08039660B2
公开(公告)日：2011-10-18
申请号：US12244233
申请日：2008-10-02
申请人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
发明人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
IPC分类号： C07C253/10 , C07C255/03
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ε-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.
摘要翻译：本发明涉及通过与氰化氢反应从不饱和有机化合物制备腈化合物。更具体地涉及用于合成己二腈的腈化合物的制备，其是主要化学化合物如六亚甲基二胺和ε-己内酰胺的制造中的重要化学中间体。本发明提供一种制备包含至少一个腈官能团的有机化合物的方法，该方法是通过在氰化氢与包含至少一个烯属不饱和键的有机化合物之间进行氢氰化反应。该反应在包含选自镍，铂和钯的金属元素和有机磷配体的催化体系的存在下进行，所述反应介质另外包含处于液态的离子液体，至少在进行氢化反应。

2. 发明申请

US20090247780A1 METHOD OF PRODUCING NITRILE COMPOUNDS 失效
标题翻译：生产氮化合物的方法
公开(公告)号：US20090247780A1
公开(公告)日：2009-10-01
申请号：US12244233
申请日：2008-10-02
申请人： Jean-Marie BASSET , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
发明人： Jean-Marie BASSET , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
IPC分类号： C07C253/10
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ε-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.
摘要翻译：本发明涉及通过与氰化氢反应从不饱和有机化合物制备腈化合物。更具体地涉及用于合成己二腈的腈化合物的制备，其是主要化学化合物如六亚甲基二胺和ε-己内酰胺的制造中的重要化学中间体。本发明提供一种制备包含至少一个腈官能团的有机化合物的方法，该方法是通过在氰化氢和包含至少一个烯属不饱和键的有机化合物之间进行氢氰化反应。该反应在包含选自镍，铂和钯的金属元素和有机磷配体的催化体系的存在下进行，所述反应介质另外包含处于液态的离子液体，至少在进行氢化反应。

3. 发明授权

US07105696B2 Method for making nitrile compounds from ethylenically unsaturated compounds 有权
标题翻译：由烯键式不饱和化合物制备腈化合物的方法
公开(公告)号：US07105696B2
公开(公告)日：2006-09-12
申请号：US10250477
申请日：2001-12-21
申请人： Paolo Burattin , Alex Chamard , Jean-Christophe Galland
发明人： Paolo Burattin , Alex Chamard , Jean-Christophe Galland
IPC分类号： C07C253/00
CPC分类号： C07C253/10 , C07C255/04
摘要： The invention concerns a method for hydrocyanation of ethylenically unsaturated organic compounds comprising at least a nitrile function. The invention provides a method for hydrocyanation of an ethylenically unsaturated hydrocarbon compound by reacting in liquid medium the hydrogen cyanide in the presence of a catalyst comprising a metal element selected among transition metals and an organophosphorous ligand, characterised in that the organophosphorous ligand is a furylphosphine. The invention is in particular useful for synthesizing adiponitrile from butadiene.
摘要翻译：本发明涉及一种含有至少一个腈官能团的烯属不饱和有机化合物的氢氰化方法。本发明提供了一种通过在液体介质中在含有选自过渡金属和有机磷配体的金属元素的催化剂存在下，使氰化氢反应的方法，其特征在于有机磷配体是呋喃基膦。本发明特别适用于从丁二烯合成己二腈。

4. 发明授权

US06590100B2 Process for preparing a polyaromatic compound 失效
标题翻译：制备多芳族化合物的方法
公开(公告)号：US06590100B2
公开(公告)日：2003-07-08
申请号：US10146263
申请日：2002-05-15
申请人： Jean-Christophe Galland , Monique Savignac , Jean-Pierre Genet
发明人： Jean-Christophe Galland , Monique Savignac , Jean-Pierre Genet
IPC分类号： C07F502
CPC分类号： C07C17/263 , C07C1/321 , C07C45/68 , C07C213/08 , C07C221/00 , C07D333/06 , C07C15/00 , C07C225/22
摘要： The present invention provides a process for preparing a polyaromatic compound comprising at least one sequence of two aromatic rings. The process of the invention, which consists in reacting an aromatic compound bearing a leaving group and an arylboronic acid and/or its derivatives in the presence of a base and an effective amount of a nickel catalyst, is characterized in that the reaction is conducted in a reaction solvent which is water optionally in a mixture with an organic solvent and in the presence of an effective amount of a catalyst based on nickel with at least one water-soluble phosphine ligand.
摘要翻译：本发明提供了一种制备包含至少一个两个芳香环序列的多芳族化合物的方法。本发明的方法包括使带有离去基团的芳族化合物与芳基硼酸和/或其衍生物在存在下反应的碱和有效量的镍催化剂的特征在于反应在反应溶剂中进行，反应溶剂是任选与有机溶剂的混合物的水，并且在有效量的基于镍的催化剂存在下，至少一种水溶性膦配体。

5. 发明授权

US07531682B2 Method for making nitrile compounds from ethylenically unsaturated compounds 失效
标题翻译：由烯键式不饱和化合物制备腈化合物的方法
公开(公告)号：US07531682B2
公开(公告)日：2009-05-12
申请号：US10521324
申请日：2003-07-11
申请人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
发明人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
IPC分类号： C07C253/10 , C07F9/02
CPC分类号： C07F9/65746 , B01J31/1608 , B01J31/185 , B01J2231/322 , B01J2231/52 , B01J2531/0266 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/26 , B01J2531/27 , B01J2531/28 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2540/10 , B01J2540/30 , B01J2540/34 , B01J2540/527 , C07C253/10 , C07C253/30 , C07F9/1412 , C07F9/145 , C07F9/5325 , C07F9/58 , C07F9/65515 , C07F9/65517 , C07F9/65522 , C07C255/04 , C07C255/07
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译：本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。

6. 发明授权

US07442825B2 Making nitrile compounds from ethylenically unsaturated compounds 有权
标题翻译：由烯属不饱和化合物制备腈化合物
公开(公告)号：US07442825B2
公开(公告)日：2008-10-28
申请号：US10521187
申请日：2003-07-11
申请人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
发明人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
IPC分类号： C07C253/10
CPC分类号： C07F9/2479 , C07C253/10 , C07C253/30 , C07F9/1415 , C07F9/145 , C07F9/2466 , C07F9/2475 , C07F9/58 , C07F9/65517 , C07F9/657154 , C07F9/65746 , C07C255/04 , C07C255/07
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译：本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。

7. 发明授权

US07485741B2 Method of producing nitrile compounds from ethylenically-unsaturated compounds 有权
标题翻译：由烯属不饱和化合物制备腈化合物的方法
公开(公告)号：US07485741B2
公开(公告)日：2009-02-03
申请号：US10537260
申请日：2003-11-25
申请人： Damien Bourgeois , Jean-Christophe Galland , Blaise Didillon , Philippe Marion
发明人： Damien Bourgeois , Jean-Christophe Galland , Blaise Didillon , Philippe Marion
IPC分类号： C07C253/00
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.
摘要翻译：本发明涉及一种在含有选自过渡金属和有机磷配体的金属元素的催化剂存在下，在液体介质中与氰化氢反应，使含有至少一个烯属不饱和基团的烃类化合物氢氰化的方法，其特征在于：有机磷配体是单齿有机磷化合物。本发明特别适用于从丁二烯合成己二腈。

8. 发明授权

US07253298B2 Process for preparing nitrile compounds from ethylenically unsaturated compounds 有权
标题翻译：由烯属不饱和化合物制备腈化合物的方法
公开(公告)号：US07253298B2
公开(公告)日：2007-08-07
申请号：US11166595
申请日：2005-06-24
申请人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
发明人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
IPC分类号： C07C253/10 , C07F9/02
CPC分类号： C07C253/10 , B01J31/185 , B01J31/38 , B01J2231/322 , B01J2531/847 , C07C255/04
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译：本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。

9. 发明申请

US20060128980A1 Method for making nitrile compounds from ethylenically unsaturated compounds 失效
公开(公告)号：US20060128980A1
公开(公告)日：2006-06-15
申请号：US10521324
申请日：2003-07-11
申请人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
发明人： Jean-Christophe Galland , Blaise Didillon , Philippe Marion , Damien Bourgeois
IPC分类号： C07C253/10
CPC分类号： C07F9/65746 , B01J31/1608 , B01J31/185 , B01J2231/322 , B01J2231/52 , B01J2531/0266 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/26 , B01J2531/27 , B01J2531/28 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2540/10 , B01J2540/30 , B01J2540/34 , B01J2540/527 , C07C253/10 , C07C253/30 , C07F9/1412 , C07F9/145 , C07F9/5325 , C07F9/58 , C07F9/65515 , C07F9/65517 , C07F9/65522 , C07C255/04 , C07C255/07
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.

10. 发明授权

US07884225B2 Process for the preparation of halogenoalkyldialkyl chlorosilane 失效
标题翻译：卤代烷基二烷基氯硅烷的制备方法
公开(公告)号：US07884225B2
公开(公告)日：2011-02-08
申请号：US12173968
申请日：2008-07-16
申请人： Nathalie Guennouni , Jean-Christophe Galland
发明人： Nathalie Guennouni , Jean-Christophe Galland
IPC分类号： C07F7/04
CPC分类号： C07F7/14
摘要： The present invention relates to a process for the preparation of 3-chloropropyldimethylchlorosilane by hydrosilylation reaction in a reaction medium comprising dimethylhydrochlorosilane and allyl chloride, in the presence of a catalytically effective amount of di-μ-chlorobis(η-1,5-cyclooctadiene)diiridium, the said process being characterized in that at least one auxiliary in the free or supported state selected from the group of compounds consisting of: (i) ketones, (ii) ethers, (iii) quinones, (iv) anhydrides, (v) unsaturated hydrocarbon compounds (UHC) having an aromatic nature and/or comprising at least one C═C double bond and/or at least one C≡C triple bond, it being possible for these unsaturated bonds to be conjugated or nonconjugated, the said UHCs being linear or cyclic (mono- or polycyclic), having from 4 to 30 carbon atoms, having from 1 to 8 ethylenic and/or acetylenic unsaturations and optionally comprising one or more heteroatoms, (vi) and their mixtures, is added to the reaction medium, with the condition according to which, when the auxiliary comprises one or more UHCs as defined above, then this (these) UHC(s) is (are) mixed with at least one other auxiliary other than a UHC.
摘要翻译：本发明涉及通过氢化硅烷化反应在包含二甲基氢氯硅烷和烯丙基氯的反应介质中，在催化有效量的二μ-氯双（e-g -1 -1,5-环辛二烯）存在下制备3-氯丙基二甲基氯硅烷的方法）二铱，所述方法的特征在于，游离或负载状态的至少一种辅助剂选自由以下组成的化合物组：（i）酮，（ii）醚，（iii）醌，（iv）酸酐， v）具有芳族性质和/或包含至少一个C = C双键和/或至少一个C≡C三键的不饱和烃化合物（UHC），这些不饱和键可能是共轭或非共轭的，所述UHC为具有4至30个碳原子的直链或环状（单环或多环），具有1至8个烯属和/或炔属不饱和基团，并且任选地包含一个或多个杂原子，（vi）及其混合物，其为ad 根据这样的条件，当辅助物质包含如上定义的一种或多种UHC时，则（这些）UHC与至少一种除了UHC之外的其它辅助剂混合。

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