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1. 发明申请

US20090247780A1 METHOD OF PRODUCING NITRILE COMPOUNDS 失效
标题翻译：生产氮化合物的方法
公开(公告)号：US20090247780A1
公开(公告)日：2009-10-01
申请号：US12244233
申请日：2008-10-02
申请人： Jean-Marie BASSET , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
发明人： Jean-Marie BASSET , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
IPC分类号： C07C253/10
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ε-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.
摘要翻译：本发明涉及通过与氰化氢反应从不饱和有机化合物制备腈化合物。更具体地涉及用于合成己二腈的腈化合物的制备，其是主要化学化合物如六亚甲基二胺和ε-己内酰胺的制造中的重要化学中间体。本发明提供一种制备包含至少一个腈官能团的有机化合物的方法，该方法是通过在氰化氢和包含至少一个烯属不饱和键的有机化合物之间进行氢氰化反应。该反应在包含选自镍，铂和钯的金属元素和有机磷配体的催化体系的存在下进行，所述反应介质另外包含处于液态的离子液体，至少在进行氢化反应。

2. 发明授权

US08039660B2 Method of producing nitrile compounds 失效
标题翻译：腈化合物的制备方法
公开(公告)号：US08039660B2
公开(公告)日：2011-10-18
申请号：US12244233
申请日：2008-10-02
申请人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
发明人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
IPC分类号： C07C253/10 , C07C255/03
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ε-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.
摘要翻译：本发明涉及通过与氰化氢反应从不饱和有机化合物制备腈化合物。更具体地涉及用于合成己二腈的腈化合物的制备，其是主要化学化合物如六亚甲基二胺和ε-己内酰胺的制造中的重要化学中间体。本发明提供一种制备包含至少一个腈官能团的有机化合物的方法，该方法是通过在氰化氢与包含至少一个烯属不饱和键的有机化合物之间进行氢氰化反应。该反应在包含选自镍，铂和钯的金属元素和有机磷配体的催化体系的存在下进行，所述反应介质另外包含处于液态的离子液体，至少在进行氢化反应。

3. 发明授权

US07915426B2 Imidazolium salts and their use of these ionic liquids as a solvent 有权
标题翻译：咪唑盐及其使用这些离子液体作为溶剂
公开(公告)号：US07915426B2
公开(公告)日：2011-03-29
申请号：US10399908
申请日：2001-10-25
申请人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
发明人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
IPC分类号： C07D233/64 , C07D233/66
CPC分类号： C07F7/10 , B01J31/0239 , B01J31/0244 , B01J31/0284 , B01J31/2404 , B01J31/4038 , B01J31/4053 , B01J2231/20 , B01J2531/824 , C07C311/48 , C07D231/12 , C07D233/56 , C07D249/08 , C07F5/022 , C07F7/0814 , Y02P20/542 , Y02P20/584
摘要： New 1,2,3- or 1,2,3,4- or 1,2,3,4,5- substituted imidazolium salts and their uses as solvent in catalyzed organic reactions, as well as compositions containing them and a transition metal compound. They can be used in the following reactions: the telomerisation of conjugated dienes, dimerisation of olefins, the oligomerisation of olefins, polymerization of olefins, alkylation of olefins, hydrogenation of olefins, olefin metathesis, hydroformylation of olefins, ring-closing metathesis of olefins, ring-opening metathesis polymerisation of olefins, symetric or asymetric epoxidation of olefins (including heteroatom substituted olefins) and the cyclopropanation of olefins, condensation reaction, hydrogenation reaction, isomerization reaction, Suzuki cross-coupling reactions, amination reaction, partial oxidation of alkancs, kinetic resolution of racemic mixtures, hydrogenation of imines, hydrogenation of ketones, transfer hydrogenation and hydroxylation of aromatic organic compounds.
摘要翻译：新的1,2,3-或1,2,3,4-或1,2,3,4,5-取代咪唑鎓盐及其作为催化有机反应中的溶剂的用途，以及含有它们的组合物和过渡金属复合。它们可以用于以下反应：共轭二烯的调聚，烯烃的二聚，烯烃的低聚，烯烃的聚合，烯烃的烷基化，烯烃的氢化，烯烃的复分解，烯烃的加氢甲酰化，烯烃的闭合复分解，烯烃的开环易位聚合，烯烃（包括杂原子取代烯烃）的对称或不对称环氧化和烯烃的环丙烷化，缩合反应，氢化反应，异构化反应，Suzuki交叉偶联反应，胺化反应，烷基部分氧化，动力学外消旋混合物的拆分，亚胺的氢化，酮的氢化，转移氢化和芳族有机化合物的羟基化。

4. 发明授权

US06525228B2 Process of telomerizing conjugated dienes 失效
公开(公告)号：US06525228B2
公开(公告)日：2003-02-25
申请号：US10036265
申请日：2001-10-22
申请人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
发明人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
IPC分类号： C07C4101
CPC分类号： B01J31/0284 , B01J31/2239 , B01J31/2404 , B01J2231/20 , B01J2531/824 , B01J2531/96 , B01J2540/32 , C07C29/36 , C07C41/06 , Y02P20/584 , C07C43/15 , C07C33/02
摘要： The present invention is related to a process for telomerizing a conjugated diene which comprises reacting said conjugated diene with a compound containing active hydrogen in the presence of a catalyst system comprising at least one transition metal compound, at least one phosphorus-containing compound, and at least one salt which forms a liquid under the conditions of the telomerization process.

5. 发明授权

US08470940B2 Complexes and method for synthesis of group 4 organometallics grafted on anions olefin oligomerization and polymerization method 失效
标题翻译：用于合成第4族有机金属化合物的络合物和方法接枝在阴离子烯烃低聚和聚合方法上
公开(公告)号：US08470940B2
公开(公告)日：2013-06-25
申请号：US12667557
申请日：2008-07-03
申请人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
发明人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
IPC分类号： C08F4/52 , C08F4/64 , C08F4/76 , B01J31/38 , C07F7/00
CPC分类号： C07F17/00 , C07F7/00 , C08F4/65912 , C08F10/00 , C08F10/02 , C08F2410/03 , C08F4/659 , C08F4/65908 , C08F4/643 , C08F4/65925
摘要： Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminum comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.
摘要翻译：通过至少一种包含至少一个羟基的硼酸盐或铝与至少一种4族过渡金属化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新型4族有机金属化合物。这些化合物用于以烯烃低聚或聚合方法实施的催化组合物。

6. 发明申请

US20100286349A1 NOVEL COMPLEXES AND METHOD FOR SYNTHESIS OF GROUP 4 ORGANOMETALLICS GRAFTED ON ANIONS OLEFIN OLIGOMERIZATION AND POLYMERIZATION METHOD 失效
标题翻译：合成低聚物和聚合方法的组合4组分的新型复合物和方法
公开(公告)号：US20100286349A1
公开(公告)日：2010-11-11
申请号：US12667557
申请日：2008-07-03
申请人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
发明人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
IPC分类号： C08F4/52 , C07D233/58 , C07F9/54 , C07D207/06 , B01J31/14
CPC分类号： C07F17/00 , C07F7/00 , C08F4/65912 , C08F10/00 , C08F10/02 , C08F2410/03 , C08F4/659 , C08F4/65908 , C08F4/643 , C08F4/65925
摘要： Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminium comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.
摘要翻译：通过至少一种包含至少一个羟基的硼酸盐或铝与至少一种4族过渡金属化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新型4族有机金属化合物。这些化合物用于以烯烃低聚或聚合方法实施的催化组合物。

7. 发明授权

US08680307B2 Complexes and method for synthesis of group 6 organometallics grafted on anions, and use thereof in an olefin metathesis method 失效
标题翻译：用于合成接枝在阴离子上的6族有机金属化合物的复合物和方法及其在烯烃复分解方法中的应用
公开(公告)号：US08680307B2
公开(公告)日：2014-03-25
申请号：US12912032
申请日：2010-10-26
申请人： Ludovic Chahen , Mikaël Berthod , Vinciane Kelsen , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
发明人： Ludovic Chahen , Mikaël Berthod , Vinciane Kelsen , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
IPC分类号： C07F5/02
CPC分类号： C07F11/00
摘要： Novel group 6 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminate comprising at least one hydroxy group with at least one compound of a group 6 transition metal. These compounds are used in a catalytic composition utilized in an olefin metathesis method.
摘要翻译：通过至少一种包含至少一个羟基的硼酸盐或铝酸盐与至少一种第6族过渡金属的化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新的6族有机金属化合物。这些化合物用于用于烯烃复分解法的催化组合物中。

8. 发明申请

US20110098497A1 NOVEL COMPLEXES AND METHOD FOR SYNTHESIS OF GROUP 6 ORGANOMETALLICS GRAFTED ON ANIONS, AND USE THEREOF IN AN OLEFIN METATHESIS METHOD 失效
标题翻译：用于合成在阴离子上接枝的6族有机物的新型复合物和方法，以及其在烯烃元素方法中的应用
公开(公告)号：US20110098497A1
公开(公告)日：2011-04-28
申请号：US12912032
申请日：2010-10-26
申请人： Ludovic Chahen , Mikaël Berthod , Vinciane Kelsen , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
发明人： Ludovic Chahen , Mikaël Berthod , Vinciane Kelsen , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
IPC分类号： C07F5/02 , B01J31/14 , C07C6/02
CPC分类号： C07F11/00
摘要： Novel group 6 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminate comprising at least one hydroxy group with at least one compound of a group 6 transition metal. These compounds are used in a catalytic composition utilized in an olefin metathesis method.
摘要翻译：通过至少一种包含至少一个羟基的硼酸盐或铝酸盐与至少一种第6族过渡金属的化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新的6族有机金属化合物。这些化合物用于用于烯烃复分解法的催化组合物中。

9. 发明授权

US5874638A Process for hydroformylation of olefinic compounds 失效
标题翻译：烯烃化合物加氢甲酰化方法
公开(公告)号：US5874638A
公开(公告)日：1999-02-23
申请号：US755853
申请日：1996-12-02
申请人： Yves Chauvin , Helene Olivier , Lothar Mussmann
发明人： Yves Chauvin , Helene Olivier , Lothar Mussmann
IPC分类号： B01J31/16 , C07B61/00 , C07C45/50 , C07C47/02 , C07C47/12
CPC分类号： C07C45/50
摘要： A hydroformylation process for unsaturated compounds such as monoolefins and diolefins is carried out in an ionic medium in which the catalytic species is dissolved, but in which the reaction products (aldehydes) formed are only slightly soluble or are insoluble. The ionic medium is liquid at a temperature below 90.degree. C. and comprises at least one quaternary ammonium and/or phosphonium cation and at least one anion which is preferably selected from the group formed by tetrafluoroborate when the cation is ammonium, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, perfluoroalkylsulphonates, fluorosulphonate, bis-perfluoroalkylsulphonyl amides or dichlorocuprate, tetrachlorocuprate, tetrachloroaluminate, or trichlorozincate. At the end of the reaction, the organic phase is separated out and the polar phase containing the catalyst is used again.
摘要翻译：用于不饱和化合物如单烯烃和二烯烃的加氢甲酰化方法在其中溶解催化物质的离子介质中进行，但其中形成的反应产物（醛）仅仅是微溶或不溶解的。离子介质在低于90℃的温度下是液体，并且包含至少一种季铵和/或鏻阳离子和至少一种阴离子，当阳离子是铵，六氟磷酸盐，六氟锑酸盐时，优选选自四氟硼酸盐形成的基团，六氟砷酸盐，全氟烷基磺酸盐，氟磺酸盐，双全氟烷基磺酰胺或二氯磷酸盐，四氯磷酸盐，四氯铝酸盐或三氯酸锌。在反应结束时，分离有机相，再次使用含有催化剂的极性相。

10. 发明授权

US5633416A Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms 失效
$Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms$
标题翻译：通过包含含有5至8个碳原子的烯烃的烃馏分的醚化的方法产生的燃料
公开(公告)号：US5633416A
公开(公告)日：1997-05-27
申请号：US459691
申请日：1995-06-02
申请人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
发明人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
IPC分类号： C10L1/02 , C07C5/22 , C07C5/27 , C07C41/00
CPC分类号： C10L1/023
摘要： An internal combustion engine fuel is produced from a mixture of hydrocarbons comprising olefinic hydrocarbons containing 5 to 8 carbon atoms characterized in that it is produced by a process comprising a) a catalytic etherification step for at least a portion of the etherifiable olefins contained in said hydrocarbon mixture, using at least one alcohol containing 1 to 4 carbon atoms, the quantity of alcohol employed being such that the alcohol:etherifiable olefin molar ratio is at least 1:1, and b) a water washing step for the ether-containing product before recovery as a fuel.
摘要翻译：由含有5-8个碳原子的烯烃的烃的混合物产生内燃机燃料，其特征在于它是通过以下方法生产的：a）催化醚化步骤，用于至少部分所述烃中所含的可醚化烯烃混合物，使用至少一种含有1至4个碳原子的醇，所使用的醇的量使得醇：可醚化烯烃摩尔比至少为1:1，和b）含醚产物的水洗步骤作为燃料的回收。

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