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1. 发明专利

JP2008231330A Radiation-crosslinked fluorine-containing copolymer 有权
标题翻译：辐射交联含氟聚合物共聚物
公开(公告)号：JP2008231330A
公开(公告)日：2008-10-02
申请号：JP2007075880
申请日：2007-03-23
申请人： Japan Atomic Energy Agency , Yunimatekku Kk , ユニマテック株式会社 , 独立行政法人日本原子力研究開発機構
发明人： KANEGA ATSUSHI , ENOKIDA TAKASHI , ASANO MASAHARU , YAMAKI TETSUYA , YOSHIDA MASARU , MAEKAWA YASUNARI
IPC分类号： C08J3/28 , C08F291/04
摘要： PROBLEM TO BE SOLVED: To provide a radiation-crosslinked fluorine-containing copolymer enabling the radiation crosslinking under a mild condition, and having more improved mechanical characteristics and compression set characteristics. SOLUTION: The radiation-crosslinked fluorine-containing copolymer is obtained by irradiating a fluorine-containing copolymer composition obtained by compounding 1-20 pts.wt. triallyl isocyanurate polymer having 500-100,000 number average molecular weight Mn with 100 pts.wt. tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer having ≤10 J/g heat quantity ΔH for melting a crystal with radiation. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够在温和条件下进行辐射交联并具有更好的机械特性和压缩永久变形特性的辐射交联的含氟共聚物。解决方案：辐射交联的含氟共聚物是通过将通过混合1-20重量份得到的含氟共聚物组合物具有500-100,000数均分子量Mn和100重量份的三烯丙基异氰脲酸酯聚合物具有≤10J/ g热量ΔH的四氟乙烯 - 全氟（烷基乙烯基醚）共聚物，用于熔化具有辐射的晶体。版权所有（C）2009，JPO＆INPIT

2. 发明专利

JP2008231331A Radiation-crosslinked fluorine-containing copolymer 有权
标题翻译：辐射交联含氟聚合物共聚物
公开(公告)号：JP2008231331A
公开(公告)日：2008-10-02
申请号：JP2007075881
申请日：2007-03-23
申请人： Japan Atomic Energy Agency , Yunimatekku Kk , ユニマテック株式会社 , 独立行政法人日本原子力研究開発機構
发明人： KANEGA ATSUSHI , ENOKIDA TAKASHI , ASANO MASAHARU , YAMAKI TETSUYA , YOSHIDA MASARU , MAEKAWA YASUNARI
IPC分类号： C08J3/28 , C08F291/04
摘要： PROBLEM TO BE SOLVED: To provide a radiation-crosslinked fluorine-containing copolymer enabling the radiation crosslinking under a milder condition, and having good mechanical characteristics and compression set characteristics even in a high-temperature condition of ≥100°C. SOLUTION: The radiation-crosslinked fluorine-containing copolymer is obtained by irradiating a fluorine-containing copolymer composition obtained by compounding 0.1-10 pts.wt. fluorine-containing divinyl polyether compound represented by the general formula: CF 2 =CFO-Rf-OCF=CF 2 (wherein, Rf is a 1-15C fluoroalkylene group which may contain an ethereal oxygen atom) with 100 pts.wt. tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer having ≤10 J/g heat quantity ΔH for melting a crystal with radiation. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供即使在≥100℃的高温条件下也能够在较温和的条件下进行辐射交联并具有良好机械特性和压缩永久变形特性的辐射交联含氟共聚物。解决方案：辐射交联的含氟共聚物是通过将通过混合0.1-10重量份的获得的含氟共聚物组合物由以下通式表示的含氟二乙烯基聚醚化合物：CF 2 SBR = CFO-Rf-OCF = CF SB 2（其中，Rf是1-15C氟亚烷基，含有醚类氧原子）与100重量份具有≤10J/ g热量ΔH的四氟乙烯 - 全氟（烷基乙烯基醚）共聚物，用于熔化具有辐射的晶体。版权所有（C）2009，JPO＆INPIT

3. 发明专利

JP2007137982A Radiation-crosslinkable fluorine-containing copolymer 有权
标题翻译：含有可透过荧光的含氟共聚聚合物
公开(公告)号：JP2007137982A
公开(公告)日：2007-06-07
申请号：JP2005332302
申请日：2005-11-17
申请人： Japan Atomic Energy Agency , Yunimatekku Kk , ユニマテック株式会社 , 独立行政法人日本原子力研究開発機構
发明人： KANEGA ATSUSHI , ENOKIDA TAKASHI , YAMAKI TETSUYA , ASANO MASAHARU , YOSHIDA MASARU
IPC分类号： C08J3/28 , C08J7/00
摘要： PROBLEM TO BE SOLVED: To provide a radiation-crosslinkable fluorine-containing copolymer carrying out radiation crosslinking under milder conditions. SOLUTION: The radiation-crosslinkable fluorine-containing copolymer is obtained by irradiating a tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer having ≤10 J/g crystal melting heat quantity ▵H. The radiation-crosslinkable fluorine-containing copolymer is crosslinkable by exposure to radiation under the mild conditions such as ≤100°C solely in various kinds of perfluoropolymers. The radiation-crosslinkable fluorine-containing copolymer is suitable for uses as a molded product used under radiation environments such as nuclear facilities or space. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供在更温和的条件下进行辐射交联的可辐射交联的含氟共聚物。解决方案：通过照射具有≤10J/ g晶体熔融热量▵H的四氟乙烯 - 全氟（烷基乙烯基醚）共聚物获得辐射交联性含氟共聚物。辐射交联性含氟共聚物可以通过在温和条件下暴露于辐射下进行交联，例如≤100℃，仅在各种全氟聚合物中。辐射交联性含氟共聚物适用于在核设施或空间等辐射环境下使用的成型体。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2008195748A Crosslinked aromatic polymer electrolyte membrane and its manufacturing method 审中-公开
标题翻译：交联芳香族聚合物电解质膜及其制造方法
公开(公告)号：JP2008195748A
公开(公告)日：2008-08-28
申请号：JP2007029223
申请日：2007-02-08
申请人： Japan Atomic Energy Agency , 独立行政法人日本原子力研究開発機構
发明人： CHIN SHINKA , MAEKAWA YASUNARI , ASANO MASAHARU , YOSHIDA MASARU
IPC分类号： C08J5/22 , C08J7/12 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： H01M8/1018 , H01M8/0289 , H01M8/04197 , H01M8/1011 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1088 , Y02E60/523 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a crosslinked aromatic polymer electrolyte membrane that has a low water content and exhibits high proton conductivity, low methanol permeability, a high antioxidative property and excellent mechanical properties, and its manufacturing method. SOLUTION: An aromatic polymer film substrate or a grafted aromatic polymer film substrate having a monomer introduced thereinto as a graft chain is given a crosslinked structure by ionizing radiation irradiation. As the aromatic polymer film substrate and the grafted aromatic polymer film substrate endowed with the crosslinked structure are insoluble in a sulfonating solution, these film substrates are directly sulfonated to give the crosslinked aromatic polymer electrolyte membrane. As introduction of the monomer as the graft chain permits control of the crosslinked structure of the electrolyte membrane and of the microphase separation structure in a proton conductive domain, the crosslinked aromatic polymer electrolyte membrane, which has a low water content and exhibits high proton conductivity, low methanol permeability, a high antioxidative property and excellent mechanical properties, can be prepared. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供具有低含水量并且显示出高质子传导性，低甲醇渗透性，高抗氧化性和优异机械性能的交联芳族聚合物电解质膜及其制造方法。解决方案：通过电离辐射照射将具有引入其中的单体作为接枝链的芳族聚合物膜基材或接枝的芳族聚合物膜基材赋予交联结构。由于芳族聚合物膜基材和具有交联结构的接枝芳族聚合物膜基材不溶于磺化溶液，所以这些膜基材直接磺化，得到交联的芳族聚合物电解质膜。由于作为接枝链的单体的引入允许控制质子传导区域中的电解质膜和微相分离结构的交联结构，所以具有低含水量并且显示出高质子传导性的交联芳族聚合物电解质膜，可以制备低甲醇渗透性，高抗氧化性和优异的机械性能。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2007031650A Resin composition colored by quantum beam and nano imaging formation method 审中-公开
标题翻译：通过量子束和纳米成像方法着色的树脂组合物
公开(公告)号：JP2007031650A
公开(公告)日：2007-02-08
申请号：JP2005220517
申请日：2005-07-29
申请人： Japan Atomic Energy Agency , 独立行政法人日本原子力研究開発機構
发明人： MAEKAWA YASUNARI , YOSHIDA MASARU
IPC分类号： C08L101/00 , C08K5/18 , C08K5/34 , C09K3/00
摘要： PROBLEM TO BE SOLVED: To solve the problem that almost no reaction mechanisms of highly practicable organic molecules such as photochromic molecules with quantum beams have been made clear and that no promising proposals have been made concerning next-generation recording systems that enhance recording density by leaps and bounds though utilization of quantum beams having a wavelength of a pattern size or less is inevitable as light used for densification.
SOLUTION: A resin film, comprised of a compound generating an acid by quantum beams (acid-generating agent) and an environmentally chromic molecule chemically convertible from a colorless substance to a colored substance by the acid with good efficiency, is irradiated with quantum nano beams operable at a high speed thereby to realize writing technology of colored patterns having nano scale resolution that attains a recording density several figures higher than that of conventional recording media utilizing light.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：为了解决几乎没有高度实用的有机分子如光致变色分子与量子束的反应机理已经清楚的问题，并且对于增强记录的下一代记录系统没有提出有希望的建议尽管利用具有图案尺寸或更小的波长的量子束，但是由于用于致密化的光是不可避免的，所以通过跨越式的密度来实现。
解决方案：通过量子光（酸产生剂）产生酸的化合物和通过酸从无色物质化学转化成有色物质的环境色度分子的树脂膜被照射到具有良好效率的酸中能够以高速操作的量子纳米光束，从而实现具有纳米级分辨率的彩色图案的写入技术，其具有比利用光的常规记录介质高几十倍的记录密度。版权所有（C）2007，JPO＆INPIT

6. 发明专利

JP2009146758A Electrolyte membrane for fuel cell, and manufacturing method thereof 审中-公开
标题翻译：燃料电池用电解质膜及其制造方法
公开(公告)号：JP2009146758A
公开(公告)日：2009-07-02
申请号：JP2007323426
申请日：2007-12-14
申请人： Japan Atomic Energy Agency , Toyota Motor Corp , トヨタ自動車株式会社 , 独立行政法人日本原子力研究開発機構
发明人： KOBAYASHI MISAKI , YAMAKI TETSUYA , ASANO MASAHARU , YOSHIDA MASARU , MAEKAWA YASUNARI
IPC分类号： H01M8/02 , H01B1/06 , H01B13/00 , H01M8/10
CPC分类号： H01B1/122 , C08J5/2218 , H01M8/1067 , H01M8/1076 , H01M8/1079 , H01M8/1086 , H01M2008/1095 , H01M2300/0082 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a polymer electrolyte membrane for fuel cell which has both high proton conductivity and gas barrier performance of a polymer film substrate at the same time and is superior in humidity dimension change, tensile strength, and discharge performance, and to provide a manufacturing method thereof. SOLUTION: The polymer electrolyte membrane for fuel cell which has (1) a plurality of proton conductive paths penetrated in thickness direction of a polymer film substrate and (2) a proton conduction layer formed in layers on one or both surfaces of the polymer film substrate is manufactured through a first irradiation process in which high energy heavy ions are irradiated so as to generate active species in such a way that they penetrate in thickness direction of the polymer film substrate, a second irradiation process in which electron beams or ion beams are irradiated so as to generate active species in layers in the surface layer of the substrate, and a graft polymerization process in which, after the irradiation processes, the film substrate and a monomer are graft polymerized by adding the monomer of one kind or more selected from a group of monomers having a proton conductive functional group or capable of introducing the proton conductive functional group in a later process. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供同时具有高质子传导性和高分子膜基材的气体阻隔性能的燃料电池用聚合物电解质膜，并且具有优异的湿度尺寸变化，拉伸强度和放电性能，并提供其制造方法。解决方案：一种用于燃料电池的聚合物电解质膜，其具有（1）多个质子传导路径，在聚合物膜基材的厚度方向上穿透;以及（2）在该层的一个或两个表面上形成的质子传导层通过照射高能重离子的第一照射工艺制造聚合物膜基材，以便以这样的方式产生活性物质，使得它们在聚合物膜基材的厚度方向上穿透，其中电子束或离子照射光束以在衬底的表面层中产生层中的活性物质，以及接枝聚合方法，其中在照射工艺之后，通过添加一种或更多种的单体将膜基材和单体接枝聚合选自一组具有质子传导性官能团的单体或能够在稍后的工艺中引入质子传导性官能团。版权所有（C）2009，JPO＆INPIT

7. 发明专利

JP2009014468A Manufacturing method of biological tissue hardened body 有权
标题翻译：生物组织硬化体的制备方法
公开(公告)号：JP2009014468A
公开(公告)日：2009-01-22
申请号：JP2007175814
申请日：2007-07-04
申请人： Akita Univ , Gunma Univ , Japan Atomic Energy Agency , 国立大学法人秋田大学 , 国立大学法人群馬大学 , 独立行政法人日本原子力研究開発機構
发明人： ASANO MASAHARU , YAMAKI TETSUYA , YOSHIDA MASARU , MAEKAWA YASUNARI , ABE HIROSHI , SUZUKI YOSHIKUNI , NIBE TSUNEMI , ISHIZAWA AKIMITSU , SHU AKIRA , YORIFUJI HIROSHI , SATO MASATO
IPC分类号： G01N1/36 , A01N1/02 , G01N1/30 , G01N33/48
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of a biological tissue hardened body preservable in the state similar to the living state unaccompanied by contraction in a short time.
SOLUTION: A biological tissue is impregnated into mixed solution acquired by combining a monofunctional vinyl monomer, a polyfunctional vinyl monomer, and a solvent together, and then polymerized by being irradiated with an ionizing radiation.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种生物组织硬化体的制造方法，该制造方法可以在与短时间内收缩无关的生活状态相似的状态下保存。解决方案：将生物组织浸渍在通过将单官能乙烯基单体，多官能乙烯基单体和溶剂组合在一起而获得的混合溶液中，然后通过用电离辐射照射而聚合。版权所有（C）2009，JPO＆INPIT

8. 发明专利

JP2008097868A Fuel-cell polymer electrolyte membrane imparted with silane cross-linked structure and fuel-cell membrane/electrode assembly including the same 有权
标题翻译：燃料电池聚合物电解质薄膜与硅烷交联结构和燃料电池/电极组件包括其中
公开(公告)号：JP2008097868A
公开(公告)日：2008-04-24
申请号：JP2006275122
申请日：2006-10-06
申请人： Japan Atomic Energy Agency , Nitto Denko Corp , 日東電工株式会社 , 独立行政法人日本原子力研究開発機構
发明人： YOSHIDA MASARU , ASANO MASAHARU , CHIN SHINKA , MAEKAWA YASUNARI , TACHIBANA TOSHIMITSU , NAGAI YOZO , NISHIYAMA SOJI
IPC分类号： H01M8/02 , C08F291/00 , C08J5/22 , C08J7/18 , H01B1/06 , H01B13/00 , H01M8/10
CPC分类号： C08F255/00 , C08F8/00 , C08F8/12 , C08F8/36 , C08F259/08 , C08J5/2293 , C08J7/18 , C08J2323/06 , C08J2327/18 , H01B1/122 , H01M8/1027 , H01M8/1037 , H01M8/1039 , H01M8/1044 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56 , C08F230/08
摘要： PROBLEM TO BE SOLVED: To provide an electrolyte membrane which can maintain excellent battery characteristics for a long period of time under high temperature and low moisture retention conditions that is the most important thing in a fuel cell. SOLUTION: A manufacturing method for a fuel-cell polymer electrolyte membrane includes a step, in which a graft molecular chain is formed by graft-polymerizing a vinylsilane coupling agent having a phenyl group capable of retaining a sulfonic acid group onto a polymer film base material, a step for introducing a sulfon acid group into a phenyl group in a graft molecular chain, and a step, in which a silane bridge structure is imparted between graft molecular chains by hydrolyzing and condensing an alkoxy group in a graft molecular chain, in turn. It is devised to obtain the fuel-cell polymer electrolyte membrane manufactured by such a manufacturing method. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种电解质膜，其可以在燃料电池中最重要的高温和低保湿条件下长时间保持优异的电池特性。解决方案：燃料电池聚合物电解质膜的制造方法包括以下步骤：其中通过将具有能够保持磺酸基的苯基的乙烯基硅烷偶联剂接枝聚合到聚合物上形成接枝分子链膜基材，将磺酸基引入接枝分子链中的苯基的步骤，以及通过在接枝分子链中水解和缩合烷氧基而在接枝分子链之间施加硅烷桥结构的步骤，反过来。设计得到通过这样的制造方法制造的燃料电池用聚合物电解质膜。版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2006282969A Method for producing functional inorganic/graft polymer hybrid ion exchange membrane and electrolyte membrane for fuel cell 有权
标题翻译：生产功能无机/聚酰胺混合离子交换膜和电解槽的电解质膜的方法
公开(公告)号：JP2006282969A
公开(公告)日：2006-10-19
申请号：JP2005108561
申请日：2005-04-05
申请人： Japan Atomic Energy Agency , Nitto Denko Corp , 日東電工株式会社 , 独立行政法人日本原子力研究開発機構
发明人： YOSHIDA MASARU , YAMAKI TETSUYA , ASANO MASAHARU , MORITA YOSUKE , NISHIYAMA SOJI , TACHIBANA TOSHIMITSU , NAGAI YOZO
IPC分类号： C08J7/16 , B01D67/00 , B01D71/02 , B01D71/26 , B01D71/28 , B01D71/32 , B01D71/34 , B01D71/36 , B01D71/44 , B01D71/48 , B01D71/56 , B01D71/64 , B01D71/78 , B01D71/82 , C08F291/18 , C08L27/18 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： C08J5/2281 , C08J2323/06 , C08J2327/18
摘要： PROBLEM TO BE SOLVED: To solve problems: defects in a polymer ion exchange membrane such as low ion exchange capacity, low electric conductivity, in addition, bad oxidation resistance of the membrane, and the like.
SOLUTION: The polymer ion exchange membrane having excellent electroconductivity, water retentivity and oxidation resistance is produced by uniformly mixing a functional inorganic material having a function for accelerating graft polymerization of a polymerizable monomer, a function for absorbing water and a function for transmitting hydrogen ions with an organic polymer to obtain a functional inorganic/polymer membrane, irradiating radioactive rays to the functional inorganic/polymer membrane to graft polymerize or co-graft polymerize the polymerizable monomer having functional groups and introducing sulfonate groups to graft chains.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决问题：解决问题：离子交换容量低，导电性差，聚合物离子交换膜的缺陷，膜的耐氧化性差等。解决方案：具有优异的导电性，保水性和抗氧化性的聚合物离子交换膜通过均匀混合具有促进可聚合单体的接枝聚合功能的功能性无机材料，吸水功能和发射功能而制备氢离子与有机聚合物反应获得功能性无机/聚合物膜，向功能性无机/聚合物膜照射放射线，将具有官能团的可聚合单体和引入磺酸盐基团的接枝聚合或共聚接枝聚合到接枝链上。版权所有（C）2007，JPO＆INPIT

10. 发明专利

JP2010140756A Polymer fuel battery cell 有权
标题翻译：聚合物燃料电池
公开(公告)号：JP2010140756A
公开(公告)日：2010-06-24
申请号：JP2008315878
申请日：2008-12-11
申请人： Japan Atomic Energy Agency , 独立行政法人日本原子力研究開発機構
发明人： CHIN SHINKA , MAEKAWA YASUNARI , ASANO MASAHARU , YOSHIDA MASARU
IPC分类号： H01M8/02 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a polymer fuel battery cell having a polymer electrolyte membrane-electrode-gas seal frame body assembly for preventing breakage and deterioration of a polymer electrolyte membrane due to pressure difference working on the polymer electrolyte membrane during operation, mechanical stress, heat-humidity history and oxidation reaction of residual water or oxygen gas. SOLUTION: The polymer fuel battery cell is composed of a polymer electrolyte membrane 1 and a polymer electrolyte membrane-porous catalyst electrode-gas seal frame body assembly in which a both-surface adhesive frame body 3 having an inner periphery part smaller than an external periphery part of an electrode 4, an external periphery part larger than the inner periphery part of the gas seal frame 2 and a thickness of 20 μm or less are adhered and integrated, and which is pinched by a separator 5 between a gas seal frame 2 and an electrode 4. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种聚合物燃料电池单元，其具有聚合物电解质膜 - 电极 - 气体密封框架体组件，用于防止在操作期间由于在聚合物电解质膜上的压力差而导致的聚合物电解质膜的破裂和劣化，机械应力，热湿历史和残余水或氧气的氧化反应。解决方案：聚合物燃料电池单元由聚合物电解质膜1和聚合物电解质膜多孔催化剂电极 - 气体密封框架体组合体组成，其中内周部分小于电极4的外周部分，大于气体密封框架2的内周部分的外周部分和20μm以下的厚度被粘附并整合，并且被气体密封件框架2和电极4.版权所有（C）2010，JPO＆INPIT

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