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    • 2. 发明授权
    • Process for preparing metal oxide slurry suitable for semiconductor chemical mechanical polishing
    • 制备适用于半导体化学机械抛光的金属氧化物浆料的方法
    • US06551367B2
    • 2003-04-22
    • US09867522
    • 2001-05-31
    • Kil Sung LeeJae Seok LeeSeok Jin KimTu Won Chang
    • Kil Sung LeeJae Seok LeeSeok Jin KimTu Won Chang
    • C09K314
    • C09K3/1463C09G1/02
    • There is disclosed a process for preparing a metal oxide CMP slurry suitable for semiconductor devices, wherein a mixture comprising 1 to 50 weight % of a metal oxide and 50 to 99 weight % of water is mixed in a pre-mixing tank, transferred to a dispersion chamber with the aid of a transfer pump, allowed to have a flow rate of not less than 100 m/sec by pressurization with a high pressure pump, and subjected to counter collision for dispersion through two orifices in the dispersion chamber. The slurry has particles which are narrow in particle size distribution, showing an ultrafine size ranging from 30 to 500 nm. Also, the slurry is not polluted at all during its preparation and shows no tailing phenomena, so that it is preventive of &mgr;-scratching. Therefore, it can be used in the planarization for shallow trench isolation, interlayer dielectrics and inter metal dielectrics through a CMP process.
    • 公开了一种制备适用于半导体器件的金属氧化物CMP浆料的方法,其中将包含1至50重量%的金属氧化物和50至99重量%的水的混合物混合在预混合罐中,转移至 借助于输送泵的分散室,通过用高压泵加压使其具有不小于100m /秒的流速,并通过分散室中的两个孔进行反向碰撞以进行分散。 该浆料具有粒径分布窄的粒子,显示出30〜500nm的超细尺寸。 此外,浆料在其制备过程中根本不会被污染,并且不显示拖尾现象,因此可以防止刮擦。 因此,可以通过CMP工艺在浅沟槽隔离,层间电介质和金属间电介质的平面化中使用。
    • 4. 发明授权
    • Methods of forming integrated circuit devices having polished tungsten metal layers therein
    • 形成其中具有抛光的钨金属层的集成电路器件的方法
    • US07452815B2
    • 2008-11-18
    • US11148670
    • 2005-06-09
    • Jae Seok LeeKil Sung Lee
    • Jae Seok LeeKil Sung Lee
    • H01L21/302H01L21/461
    • C11D3/14C09G1/02C11D7/06C11D7/08C11D7/263C11D11/0047H01L21/3212
    • Methods of forming integrated circuit devices use metal CMP slurry compositions having relatively low chemical etch rate and relatively high mechanical polishing rate characteristics. The relatively high mechanical polishing rate characteristics are achieved using relatively high concentrations of mechanical abrasive (e.g., ≧8 wt %) in combination with sufficient quantities of a wetting agent to inhibit micro-scratching of underlying surfaces (e.g., insulating layers, conductive vias, . . . ) being polished. The slurry compositions also include a highly stable metal-propylenediaminetetraacetate (M-PDTA) complex, which may operate to inhibit metal-oxide re-adhesion on the metal surface being polished and/or inhibit oxidation of the metal surface by chelating with the surface.
    • 形成集成电路器件的方法使用具有相对低的化学蚀刻速率和相对高的机械抛光速率特性的金属CMP浆料组合物。 使用相对高浓度的机械磨料(例如> = 8重量%)与足够量的润湿剂组合以抑制下面的表面(例如,绝缘层,导电通孔)的微划痕来实现相对较高的机械抛光速率特性 ,...)被抛光。 浆料组合物还包括高度稳定的金属 - 丙二胺四乙酸酯(M-PDTA)络合物,其可以用于抑制正在抛光的金属表面上的金属氧化物再附着和/或通过与表面螯合来抑制金属表面的氧化。