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1. 发明授权

US07316988B2 Gas turbine single plant modifying method, a catalyst re-using method and a re-produced catalyst 有权
标题翻译：燃气轮机单厂改造方法，催化剂再利用方法和再生催化剂
公开(公告)号：US07316988B2
公开(公告)日：2008-01-08
申请号：US10405618
申请日：2003-04-03
申请人： Hitoshi Nakamura , Norihisa Kobayashi , Kozo Iida , Osamu Naito , Yoshiaki Obayashi
发明人： Hitoshi Nakamura , Norihisa Kobayashi , Kozo Iida , Osamu Naito , Yoshiaki Obayashi
IPC分类号： B01J23/00 , B01J23/24 , B01J21/00
CPC分类号： B01J23/92 , B01D53/8628 , B01D53/96 , B01J38/485 , F01K23/10 , Y02E20/16
摘要： A high temperature denitration catalyst of a gas turbine single plant contains TiO2, at least one of WO3 and MoO3 and V2O5 of 0.5 wt % or less, preferably 0.2 wt % or less, or none of V2O5, and is optimized to be used in a temperature range up to a maximum 450 to 600° C. The used high temperature denitration catalyst is immersed into a V-containing water solution and dried and/or burned. An intermediate temperature denitration catalyst is produced containing a V2O5 component of 0.5 wt % or more, preferably 1.0 wt % or more, and is optimized for use in a temperature range of 250 to 450° C. This intermediate temperature denitration catalyst is re-used in a combined cycle plant after being modified or in other plants.
摘要翻译：燃气轮机单一工厂的高温脱硝催化剂含有TiO 2，WO 3 3和MoO 3 3和V 3中的至少一个， 0.5重量％以下，优选0.2重量％以下，或者不是V 2 O 5 O 5，并优化为在最高达450至600℃的温度范围内使用。将所使用的高温脱硝催化剂浸入含V的水溶液中并干燥和/或燃烧。制备含有0.5重量％以上，优选1.0重量％以上的V 2 O 5 O 5成分的中间温度脱硝催化剂，优选用于温度范围为250至450℃。该中间温度脱硝催化剂在经修改后或在其它工厂中再次用于联合循环设备中。

2. 发明授权

US6156698A Honeycomb catalyst and manufacturing method therefor 失效
标题翻译：蜂窝催化剂及其制备方法
公开(公告)号：US6156698A
公开(公告)日：2000-12-05
申请号：US67631
申请日：1998-04-28
申请人： Kozo Iida , Shigeru Nojima , Yoshiaki Obayashi , Atsushi Morii , Osamu Naito
发明人： Kozo Iida , Shigeru Nojima , Yoshiaki Obayashi , Atsushi Morii , Osamu Naito
IPC分类号： B01D53/88 , B01D53/94 , B01J35/04 , B01J37/00 , B28B3/20 , B28B3/26 , F01N3/28 , B01J21/04
CPC分类号： B28B3/269 , B01D53/885 , B01D53/9431 , B01J35/04 , B01J37/0009 , F01N3/2825 , F01N2330/38 , Y10T428/12333 , Y10T428/24744
摘要： There are provided a honeycomb catalyst in which irregularities are formed on a catalyst inside wall in a honeycomb hole, and a manufacturing method for a honeycomb catalyst by using an extrusion molding method, in which extrusion molding is effected by using a mold having a means for providing irregularities to a catalyst inside wall of a honeycomb hole.
摘要翻译：提供了一种蜂窝状催化剂，其中在蜂窝状孔中的催化剂内壁上形成凹凸，并且使用挤出成型方法制造蜂窝催化剂的方法，其中挤出成型是通过使用具有向蜂巢孔的催化剂内壁提供不规则性。

3. 发明授权

US5882422A Method for removing clogging dust in honeycomb catalyst 失效
标题翻译：消除蜂窝催化剂堵塞灰尘的方法
公开(公告)号：US5882422A
公开(公告)日：1999-03-16
申请号：US873380
申请日：1997-06-12
申请人： Yoshiaki Obayashi , Kozo Iida , Kazuo Ideue , Mitsunori Ooizumi , Osamu Naito
发明人： Yoshiaki Obayashi , Kozo Iida , Kazuo Ideue , Mitsunori Ooizumi , Osamu Naito
IPC分类号： F23J3/00 , B01J37/34 , B01J38/00 , B01J38/48 , F23C13/00 , F23C99/00 , B08B3/12 , B08B5/04
CPC分类号： B01J38/00 , B01J37/34 , B01J38/48
摘要： The present invention relates to a method for removing clogging dust in gas passing holes in a honeycomb catalyst. A honeycomb catalyst whose gas passing holes are clogged with dust in exhaust gas is immersed in water in a vessel, and then the vessel is closed and vacuum suction is exerted, by which water is allowed to flow in the gas passing holes in the honeycomb catalyst to remove dust in the gas passing holes.
摘要翻译：本发明涉及一种去除蜂窝催化剂中通气孔堵塞灰尘的方法。将排气中的气体通孔堵塞的蜂窝体催化剂浸渍在容器内的水中，然后关闭容器，并施加真空吸引，通过该真空吸引水在蜂窝催化剂的气体通过孔中流动去除气体通过孔中的灰尘。

4. 发明授权

US5869419A Nitrogen oxide removal catalyst 失效
标题翻译：氧化氮去除催化剂
公开(公告)号：US5869419A
公开(公告)日：1999-02-09
申请号：US871520
申请日：1997-06-09
申请人： Yoshiaki Obayashi , Kozo Iida , Shigeru Nojima , Atsushi Morii , Osamu Naito
发明人： Yoshiaki Obayashi , Kozo Iida , Shigeru Nojima , Atsushi Morii , Osamu Naito
IPC分类号： B01D53/86 , B01D53/94 , B01D53/96 , B01J23/30 , B01J37/02 , B01J38/00 , B01J23/00 , B01J8/00 , B01J23/16
CPC分类号： B01J38/00 , B01D53/8628 , B01D53/8631 , B01J23/30 , B01J37/0244
摘要： This invention effectively utilizes a solid type honeycomb-shaped NO.sub.x removal catalyst which has been used in a catalytic ammonia reduction process and hence reduced in NO.sub.x removal power, and thereby provides an inexpensive catalyst having NO.sub.x removal power equal to that of a fresh catalyst. The nitrogen oxide removal catalyst of this invention, which is useful in a process wherein ammonia is added to exhaust gas and nitrogen oxides present in the exhaust gas are catalytically reduced, has a two-layer structure composed of a lower layer comprising a spent solid type nitrogen oxide removal catalyst and an upper layer comprising a fresh TiO.sub.2 -WO.sub.3 -V.sub.2 O.sub.5 ternary or TiO.sub.2 -WO.sub.3 binary catalyst powder which has been applied to the lower layer so as to give a coating thickness of 100 to 250 .mu.m. Moreover, the catalyst power constituting the upper layer is a catalyst powder obtained by pulverizing a spent solid type nitrogen oxide removal catalyst.
摘要翻译：本发明有效地利用了催化氨还原方法中使用的固体型蜂窝状NOx去除催化剂，从而降低了NOx去除能力，从而提供了具有等于新鲜催化剂的NOx去除功率的便宜的催化剂。本发明的氮氧化物去除催化剂可用于将排放气体中存在氨和排出气体中存在的氮氧化物的方法进行催化还原的方法中，具有由下层构成的二层结构，该下层由废固体型氮氧化物去除催化剂和上层，其包含新的TiO 2 -WO 3-V 2 O 5三元或TiO 2 -WO 3二元催化剂粉末，其被施加到下层以使涂层厚度为100-250μm。此外，构成上层的催化剂功率是通过粉碎废固体型氮氧化物去除催化剂而获得的催化剂粉末。

5. 发明申请

US20120039758A1 Catalyst for Removing Nitrogen Oxides 有权
标题翻译：用于去除氮氧化物的催化剂
公开(公告)号：US20120039758A1
公开(公告)日：2012-02-16
申请号：US13279818
申请日：2011-10-24
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
IPC分类号： B01D53/56
CPC分类号： B01J23/002 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/0009 , B01J37/0018 , B01J2523/00 , B01J2523/47 , B01J2523/55 , B01J2523/69 , B01J2523/842 , B01J2523/17 , B01J2523/67 , B01J2523/41
摘要： The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.
摘要翻译：本发明提供一种用于除去氮氧化物的催化剂，其能够保持足够的脱氮性能，即，具有高NO 2含量的废气中的氮氧化物的高除去率，特别是在排气中的NO 2 / NO的比例气体为1以上，其催化剂成型体和废气处理方法。催化剂被设计用于除去氮氧化物，其用于使具有高NO 2含量的氮氧化物的废气脱氮，其包括：选自氧化铜，氧化铬和氧化铁中的至少一种氧化物，将NO2还原为NO的成分; 并且还包括：至少一种氧化钛; 至少一种氧化钨; 和至少一种氧化钒作为将NO还原成N2的组分。

6. 发明申请

US20090022643A1 SO3 REDUCTION CATALYST FOR PURIFYING AN EXHAUST GAS, PREPARATION PROCESS THEREOF, AND EXHAUST GAS PURIFYING METHOD USING THE CATALYST 审中-公开
标题翻译：用于净化排气的SO3还原催化剂，其制备方法和使用催化剂的排气净化方法
公开(公告)号：US20090022643A1
公开(公告)日：2009-01-22
申请号：US11908902
申请日：2005-04-06
申请人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
发明人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
IPC分类号： B01D53/50 , B01J23/46 , B01J21/08 , B01J27/25 , B01J27/10 , B01J27/08 , B01J27/053 , B01J27/24 , B01J31/12 , B01J23/28 , B01J23/30 , B32B3/12
CPC分类号： B01D53/8628 , B01D53/8609 , B01J21/063 , B01J21/066 , B01J23/46 , B01J23/462 , B01J23/468 , B01J23/652 , B01J23/6525 , B01J23/6527 , B01J35/0073 , B01J35/04 , B01J37/0211 , Y10T428/24149
摘要： To provide an SO3 reduction catalyst for purifying an exhaust gas capable of efficiently reducing the amount of SO3 that is present in a combustion exhaust gas and is a starting substance of S-containing substances such as acid ammonium sulfate causing deterioration of performance of the catalyst or corrosion of apparatuses disposed downstream of the catalyst, or capable of controlling the generation of SO3 in the catalyst itself; a preparation process of the catalyst; and an exhaust gas purifying method using the catalyst.In the catalyst for purifying a combustion exhaust gas containing nitrogen oxides, 50 wt. % or greater of the amount of Ru and/or Ir to be supported is adjusted to fall within a depth of 150 μm from the surface layer of a substrate; and the catalyst is prepared by immersing the substrate in a metal colloid solution of Ru and/or Ir to be supported or an aqueous solution containing at least one compound selected from compounds of Ru and/or Ir to be supported.
摘要翻译：提供一种用于净化排气的SO 3还原催化剂，其能够有效地减少燃烧废气中存在的SO 3的量，并且是含有S的物质如酸式硫酸铵的起始物质，导致催化剂的性能降低，或者设置在催化剂下游的装置的腐蚀，或能够控制催化剂本身中SO 3的产生; 催化剂的制备方法; 和使用该催化剂的排气净化方法。在用于净化含有氮氧化物的燃烧废气的催化剂中，要负载的Ru和/或Ir的量的％或更多的量被调节为落在离衬底的表面层150μm的深度内; 并将催化剂浸渍在待负载的Ru和/或Ir的金属胶体溶液中，或含有至少一种选自待负载的Ru和/或Ir化合物的化合物的水溶液中。

7. 发明授权

US4564604A Catalyst for treating waste gases 失效
标题翻译：用于处理废气的催化剂
公开(公告)号：US4564604A
公开(公告)日：1986-01-14
申请号：US671698
申请日：1984-11-15
申请人： Kozo Iida , Yoshiaki Obayashi
发明人： Kozo Iida , Yoshiaki Obayashi
IPC分类号： B01D53/94 , B01D53/86 , B01J21/06 , B01J23/22 , B01J23/24 , B01J29/06 , B01J37/02 , B01J29/08 , B01J29/18 , B01J29/28
CPC分类号： B01D53/8628 , B01J37/0246 , B01J21/063 , B01J23/22 , B01J23/24
摘要： A catalyst for treating waste gases comprising nitrogen oxides, which catalyst comprises a protonized zeolite coating formed on the surface of a catalytic ingredient. This type of catalyst has a prolonged life and is very useful in treating waste gases comprising nitrogen oxides by adding ammonia to the waste gas and reducing the nitrogen oxides in the waste gas with the catalyst to render the nitrogen oxides non-noxious.
摘要翻译：一种用于处理含氮氧化物的废气的催化剂，该催化剂包括在催化成分的表面上形成的质子化沸石涂层。这种类型的催化剂具有延长的使用寿命，并且通过向废气中加入氨并且用催化剂还原废气中的氮氧化物来使氮氧化物无毒，对于处理包含氮氧化物的废气非常有用。

8. 发明申请

US20050137082A1 Catalyst for removing nitrogen oxides, catalyst molded product therefore, and exhaust gas treating method, and composite power generation system 有权
标题翻译：因此，用于除去氮氧化物的催化剂，催化剂成型体，废气处理方法以及复合发电系统
公开(公告)号：US20050137082A1
公开(公告)日：2005-06-23
申请号：US10822441
申请日：2004-04-12
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
IPC分类号： F01N3/10 , B01D53/86 , B01D53/94 , B01J21/06 , B01J23/00 , B01J23/22 , B01J23/30 , B01J23/85 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/00 , B01J37/04
CPC分类号： B01J23/002 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/0009 , B01J37/0018 , B01J2523/00 , B01J2523/47 , B01J2523/55 , B01J2523/69 , B01J2523/842 , B01J2523/17 , B01J2523/67 , B01J2523/41
摘要： The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.
摘要翻译：本发明提供一种除去氮氧化物的催化剂，其能够保持足够的脱氮性能，即具有高NO 2 2含量的废气中的氮氧化物的高去除率，特别是在排气中的NO 2 2 / NO的比例为1以上，催化剂成型体和废气处理方法。催化剂设计用于除去氮氧化物，其用于使具有高NO 2 2 N含量的氮氧化物的废气脱氮，该氮氧化物包括：至少一种选自氧化铜，氧化铬和氧化铁作为将NO 2还原成NO的组分; 并且还包括：至少一种氧化钛; 至少一种氧化钨; 和至少一种氧化钒作为用于将NO还原成N 2的组分。

9. 发明申请

US20050054523A9 Flue gas denitration catalyst and preparation process thereof 有权
标题翻译：烟气脱硝催化剂及其制备方法
公开(公告)号：US20050054523A9
公开(公告)日：2005-03-10
申请号：US10705365
申请日：2003-11-10
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Katsumi Nochi , Masashi Kiyosawa
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Katsumi Nochi , Masashi Kiyosawa
IPC分类号： B01D53/94 , B01D53/86 , B01J23/00 , B01J23/30 , B01J35/04 , B01J37/02
CPC分类号： B01D53/8631 , B01D53/8628 , B01J23/002 , B01J23/30 , B01J35/04 , B01J37/0238
摘要： Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
摘要翻译：本发明提供一种脱硝活性高，能够抑制副反应即SO2氧化的烟道气脱硝催化剂。和催化剂的制备方法。烟气脱硝催化剂包括TiO 2，WO 3和V 2 O 5。在催化剂的表面200μm以内的表面层中，将V 2 O 5负载在含有TiO 2和WO 3的载体上。 V2O5的负载量为0.4〜5wt。％，基于表层的重量，为0.1-0.9wt。％，基于催化剂的总重量。如此支持的V 2 O 5通过X射线衍射测得的微晶尺寸小于10nm。催化剂可以通过制备含有TiO 2和WO 3的混合物并且通过气相法将V 2 O 5负载在所制备的混合物的挤出产品的表面上来获得。催化剂也可以通过使V 2 O 5通过气相法在制备的混合物的粉末上负载并将所得粉末负载在成形产品的表面上来获得。

10. 发明授权

US4952381A Method for denitrizing nitrogen oxides contained in waste gas 失效
标题翻译：废气中所含氮氧化物脱氮的方法
公开(公告)号：US4952381A
公开(公告)日：1990-08-28
申请号：US284764
申请日：1988-12-12
申请人： Horiaki Rikimaru , Tadao Nakatsuji , Toshikatsu Umaba , Kazuhiko Nagano , Kazuya Mishina , Hiromitsu Shimizu , Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Touru Seto , Shigeaki Mitsuoka , Masayuki Hanada , Morio Fukuda , Kiyoshi Nagano , Makoto Imanari , Takeo Koshikawa , Akihiro Yamauchi
发明人： Horiaki Rikimaru , Tadao Nakatsuji , Toshikatsu Umaba , Kazuhiko Nagano , Kazuya Mishina , Hiromitsu Shimizu , Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Touru Seto , Shigeaki Mitsuoka , Masayuki Hanada , Morio Fukuda , Kiyoshi Nagano , Makoto Imanari , Takeo Koshikawa , Akihiro Yamauchi
IPC分类号： B01D53/86 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/34 , B01J23/843 , B01J23/889
CPC分类号： B01J23/34 , B01D53/8628 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/8432 , B01J23/8892
摘要： A catalyst for denitrizing nitrogen oxides contained in waste gas which contains a substantial amount of arsenic compounds therein, which comprises:(a) titanium, and(b) at least one element selected from the group consisting of arsenic and manganese. The catalyst is resistant to deactivation by arsenic compounds and retains high denitrizing activity over a long period of time. The catalyst may further contain at least one base metal selected from the group consisting of V, W, Mo, Cu, Fe, Cr, Co, Ni, Zn and Sn.

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