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1. 发明授权

US6156698A Honeycomb catalyst and manufacturing method therefor 失效
标题翻译：蜂窝催化剂及其制备方法
公开(公告)号：US6156698A
公开(公告)日：2000-12-05
申请号：US67631
申请日：1998-04-28
申请人： Kozo Iida , Shigeru Nojima , Yoshiaki Obayashi , Atsushi Morii , Osamu Naito
发明人： Kozo Iida , Shigeru Nojima , Yoshiaki Obayashi , Atsushi Morii , Osamu Naito
IPC分类号： B01D53/88 , B01D53/94 , B01J35/04 , B01J37/00 , B28B3/20 , B28B3/26 , F01N3/28 , B01J21/04
CPC分类号： B28B3/269 , B01D53/885 , B01D53/9431 , B01J35/04 , B01J37/0009 , F01N3/2825 , F01N2330/38 , Y10T428/12333 , Y10T428/24744
摘要： There are provided a honeycomb catalyst in which irregularities are formed on a catalyst inside wall in a honeycomb hole, and a manufacturing method for a honeycomb catalyst by using an extrusion molding method, in which extrusion molding is effected by using a mold having a means for providing irregularities to a catalyst inside wall of a honeycomb hole.
摘要翻译：提供了一种蜂窝状催化剂，其中在蜂窝状孔中的催化剂内壁上形成凹凸，并且使用挤出成型方法制造蜂窝催化剂的方法，其中挤出成型是通过使用具有向蜂巢孔的催化剂内壁提供不规则性。

2. 发明授权

US5869419A Nitrogen oxide removal catalyst 失效
标题翻译：氧化氮去除催化剂
公开(公告)号：US5869419A
公开(公告)日：1999-02-09
申请号：US871520
申请日：1997-06-09
申请人： Yoshiaki Obayashi , Kozo Iida , Shigeru Nojima , Atsushi Morii , Osamu Naito
发明人： Yoshiaki Obayashi , Kozo Iida , Shigeru Nojima , Atsushi Morii , Osamu Naito
IPC分类号： B01D53/86 , B01D53/94 , B01D53/96 , B01J23/30 , B01J37/02 , B01J38/00 , B01J23/00 , B01J8/00 , B01J23/16
CPC分类号： B01J38/00 , B01D53/8628 , B01D53/8631 , B01J23/30 , B01J37/0244
摘要： This invention effectively utilizes a solid type honeycomb-shaped NO.sub.x removal catalyst which has been used in a catalytic ammonia reduction process and hence reduced in NO.sub.x removal power, and thereby provides an inexpensive catalyst having NO.sub.x removal power equal to that of a fresh catalyst. The nitrogen oxide removal catalyst of this invention, which is useful in a process wherein ammonia is added to exhaust gas and nitrogen oxides present in the exhaust gas are catalytically reduced, has a two-layer structure composed of a lower layer comprising a spent solid type nitrogen oxide removal catalyst and an upper layer comprising a fresh TiO.sub.2 -WO.sub.3 -V.sub.2 O.sub.5 ternary or TiO.sub.2 -WO.sub.3 binary catalyst powder which has been applied to the lower layer so as to give a coating thickness of 100 to 250 .mu.m. Moreover, the catalyst power constituting the upper layer is a catalyst powder obtained by pulverizing a spent solid type nitrogen oxide removal catalyst.
摘要翻译：本发明有效地利用了催化氨还原方法中使用的固体型蜂窝状NOx去除催化剂，从而降低了NOx去除能力，从而提供了具有等于新鲜催化剂的NOx去除功率的便宜的催化剂。本发明的氮氧化物去除催化剂可用于将排放气体中存在氨和排出气体中存在的氮氧化物的方法进行催化还原的方法中，具有由下层构成的二层结构，该下层由废固体型氮氧化物去除催化剂和上层，其包含新的TiO 2 -WO 3-V 2 O 5三元或TiO 2 -WO 3二元催化剂粉末，其被施加到下层以使涂层厚度为100-250μm。此外，构成上层的催化剂功率是通过粉碎废固体型氮氧化物去除催化剂而获得的催化剂粉末。

3. 发明授权

US06479026B1 Method of denitrating exhaust gas 有权
标题翻译：废气排放方法
公开(公告)号：US06479026B1
公开(公告)日：2002-11-12
申请号：US09405535
申请日：1999-09-24
申请人： Kozo Iida , Shigeru Nojima , Yoshiaki Obayashi , Atsushi Morii
发明人： Kozo Iida , Shigeru Nojima , Yoshiaki Obayashi , Atsushi Morii
IPC分类号： B01D5356
CPC分类号： B01D53/8625 , B01D53/8628 , B01D53/8634
摘要： The present invention provides a method of denitrating exhaust gas, which can control the NOx removal efficiency of exhaust gas at 90% or higher while suppressing the release of unreacted ammonia to 0.1 ppm or less. The method carries out denitration of exhaust gas for removing nitrogen oxides with catalytic reduction by introducing a nitrogen-oxide-containing gas into a catalyst-filled reaction chamber and adding ammonia as reducing agent in an excessive amount to the same chamber. The method comprises the steps of: introducing exhaust gas and ammonia into a first denitrating catalyst layer disposed on the most upstream side in the gas stream to remove nitrogen oxides; supplying the gas into a first ammonia decomposing catalyst layer disposed on the downstream side of the first denitrating catalyst layer to control the ammonia content to be suitable for the subsequent denitrating process, the first ammonia decomposing catalyst layer having ability to oxidatively decompose unreacted ammonia into nitrogen and nitrogen oxides; then supplying the gas into a second denitrating catalyst layer disposed on the downstream side of the first ammonia decomposing catalyst layer; thereafter supplying the gas into a second ammonia decomposing catalyst layer disposed on the most downstream side to remove the residual ammonia, the second ammonia decomposing catalyst layer being provided with a catalyst which can oxidatively decompose the residual ammonia into nitrogen and nitrogen oxides or a catalyst which can oxidatively decompose the residual ammonia into nitrogen oxides.
摘要翻译：本发明提供一种排气废气的方法，其可以将废气的NOx去除效率控制在90％以上，同时将未反应氨的释放抑制在0.1ppm以下。该方法通过将含氮氧化物的气体引入填充有催化剂的反应室中并且将氨作为还原剂过量加入到相同的室中，通过催化还原来进行用于除去氮氧化物的废气的脱硝。该方法包括以下步骤：将排气和氨引入设置在气流中最上游侧的第一脱硝催化剂层中以除去氮氧化物; 将气体供给到设置在第一脱硝催化剂层的下游侧的第一氨分解催化剂层，以控制氨含量适合于随后的脱硝工艺，第一氨分解催化剂层具有将未反应的氨氧化分解成氮的能力和氮氧化物; 然后将气体供给到设置在第一氨分解催化剂层的下游侧的第二脱硝催化剂层中; 然后将气体供给到设置在最下游侧的第二氨分解催化剂层以除去残留的氨，第二氨分解催化剂层设置有可将残留的氨氧化分解成氮和氮氧化物的催化剂或催化剂，可以将残留的氨氧化分解成氮氧化物。

4. 发明授权

US5677254A Catalyst for purifying an exhaust gas 失效
标题翻译：用于净化废气的催化剂
公开(公告)号：US5677254A
公开(公告)日：1997-10-14
申请号：US665820
申请日：1996-06-19
申请人： Shigeru Nojima , Kozo Iida , Norihisa Kobayashi , Satoru Serizawa , Atsushi Morii
发明人： Shigeru Nojima , Kozo Iida , Norihisa Kobayashi , Satoru Serizawa , Atsushi Morii
IPC分类号： B01J29/04 , B01J29/88 , B01J29/46 , B01J29/48
CPC分类号： B01J29/88 , B01J29/04
摘要： This invention relates to a catalyst for purifying an exhaust gas, which has a denitrification property in the lean atmosphere and good durability and is hardly deteriorated even in a high temperature rich atmosphere. The feature thereof consists in a catalyst for purifying an exhaust gas, comprising a crystalline silicate having the specified X-ray diffraction pattern and a chemical composition represented by the following chemical formula in the term of mole ratios of oxides under dehydrated state, (1.+-.0.8)R.sub.2 O.�aM.sub.2 O.sub.3.bM'O.cAl.sub.2 O.sub.3 !.ySiO.sub.2 in which R is at least one of alkali metal ions and hydrogen ion, M is at least one elementary ion selected from the group consisting of Group VIII elements of Periodic Table, rare earth elements, titanium, vanadium, chromium, niobium, antimony and gallium, M' is an alkaline earth metal ion selected from magnesium, calcium, strontium and barium ions, a>0, 20>b.gtoreq.0, a+c=1 and 3000>y>11, on which (I) at least one member selected from platinum group metals and (II) at least one metal selected from platinum group metals and at least one metal selected from the group consisting of rare earth elements are supported.
摘要翻译：本发明涉及一种排气净化用催化剂，其在贫气氛下具有脱氮性，耐久性良好，即使在高温环境下也难以劣化。其特征在于，用于净化废气的催化剂，包括具有规定的X射线衍射图的结晶硅酸盐和由脱水状态的氧化物的摩尔比表示的以下化学式表示的化学组成，（1+ /0.8)R2O.Am2O3.bM'O.cAl2O3.p.SiO2，其中R是碱金属离子和氢离子中的至少一种，M是至少一种选自元素周期的VIII族元素的元素离子表，稀土元素，钛，钒，铬，铌，锑和镓，M'是选自镁，钙，锶和钡离子的碱土金属离子，a> 0,20> b> / = 0，a + c = 1和3000> y> 11，其中（I）选自铂族金属中的至少一种和（II）选自铂族金属中的至少一种金属和选自稀有金属中的至少一种金属支持地球元素。

5. 发明授权

US6025292A Method for the regeneration of a denitration catalyst 失效
标题翻译：脱硝催化剂再生方法
公开(公告)号：US6025292A
公开(公告)日：2000-02-15
申请号：US023219
申请日：1998-02-12
申请人： Yoshiaki Obayashi , Kouzo Iida , Atsushi Morii , Osamu Naito , Akira Hattori
发明人： Yoshiaki Obayashi , Kouzo Iida , Atsushi Morii , Osamu Naito , Akira Hattori
IPC分类号： B01D53/86 , B01D53/94 , B01D53/96 , B01J23/92 , B01J38/60 , B01J27/28
CPC分类号： B01J23/92 , B01D53/8625 , B01J38/60 , Y02C20/30
摘要： Disclosed are (1) a method for the regeneration of a denitration catalyst wherein, in order to regenerate a denitration catalyst having reduced denitration power, the catalyst is cleaned with a cleaning fluid having a hydrofluoric acid concentration of 0.3 to 3% by weight and maintained at a temperature of 20 to 80.degree. C., and (2) a method for the regeneration of a denitration catalyst which comprises the steps of cleaning a denitration catalyst having reduced denitration power under the conditions described in (1) above, drying the cleaned catalyst, and impregnating the catalyst with a catalytically active component so as to support it on the catalyst.
摘要翻译：公开了（1）一种用于再生脱硝催化剂的方法，其中为了再生具有降低的脱硝功率的脱硝催化剂，用具有0.3至3重量％的氢氟酸浓度的清洁流体清洁催化剂，并保持温度为20〜80℃，（2）脱硝催化剂的再生方法，其特征在于，在上述（1）所述的条件下，对具有降低的脱硝功率的脱硝催化剂进行清洗，催化剂，并用催化活性组分浸渍催化剂以便将其载于催化剂上。

6. 发明授权

US4869735A Adsorbent for arsenic compound and method for removing arsenic compound from combustion gas 失效
标题翻译：用于砷化合物的吸附剂和从燃烧气体中除去砷化合物的方法
公开(公告)号：US4869735A
公开(公告)日：1989-09-26
申请号：US187470
申请日：1988-04-28
申请人： Masaki Miyazawa , Norihisa Kobayashi , Hiromu Takatsuka , Atsushi Morii , Toshio Koyanagi , Touru Seto , Kozo Iida , Shigeaki Mitsuoka , Hiroaki Rikimaru , Makoto Imanari , Takeo Koshikawa , Akihiro Yamauchi , Masayuki Hanada , Morio Fukuda , Kiyoshi Nagano
发明人： Masaki Miyazawa , Norihisa Kobayashi , Hiromu Takatsuka , Atsushi Morii , Toshio Koyanagi , Touru Seto , Kozo Iida , Shigeaki Mitsuoka , Hiroaki Rikimaru , Makoto Imanari , Takeo Koshikawa , Akihiro Yamauchi , Masayuki Hanada , Morio Fukuda , Kiyoshi Nagano
IPC分类号： B01D53/64 , B01D53/10 , B01D53/46 , B01D53/86 , B01D53/94 , B01J20/02 , B01J20/10 , B01J20/18 , B01J20/28 , B01D19/00 , B01D53/02
CPC分类号： B01D53/46 , B01D53/10 , B01D53/8625 , B01D53/8628 , B01J20/02 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/186 , Y10S95/902
摘要： Here is provided an adsorbent for adsorbing and removing an arsenic compound which becomes a catalyst poison in a selective contact reduction process for removing nitrogen oxides (NOx) from a combustion exhaust gas by the use of an ammonia as a reducing agent and a denitrating catalyst.The adsorbent of the present invention comprises a material in which the total volume of pores is 0.2 to 0.7 cc/g and the volume of the pores having a pore diameter of 300 .ANG. or more is 10% or more with respect to the total pore volume, and the material is a specific element, its oxide, an ion-exchanged zeolite or the like.In addition, the present invention is directed to a method for removing the arsenic compound from the combustion exhaust gas by injecting the adsorbent into the flow of the gas on the upstream side of the denitrating catalyst.

7. 发明授权

US5897687A Ammonia adsorption apparatus 失效
标题翻译：氨吸附装置
公开(公告)号：US5897687A
公开(公告)日：1999-04-27
申请号：US546102
申请日：1995-10-20
申请人： Teruko Shimada , Toshiyuki Onishi , Satoru Serizawa , Atsushi Morii , Osamu Naito , Shigeyuki Nishijima
发明人： Teruko Shimada , Toshiyuki Onishi , Satoru Serizawa , Atsushi Morii , Osamu Naito , Shigeyuki Nishijima
IPC分类号： B01D53/04 , B01D53/86 , B01D53/02
CPC分类号： B01D53/0462 , B01D53/8631 , B01D2257/406 , B01D2259/40056 , B01D2259/40081 , B01D2259/4009 , B01D2259/402
摘要： Disclosed is an ammonia adsorption apparatus for removing ammonia contained in a treated gas discharged from a denitrator for decomposing nitrogen oxides present in exhaust gas using ammonia as a reducing agent, comprising at least two adsorption towers into which ammonia-containing exhaust gas is introduced in a vertical direction for removing the ammonia by adsorption, wherein, during regeneration of each adsorption tower, hot gas used for desorption purposes flows from a top toward a bottom of the adsorption tower and cooling gas flows from the bottom toward the top of the adsorption tower.
摘要翻译：公开了一种氨吸附装置，用于除氨中排出的处理气体中所含的氨，其中所述处理气体用于使用氨作为还原剂分解废气中存在的氮氧化物，所述脱氮器包括至少两个吸附塔，所述吸附塔中含有氨的废气被引入到通过吸附除去氨的垂直方向，其中，在每个吸附塔的再生期间，用于解吸目的的热气从吸附塔的顶部向底部流动，冷却气体从吸附塔的底部向顶部流动。

8. 发明授权

US5680884A Rectifying device 失效
标题翻译：整流装置
公开(公告)号：US5680884A
公开(公告)日：1997-10-28
申请号：US639999
申请日：1996-04-30
申请人： Shigeyuki Nishijima , Masaaki Taniguchi , Atsushi Morii , Osamu Naito
发明人： Shigeyuki Nishijima , Masaaki Taniguchi , Atsushi Morii , Osamu Naito
IPC分类号： F15D1/02 , B01D53/34 , B01F5/06 , B01J19/24 , B01J19/32
CPC分类号： B01J19/32 , B01F5/061 , B01F5/0614 , B01J19/24 , B01J2219/00072 , B01J2219/32286 , B01J2219/32293 , B01J2219/32296 , B01J2219/326
摘要： A high-performance rectifying device promotes the diffusion of energy, temperature and concentration in a fluid stream with a small pressure loss. The device is a lattice type rectifying device provided within a fluid flow passageway for equalizing the flow velocity distribution of the same fluid. Lattice elements each consist of two triangular plates disposed so as to form two opposed surfaces of a pyramid having its apex on the downstream side of the fluid flow and two other triangular plates forming two opposed surfaces of another pyramid having its apex jointed with the first-mentioned apex and having its bottom surface positioned on the downstream side of the fluid flow. The latter two opposed surfaces have their orientations deviated by 90 degrees from the two opposed surfaces on the upstream side. The lattice elements are arrayed in juxtaposition in directions perpendicular to the fluid flow with the orientation of adjacent lattice elements deviated by 90 degrees from each other and are connected in such a manner that the bottom surfaces of the above-mentioned pyramids may form a lattice. Furthermore the ratio of the length, in a direction parallel to the flow, of the lattice element to the breadth, in the direction perpendicular to the flow, of the lattice element should be kept in a range of 1.5-2.0. The lattice element may also be formed of a rectangular plate twisted by 90 degrees in the direction along the direction of the fluid flow.
摘要翻译：高性能整流装置促进能量，温度和浓度在流体流中的扩散，压力损失小。该装置是设置在流体流动通道内用于均衡相同流体的流速分布的格子式整流装置。晶格元件由两个三角形板组成，两个三角形板被设置成在流体流动的下游侧形成具有顶点的金字塔的两个相对表面，另外两个三角形板形成另一个金字塔的相对表面，其另一个金字塔的顶点与第一 - 并且其底表面位于流体流的下游侧。后两个相对的表面具有从上游侧的两个相对表面偏离90度的方向。晶格元素在垂直于流体流动的方向上并列排列，其中相邻晶格元素的取向相互偏离90度，并以上述棱锥的底表面形成晶格的方式连接。此外，在晶格元素的与流动方向垂直的方向上的平行于流动的方向上的晶格长度与宽度的比例应保持在1.5-2.0的范围内。格子元件也可以由沿流体流动方向的方向扭转90度的矩形板形成。

9. 发明授权

US6025298A Catalyst and process for the production thereof 有权
标题翻译：催化剂及其制备方法
公开(公告)号：US6025298A
公开(公告)日：2000-02-15
申请号：US243446
申请日：1999-02-03
申请人： Kiyoaki Imoto , Jun Tanabe , Osamu Naito , Atsushi Morii , Shuya Nagayama
发明人： Kiyoaki Imoto , Jun Tanabe , Osamu Naito , Atsushi Morii , Shuya Nagayama
IPC分类号： B01D53/94 , B01D53/86 , B01J21/06 , B01J23/22 , B01J23/24 , B01J23/28 , B01J23/30 , B01J35/04 , B01J35/06 , B01J37/02 , B01J23/00
CPC分类号： B01D53/8628 , B01J35/04 , B01J21/063 , B01J21/066 , B01J23/22 , B01J23/28 , B01J23/30 , B01J37/0201
摘要： The present invention provides a denitration catalyst which is designed to show a drop of the mechanical strength of the carrier to an acceptable extent even when used with an exhaust gas containing sulfur oxides while making the use of excellent water resistance or electrical insulating properties inherent to glass fibers and a process therefor. The denitration catalyst comprises a catalytically active component supported on a structure comprising a glass fiber free of B.sub.2 O.sub.3, an inorganic filler and an inorganic binder.
摘要翻译：本发明提供一种脱硝催化剂，其设计成即使在与含硫氧化物的废气一起使用时也能将载体的机械强度降低至可接受的程度，同时利用玻璃固有的优异的耐水性或电绝缘性能纤维及其工艺。脱硝催化剂包括负载在包含不含B2O3的玻璃纤维，无机填料和无机粘合剂的结构上的催化活性组分。

10. 发明授权

US5505919A Method for the denitration of exhaust gas 失效
标题翻译：废气脱硝方法
公开(公告)号：US5505919A
公开(公告)日：1996-04-09
申请号：US282962
申请日：1994-07-29
申请人： Atsushi Morii , Satoru Serizawa , Osamu Naito , Masanori Demoto , Toshiyuki Onishi , Norihisa Kobayashi , Kouzo Iida
发明人： Atsushi Morii , Satoru Serizawa , Osamu Naito , Masanori Demoto , Toshiyuki Onishi , Norihisa Kobayashi , Kouzo Iida
IPC分类号： B01D53/86 , B01D53/94 , F01N3/08 , B01J8/02
CPC分类号： B01D53/8625 , B01D53/8628 , Y02C20/10
摘要： A method for the denitration of exhaust gas from a gas turbine or an internal combustion engine which comprises (a) reducing a part of the NO.sub.2 constituting NO.sub.x contained in the exhaust gas to NO by means of a reduction catalyst bed for reducing NO.sub.2 to NO, the reduction catalyst bed being installed in flow communication with the exhaust gas outlet of the gas turbine or internal combustion engine, and (b) injecting NH.sub.3 into the exhaust gas within an exhaust heat recovery unit and then decomposing and removing NO.sub.x contained in the exhaust gas and now composed chiefly of NO, by means a denitration catalyst bed installed within the exhaust heat recovery unit to effect the catalytic reduction of NO.sub.x with NH.sub.3.
摘要翻译：一种用于从燃气轮机或内燃机脱硝废气的方法，该方法包括：（a）通过用于将NO 2还原为NO的还原催化剂床将排气中所含的构成NO 2的NO 2的一部分还原为NO，所述还原催化剂床安装成与所述燃气轮机或内燃机的排气出口流动连通，以及（b）将NH 3喷射到排气热回收单元内的废气中，然后分解和除去废气中所含的NOx 现在主要由NO组成，通过设置在废热回收装置内的脱硝催化剂床，以实现用NH 3催化还原NOx。

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