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1. 发明申请

US20050054523A9 Flue gas denitration catalyst and preparation process thereof 有权
标题翻译：烟气脱硝催化剂及其制备方法
公开(公告)号：US20050054523A9
公开(公告)日：2005-03-10
申请号：US10705365
申请日：2003-11-10
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Katsumi Nochi , Masashi Kiyosawa
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Katsumi Nochi , Masashi Kiyosawa
IPC分类号： B01D53/94 , B01D53/86 , B01J23/00 , B01J23/30 , B01J35/04 , B01J37/02
CPC分类号： B01D53/8631 , B01D53/8628 , B01J23/002 , B01J23/30 , B01J35/04 , B01J37/0238
摘要： Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
摘要翻译：本发明提供一种脱硝活性高，能够抑制副反应即SO2氧化的烟道气脱硝催化剂。和催化剂的制备方法。烟气脱硝催化剂包括TiO 2，WO 3和V 2 O 5。在催化剂的表面200μm以内的表面层中，将V 2 O 5负载在含有TiO 2和WO 3的载体上。 V2O5的负载量为0.4〜5wt。％，基于表层的重量，为0.1-0.9wt。％，基于催化剂的总重量。如此支持的V 2 O 5通过X射线衍射测得的微晶尺寸小于10nm。催化剂可以通过制备含有TiO 2和WO 3的混合物并且通过气相法将V 2 O 5负载在所制备的混合物的挤出产品的表面上来获得。催化剂也可以通过使V 2 O 5通过气相法在制备的混合物的粉末上负载并将所得粉末负载在成形产品的表面上来获得。

2. 发明授权

US07256155B2 Flue gas denitration catalyst and preparation process thereof 有权
标题翻译：烟气脱硝催化剂及其制备方法
公开(公告)号：US07256155B2
公开(公告)日：2007-08-14
申请号：US10705365
申请日：2003-11-10
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Katsumi Nochi , Masashi Kiyosawa
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Katsumi Nochi , Masashi Kiyosawa
IPC分类号： B01J23/00 , B01J21/00
CPC分类号： B01D53/8631 , B01D53/8628 , B01J23/002 , B01J23/30 , B01J35/04 , B01J37/0238
摘要： Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
摘要翻译：提供了具有高脱硝活性并能够抑制副反应，即SO 2氧化的烟道气脱硝催化剂。和催化剂的制备方法。烟道气脱硝催化剂包括TiO 2，WO 3和V 2 O 5。在催化剂的表面200μm以内的表面层中，V 2 O 2 O 5负载在含有TiO 2和WO 2的载体上 3 。 V 2 O 5的支持量为0.4-5重量％。％，基于表层的重量，为0.1-0.9wt。％，基于催化剂的总重量。如此支撑的V 2 O 5 5具有通过X射线衍射测量的小于10nm的微晶尺寸。催化剂可以通过制备含有TiO 2和WO 3的混合物并具有V 2 O 5 O 5 在制备的混合物的挤出产物的表面上通过气相法。催化剂也可以通过使V 2 O 2 O 5通过气相法负载在所制备的混合物的粉末上，并将所得粉末负载在表面上成型产品。

3. 发明申请

US20080176742A1 Method For Producing Catalyst For Treating Exhaust Gas 审中-公开
标题翻译：生产废气处理催化剂的方法
公开(公告)号：US20080176742A1
公开(公告)日：2008-07-24
申请号：US11576041
申请日：2005-03-04
申请人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
发明人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
IPC分类号： B01J37/02 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/63 , B01J23/648 , B01J23/652 , B01J23/656 , B01J23/89 , B01J27/185
CPC分类号： B01J35/0013 , B01D53/864 , B01D53/8668 , B01D2257/708 , B01J21/04 , B01J23/38 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/462 , B01J23/464 , B01J23/468 , B01J23/48 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/63 , B01J23/6482 , B01J23/652 , B01J23/6562 , B01J23/89 , B01J37/0211 , B01J37/0213 , B01J37/0242 , B01J37/16
摘要： An object of the present invention is to provide a method for producing a catalyst for treating exhaust gas, enabling a smaller amount of a noble metal to be supported and reducing the production cost thereof. There is provided a method for producing a catalyst for treating an exhaust gas containing carbon monoxide and volatile organic compounds, wherein the method comprises: preparing, as a pH buffer solution, an aqueous metal salt solution in which at least one metal salt is dissolved; reductively-treating the aqueous metal salt solution while keeping the pH constant to prepare a metal colloid solution; and immersing a carrier in the metal colloid solution to support the metal on the carrier. The supported amount of metal may be 0.7 g/L or less per one of the metals.
摘要翻译：本发明的目的在于提供一种废气处理用催化剂的制造方法，能够减少贵金属的负载量，降低其制造成本。提供了一种用于处理含有一氧化碳和挥发性有机化合物的废气的催化剂的方法，其中所述方法包括：制备溶解有至少一种金属盐的金属盐水溶液作为pH缓冲溶液; 在保持pH恒定的同时还原性处理金属盐水溶液以制备金属胶体溶液; 并将载体浸渍在金属胶体溶液中以将金属支撑在载体上。每个金属的金属的负载量可以为0.7g / L以下。

4. 发明申请

US20090022643A1 SO3 REDUCTION CATALYST FOR PURIFYING AN EXHAUST GAS, PREPARATION PROCESS THEREOF, AND EXHAUST GAS PURIFYING METHOD USING THE CATALYST 审中-公开
标题翻译：用于净化排气的SO3还原催化剂，其制备方法和使用催化剂的排气净化方法
公开(公告)号：US20090022643A1
公开(公告)日：2009-01-22
申请号：US11908902
申请日：2005-04-06
申请人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
发明人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
IPC分类号： B01D53/50 , B01J23/46 , B01J21/08 , B01J27/25 , B01J27/10 , B01J27/08 , B01J27/053 , B01J27/24 , B01J31/12 , B01J23/28 , B01J23/30 , B32B3/12
CPC分类号： B01D53/8628 , B01D53/8609 , B01J21/063 , B01J21/066 , B01J23/46 , B01J23/462 , B01J23/468 , B01J23/652 , B01J23/6525 , B01J23/6527 , B01J35/0073 , B01J35/04 , B01J37/0211 , Y10T428/24149
摘要： To provide an SO3 reduction catalyst for purifying an exhaust gas capable of efficiently reducing the amount of SO3 that is present in a combustion exhaust gas and is a starting substance of S-containing substances such as acid ammonium sulfate causing deterioration of performance of the catalyst or corrosion of apparatuses disposed downstream of the catalyst, or capable of controlling the generation of SO3 in the catalyst itself; a preparation process of the catalyst; and an exhaust gas purifying method using the catalyst.In the catalyst for purifying a combustion exhaust gas containing nitrogen oxides, 50 wt. % or greater of the amount of Ru and/or Ir to be supported is adjusted to fall within a depth of 150 μm from the surface layer of a substrate; and the catalyst is prepared by immersing the substrate in a metal colloid solution of Ru and/or Ir to be supported or an aqueous solution containing at least one compound selected from compounds of Ru and/or Ir to be supported.
摘要翻译：提供一种用于净化排气的SO 3还原催化剂，其能够有效地减少燃烧废气中存在的SO 3的量，并且是含有S的物质如酸式硫酸铵的起始物质，导致催化剂的性能降低，或者设置在催化剂下游的装置的腐蚀，或能够控制催化剂本身中SO 3的产生; 催化剂的制备方法; 和使用该催化剂的排气净化方法。在用于净化含有氮氧化物的燃烧废气的催化剂中，要负载的Ru和/或Ir的量的％或更多的量被调节为落在离衬底的表面层150μm的深度内; 并将催化剂浸渍在待负载的Ru和/或Ir的金属胶体溶液中，或含有至少一种选自待负载的Ru和/或Ir化合物的化合物的水溶液中。

5. 发明申请

US20050137082A1 Catalyst for removing nitrogen oxides, catalyst molded product therefore, and exhaust gas treating method, and composite power generation system 有权
标题翻译：因此，用于除去氮氧化物的催化剂，催化剂成型体，废气处理方法以及复合发电系统
公开(公告)号：US20050137082A1
公开(公告)日：2005-06-23
申请号：US10822441
申请日：2004-04-12
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
IPC分类号： F01N3/10 , B01D53/86 , B01D53/94 , B01J21/06 , B01J23/00 , B01J23/22 , B01J23/30 , B01J23/85 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/00 , B01J37/04
CPC分类号： B01J23/002 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/0009 , B01J37/0018 , B01J2523/00 , B01J2523/47 , B01J2523/55 , B01J2523/69 , B01J2523/842 , B01J2523/17 , B01J2523/67 , B01J2523/41
摘要： The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.
摘要翻译：本发明提供一种除去氮氧化物的催化剂，其能够保持足够的脱氮性能，即具有高NO 2 2含量的废气中的氮氧化物的高去除率，特别是在排气中的NO 2 2 / NO的比例为1以上，催化剂成型体和废气处理方法。催化剂设计用于除去氮氧化物，其用于使具有高NO 2 2 N含量的氮氧化物的废气脱氮，该氮氧化物包括：至少一种选自氧化铜，氧化铬和氧化铁作为将NO 2还原成NO的组分; 并且还包括：至少一种氧化钛; 至少一种氧化钨; 和至少一种氧化钒作为用于将NO还原成N 2的组分。

6. 发明申请

US20120039758A1 Catalyst for Removing Nitrogen Oxides 有权
标题翻译：用于去除氮氧化物的催化剂
公开(公告)号：US20120039758A1
公开(公告)日：2012-02-16
申请号：US13279818
申请日：2011-10-24
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
IPC分类号： B01D53/56
CPC分类号： B01J23/002 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/0009 , B01J37/0018 , B01J2523/00 , B01J2523/47 , B01J2523/55 , B01J2523/69 , B01J2523/842 , B01J2523/17 , B01J2523/67 , B01J2523/41
摘要： The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.
摘要翻译：本发明提供一种用于除去氮氧化物的催化剂，其能够保持足够的脱氮性能，即，具有高NO 2含量的废气中的氮氧化物的高除去率，特别是在排气中的NO 2 / NO的比例气体为1以上，其催化剂成型体和废气处理方法。催化剂被设计用于除去氮氧化物，其用于使具有高NO 2含量的氮氧化物的废气脱氮，其包括：选自氧化铜，氧化铬和氧化铁中的至少一种氧化物，将NO2还原为NO的成分; 并且还包括：至少一种氧化钛; 至少一种氧化钨; 和至少一种氧化钒作为将NO还原成N2的组分。

7. 发明授权

US08852518B2 Catalyst for removing nitrogen oxides 有权
公开(公告)号：US08852518B2
公开(公告)日：2014-10-07
申请号：US12117267
申请日：2008-05-08
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
IPC分类号： B01D50/00 , B01D53/34 , B01J23/00 , B01J23/70 , B01J23/72 , B01J23/888 , B01D53/86 , B01J35/04 , B01J23/86 , B01J37/00 , B01J21/06
CPC分类号： B01J23/002 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/0009 , B01J37/0018 , B01J2523/00 , B01J2523/47 , B01J2523/55 , B01J2523/69 , B01J2523/842 , B01J2523/17 , B01J2523/67 , B01J2523/41
摘要： The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.

8. 发明授权

US08663567B2 Catalyst for removing nitrogen oxides 有权
标题翻译：用于除去氮氧化物的催化剂
公开(公告)号：US08663567B2
公开(公告)日：2014-03-04
申请号：US13279818
申请日：2011-10-24
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
IPC分类号： B01D50/00 , B01D53/34 , B01J23/00 , B01J21/00
CPC分类号： B01J23/002 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/0009 , B01J37/0018 , B01J2523/00 , B01J2523/47 , B01J2523/55 , B01J2523/69 , B01J2523/842 , B01J2523/17 , B01J2523/67 , B01J2523/41
摘要： The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.
摘要翻译：本发明提供一种用于除去氮氧化物的催化剂，其能够保持足够的脱氮性能，即，具有高NO 2含量的废气中的氮氧化物的高除去率，特别是在排气中的NO 2 / NO的比例气体为1以上，其催化剂成型体和废气处理方法。催化剂被设计用于除去氮氧化物，其用于使具有高NO 2含量的氮氧化物的废气脱氮，其包括：选自氧化铜，氧化铬和氧化铁中的至少一种氧化物，将NO2还原为NO的成分; 并且还包括：至少一种氧化钛; 至少一种氧化钨; 和至少一种氧化钒作为将NO还原成N2的组分。

9. 发明授权

US07413715B2 Catalyst for removing nitrogen oxides 有权
标题翻译：用于除去氮氧化物的催化剂
公开(公告)号：US07413715B2
公开(公告)日：2008-08-19
申请号：US10822441
申请日：2004-04-12
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Masashi Kiyosawa , Masanori Demoto
IPC分类号： B01J23/00 , B01D50/00 , B01D53/34
CPC分类号： B01J23/002 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/86 , B01J23/888 , B01J35/04 , B01J37/0009 , B01J37/0018 , B01J2523/00 , B01J2523/47 , B01J2523/55 , B01J2523/69 , B01J2523/842 , B01J2523/17 , B01J2523/67 , B01J2523/41
摘要： The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to No; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.
摘要翻译：本发明提供一种除去氮氧化物的催化剂，其能够保持足够的脱氮性能，即具有高NO 2 2含量的废气中的氮氧化物的高去除率，特别是在排气中的NO 2 2 / NO的比例为1以上，催化剂成型体和废气处理方法。催化剂设计用于除去氮氧化物，其用于使具有高NO 2 2 N含量的氮氧化物的废气脱氮，该氮氧化物包括：至少一种选自氧化铜，氧化铬和氧化铁作为将NO 2还原为No的组分; 并且还包括：至少一种氧化钛; 至少一种氧化钨; 和至少一种氧化钒作为用于将NO还原成N 2的组分。

10. 发明授权

US4952381A Method for denitrizing nitrogen oxides contained in waste gas 失效
标题翻译：废气中所含氮氧化物脱氮的方法
公开(公告)号：US4952381A
公开(公告)日：1990-08-28
申请号：US284764
申请日：1988-12-12
申请人： Horiaki Rikimaru , Tadao Nakatsuji , Toshikatsu Umaba , Kazuhiko Nagano , Kazuya Mishina , Hiromitsu Shimizu , Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Touru Seto , Shigeaki Mitsuoka , Masayuki Hanada , Morio Fukuda , Kiyoshi Nagano , Makoto Imanari , Takeo Koshikawa , Akihiro Yamauchi
发明人： Horiaki Rikimaru , Tadao Nakatsuji , Toshikatsu Umaba , Kazuhiko Nagano , Kazuya Mishina , Hiromitsu Shimizu , Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi , Touru Seto , Shigeaki Mitsuoka , Masayuki Hanada , Morio Fukuda , Kiyoshi Nagano , Makoto Imanari , Takeo Koshikawa , Akihiro Yamauchi
IPC分类号： B01D53/86 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/34 , B01J23/843 , B01J23/889
CPC分类号： B01J23/34 , B01D53/8628 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/8432 , B01J23/8892
摘要： A catalyst for denitrizing nitrogen oxides contained in waste gas which contains a substantial amount of arsenic compounds therein, which comprises:(a) titanium, and(b) at least one element selected from the group consisting of arsenic and manganese. The catalyst is resistant to deactivation by arsenic compounds and retains high denitrizing activity over a long period of time. The catalyst may further contain at least one base metal selected from the group consisting of V, W, Mo, Cu, Fe, Cr, Co, Ni, Zn and Sn.

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