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1. 发明申请

US20050244588A1 Method of observing monolayer ultraviolet decomposition process, method of controlling degree of surface decomposition, and patterning method 有权
标题翻译：观察单层紫外分解过程的方法，控制表面分解程度的方法和图案化方法
公开(公告)号：US20050244588A1
公开(公告)日：2005-11-03
申请号：US10913523
申请日：2004-08-09
申请人： Hitoshi Fukushima , Masaya Ishida , Stephen Evans , Kevin Critchley
发明人： Hitoshi Fukushima , Masaya Ishida , Stephen Evans , Kevin Critchley
IPC分类号： G01N23/227 , B05D3/00 , G01N13/02 , G03F7/004 , G03F7/075 , G03F7/16 , G03F7/20 , H01L21/66
CPC分类号： G01N23/2273 , G03F7/0046 , G03F7/0754 , G03F7/165
摘要： Aspects of the invention can provide a method of effectively observing the photodecomposition process of a monolayer in real time. The invention can provide a method of observing the decomposition process of a monolayer when the monolayer is irradiated with UV rays, where the structure of the constituent molecule of the monolayer in an ultrahigh vacuum atmosphere and an oxygen-containing atmosphere respectively can be measured by a molecular structure measuring device during the UV irradiation. The invention can also provide a method of controlling the degree of surface decomposition of the monolayer that controls the ozone concentration accompanying the UV irradiation based on observation results obtained by using the observation method. The invention can further provide a method of patterning the monolayer that employs the control method.
摘要翻译：本发明的方面可以提供一种实时有效观察单层光分解过程的方法。本发明可以提供一种在用UV射线照射单层时观察单层的分解过程的方法，其中分层的超高真空气氛和含氧气氛中的单层构成分子的结构可以通过紫外线照射下的分子结构测量装置。本发明还可以提供一种控制根据通过使用观察方法获得的观察结果来控制伴随UV照射的臭氧浓度的单层的表面分解程度的方法。本发明还可以提供采用该控制方法的单层图案化方法。

2. 发明授权

US07326580B2 Method of observing monolayer ultraviolet decomposition process, method of controlling degree of surface decomposition, and patterning method 有权
标题翻译：观察单层紫外分解过程的方法，控制表面分解程度的方法和图案化方法
公开(公告)号：US07326580B2
公开(公告)日：2008-02-05
申请号：US10913523
申请日：2004-08-09
申请人： Hitoshi Fukushima , Masaya Ishida , Stephen Evans , Kevin Critchley
发明人： Hitoshi Fukushima , Masaya Ishida , Stephen Evans , Kevin Critchley
IPC分类号： H01L21/00
CPC分类号： G01N23/2273 , G03F7/0046 , G03F7/0754 , G03F7/165
摘要： Aspects of the invention can provide a method of effectively observing the photodecomposition process of a monolayer in real time. The invention can provide a method of observing the decomposition process of a monolayer when the monolayer is irradiated with UV rays, where the structure of the constituent molecule of the monolayer in an ultrahigh vacuum atmosphere and an oxygen-containing atmosphere respectively can be measured by a molecular structure measuring device during the UV irradiation. The invention can also provide a method of controlling the degree of surface decomposition of the monolayer that controls the ozone concentration accompanying the UV irradiation based on observation results obtained by using the observation method. The invention can further provide a method of patterning the monolayer that employs the control method.
摘要翻译：本发明的方面可以提供一种实时有效观察单层光分解过程的方法。本发明可以提供一种在用UV射线照射单层时观察单层的分解过程的方法，其中分层的超高真空气氛和含氧气氛中的单层构成分子的结构可以通过紫外线照射下的分子结构测量装置。本发明还可以提供一种控制根据通过使用观察方法获得的观察结果来控制伴随UV照射的臭氧浓度的单层的表面分解程度的方法。本发明还可以提供采用该控制方法的单层图案化方法。

3. 发明申请

US20050245739A1 UV decomposable molecules and a photopatternable monomolecular film formed therefrom 失效
标题翻译：可UV分解分子和由其形成的可光化图案的单分子膜
公开(公告)号：US20050245739A1
公开(公告)日：2005-11-03
申请号：US11116265
申请日：2005-04-28
申请人： Hitoshi Fukushima , Hiroshi Takiguchi , Tatsuya Shimoda , Takashi Masuda , Richard Bushby , Stephan Evans , J.P. Jeyadevan , Kevin Critchley
发明人： Hitoshi Fukushima , Hiroshi Takiguchi , Tatsuya Shimoda , Takashi Masuda , Richard Bushby , Stephan Evans , J.P. Jeyadevan , Kevin Critchley
IPC分类号： C07D207/40 , C07D207/404 , G03F7/004 , G03F7/16 , C07D487/04
CPC分类号： C07D207/404 , B82Y30/00 , G03F7/0045 , G03F7/165 , Y10S430/116 , Y10S430/136
摘要： Aspects of the invention provide a method of controlling the solid-state property of the solid-phase surface or controlling forming reactive region. The method can be attained by using a device for ejecting droplets and a molecule for inclusion in a SAM which can be photo-patterned in a short period of time using low energy UV radiation, that is TV radiation having a relatively long wavelength. The invention can provide monomolecular film that is formed from molecules comprising a structural component (B) which is hydrophobic and/or lipophobic, and a structural component (A) which decomposes when irradiated with UV light having a wavelength in the range 254-400 nm to cleave away a part of the molecule having the structural component (B) leaving a residual hydrophilic structural component (C). Further, the invention can provide a method of forming a film pattern comprising; at least a step of ejecting a droplet, which includes a compound represented as the following Formula (0), on a solid-phase surface having a functional moiety: X—Y—Z (0) where, X represents a structure having reactivity to a functional moiety which exists at the solid-phase surface, Y represents a decomposable structure by itself and Z represents a structure which is capable of changing solid-state properties on the solid-phase surface or a reactive structure.
摘要翻译：本发明的方面提供了一种控制固相表面的固态特性或控制成形反应区的方法。该方法可以通过使用用于喷射液滴的装置和用于包含在SAM中的分子来实现，该SAM可以使用低能量UV辐射（即具有相对长的波长的电视辐射）在短时间内进行光刻图案化。本发明可以提供由分子构成的单分子膜，该分子包含疏水性和/或疏水性的结构成分（B）和当波长为254-400nm的紫外线照射时分解的结构成分（A）以除去具有结构组分（B）的分子的一部分，留下残留的亲水结构组分（C）。此外，本发明可以提供一种形成膜图案的方法，包括：在具有功能部分的固相表面上至少喷射包含下述式（0）表示的化合物的液滴的步骤：<？in-line-formula description =“In-line Formulas”end = “lead”？> XYZ（0）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中，X表示与固相存在的功能部分具有反应性的结构表面，Y表示本身可分解的结构，Z表示能够改变固相表面或反应性结构的固态性质的结构。

4. 发明授权

US07479362B2 UV decomposable molecules and a photopatternable monomolecular film formed therefrom 失效
标题翻译：可UV分解分子和由其形成的可光化图案的单分子膜
公开(公告)号：US07479362B2
公开(公告)日：2009-01-20
申请号：US11116265
申请日：2005-04-28
申请人： Hitoshi Fukushima , Hiroshi Takiguchi , Tatsuya Shimoda , Takashi Masuda , Richard James Bushby , Stephan Evans , J.P. Jeyadevan , Kevin Critchley
发明人： Hitoshi Fukushima , Hiroshi Takiguchi , Tatsuya Shimoda , Takashi Masuda , Richard James Bushby , Stephan Evans , J.P. Jeyadevan , Kevin Critchley
IPC分类号： G03F7/00 , G03F7/004
CPC分类号： C07D207/404 , B82Y30/00 , G03F7/0045 , G03F7/165 , Y10S430/116 , Y10S430/136
摘要： Aspects of the invention provide a method of controlling the solid-state property of the solid-phase surface or controlling forming reactive region. The method can be attained by using a device for ejecting droplets and a molecule for inclusion in a SAM which can be photo-patterned in a short period of time using low energy UV radiation, that is TV radiation having a relatively long wavelength. The invention can provide monomolecular film that is formed from molecules comprising a structural component (B) which is hydrophobic and/or lipophobic, and a structural component (A) which decomposes when irradiated with UV light having a wavelength in the range 254-400 nm to cleave away a part of the molecule having the structural component (B) leaving a residual hydrophilic structural component (C). Further, the invention can provide a method of forming a film pattern comprising; at least a step of ejecting a droplet, which includes a compound represented as the following Formula (0), on a solid-phase surface having a functional moiety: X—Y-Z (0) where, X represents a structure having reactivity to a functional moiety which exists at the solid-phase surface, Y represents a decomposable structure by itself and Z represents a structure which is capable of changing solid-state properties on the solid-phase surface or a reactive structure.
摘要翻译：本发明的方面提供了一种控制固相表面的固态特性或控制成形反应区的方法。该方法可以通过使用用于喷射液滴的装置和用于包含在SAM中的分子来实现，该SAM可以使用低能量UV辐射（即具有相对长的波长的电视辐射）在短时间内进行光刻图案化。本发明可以提供由分子构成的单分子膜，该分子包含疏水性和/或疏水性的结构成分（B）和当波长为254-400nm的紫外线照射时分解的结构成分（A）以除去具有结构组分（B）的分子的一部分，留下残留的亲水结构组分（C）。此外，本发明可以提供一种形成膜图案的方法，包括：在具有功能部分的固相表面上至少喷射包含下述式（0）表示的化合物的液滴的步骤：<？in-line-formula description =“In-line Formulas”end = “lead”？> XYZ（0）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中，X表示与固相存在的功能部分具有反应性的结构表面，Y表示本身可分解的结构，Z表示能够改变固相表面或反应性结构的固态性质的结构。

5. 发明授权

US07524998B2 Fabrication of self-assembled dendron monolayers 有权
标题翻译：自组装树枝状单层的制备
公开(公告)号：US07524998B2
公开(公告)日：2009-04-28
申请号：US11170057
申请日：2005-06-30
申请人： Hitoshi Fukushima , Satoshi Nebashi , Masaya Ishida , Wilhelm J S Huck , Andrew B Holmes , Christine K Luscombe
发明人： Hitoshi Fukushima , Satoshi Nebashi , Masaya Ishida , Wilhelm J S Huck , Andrew B Holmes , Christine K Luscombe
IPC分类号： C07C22/08 , C07C22/04 , C07C22/02 , C07C22/00 , B32B9/04 , B32B17/06 , B32B17/00
CPC分类号： C08G83/003 , B82Y30/00 , B82Y40/00 , C07C323/12 , Y10S977/754 , Y10T428/31504
摘要： A dendron (2) comprising a focal point (4) and a plurality of fluorinated end groups (9) is disclosed, including one having a thiol, a silane, a carboxylic acid, a phosphonate or another moiety at the focal point suitable for chemisorption to a substrate (3). A self-assembled monolayer comprising a plurality of dendrons bonded to a substrate and a device comprising the self-assembled monolayer are also disclosed.
摘要翻译：公开了包含焦点（4）和多个氟化端基（9）的树突（2），其包括在适于化学吸附的焦点上具有硫醇，硅烷，羧酸，膦酸酯或另一部分的树枝状体到基板（3）。还公开了一种包含多个结合到基底上的树突的自组装单层和包括该自组装单层的器件。

6. 发明申请

US20060008678A1 Fabrication of self-assembled dendron monolayers 有权
公开(公告)号：US20060008678A1
公开(公告)日：2006-01-12
申请号：US11170057
申请日：2005-06-30
申请人： Hitoshi Fukushima , Satoshi Nebashi , Masaya Ishida , Wilhelm Huck , Andrew Holmes , Christine Luscombe
发明人： Hitoshi Fukushima , Satoshi Nebashi , Masaya Ishida , Wilhelm Huck , Andrew Holmes , Christine Luscombe
IPC分类号： B32B9/04 , B32B17/06
CPC分类号： C08G83/003 , B82Y30/00 , B82Y40/00 , C07C323/12 , Y10S977/754 , Y10T428/31504
摘要： A dendron (2) comprising a focal point (4) and a plurality of fluorinated end groups (9) is disclosed, including one having a thiol, a silane, a carboxylic acid, a phosphonate or another moiety at the focal point suitable for chemisorption to a substrate (3). A self-assembled monolayer comprising a plurality of dendrons bonded to a substrate and a device comprising the self-assembled monolayer are also disclosed.

7. 发明授权

US07098145B2 Fabrication of self-assembled monolayers 有权
标题翻译：自组装单层膜的制作
公开(公告)号：US07098145B2
公开(公告)日：2006-08-29
申请号：US10006794
申请日：2001-12-04
申请人： Hitoshi Fukushima , Satoru Miyashita , Masaya Ishida , Andrew Holmes , Wilhelm Huck , Christine K Luscombe
发明人： Hitoshi Fukushima , Satoru Miyashita , Masaya Ishida , Andrew Holmes , Wilhelm Huck , Christine K Luscombe
IPC分类号： H01L21/31 , H01L21/469 , C23C16/00
CPC分类号： B82Y30/00 , B05D1/185 , B05D2401/90 , B82Y40/00 , H01L51/0075
摘要： A self-assembled monolayer (SAM) is fabricated using either a semi-fluorinated sulphur containing compound, or a sem-fluorinated silane derivative and compressed carbon dioxide (CO2) as the solvent medium. The temperature and/or pressure of the compressed CO2 may be varied during the fabrication process to improve the molecular packing density of the monolayer.By using compressed CO2 as the solvent medium, monolayers with good molecular packing density can be fabricated relatively quickly without the use of environmentally unfriendly solvents.
摘要翻译：使用半氟化含硫化合物或半氟化硅烷衍生物和压缩二氧化碳（CO 2 CO 2）作为溶剂介质制备自组装单层（SAM）。压缩的CO 2的温度和/或压力可以在制造过程中变化，以改善单层的分子堆积密度。通过使用压缩的CO 2 2作为溶剂介质，可以相对快速地制备具有良好分子堆积密度的单层，而不使用环境不友好的溶剂。

8. 发明申请

US20130345408A1 ANTIBODY AGAINST AMYLOID PRECURSOR PROTEIN SIGNAL PEPTIDE 有权
标题翻译：抗体蛋白前体蛋白信号肽抗体
公开(公告)号：US20130345408A1
公开(公告)日：2013-12-26
申请号：US13978584
申请日：2012-01-06
申请人： Hitoshi Fukushima , Masato Hanamura , Mikio Niwa , Masaji Okamoto , Tomoko Naoe , Tetsuhiko Yoshida
发明人： Hitoshi Fukushima , Masato Hanamura , Mikio Niwa , Masaji Okamoto , Tomoko Naoe , Tetsuhiko Yoshida
IPC分类号： C07K16/18
CPC分类号： C07K16/18 , C12N5/12
摘要： An advantage of some aspects of the invention is to provide an antibody against an amyloid precursor protein signal peptide. The invention provides an amyloid precursor protein signal peptide.
摘要翻译：本发明的一些方面的优点是提供抗淀粉样蛋白前体蛋白信号肽的抗体。本发明提供淀粉样蛋白前体蛋白信号肽。

9. 发明授权

US07998413B2 Biosensor and method of manufacturing biosensor 有权
标题翻译：生物传感器和生物传感器的制造方法
公开(公告)号：US07998413B2
公开(公告)日：2011-08-16
申请号：US12216203
申请日：2008-07-01
申请人： Hitoshi Fukushima , Takayuki Kondo
发明人： Hitoshi Fukushima , Takayuki Kondo
IPC分类号： G01N21/00 , G02B6/00 , G01N33/53
CPC分类号： G01N21/6452 , G01N21/553 , G01N21/6428 , G01N21/6454
摘要： Aspects of the invention can be an inexpensive biosensor capable of measuring a number of samples in a short time, and suitable for only one-time use (expendable). The biosensor according to the invention can include a light transmissive substrate, a probe fixing region provided on one face of the light transmissive substrate, a light emitting element provided on the other face of the substrate that irradiates the probe fixing region from the back side thereof, and a light receiving element provided on the other face of the substrate that detects the light intensity of the reflected light from the back side of the probe fixing region. Thereby, a biosensor formed in one substrate can be obtained.
摘要翻译：本发明的方面可以是一种廉价的生物传感器，其能够在短时间内测量多个样品，并且仅适合于一次使用（一次性）。根据本发明的生物传感器可以包括透光基板，设置在透光基板的一个面上的探针固定区域，设置在从其背面照射探针固定区域的基板的另一面上的发光元件以及设置在基板的另一面上的光接收元件，其检测来自探针固定区域的背侧的反射光的光强度。由此，能够得到在一个基板上形成的生物传感器。

10. 发明授权

US07491496B2 Method for immobilizing nucleic acid and method for manufacturing biosensor using the same method 失效
标题翻译：用于固定核酸的方法和使用相同方法制造生物传感器的方法
公开(公告)号：US07491496B2
公开(公告)日：2009-02-17
申请号：US11090238
申请日：2005-03-28
申请人： Hiroshi Takiguchi , Hitoshi Fukushima
发明人： Hiroshi Takiguchi , Hitoshi Fukushima
IPC分类号： C12Q1/68 , C12M1/00
CPC分类号： B82Y30/00 , C12Q1/6832 , C12Q2565/518 , C12Q2527/125 , C12Q2525/197
摘要： A method is provided to enable high-density absorption when immobilizing nucleic acid probes onto a solid support surface by suppressing electrostatic repulsion among the nucleic acids. A nucleic acid immobilization method to immobilize a nucleic acid onto a solid support, includes: preparing a solution containing a probe molecule which includes a nucleic acid, a spacer molecule, and at least one kind of a divalent cation; and contacting the solution with the solid support for incubation.
摘要翻译：提供了一种通过抑制核酸之间的静电排斥将核酸探针固定在固体支持物表面上以实现高密度吸收的方法。将核酸固定在固体支持体上的核酸固定方法包括：制备含有探针分子的溶液，所述探针分子包括核酸，间隔子分子和至少一种二价阳离子; 并将溶液与固体支持物接触以进行孵育。

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