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1. 发明授权

US5851323A Pneumatic tire with air permeation preventive layer 失效
标题翻译：带防透气层的气动轮胎
公开(公告)号：US5851323A
公开(公告)日：1998-12-22
申请号：US750022
申请日：1997-02-19
申请人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe , Zenichiro Shida , Yoshiaki Hashimura
发明人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe , Zenichiro Shida , Yoshiaki Hashimura
IPC分类号： B60C1/00 , B60C5/14
CPC分类号： B60C1/0008 , B60C5/14 , B60C5/142 , Y10T152/10855
摘要： A pneumatic tire has an air permeation preventive layer comprising a film composed of a polymer composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer having an air permeation coefficient of not more than 25.times.10.sup.-12 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg and a Young's modulus of 1 to 1000 MPa which is arranged so as to substantially cover the inner surface of the tire at least in the range of 20 mm from the position of the two ends of the belt to the direction of the crown center and is also arranged so as to substantially cover the inner surface of the tire at the crown center side of a position a maximum of 20 mm from the position of the two ends of the belt to the direction of the bead portion and applies an air permeation preventive layer comprised of rubber so as to substantially cover the rest of the inner surface of the tire and using an air permeation preventive layer having an actual elongation at break of at least 15% in the circumferential direction and radial direction at the tire side portions in a range of at least 0.5H to 0.65H of the tire sectional height H.
摘要翻译： PCT No.PCT / JP96 / 00737 Sec。 371日期1997年2月19日 102（e）日期1997年2月19日PCT 1996年3月21日PCT公布。 WO96 / 30221 PCT出版物日期：1996年3月10日充气轮胎具有防透气层，其包含由含有热塑性树脂的聚合物组合物或热塑性树脂与弹性体的共混物构成的膜，该透气系数为25×10 12 cc×cm 3 / cm 2×sec×cmHg的杨氏模量和1〜1000MPa的杨氏模量，其布置成基本上覆盖轮胎的内表面至少在从带的两端的位置到冠中心的方向的20mm的范围内，以及还布置成基本上覆盖轮胎的内表面，该轮胎在冠部中心侧距离带的两端的位置至胎圈部分的方向最大为20mm的位置，并且施加防透气性由橡胶组成，以便基本上覆盖轮胎的内表面的其余部分，并且使用具有至少15％的实际断裂伸长率的防空气层在轮胎侧部的轮胎截面高度H的至少0.5H〜0.65H的范围内的方向和径向。

2. 发明授权

US6136123A Process of production of pneumatic tire 失效
标题翻译：充气轮胎生产工艺
公开(公告)号：US6136123A
公开(公告)日：2000-10-24
申请号：US765425
申请日：1996-12-31
申请人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe , Noriaki Kuroda , Gou Kawaguchi
发明人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe , Noriaki Kuroda , Gou Kawaguchi
IPC分类号： B60C1/00 , B60C5/14 , B29D30/08
CPC分类号： C08G18/44 , B60C1/0008 , B60C5/14 , C08G18/42 , C08G18/4277 , C08J5/125 , C08J5/128 , C09J107/00 , C09J175/04 , B60C2005/145 , C08J2321/00
摘要： A process for producing a pneumatic tire using, as an air permeation preventive layer, a strip-shaped or cylindrical-shaped single-layer or multiple-layer thermoplastic film, comprising:applying, to at least a part of the joining portion of the thermoplastic film or tire member facing the thermoplastic film, a tackifier-adhesive composition containing a polymer component having an absolute value of the difference of the critical surface tension with the rubber component of the tire member and the polymer component of the surface layer of the thermoplastic film of not more than 6 mN/m, respectively.
摘要翻译： PCT No.PCT / JP96 / 01031 Sec。 371日期1996年12月31日第 102（e）1996年12月31日PCT PCT 1996年4月15日PCT公布。公开号WO96 / 34736 日期：1996年7月11日利用带状或圆筒状的单层或多层热塑性薄膜作为防透气层的充气轮胎的制造方法，其特征在于，包括：向所述充气轮胎的至少一部分面向热塑性薄膜的热塑性薄膜或轮胎构件的接合部分，包含聚合物组分的增粘剂 - 粘合剂组合物，其具有临界表面张力与轮胎构件的橡胶组分的绝对值和表面的聚合物组分热塑性膜层分别不超过6mN / m。

3. 发明授权

US06402867B1 Process of production of pneumatic tire 有权
标题翻译：充气轮胎生产工艺
公开(公告)号：US06402867B1
公开(公告)日：2002-06-11
申请号：US09358691
申请日：1999-07-21
申请人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe , Noriaki Kuroda , Gou Kawaguchi
发明人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe , Noriaki Kuroda , Gou Kawaguchi
IPC分类号： B29D3008
CPC分类号： C08G18/44 , B60C1/0008 , B60C5/14 , B60C2005/145 , C08G18/42 , C08G18/4277 , C08J5/125 , C08J5/128 , C08J2321/00 , C09J107/00 , C09J175/04
摘要： A process for producing a pneumatic tire using, as an air permeation preventive layer, a strip-shaped or cylindrical-shaped single-layer or multiple-layer thermoplastic film, comprising: applying, to at least a part of the joining portion of the thermoplastic film or tire member facing the thermoplastic film, a tackifier-adhesive composition containing a polymer component having an absolute value of the difference of the critical surface tension with the rubber component of the tire member and the polymer component of the surface layer of the thermoplastic film of not more than 6 mN/m, respectively.
摘要翻译：一种使用带状或圆筒形单层或多层热塑性薄膜作为透气防止层的充气轮胎的制造方法，其特征在于，包括：向所述热塑性塑料的至少一部分接合部分面向热塑性膜的薄膜或轮胎构件，包含聚合物组分的增粘剂 - 粘合剂组合物，其具有临界表面张力与轮胎构件的橡胶组分的绝对值和热塑性膜的表面层的聚合物组分分别不超过6mN / m。

4. 发明授权

US5992486A Laminate gas barrier layer for pneumatic tires 失效
标题翻译：充气轮胎层压气体阻隔层
公开(公告)号：US5992486A
公开(公告)日：1999-11-30
申请号：US527214
申请日：1995-09-12
申请人： Shogo Katsuki , Kazuto Yamakawa , Jiro Watanabe , Hiroyuki Kaido
发明人： Shogo Katsuki , Kazuto Yamakawa , Jiro Watanabe , Hiroyuki Kaido
IPC分类号： B32B25/08 , B60C1/00 , B60C5/14 , B60C5/02 , B32B25/04
CPC分类号： B32B25/08 , B60C1/0008 , B60C5/14 , B29L2030/00 , B60C2005/145 , B60C2005/147 , Y10S152/16 , Y10T428/24967 , Y10T428/31743 , Y10T428/31746 , Y10T428/3175 , Y10T428/31797 , Y10T428/31826 , Y10T428/31891 , Y10T428/31909 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935
摘要： The invention provides a laminate suitable for use with a pneumatic tire having an inner liner or like air-impermeable layer capable of, for example, maintaining a requisite air pressure. The laminate I of the invention includes laminated films and a rubber layer (R), the laminated films being made of a gas barrier layer (A) and an adhesive layer (B), the layer (B) being provided on at least one side of the layer (A), the layer (A) being formed of at least one member selected from polyamide resins, polyester resins, polyarylate resins, polyamide-based alloys and polyester-based alloys, the laminated films being irradiated in at least one periphery with an electron beam, and the adhesive layer (B) being heat-bonded to the rubber layer (R). The laminate II of the invention includes laminated films and a rubber layer (R), the laminated films being made of a rubber-adhering layer (D), an adhesive layer (B) and a gas barrier layer (A), the layers (D), (B) and (A) being laminated in this order with a structure of at least three layers, the rubber-adhering layer (D) being formed of at least one polyolefin resin, the gas barrier layer (A) being formed of at least one member selected from polyamide resins, polyester resins, polyarylate resins, polyamide-based alloys and polyester-based alloys, the laminated films being irradiated in at least one periphery with an electron beam, and the rubber-adhering layer (D) being heat-bonded to the rubber layer (R).
摘要翻译：本发明提供一种适用于具有内衬或类似不透气层的充气轮胎的层压板，其能够例如维持必要的空气压力。本发明的层叠体I包括层叠膜和橡胶层（R），层叠膜由阻气层（A）和粘合剂层（B）构成，所述层（B）设置在至少一面的层（A）中，所述层（A）由选自聚酰胺树脂，聚酯树脂，聚芳酯树脂，聚酰胺类合金和聚酯类合金中的至少一种构成，所述层叠膜在至少一个周边并且粘合剂层（B）被热粘合到橡胶层（R）上。本发明的层压体II包括层叠膜和橡胶层（R），层压膜由橡胶粘附层（D），粘合层（B）和阻气层（A），层 D），（B）和（A）以至少三层的结构依次层叠，橡胶粘附层（D）由至少一种聚烯烃树脂形成，形成阻气层（A）的选自聚酰胺树脂，聚酯树脂，聚芳酯树脂，聚酰胺类合金和聚酯类合金中的至少一种，层压膜在电子束的至少一个周边照射，橡胶粘合层（D）被热粘合到橡胶层（R）上。

5. 发明授权

US5938869A Pneumatic tire with air permeation preventive layer 失效
标题翻译：带防透气层的气动轮胎
公开(公告)号：US5938869A
公开(公告)日：1999-08-17
申请号：US737880
申请日：1997-02-11
申请人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe
发明人： Hiroyuki Kaido , Kazuto Yamakawa , Jiro Watanabe
IPC分类号： B60C1/00 , B60C5/14 , B29D30/06 , B60C9/02
CPC分类号： B29D30/0681 , B60C1/0008 , B60C5/14 , B29D2030/0682 , B60C2005/145 , Y10T152/10855
摘要： A pneumatic tire has an air permeation preventive layer comprised of a film or sheet composed of a polymer composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer with an air permeation coefficient of not more than 25.times.10.sup.-12 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg and a Young's modulus of 1 to 500 MPa and wherein the film or sheet is arranged so that at least one turn of the film or sheet in the tire circumferential direction is free from a join.
摘要翻译： PCT No.PCT / JP96 / 00736 Sec。 371日期1997年2月11日 102（e）日期1997年2月11日PCT提交1996年3月21日PCT公布。公开号WO96 / 30220 PCT 日期：1996年10月3日充气轮胎具有防透气层，其由含有热塑性树脂的聚合物组合物或热塑性树脂与弹性体的共混物构成的膜或片，透气系数为25×10 12〜 12ccxcm / cm2xsecxcmHg，杨氏模量为1〜500MPa，并且其中所述膜或片被布置成使得所述膜或片材在轮胎周向上的至少一圈没有接合。

6. 发明授权

US06861470B2 Thermoplastic elastomer composition and process for producing the same and pneumatic tire and hose using the same 有权
标题翻译：热塑性弹性体组合物及其制造方法及使用其的充气轮胎和软管
公开(公告)号：US06861470B2
公开(公告)日：2005-03-01
申请号：US10347283
申请日：2003-01-21
申请人： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
发明人： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
IPC分类号： B60C1/00 , C08L23/02 , C08L23/28 , C08L77/00 , C98L77/00
CPC分类号： C08L23/02 , B60C1/00 , B60C1/0008 , C08L23/283 , C08L77/00 , C08L2312/00 , Y10T152/10495 , C08L2666/04 , C08L2666/20
摘要： A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. The method includes mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (φA/φB)×(ηB/ηA)
摘要翻译：一种热塑性弹性体组合物，其动态硫化至50至95％的凝胶化速率，其耐热性和耐久性优异，同时保持柔软性和优异的防透气性，可有效地用作例如充气轮胎作为空气渗透预防层。该方法包括将橡胶组合物（A）/树脂（B）的熔融粘度比为0.8〜1.2，式（phiA / phiB）×（etaB / etaA））1.0的混合条件下混合的组合物（C）在橡胶组合物（D）/组合物（C）的熔体粘度比为0.8至1.2和式（phiD / phiC）x（etaC / etaD）<1.0的条件下，其中phiA：橡胶组合物的体积分数 A），phiB：树脂（B）的体积分数，etaA：橡胶组合物（A）的熔融粘度，etaB：树脂（B）的熔融粘度，phiC：组合物的体积分数（C），phiD：橡胶体积分数组成（D），etaC：组合物（C）的熔融粘度，etaD：橡胶组合物（D）的熔融粘度。

7. 发明授权

US06538066B2 Thermoplastic elastomer composition and process for producing the same and pneumatic tire and hose using the same 有权
标题翻译：热塑性弹性体组合物及其制造方法及使用其的充气轮胎和软管
公开(公告)号：US06538066B2
公开(公告)日：2003-03-25
申请号：US09800782
申请日：2001-03-08
申请人： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
发明人： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
IPC分类号： C08L4700
CPC分类号： C08L23/02 , B60C1/00 , B60C1/0008 , C08L23/283 , C08L77/00 , C08L2312/00 , Y10T152/10495 , C08L2666/04 , C08L2666/20
摘要： A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer.
摘要翻译：一种热塑性弹性体组合物，其动态硫化至50至95％的凝胶化速率，其耐热性和耐久性优异，同时保持柔软性和优异的防透气性，可有效地用作例如充气轮胎作为空气渗透预防层。

8. 发明授权

US06359071B1 Thermoplastic elastomer composition, process for producing the same, and pneumatic tire and hose made with the same 有权
标题翻译：热塑性弹性体组合物及其制造方法，以及由其制成的充气轮胎和软管
公开(公告)号：US06359071B1
公开(公告)日：2002-03-19
申请号：US09380588
申请日：1999-12-07
申请人： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
发明人： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
IPC分类号： C08L7700
CPC分类号： C08L23/02 , B60C1/00 , B60C1/0008 , C08L23/283 , C08L77/00 , C08L2312/00 , Y10T152/10495 , C08L2666/04 , C08L2666/20
摘要： A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. In particular, a thermoplastic elastomer composition having a reduced particle size of the domain rubber is produced by a material having a high rubber ratio by mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (&phgr;A/&phgr;B)×(&eegr;B/&eegr;A)
摘要翻译：一种热塑性弹性体组合物，其动态硫化至50至95％的凝胶化速率，其耐热性和耐久性优异，同时保持柔软性和优异的防透气性，可有效地用作例如充气轮胎作为空气渗透预防层。特别地，通过混合在橡胶组合物（A）/（A）的熔体粘度的比例的条件下混合的组合物（C），通过使用具有高橡胶比的材料来制造具有减小的领域橡胶粒径的热塑性弹性体组合物，在橡胶组合物（D）/组合物（C）的熔融粘度比为0.8〜1.2的条件下，树脂（B）为0.8〜1.2，式（phiA / phiB）x（etaB / etaA）公式（phiD / phiC）x（etaC / etaD）<1.0，其中phiA：橡胶组合物（A）的体积分数，phiB：树脂（B）的体积分数，etaA：橡胶组合物（A）的熔融粘度，etaB：树脂（B）的熔融粘度，phiC：组合物（C）的体积分数，phiD：橡胶组合物的体积分数（D），etaC：组合物（C）的熔融粘度，etaD：橡胶组合物（D）的熔融粘度。

9. 发明申请

US20130068338A1 Hose For Transporting Refrigerant 有权
标题翻译：用于输送制冷剂的软管
公开(公告)号：US20130068338A1
公开(公告)日：2013-03-21
申请号：US13701493
申请日：2011-05-31
申请人： Yasuaki Shinoda , Kazuto Yamakawa
发明人： Yasuaki Shinoda , Kazuto Yamakawa
IPC分类号： F16L9/14
CPC分类号： F16L11/085 , B32B1/08 , B32B25/08 , B32B27/34 , B32B2597/00
摘要： A hose for transporting refrigerant of this invention is a hose comprising an inner tube layer including a gas barrier layer and a rubber layer adjacent to an outer surface of the gas barrier layer. The rubber layer comprises a rubber composition comprising from 1 to 15 parts by mass of an alkylphenol-formaldehyde resin and from 1 to 8 parts by mass of a hydrotalcite per 100 parts by mass of a raw rubber. The raw rubber comprises at least one selected from the group consisting of a BIMS and a butyl rubber and/or a halogenated butyl rubber, which is a copolymer rubber. The gas barrier layer comprises a polyamide resin composition comprising a modified polyamide obtained by blending a polyamide and a carboxyl group-containing modified polyolefin. The hose for transporting refrigerant of this invention has superior adhesion between the gas barrier layer and the rubber layer.
摘要翻译：用于输送本发明的制冷剂的软管是包括内管层的软管，该内管层包括阻气层和与阻气层的外表面相邻的橡胶层。橡胶层包含每100质量份生橡胶1〜15质量份烷基苯酚 - 甲醛树脂和1〜8质量份水滑石的橡胶组合物。该生橡胶包括选自由BIMS和丁基橡胶和/或卤化丁基橡胶组成的组中的至少一种，其为共聚物橡胶。阻气层包括聚酰胺树脂组合物，其包含通过共混聚酰胺和含羧基的改性聚烯烃获得的改性聚酰胺。用于输送本发明的制冷剂的软管在阻气层和橡胶层之间具有优异的粘合性。

10. 发明申请

US20080223494A1 PNEUMATIC TIRE 审中-公开
标题翻译：气动轮胎
公开(公告)号：US20080223494A1
公开(公告)日：2008-09-18
申请号：US11832933
申请日：2007-08-02
申请人： Naoya Amino , Yoshihiro Kameda , Kazuto Yamakawa , Akitomo Sato
发明人： Naoya Amino , Yoshihiro Kameda , Kazuto Yamakawa , Akitomo Sato
IPC分类号： B60C11/00
CPC分类号： C08L19/006 , B60C1/0016 , C08K3/013 , C08K3/04 , C08K3/36 , C08K5/0016 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A pneumatic tire using as a tread part, a rubber composition containing a high silica-content rubber composition having a difference F-S between an amount of filler F and an amount of a softening agent S of 60 to 90 parts by weight and having a durometer hardness measured at 20° C. of 65 to 76.
摘要翻译：作为胎面部使用的充气轮胎，含有填料F量与软化剂S量相差60〜60重量份的高二氧化硅含量橡胶组合物的橡胶组合物，硬度为硬度在20℃下测得为65至76。

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