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    • 2. 发明授权
    • Thermoplastic resin composition and interior or exterior parts for vehicle thereof
    • 热塑性树脂组合物及其车辆的内部或外部部件
    • US06277913B1
    • 2001-08-21
    • US09315812
    • 1999-05-21
    • Ikuhiro MishimaKazuhito Wada
    • Ikuhiro MishimaKazuhito Wada
    • C08L5108
    • C08L33/12C08F255/00C08F265/04C08F279/02C08F283/12C08L23/02C08L25/14C08L33/06C08L33/062C08L33/08C08L33/10C08L35/06C08L51/04C08L51/06C08L55/02C08L2666/02C08L2666/24C08L2666/06C08L2666/14C08L2666/04
    • There is provided a thermoplastic resin composition and interior or exterior parts for vehicle using thereof, which is excellent in flexibility, surface appearance, heat deformation property at heating and has low tackiness at a high temperature. The thermoplastic resin composition comprises 25 to 90 parts by weight of a (meth)acrylic ester copolymer (X), which is prepared by polymerizing 40 to 95% by weight of a (meth)acrylic ester, 0 to 40% by weight of a vinyl cyanide compound, not more than 60% by weight of an aromatic vinyl compound and 0 to 40% by weight of a monomer copolymerizable therewith, and has a glass transition temperature of not more than 20° C. and a gel content of not more than 50% by weight, 5 to 75 parts by weight of a copolymer (Y), which has a glass transition temperature or a melting point not less than 50° C., and 0 to 70 parts by weight of a graft copolymer (Z), which is prepared by polymerizing 5 to 95% by weight of a rubber polymer (A) and 5 to 95% by weight of a vinyl monomer (B), and wherein hardness thereof at 20° C. measured by the method of JIS K6301 is 30 to 100.
    • 提供一种热塑性树脂组合物及其使用的车辆内部或外部部件,其柔软性,表面外观,加热时的热变形性优异,并且在高温下具有低粘性。 热塑性树脂组合物包含25〜90重量份的(甲基)丙烯酸酯共聚物(X),其通过聚合40〜95重量%的(甲基)丙烯酸酯,0〜40重量%的 乙烯基氰化合物,不超过60重量%的芳族乙烯基化合物和0至40重量%的可与其共聚的单体,并且玻璃化转变温度不超过20℃,凝胶含量不超过 50重量%,5〜75重量份的玻璃化转变温度或熔点不低于50℃的共聚物(Y)和0〜70重量份的接枝共聚物(Z ),其通过使5〜95重量%的橡胶聚合物(A)和5〜95重量%的乙烯基单体(B)聚合而制备,并且其中在20℃下的硬度通过JIS K6301是30到100。
    • 4. 发明授权
    • Rubber latexes, graft copolymers, and thermoplastic resin compositions
    • 橡胶胶乳,接枝共聚物和热塑性树脂组合物
    • US6136918A
    • 2000-10-24
    • US68014
    • 1998-04-30
    • Ikuhiro MishimaNorito DoiYouichi MatsumuraShigemi MatsumotoShinobu OchikoshiKazuhito WadaHiroki Yoshino
    • Ikuhiro MishimaNorito DoiYouichi MatsumuraShigemi MatsumotoShinobu OchikoshiKazuhito WadaHiroki Yoshino
    • C08C1/07C08F265/04C08F279/02C08L21/02C08L51/04C08F291/02C08L33/06
    • C08L21/02C08C1/07C08F265/04C08F279/02C08L51/04
    • A rubber latex with its particles grown through cohesion by adding 100 weight parts of (B) a rubber latex (solid), 0.1-15 weight parts (solid) of (A) an acid group-containing latex having an average particle size of 50-500 nm prepared by polymerizing a monomer mixture comprising (a), (b), (c) and (d) [wherein (a)+(b)+(c)+(d)=100 weight %]: (a) 5-25 weight % of at least one of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid and crotonic acid, (b) 20-95 weight % of at least one of alkyl methacrylates with its alkyl group 1-12 in carbon number, (c) 0-30 weight % of at least one of alkyl acrylates with its alkyl group 1-12 in carbon number, (d) 0-40 weight % of at least one selected from the group consisting of aromatic vinyls, compounds having at least two polymerizable functional groups in a molecule and vinyl cyanides, copolymerizable with the aforementioned (a), (b) and (c) is provided. The rubber latex and a graft copolymer containing it and thermoplastic resins incorporating said graft copolymer are excellent in impact strength, heat resistance and workability.
    • PCT No.PCT / JP95 / 02548 Sec。 371日期:1998年4月30日 102(e)1998年4月30日PCT 1995年12月13日PCT PCT。 出版物WO97 / 21770 日期:1996年6月19日通过加入100重量份(B)橡胶胶乳(固体),0.1-15重量份(固体)(A)含酸基胶乳的胶乳(其具有 通过聚合包含(a),(b),(c)和(d)[其中(a)+(b)+(c)+(d))= 100重量的单体混合物制备的平均粒径为50-500nm %):(a)5-25重量%的选自丙烯酸,甲基丙烯酸,衣康酸和巴豆酸的不饱和酸中的至少一种,(b)20-95重量%的至少一种烷基 其碳原子数为1-12的甲基丙烯酸酯,(c)0-30重量%的碳原子数为1-12的烷基丙烯酸烷基酯中的至少一种,(d)0-40重量%的至少一种 选自芳族乙烯基,分子中具有至少两个可聚合官能团的化合物和可与上述(a),(b)和(c)共聚的乙烯基氰化物)。 橡胶胶乳和含有它的接枝共聚物和结合所说接枝共聚物的热塑性树脂具有优异的冲击强度,耐热性和可加工性。
    • 9. 发明授权
    • Methacrylic resin composition
    • 甲基丙烯酸树脂组合物
    • US07999032B2
    • 2011-08-16
    • US11994746
    • 2006-07-05
    • Kazuhito WadaKimihide NishimuraNorito Doi
    • Kazuhito WadaKimihide NishimuraNorito Doi
    • C04B35/634
    • C08J5/18B32B27/18B32B27/30C08F265/06C08J2351/00C08K5/3475C08L33/06C08L33/12C08L51/00C09D5/32Y10T428/254Y10T428/31909Y10T428/31928C08F220/14C08L2666/24C08L2666/04
    • An acrylic resin composition suitable for use as films excellent in transparency, weatherability, hardness, impact resistance, flex cracking resistance, and formability. The resin composition comprises an acrylic graft copolymer (A) including a rubbery acrylic ester polymer (A-a) and a methacrylic polymer (B) comprising 80 wt. % or more methyl methacrylate units, the acrylic resin composition having a specific value of reduced viscosity (0.2-0.8 dl/g), specific values of content (5-45 wt. %) and average particle diameter (50-200 nm) of the rubbery polymer (A-a), a specific relationship between the particle diameter and the crosslinking agent amount (0.02d≦w≦0.05d; d, average particle diameter (nm); w, amount of crosslinking agent (wt. %)), and a specific value of the degree of grafting (50-250%). The resin composition contains an ultraviolet absorber incorporated therein through copolymerization.
    • 适合用作透明性,耐候性,硬度,耐冲击性,抗开裂性和成型性优异的薄膜的丙烯酸树脂组合物。 树脂组合物包含丙烯酸接枝共聚物(A),其包含橡胶状丙烯酸酯聚合物(A-a)和甲基丙烯酸类聚合物(B),其包含80重量% %以上的甲基丙烯酸甲酯单元,丙烯酸树脂组合物的比浓粘度(0.2〜0.8dl / g),比重值(5-45重量%)和平均粒径(50〜200nm) 橡胶状聚合物(Aa),粒径与交联剂量的相关关系(0.02d≦̸ w≦̸ 0.05d; d,平均粒径(nm); w,交联剂量(重量%)) 和接枝度的具体值(50-250%)。 该树脂组合物含有通过共聚合结合在其中的紫外线吸收剂。