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    • 2. 发明授权
    • Graft copolymers and impact-resistant flame-retardant resin compositions containing the same
    • 含有它们的接枝共聚物和耐冲击阻燃树脂组合物
    • US07615594B2
    • 2009-11-10
    • US10466130
    • 2003-02-17
    • Tomomichi HashimotoKazunori SaegusaHiroshi TsuneishiNobuo MiyatakeAkira Takaki
    • Tomomichi HashimotoKazunori SaegusaHiroshi TsuneishiNobuo MiyatakeAkira Takaki
    • C08F283/12
    • C08L51/085C08F283/12C08F285/00C08L69/00C08L2201/02C08L2666/02C08L2666/24
    • The present invention provides a polyorganosiloxane-containing graft copolymer which is obtainable by polymerizing 0.5 to 10 parts by weight of a vinyl monomer (B) comprising 100 to 50% by weight of a polyfunctional monomer (b-1) containing two or more polymerizable unsaturated bonds in the presence of 40 to 90 parts of polyorganosiloxane particles, followed by further polymerizing 5 to 50 parts by weight of a vinyl monomer (C); A polyorganosiloxane-containing graft copolymer which is obtainable by polymerizing 0 to 10 parts by weight of a vinyl monomer (B) comprising 100 to 50% by weight of a polyfunctional monomer containing two or more polymerizable unsaturated bonds in the presence of 30 to 95 parts of a polyorganosiloxane in a latex form as obtained by seed polymerization using, as a seed polymer, a hydrophilic polymer capable of swelling in the corresponding organosiloxane, followed by further polymerizing 5 to 70 parts by weight of a vinyl monomer (C); a flame retardant which comprises said copolymer; and a resin composition which comprises said retardant and a thermoplastic resin.
    • 本发明提供一种含聚有机硅氧烷的接枝共聚物,其通过使0.5〜10重量份的含有100〜50重量%的含有2个以上的可聚合不饱和单体的多官能单体(b-1)的乙烯基单体(B) 在40〜90份的聚有机硅氧烷粒子的存在下,进一步聚合5〜50重量份的乙烯基单体(C); 一种含聚有机硅氧烷的接枝共聚物,其可通过在0〜10重量份的乙烯基单体(B)中聚合而获得,所述乙烯基单体(B)含有100〜50重量%的含有2个以上聚合性不饱和键的多官能单体, 的聚有机硅氧烷,其通过使用作为种子聚合物的种子聚合获得的亲水性聚合物,其能够在相应的有机硅氧烷中溶胀,然后进一步聚合5至70重量份的乙烯基单体(C); 包含所述共聚物的阻燃剂; 以及包含所述阻燃剂和热塑性树脂的树脂组合物。
    • 9. 发明授权
    • Amorphous polyolefin resin composition
    • 无定形聚烯烃树脂组合物
    • US06395829B1
    • 2002-05-28
    • US09507789
    • 2000-02-22
    • Masahiro MiyamotoHideki KawaiAkira Takaki
    • Masahiro MiyamotoHideki KawaiAkira Takaki
    • C08L2500
    • C08L23/02C08L23/16C08L53/00C08L2205/02C08L2666/24
    • An amorphous polyolefin resin composition being excellent in the balance of the impact resistance with the surface smoothness and, further, the balance of the impact resistance with the transparency. In this amorphous polyolefin resin composition, a block copolymer (B-1) having at least one polymer block unit which is poor in the affinity with an amorphous polyolefin (A) but excellent in the affinity with a core-shell type elastomer (B-2) is combined with a core-shell type elastomer (B-2) which is excellent in the affinity with at least one polymer block of the block copolymer (B-1) and has a specific composition and a specific structure, and these components are composited in the amorphous polyolefin resin composition, thereby achieving well-balanced properties, i.e., an excellent impact resistance, an excellent surface glossiness and a high transparency.
    • 一种无定形聚烯烃树脂组合物,其耐冲击性与表面平滑度的平衡优异,另外抗冲击性与透明性的平衡优异。 在该无定形聚烯烃树脂组合物中,具有至少一种聚合物嵌段单元的嵌段共聚物(B-1),其与无定形聚烯烃(A)的亲和性差,与核 - 壳型弹性体(B- 2)与嵌段共聚物(B-1)的至少一个聚合物嵌段的亲和性优异的核 - 壳型弹性体(B-2)组合,具有特定的组成和特定结构,这些成分 复合在无定形聚烯烃树脂组合物中,从而获得良好的平衡性能,即优异的抗冲击性,优异的表面光泽度和高透明度。