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1. 发明授权

US5571853A Gel-forming silicone composition 失效
标题翻译：凝胶形成硅酮组合物
公开(公告)号：US5571853A
公开(公告)日：1996-11-05
申请号：US504489
申请日：1995-07-20
申请人： Masayuki Ikeno , Hironao Fujiki
发明人： Masayuki Ikeno , Hironao Fujiki
IPC分类号： C08L83/04 , C08L83/05 , C08L83/07 , C08K5/54
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/70
摘要： A gel-forming silicone composition comprising (A) an organopolysiloxane containing a silicon-bonded alkenyl group or groups in an average amount of from 0.15 to 0.35 mol % based on all silicon-bonded organic groups contained per molecule, (B) a non-functional organopolysiloxane, (C) an organohydrogenpolysiloxane containing an average of 2 silicon-bonded hydrogen atoms per molecule, and (D) an addition reaction catalyst. The silicone composition is able to give a gel-like cured silicone product with low modulus of elasticity while retaining flexibility.
摘要翻译：一种凝胶形成硅氧烷组合物，其包含（A）含有硅键合的烯基的有机聚硅氧烷或平均含量为0.15至0.35摩尔％的基于每分子含有所有与硅键合的有机基团的组分，（B）功能性有机聚硅氧烷，（C）每分子平均含有2个与硅键合的氢原子的有机氢聚硅氧烷，（D）加成反应催化剂。有机硅组合物能够提供具有低弹性模量的凝胶状固化的硅氧烷产品，同时保持柔韧性。

2. 发明授权

US5792723A Platinum catalyst, its preparation, and curable organopolysiloxane composition comprising the same 失效
标题翻译：铂催化剂，其制备方法和包含其的可固化的有机聚硅氧烷组合物
公开(公告)号：US5792723A
公开(公告)日：1998-08-11
申请号：US752938
申请日：1996-11-20
申请人： Masayuki Ikeno , Hideki Sugahara , Hironao Fujiki
发明人： Masayuki Ikeno , Hideki Sugahara , Hironao Fujiki
IPC分类号： A61K6/093 , B01J31/22 , B01J31/28 , C07B61/00 , C07F7/08 , C07F7/21 , C07F15/00 , C08G77/398 , C08L83/04 , C08L83/07 , B01J31/02
CPC分类号： B01J31/1608 , B01J31/2291 , C08G77/398 , C08L83/04 , B01J2231/14 , B01J2231/323 , B01J2531/828 , C08G77/08 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/70
摘要： A platinum catalyst containing (A) a platinum complex having a vinyl-containing organosiloxane ligand and (B) a vinyl-containing organopolysiloxane is prepared by mixing components (A) and (B) such that at least 2 mol of vinyl group in component (B) is available per mol of platinum atom in component (A) and heating the mixture at 40.degree.-100.degree. C. for at least 1 hour. When blended in an addition reaction curing type organosiloxane composition, the platinum catalyst has the advantage that even after long-term storage at elevated temperatures, it remains stable and active enough to cause the organosiloxane composition to cure.
摘要翻译：含有（A）具有含乙烯基的有机硅氧烷配体的铂络合物和（B）含乙烯基的有机聚硅氧烷的铂催化剂通过混合组分（A）和（B）制备，使得至少2摩尔组分（ B）可以在组分（A）中每摩尔铂原子获得并在40℃-100℃下加热该混合物至少1小时。当在加成反应固化型有机硅氧烷组合物中混合时，铂催化剂的优点在于，即使在高温下长期保存后，其仍保持稳定和足够活性以使有机硅氧烷组合物固化。

3. 发明授权

US5292848A Fluorosilicone composition and its gellike cured product 失效
标题翻译：氟硅酮组合物及其胶凝固化产物
公开(公告)号：US5292848A
公开(公告)日：1994-03-08
申请号：US964946
申请日：1992-10-22
申请人： Masayuki Ikeno , Miyuki Tanaka , Hiroyasu Hara , Hironao Fujiki , Shinichi Sato , Hiroshi Inomata
发明人： Masayuki Ikeno , Miyuki Tanaka , Hiroyasu Hara , Hironao Fujiki , Shinichi Sato , Hiroshi Inomata
IPC分类号： C08L83/05 , C08L83/07 , C08L83/08 , C08L83/12 , C08G77/06
CPC分类号： C08L83/08 , C08L83/12
摘要： The present fluorosilicone composition is an addition reaction curable composition that uses, as an alkenyl group-containing organopolysiloxane, a fluorine-containing organopolysiloxane represented by the following general formula (1): ##STR1## wherein R represents a vinyl group, R.sup.1 represents an alkyl group or a phenyl group, R.sup.2 represents a group represented by the following formula (2): ##STR2## in which p is an integer of 2 to 8 and q is an integer of 1 to 10, and n and m are each a positive integer. This composition can form a gellike cured product particularly excellent in acid resistance.
摘要翻译：本发明的氟硅酮组合物是使用由以下通式（1）表示的含氟有机聚硅氧烷作为含烯基的有机聚硅氧烷的加成反应固化性组合物：（*化学结构*）（1）其中R表示乙烯基基团，R 1表示烷基或苯基，R 2表示由下式（2）表示的基团：（*化学结构*）（2）其中p为2〜8的整数，q为 1〜10，n和m各自为正整数。该组合物可以形成特别优异的耐酸性的胶凝固化产物。

4. 发明授权

US5086147A Organopolysiloxane composition 失效
标题翻译：有机硅氧烷组合物
公开(公告)号：US5086147A
公开(公告)日：1992-02-04
申请号：US556723
申请日：1990-07-25
申请人： Masayuki Ikeno , Hironao Fujiki
发明人： Masayuki Ikeno , Hironao Fujiki
IPC分类号： C09K3/00 , C08L83/04 , C08L83/05 , C08L83/07
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20
摘要： An organopolysiloxane gel composition improved upon discoloration due to thermal deterioration, which comprises (A) 100 pts. wt. of an organopolysiloxane containing alkenyl groups in side chains, (B) a specified amount of an organohydrogenpolysiloxane containing on the statistical average one terminal hydrogen and one terminal alkenyl group, and (C) a catalytic amount of addition reaction catalyst.

5. 发明授权

US06387520B1 Liquid silicone rubber coating composition and air bag fabric 失效
标题翻译：液体硅橡胶涂料组合物和气囊布
公开(公告)号：US06387520B1
公开(公告)日：2002-05-14
申请号：US09644900
申请日：2000-08-24
申请人： Hironao Fujiki , Yoshifumi Inoue , Yoshifumi Harada , Takeshi Miyao , Masayuki Ikeno
发明人： Hironao Fujiki , Yoshifumi Inoue , Yoshifumi Harada , Takeshi Miyao , Masayuki Ikeno
IPC分类号： B32B2738
CPC分类号： D06N3/128 , B60R2021/23514 , C09D183/04 , D06M11/28 , D06M11/79 , D06M15/643 , D06M2200/30 , Y10T428/31511 , Y10T428/31663 , Y10T428/31725 , Y10T428/31786 , C08L83/00 , C08L2666/44 , C08L2666/54
摘要： A solvent-free liquid silicone rubber composition comprising (A) an organopolysiloxane containing at least two alkenyl groups, (B) an organohydrogenpolysiloxane having at least two hydrogen atoms each attached to a silicon atom, (C) wet silica having a BET specific surface area of 150-250 m2/g, a mean particle size of 0.01-20 &mgr;m, and a sodium ion content of up to 0.35 wt % Na2O, (D) an adhesive agent, and (E) a platinum group catalyst is useful for coating onto air bag base fabric to form a thin film having good infiltration, strong adhesion and minimized surface tack.
摘要翻译：一种无溶剂的液体硅橡胶组合物，其包含（A）含有至少两个烯基的有机聚硅氧烷，（B）具有至少两个连接到硅原子上的氢原子的有机氢聚硅氧烷，（C）具有BET比表面积平均粒径为0.01-20μm，钠离子含量高达0.35wt％Na 2 O，（D）粘合剂，（E）铂族催化剂可用于涂覆到气囊底布上形成具有良好渗透性，强粘附性和最小化表面粘性的薄膜。

6. 发明授权

US5530060A Silicone composition capable of yeilding a cured product having good thermal conductivity 失效
标题翻译：能够使具有良好导热性的固化产物的硅酮组合物
公开(公告)号：US5530060A
公开(公告)日：1996-06-25
申请号：US410641
申请日：1995-03-21
申请人： Hironao Fujiki , Masayuki Ikeno
发明人： Hironao Fujiki , Masayuki Ikeno
IPC分类号： C08K3/22 , C08L83/04 , C08L83/05 , C08L83/07 , H01L23/29 , H01L23/31 , C08K3/10
CPC分类号： C08K3/22 , C08L83/04 , C08G77/12 , C08G77/14 , C08G77/20 , C08G77/24 , C08G77/70
摘要： A silicone composition is of the addition reaction type which comprises a vinyl group-containing organopolysiloxane, an organohydrogenpolysiloxane which has at least one hydrogen atom joined to a silicon atom in one molecule, a platinum group metal catalyst, and an aluminum oxide powder which is substantially round or spherical in shape with an average particle size of not larger than 50 .mu.m and wherein when the aluminum oxide powder is subjected to extraction of alkali metal ions and halogen ions under conditions of 121.degree. C., 2 atmospheric pressures, 100% R.H. and 20 hours, the contents of both ions are, respectively, not larger than 5 ppm. The cured product obtained from the composition has high thermal conductivity and the composition is useful as a sealant of electric and electronic parts and can prevent the parts from being corroded.
摘要翻译：硅氧烷组合物为加成反应型，其包含含乙烯基的有机聚硅氧烷，在一分子中具有至少一个连接到硅原子的氢原子的有机氢聚硅氧烷，铂族金属催化剂和基本上为平均粒径不大于50μm的圆形或球形，其中当在121℃，2个大气压，100％RH的条件下将氧化铝粉末进行碱金属离子和卤素离子萃取时和20小时，两个离子的含量分别不大于5ppm。由该组合物得到的固化物具有高导热性，并且该组合物可用作电气和电子部件的密封剂，并且可以防止该部件被腐蚀。

7. 发明授权

US5204437A Organopolysiloxane composition and its gel cured product 失效
标题翻译：有机硅氧烷组合物及其凝胶产品
公开(公告)号：US5204437A
公开(公告)日：1993-04-20
申请号：US738442
申请日：1991-07-31
申请人： Masayuki Ikeno , Hironao Fujiki
发明人： Masayuki Ikeno , Hironao Fujiki
IPC分类号： C08L83/05 , C08L83/04 , C08L83/06 , C08L83/07 , C08L83/14 , H01L23/29 , H01L23/31
CPC分类号： C08L83/04 , C08L83/06 , C08L83/14 , C08G77/12 , C08G77/14 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/70
摘要： An organopolysiloxane composition, comprising(A) an organopolysiloxane having alkenyl groups bonded to silicon atoms,(B) an organohydrogenpolysiloxane having two or more hydrogen atoms bonded to silicon atoms, and(C) an addition reaction catalyst, wherein the vinyl group containing organopolysiloxane (A) as a base polymer and the organohydrogenpolysiloxane (B) as a crosslinking agent each have at least two alkoxy group and/or at least one epoxy group in the molecule. By subjecting this composition to addition curing, a gel cured product excellent in adhesion particularly to metals is obtained.

8. 发明授权

US5352724A Silicone rubber composition with improved fluidity 失效
标题翻译：硅橡胶组合物具有改善的流动性
公开(公告)号：US5352724A
公开(公告)日：1994-10-04
申请号：US91298
申请日：1993-07-15
申请人： Hironao Fujiki , Masayuki Ikeno , Masaya Arakawa , Kaoru Michimata , Masanobu Miyakoshi , Takehide Okami
发明人： Hironao Fujiki , Masayuki Ikeno , Masaya Arakawa , Kaoru Michimata , Masanobu Miyakoshi , Takehide Okami
IPC分类号： C08L83/04 , C08K5/56
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20
摘要： An addition-curable type silicone rubber composition comprising (A) an organopolysiloxane having an alkenyl group such as vinyl in its molecule, (B) an organohydrogenpolysiloxane having at least two SiH groups in its molecule, (C) a platinum catalyst such as platinum, chloroplatinic acid, etc., (D) an inorganic filler, (E) an organic titanium compound such as tetraethyl titanate, and (F) water. The composition exhibits good fluidity, and behaves like a Newtonian fluid, even where carbon black or a silica or alumina having an average particle diameter of 1 .mu.m or above is incorporated in the composition as an inorganic filler for improving such characteristics as heat resistance, thermal conductivity, etc.
摘要翻译：一种可加成固化型硅橡胶组合物，其包含（A）分子中具有乙烯基等烯基的有机聚硅氧烷，（B）分子中具有至少两个SiH基的有机氢聚硅氧烷，（C）铂催化剂，（D）无机填料，（E）有机钛化合物如钛酸四乙酯和（F）水。该组合物表现出良好的流动性，并且表现为牛顿流体，即使将炭黑或平均粒径为1μm以上的二氧化硅或氧化铝作为无机填料掺入组合物中，以改善耐热性，导热系数等

9. 发明授权

US5276087A Curable silicone composition and cured product thereof 失效
标题翻译：可固化硅酮组合物及其固化产物
公开(公告)号：US5276087A
公开(公告)日：1994-01-04
申请号：US824304
申请日：1992-01-23
申请人： Hironao Fujiki , Masayuki Ikeno
发明人： Hironao Fujiki , Masayuki Ikeno
IPC分类号： C08K3/22 , C08K7/18 , C08L83/04 , C08K3/20 , C08K3/36 , C08L83/07
CPC分类号： C10M111/04 , C08K3/22 , C08K7/18 , C08L83/04 , C08G77/12 , C08G77/20 , C10M2201/0623 , C10M2201/1053 , C10M2229/0435 , C10M2229/0445 , C10N2210/07 , C10N2230/02 , C10N2240/20
摘要： A curable silicone composition which can cure using hydrosilylation, comprising an aluminum oxide powder and/or silica powder, the powders each consisting of substantially spherical particles with an average particle diameter of 50 .mu.m or below and an elongation of from 1.0 to 1.4 and being such that the respective amounts of alkali metal ions and halogen ions are extracted with 50 ml of water from 5 g of the powder at 121.degree. C. for 20 hours are not more than 10 ppm, wherein the amount of the component (D) is from 25 to 90% by weight based on the composition, and the ratio of the amount of hydrosilyl groups contained in the components (A) and (B) to the amount of alkenyl groups contained in the components (A) and (B) is in the range from 0.5/1 to 1.5/1. When the composition is used as a protective material or encapsulating material for devices such as ICs, generated heat can be dissipated efficiently and the devices are not be broken by abrasion. There are no fears of causing corrosion of the devices.
摘要翻译：一种可固化的硅氧烷组合物，其可以使用氢化硅烷化固化，其包含氧化铝粉末和/或二氧化硅粉末，所述粉末各自由平均粒径为50（my）m或更小的基本上球形的颗粒和1.0至1.4的伸长率组成并且使得在121℃下从5g粉末中用50ml水萃取碱金属离子和卤素离子的相应量不超过10ppm，其中组分（D ）为25〜90重量％，组分（A）和（B）中所含的氢化甲硅烷基的量与组分（A）和（B）中所含的烯基的量的比率为25至90重量％）在0.5 / 1至1.5 / 1的范围内。当组合物用作诸如IC之类的装置的保护材料或封装材料时，可以有效地消散所产生的热量，并且不会由于磨损而破坏装置。没有担心会导致器件腐蚀。

10. 发明授权

US4886865A Organopolysiloxane composition 失效
标题翻译：有机聚硅氧烷组合物
公开(公告)号：US4886865A
公开(公告)日：1989-12-12
申请号：US169849
申请日：1988-03-18
申请人： Masayuki Ikeno , Hironao Fujiki , Hiroshi Inomata
发明人： Masayuki Ikeno , Hironao Fujiki , Hiroshi Inomata
IPC分类号： C08G77/50 , C08L83/05 , C08L83/07 , C08L83/14
CPC分类号： C08G77/50 , C08L83/14
摘要： The organopolysiloxane composition is useful as a potting or encapsulating material having a gel-like consistency for protecting electronic components even at an extremely low temperature as is encountered in the space industry. The composition is basically of the type in which crosslinks are formed by the addition reaction between silicon-bonded vinyl groups in an organopolysiloxane and silicon-bonded hydrogen atoms in an organohydrogenpolysiloxane but the outstanding cold resistance of the gel-like material obtained from the composition is imparted by incorporating specific silethylene-containing units of the unit formula OSiMe--CH.sub.2 CH.sub.2 --SiMe.sub.2 O.sub.0.5 into the organopolysiloxane in a specified molar content.
摘要翻译：有机聚硅氧烷组合物可用作具有凝胶状稠度的灌封或封装材料，即使在空间工业中遇到的极低温下也能保护电子元件。组合物基本上是通过有机聚硅氧烷中与硅键合的乙烯基与有机氢聚硅氧烷中与硅键合的氢原子之间的加成反应形成交联的类型，但由组合物获得的凝胶状材料的出色的耐寒性为通过将单元式OSiMe-CH 2 CH 2 -SiMe 2 O 0.5的特定的含有亚乙烯基的单元以特定的摩尔含量加入有机聚硅氧烷中。

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