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    • 3. 发明申请
    • Low Birefringent Copolymers
    • 低双折射共聚物
    • US20100168363A1
    • 2010-07-01
    • US11989945
    • 2006-08-02
    • Ken-ichi UedaHiroko IzumiYoshitomo NakataNobuhiro Maeda
    • Ken-ichi UedaHiroko IzumiYoshitomo NakataNobuhiro Maeda
    • C08F220/10
    • C08F8/16C08F8/48C08F212/08C08F220/06C08F220/14C08F220/28C08F222/40
    • The low birefringent material of the present invention is, for example, an acrylic copolymer including a lactone ring structure which can provide a positive retardation and a structural unit which can provide a negative retardation, the acrylic copolymer satisfying following conditions that: (A) the copolymer has a glass transition temperature (Tg) of 100° C. or higher; (B) a film comprising the copolymer has a total light transmittance of 85% or higher; and (C) a retardation per 100 μm of thickness in an in-plane direction of the film is 10 nm or lower, and a difference between a retardation per 100 μm of thickness in an in-plane direction of the film after the film is drawn by 1.5 times and a retardation per 100 μm of thickness in an in-plane direction of the film before the film is drawn is 20 nm or lower. The low birefringent material of the present invention has excellent transparency and heat resistance, also has other desired properties including mechanical strength and forming processability, has low coloration properties when no nitrogen atom is contained, and particularly has high optical isotropy.
    • 本发明的低双折射材料是例如包含可提供正相位差的内酯环结构的丙烯酸共聚物和可提供负相位差的结构单元,所述丙烯酸共聚物满足以下条件:(A) 共聚物的玻璃化转变温度(Tg)为100℃以上; (B)包含共聚物的膜的总透光率为85%以上; 和(C)膜的面内方向每100μm厚度的延迟为10nm以下,膜后的膜的面内方向的每100μm厚度的延迟差为 拉伸1.5倍,并且在拉伸膜之前在膜的面内方向上每100μm厚度的延迟为20nm以下。 本发明的低双折射材料具有优异的透明性和耐热性,还具有包括机械强度和成形加工性在内的其它期望的性能,当不含氮原子时具有低着色性,特别是具有高的光学各向同性。