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    • 3. 发明申请
    • Resin Composition for Forming Ultraviolet Absorbing Layer and Laminate Comprising Ultraviolet Absorbing Layer
    • 用于形成紫外线吸收层的树脂组合物和包含紫外线吸收层的层压体
    • US20090110936A1
    • 2009-04-30
    • US11992593
    • 2006-09-27
    • Nobuhisa Noda
    • Nobuhisa Noda
    • B32B27/18C08L67/02
    • C08J7/047C08J2467/00C09D175/06Y10T428/31551Y10T428/31786
    • The object of the present invention is to find a resin composition for forming an ultraviolet absorbing layer having excellent adhesion to various plastic substrates such as polyester type films of PET etc. and provide a laminate of plastic substrate having no yellowing, excellent weather resistance and less curl formation with good productivity. There is provided a resin composition for use in forming an ultraviolet absorbing layer on the surface of a plastic substrate, having an ultraviolet absorbing polymer as a major component being synthesized from monomer mixtures containing an ultraviolet absorbing monomer, wherein the resin composition contains 0.5-5 parts by mass of a saturated polyester resin with a number-average molecular weight of 10000 or more and 0.1-30 parts by mass of a polyisocyanate based crosslinker relative to 100 parts by mass of the ultraviolet absorbing polymer, and a laminate with an ultraviolet absorbing layer made of the above composition formed on the surface of a plastic substrate.
    • 本发明的目的是找到一种用于形成对诸如PET等的聚酯型膜的各种塑料基材具有优异粘附性的紫外线吸收层的树脂组合物,并提供不具有黄变,优异的耐候性和较少的塑料基材的层压体 卷曲形成,生产效率高。 提供一种用于在塑料基材表面上形成紫外线吸收层的树脂组合物,其中紫外线吸收聚合物作为主要成分由含有紫外线吸收单体的单体混合物合成,其中树脂组合物含有0.5-5 相对于100质量份的紫外线吸收性聚合物,数均分子量为10000以上的饱和聚酯树脂和0.1〜30质量份的多异氰酸酯类交联剂,以及具有紫外线吸收性的层叠体 由塑料基板表面形成的上述组合物制成的层。
    • 4. 发明授权
    • Ultraviolet absorptive laminated resinous article
    • 紫外吸收层压树脂制品
    • US06372355B1
    • 2002-04-16
    • US09587389
    • 2000-06-05
    • Nobuhisa NodaToshifumi NishidaTakahiro Aoyama
    • Nobuhisa NodaToshifumi NishidaTakahiro Aoyama
    • B32B2730
    • B32B27/08B32B27/20B32B2307/40B32B2307/554B32B2307/712C08J7/04C08J7/047C08J2433/00Y10T428/31663
    • To provide a laminated resinous article having an improved weatherability without inviting ultraviolet-induced coloring or deterioration in interlayer adhesion and in surface hardness, and having a high surface harness and a satisfactory abrasion resistance, a weather resistant ultraviolet absorptive laminated resinous article is disclosed. The resinous article includes a resin base, a base protective layer and a surface protective layer formed on at least one surface of the resin base, which base protective layer is composed of a cross-linked cured product. The base protective layer includes a polymer obtained by polymerizing a monomer component containing at least one selected from monomers having an ultraviolet absorptive group of the formula (1) or (2) in the description, and the surface protective layer is formed as an outermost layer of the resinous article.
    • 为了提供具有改善耐候性的层压树脂制品,不会引起紫外线引起的着色或层间粘合性和表面硬度的劣化,并且具有高表面线束和令人满意的耐磨性,所以公开了耐候紫外线吸收性层压树脂制品。 树脂制品包括树脂基底,基底保护层和形成在树脂基底的至少一个表面上的表面保护层,该基底保护层由交联的固化产物组成。 基底保护层包括在说明书中聚合含有选自具有式(1)或(2)的紫外线吸收性基团的单体的至少一种的单体成分而得到的聚合物,表面保护层形成为最外层 的树脂制品。
    • 7. 发明授权
    • Thermosetting resin composition
    • 热固性树脂组合物
    • US5446099A
    • 1995-08-29
    • US327285
    • 1994-10-21
    • Masaya YoshidaNobuhisa NodaIchiro NamuraKiyoshi Kawamura
    • Masaya YoshidaNobuhisa NodaIchiro NamuraKiyoshi Kawamura
    • C08L35/00C08L39/04C09D133/06C09D135/00C09D139/04
    • C09D135/00C08L35/00C08L39/04C09D133/062C09D139/04
    • The thermosetting resin composition of the present invention comprises: a polymer (A) containing at least one monomer selected from ethylenically unsaturated dicarboxylic anhydride, mono-ester thereof and mono-amide thereof as a repeating unit; and a polymer (B) containing an addition-polymerizable oxazoline and a hydroxyl group-containing monomer as repeating units, which can rapidly form a cured film excellent in acid rain resistance and other properties at relatively low temperature of 70.degree. to 140.degree. C. The further incorporation of a basic compound (C) and/or a compound (D) selected from the group consisting of a monohydric alcohol, a .beta.-diketone and an ortho-carboxylic ester to this thermosciting resin composition can give a remarkably improved storage stability to this resin composition as a one-part type composition. This thermosciting resin composition can exhibit excellent properties as a top clear coating for motor vehicle.
    • 本发明的热固性树脂组合物包含:含有至少一种选自烯键式不饱和二羧酸酐,其单酯和单酰胺的单体作为重复单元的聚合物(A) 和含有可加成聚合的恶唑啉和含羟基的单体作为重复单元的聚合物(B),能够在70〜140℃的较低温度下快速形成耐酸雨性等优异的固化膜。 将碱性化合物(C)和/或选自一元醇,β-二酮和邻羧酸酯的化合物(D)进一步掺入到该耐热树脂组合物中可以显着提高储存稳定性 作为单组分型组合物的树脂组合物。 该耐热树脂组合物可以表现出作为机动车辆的顶部透明涂层的优异性能。
    • 8. 发明授权
    • Resin composition for forming ultraviolet absorbing layer and laminate comprising ultraviolet absorbing layer
    • 用于形成紫外线吸收层的树脂组合物和包含紫外线吸收层的层压体
    • US08003222B2
    • 2011-08-23
    • US11992593
    • 2006-09-27
    • Nobuhisa Noda
    • Nobuhisa Noda
    • B32B27/36B32B27/40C08L67/02
    • C08J7/047C08J2467/00C09D175/06Y10T428/31551Y10T428/31786
    • The object of the present invention is to find a resin composition for forming an ultraviolet absorbing layer having excellent adhesion to various plastic substrates such as polyester type films of PET etc. and provide a laminate of plastic substrate having no yellowing, excellent weather resistance and less curl formation with good productivity. There is provided a resin composition for use in forming an ultraviolet absorbing layer on the surface of a plastic substrate, having an ultraviolet absorbing polymer as a major component being synthesized from monomer mixtures containing an ultraviolet absorbing monomer, wherein the resin composition contains 0.5-5 parts by mass of a saturated polyester resin with a number-average molecular weight of 10000 or more and 0.1-30 parts by mass of a polyisocyanate based crosslinker relative to 100 parts by mass of the ultraviolet absorbing polymer, and a laminate with an ultraviolet absorbing layer made of the above composition formed on the surface of a plastic substrate.
    • 本发明的目的是找到一种用于形成对诸如PET等的聚酯型膜的各种塑料基材具有优异粘附性的紫外线吸收层的树脂组合物,并提供不具有黄变,优异的耐候性和较少的塑料基材的层压体 卷曲形成,生产效率高。 提供一种用于在塑料基材表面上形成紫外线吸收层的树脂组合物,其中紫外线吸收聚合物作为主要成分由含有紫外线吸收单体的单体混合物合成,其中树脂组合物含有0.5-5 相对于100质量份的紫外线吸收性聚合物,数均分子量为10000以上的饱和聚酯树脂和0.1〜30质量份的多异氰酸酯类交联剂,以及具有紫外线吸收性的层叠体 由塑料基板表面形成的上述组合物制成的层。
    • 10. 发明授权
    • Attachment devices
    • 附件装置
    • US06368009B1
    • 2002-04-09
    • US09619667
    • 2000-07-19
    • Nobuhisa Noda
    • Nobuhisa Noda
    • F16B1304
    • B60J3/023F16B5/0642F16B19/1081Y10T403/606Y10T403/7176
    • Attachment devices are taught that preferably include at least one compressible leg interconnected to at least one non-compressible leg. Preferably, the non-compressible leg includes a stopper for generating a compressing force in the compressible leg during an attachment operation. After the attachment device has been installed and the compressible leg exerts a retaining force against the object to which it is attached, an engagement lip preferably retains the compressible leg in the compressed state to provide a secure and reliable attachment.
    • 教导附接装置,其优选地包括互连到至少一个不可压缩腿的至少一个可压缩腿。 优选地,不可压缩腿包括用于在附接操作期间在可压缩腿中产生压缩力的止动件。 在附接装置已经安装并且可压缩腿对其所附接的物体施加保持力之后,接合唇优选地将可压缩腿保持在压缩状态,以提供安全可靠的附接。