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    • 9. 发明授权
    • Transparent electroconductive film and process for producing the same
    • 透明导电膜及其制造方法
    • US09297061B2
    • 2016-03-29
    • US12449303
    • 2008-02-15
    • Takashi KuchiyamaKenji Yamamoto
    • Takashi KuchiyamaKenji Yamamoto
    • B32B9/00C23C14/08C03C17/34
    • C23C14/086C03C17/3441C03C2217/944C03C2218/365
    • In a transparent electroconductive film including a transparent substrate and a transparent electroconductive oxide layer disposed on the transparent substrate, when the transparent electroconductive oxide layer is composed of zinc oxide, the surface resistivity of the transparent electroconductive oxide layer increases with time and thus it has been difficult to obtain a transparent electroconductive film stable against an environmental variation. Consequently, hard carbon films are provided on the surfaces of a transparent electroconductive oxide layer including at least one layer and containing zinc oxide as a main component in “the order of transparent substrate-hard carbon film-transparent electroconductive oxide layer-hard carbon film” or “the order of hard carbon film-transparent substrate-transparent electroconductive oxide layer-hard carbon film”. Alternatively, an organosilicon compound covering layer is provided on a surface of the transparent electroconductive oxide layer. Thereby, the water contact angle can be 75 degrees or more, and an increase in the resistivity of the transparent electroconductive oxide layer can be suppressed.
    • 在透明导电膜包括透明基板和透明导电氧化物层的透明导电膜上,当透明导电氧化物层由氧化锌组成时,透明导电氧化物层的表面电阻率随着时间的推移而增加, 难以获得对环境变化稳定的透明导电膜。 因此,在“透明基板 - 硬质碳膜透明导电氧化物层 - 硬质碳膜”的顺序,在包含至少一层并含有氧化锌作为主要成分的透明导电氧化物层的表面上设置硬质碳膜, 或“硬碳膜透明基板透明导电氧化物层 - 硬质碳膜的顺序”。 或者,在透明导电氧化物层的表面上设置有机硅化合物覆盖层。 因此,水接触角可以为75度以上,并且可以抑制透明导电氧化物层的电阻率的增加。