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    • 1. 发明授权
    • Optical glass fiber coating composition
    • 光学玻璃纤维涂料组合物
    • US5913004A
    • 1999-06-15
    • US840169
    • 1997-04-14
    • Hideaki TakaseMitsuhito SuwaZen KomiyaTakashi Ukachi
    • Hideaki TakaseMitsuhito SuwaZen KomiyaTakashi Ukachi
    • C03C25/10C08F290/06C08G18/10C08G18/67C09D175/16G02B6/02G02B6/16
    • C09D175/16C03C25/106C08F290/067C08G18/10C08G18/672
    • Provided is an optical glass fiber coating composition which when coated on an optical glass fiber and suitably cured provides a coating having the combination of properties (i) through (iv):(i) a stable tensile modulus that is low at room temperature and over a broad range of temperatures below room temperature,(ii) an adhesion to the optical glass fiber sufficient to prevent structural defects and microbending in the optical glass fiber,(iii) the capability of being removed by stripping from the optical glass fiber substantially no residue left on the optical glass fiber, and(iv) which satisfies each of the following inequalities (I) and (II),X.ltoreq.0.2 kg/mm.sup.2 (I)X/Y.gtoreq.1/10 (II) wherein X is the tensile modulus (kg/mm.sup.2) measured at 23.degree. C. and Y is the tensile modulus (kg/mm.sup.2) measured at -40.degree. C.,This coating composition comprises:(A) a urethane (meth)acrylate formed from,(a) a diol compound containing at least one structure represented by one of the following formulas (1) and (2), ##STR1## (b) a compound containing two isocyanate groups, and (c) a compound containing a (meth)acrylate group and a hydroxy group;(B) a second (meth)acrylate-containing compound of which the homopolymer has a glass transition temperature of at most about 0.degree. C.; and(C) a polymerization initiator.
    • 提供了一种光学玻璃纤维涂料组合物,其在光学玻璃纤维上涂覆并适当固化时提供了具有性能(i)至(iv)的组合的涂层:(i)在室温和过高时稳定的拉伸模量 低于室温的宽范围的温度,(ii)足以防止光学玻璃纤维中的结构缺陷和微弯曲的光学玻璃纤维的粘附,(iii)通过从光学玻璃纤维剥离而基本上没有残留物的去除能力 留下在光学玻璃纤维上,和(iv)满足以下不等式(I)和(II)中的每一个,X <= 0.2kg / mm 2(I)X / Y> / = 1/10(II)其中 X为在23℃下测定的拉伸弹性模量(kg / mm2),Y为在-40℃下测定的拉伸弹性模量(kg / mm2)。该涂料组合物包含:(A)形成的氨基甲酸酯(甲基) 由(a)含有由下述式(1)表示的至少一种结构的二醇化合物a nd(2),(b)含有2个异氰酸酯基的化合物,(c)含有(甲基)丙烯酸酯基和羟基的化合物; (B)第二(甲基)丙烯酸酯化合物,其均聚物的玻璃化转变温度为至多约0℃; 和(C)聚合引发剂。
    • 6. 发明授权
    • Liquid curable resin composition
    • 液体固化树脂组合物
    • US06180741B2
    • 2001-01-30
    • US09413883
    • 1999-10-07
    • Yoshikazu YamaguchiZen KomiyaTakashi Ukachi
    • Yoshikazu YamaguchiZen KomiyaTakashi Ukachi
    • C08G77458
    • G02B1/046C08G18/61C08G18/672C08L83/08C09D4/06C08G18/6674C08L83/00C08F290/148C08F290/147
    • A liquid curable resin composition exhibiting superior storing stability and suitable for use as a material for optical fiber ribbon matrix, a bundling material, and a material for up-jacketing fibers. The composition contains a first polydimethylsiloxane compound which contains (i) at least two urethane bonds, (ii) an unreactive organic group attached to at least one end of the first polydimethyl-siloxane, and (iii) a (meth)acrylol group attached to at least one end of the first polydimethylsiloxane, and a second polydimethylsiloxane compound which contains (i) at least two urethane bonds and (ii) an unreactive organic group attached to at least one end of the second polydimethylsiloxane, and optionally a third polysiloxane compound which does not contain urethane bonds.
    • 一种液体固化树脂组合物,其显示出优良的储存稳定性,适合用作光纤带状基体材料,捆扎材料和上覆纤维材料。 该组合物包含第一聚二甲基硅氧烷化合物,其包含(i)至少两个氨基甲酸酯键,(ii)连接至第一聚二甲基硅氧烷的至少一个末端的非反应性有机基团,和(iii)(甲基)丙烯酰基 第一聚二甲基硅氧烷的至少一个末端和第二聚二甲基硅氧烷化合物,其包含(i)至少两个氨基甲酸酯键和(ii)连接到第二聚二甲基硅氧烷的至少一个末端的非反应性有机基团,以及任选的第三聚硅氧烷化合物, 不含氨基甲酸酯键。
    • 9. 发明授权
    • Coated optical fiber and radiation curable resin composition
    • 涂布光纤和辐射固化树脂组合物
    • US06579618B1
    • 2003-06-17
    • US09604303
    • 2000-06-26
    • Miyuki IshikawaZen KomiyaTakashi Ukachi
    • Miyuki IshikawaZen KomiyaTakashi Ukachi
    • G02B600
    • C03C25/106C08F290/062C09D4/06Y10T428/2938C08F290/06
    • Provided is a radiation curable resin composition suitable for use as a primary coating material for optical fibers, which can form a cured coating with a low modulus of elasticity exhibiting a high breaking strength, and small light transmission loss; the coating composition comprises (A) a polymer containing polymerizable unsaturated groups in an average amount of 1.2 per molecule, a urethane bond in a molecular chain, and having a number average molecular weight from 3,000 to 30,000, (B) a poly-functional monomer having two or more polymerizable unsaturated groups, (C) a monomer having one polymerizable unsaturated group, and (D) a radiation active initiator. The secant modulus of the coating is less than 0.15 kg/mm2, the tensile strength is more than 0.15 kg/mm2.
    • 本发明提供一种适合用作光纤的一次涂层材料的辐射固化树脂组合物,其可以形成具有高断裂强度的低弹性模量和小的光透射损失的固化涂层; 涂料组合物包含(A)每分子平均含量为可聚合不饱和基团的聚合物,分子链中的氨基甲酸酯键,数均分子量为3,000至30,000,(B)多官能单体 具有两个或多个可聚合不饱和基团,(C)具有一个可聚合不饱和基团的单体和(D)辐射活性引发剂。 涂层的割线模量小于0.15kg / mm2,拉伸强度大于0.15kg / mm2。