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1. 发明授权

US06319603B1 Liquid curable resin composition 有权
标题翻译：液体固化树脂组合物
公开(公告)号：US06319603B1
公开(公告)日：2001-11-20
申请号：US09260507
申请日：1999-03-02
申请人： Zen Komiya , Yoshikazu Yamaguchi , Tsuyoshi Watanabe , Takashi Ukachi
发明人： Zen Komiya , Yoshikazu Yamaguchi , Tsuyoshi Watanabe , Takashi Ukachi
IPC分类号： G02B604
CPC分类号： G03F7/038 , C03C25/106 , C08F265/06 , C08G59/68 , C08L63/00 , C09D151/003 , G03F7/032 , Y10T428/2938 , C08L2666/04 , C08F222/1006 , C08F2220/1825 , C08F220/14 , C08F220/32
摘要： A liquid curable resin composition comprising (1) a (meth)acrylate polymer having a weight average molecular weight relative to polystyrene standard of at least about 5,000, (2) a ring-opening polymerizable monomer containing at least one epoxy group, and (3) a cationic photopolymerization initiator is disclosed. The composition produces cured products which exhibit superior heat resistance, excellent mechanical strength, and superb adhesive characteristics, and is suitable for use as a photo-curable adhesive, a photo-curable sealing material, a resin for optical three-dimensional molding, and a coating material for optical fibers, and optical fiber ribbon matrix.
摘要翻译：一种液体可固化树脂组合物，其包含（1）相对于聚苯乙烯标准重均分子量为至少约5,000的（甲基）丙烯酸酯聚合物，（2）含有至少一个环氧基的开环聚合单体和（3 ）阳离子光聚合引发剂。该组合物产生显示出优异的耐热性，优异的机械强度和极好的粘合特性的固化产物，并且适合用作光固化性粘合剂，光固化型密封材料，光学三维成型用树脂和光纤涂层材料和光纤带状基体。

2. 发明授权

US06180741B2 Liquid curable resin composition 失效
标题翻译：液体固化树脂组合物
公开(公告)号：US06180741B2
公开(公告)日：2001-01-30
申请号：US09413883
申请日：1999-10-07
申请人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
IPC分类号： C08G77458
CPC分类号： G02B1/046 , C08G18/61 , C08G18/672 , C08L83/08 , C09D4/06 , C08G18/6674 , C08L83/00 , C08F290/148 , C08F290/147
摘要： A liquid curable resin composition exhibiting superior storing stability and suitable for use as a material for optical fiber ribbon matrix, a bundling material, and a material for up-jacketing fibers. The composition contains a first polydimethylsiloxane compound which contains (i) at least two urethane bonds, (ii) an unreactive organic group attached to at least one end of the first polydimethyl-siloxane, and (iii) a (meth)acrylol group attached to at least one end of the first polydimethylsiloxane, and a second polydimethylsiloxane compound which contains (i) at least two urethane bonds and (ii) an unreactive organic group attached to at least one end of the second polydimethylsiloxane, and optionally a third polysiloxane compound which does not contain urethane bonds.
摘要翻译：一种液体固化树脂组合物，其显示出优良的储存稳定性，适合用作光纤带状基体材料，捆扎材料和上覆纤维材料。该组合物包含第一聚二甲基硅氧烷化合物，其包含（i）至少两个氨基甲酸酯键，（ii）连接至第一聚二甲基硅氧烷的至少一个末端的非反应性有机基团，和（iii）（甲基）丙烯酰基第一聚二甲基硅氧烷的至少一个末端和第二聚二甲基硅氧烷化合物，其包含（i）至少两个氨基甲酸酯键和（ii）连接到第二聚二甲基硅氧烷的至少一个末端的非反应性有机基团，以及任选的第三聚硅氧烷化合物，不含氨基甲酸酯键。

3. 发明授权

US6063888A Liquid curable resin composition 失效
标题翻译：液体固化树脂组合物
公开(公告)号：US6063888A
公开(公告)日：2000-05-16
申请号：US168938
申请日：1998-10-09
申请人： Yoshikazu Yamaguchi , Junji Yoshizawa , Zen Komiya , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Junji Yoshizawa , Zen Komiya , Takashi Ukachi
IPC分类号： G02B6/44 , C03C25/24 , C08F2/46 , C08F290/00 , C08F299/06 , C08F299/08 , C08G18/28 , C08G18/67 , C08G77/388 , C09D175/14 , C09D175/16 , C09D183/07 , C09D183/10 , G02B1/04 , G03F7/027 , G03F7/038 , G03F7/075 , C08G77/20
CPC分类号： C08G18/672 , C08G18/289 , C08G77/388 , G02B1/048 , Y10T428/2942 , Y10T428/2962 , Y10T428/2991 , Y10T428/2995 , Y10T428/2998
摘要： A liquid radiation curable resin composition comprising a polydimethylsiloxane compound which has (i) at least two urethane bonds in one molecule, (ii) an unreactive organic group at at least one of the ends of the molecule, and (iii) a radical curable ethylenically unsaturated group at the other end of the molecule. The resin composition exhibits superior shelf life in a liquid state and produces cured products having slippery surface. It is suitable as a coating material for optical fibers.
摘要翻译：一种液体辐射固化树脂组合物，其包含聚二甲基硅氧烷化合物，所述聚二甲基硅氧烷化合物在一分子中具有（i）至少两个氨基甲酸酯键，（ii）所述分子的至少一个末端的非反应性有机基团，和（iii）可自由基固化的烯属在分子另一端的不饱和基团。树脂组合物在液态下表现出优异的保存期，并产生具有光滑表面的固化产物。它适用于光纤的涂层材料。

4. 发明授权

US5986018A Liquid curable resin compositions 失效
标题翻译：液体固化树脂组合物
公开(公告)号：US5986018A
公开(公告)日：1999-11-16
申请号：US26676
申请日：1998-02-20
申请人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
IPC分类号： G02B6/44 , C03C25/24 , C08F299/06 , C08L75/16 , C08L83/04 , C09D4/06 , C09D133/14 , C09D175/16 , C08F283/04
CPC分类号： C09D133/14 , C09D175/16 , C09D4/06
摘要： A liquid curable resin composition comprising a dialkylpolysiloxane particles with at least two urethane bonds and/or urea bonds in the terminal groups. The resin composition exhibits superior shelf life in a liquid state and produces cured products having a slippery surface. It is suitable as a coating material for optical fibers, particularly as a ribbon matrix material and a bundling material.
摘要翻译：一种液体固化树脂组合物，其包含端基中具有至少两个氨基甲酸酯键和/或脲键的二烷基聚硅氧烷颗粒。树脂组合物在液态下表现出优异的保质期，并产生具有光滑表面的固化产物。它适合用作光纤的涂料，特别是作为带状基体材料和捆扎材料。

5. 发明申请

US20050256287A1 Curable liquid resin composition 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：US20050256287A1
公开(公告)日：2005-11-17
申请号：US10504863
申请日：2003-02-17
申请人： Masanobu Sugimoto , Hideki Sugimoto , Zen Komiya , Takashi Ukachi
发明人： Masanobu Sugimoto , Hideki Sugimoto , Zen Komiya , Takashi Ukachi
IPC分类号： G02B6/44 , C03C25/10 , C08F290/06 , C08G18/48 , C08G18/67 , C09D175/16 , C08G18/00
CPC分类号： C09D175/16 , C03C25/106 , C08G18/4808 , C08G18/672 , C08G18/48
摘要： The present invention discusses a curable liquid resin composition comprising a urethane (meth)acrylate obtained by using as polyol components (i) a polyether polyol comprising a structure according to formula (1): —CH2CH(CH3)O—, (ii) a polyether polyol having a cyclic structure and optionally (iii) one or more other polyols. The present invention also discusses a curable liquid resin composition which produces a cured product having high elasticity and high elongation suitable as a secondary material, in particular, as a ribbon matrix material can be provided.
摘要翻译：本发明讨论了包含通过使用多元醇组分（i）包含根据式（1）的结构的聚醚多元醇获得的氨基甲酸酯（甲基）丙烯酸酯的可固化液体树脂组合物：-CH 2 CH 2 CH 3）O-，（ii）具有环状结构的聚醚多元醇和任选地（iii）一种或多种其它多元醇。本发明还讨论了可以提供适合作为二次材料的具有高弹性和高伸长率的固化产物的可固化液体树脂组合物，特别是可以提供带状基质材料。

6. 发明授权

US06858657B2 Radiation curable resin composition 失效
标题翻译：辐射固化树脂组合物
公开(公告)号：US06858657B2
公开(公告)日：2005-02-22
申请号：US10349189
申请日：2003-01-23
申请人： Zen Komiya , Adrianus G. M. Abel , Duurt P. W. Alkema , Masahito Mase , Takashi Ukachi
发明人： Zen Komiya , Adrianus G. M. Abel , Duurt P. W. Alkema , Masahito Mase , Takashi Ukachi
IPC分类号： C03C25/10 , C08F2/46 , C08F2/48 , C08F283/00 , C08F290/06 , C08F290/14 , C08G2/00 , C08G18/28 , C08G18/48 , C08G18/67 , C09D175/16
CPC分类号： C09D175/16 , C03C25/106 , C03C25/1065 , C08F283/006 , C08F290/06 , C08F290/067 , C08F290/14 , C08F290/147 , C08G18/289 , C08G18/4866 , C08G18/672 , Y10T428/19 , Y10T428/2938 , Y10T428/294 , Y10T428/2942 , Y10T428/2956 , Y10T428/31645 , C08G18/48 , C08G18/40
摘要： The present invention provides a curable composition, comprising: a (meth)acrylate urethane compound derived from a polypropylene glycol or a propyleneoxide ethyleneoxide copolymer glycol having a molecular weight between 1,000 and 13,000 and an amount of unsaturation less than 0.01 meq/g. The liquid curable resin composition of the present invention has improved liquid stability and can produce cured products having superior mechanical characteristics by polymerization. The composition further comprises preferably a primary or secondary amine. The liquid curable resin composition can be used as a coating material for optical fibers, adhesives, and the like. The composition is particularly suitable as a coating material for optical fibers for which long-term stability is required.
摘要翻译：本发明提供一种可固化组合物，其包含：衍生自分子量为1,000至13,000的聚丙二醇或环氧丙烷环氧乙烷共聚物二醇的（甲基）丙烯酸酯氨基甲酸酯化合物，并且不饱和度的量小于0.01meq / g。本发明的液体固化型树脂组合物具有改善的液体稳定性，可以通过聚合制造具有优异的机械特性的固化物。组合物还优选包含伯胺或仲胺。液体固化性树脂组合物可以用作光纤，粘合剂等的涂料。该组合物特别适用于需要长期稳定性的光纤用涂料。

7. 发明授权

US06579618B1 Coated optical fiber and radiation curable resin composition 有权
标题翻译：涂布光纤和辐射固化树脂组合物
公开(公告)号：US06579618B1
公开(公告)日：2003-06-17
申请号：US09604303
申请日：2000-06-26
申请人： Miyuki Ishikawa , Zen Komiya , Takashi Ukachi
发明人： Miyuki Ishikawa , Zen Komiya , Takashi Ukachi
IPC分类号： G02B600
CPC分类号： C03C25/106 , C08F290/062 , C09D4/06 , Y10T428/2938 , C08F290/06
摘要： Provided is a radiation curable resin composition suitable for use as a primary coating material for optical fibers, which can form a cured coating with a low modulus of elasticity exhibiting a high breaking strength, and small light transmission loss; the coating composition comprises (A) a polymer containing polymerizable unsaturated groups in an average amount of 1.2 per molecule, a urethane bond in a molecular chain, and having a number average molecular weight from 3,000 to 30,000, (B) a poly-functional monomer having two or more polymerizable unsaturated groups, (C) a monomer having one polymerizable unsaturated group, and (D) a radiation active initiator. The secant modulus of the coating is less than 0.15 kg/mm2, the tensile strength is more than 0.15 kg/mm2.
摘要翻译：本发明提供一种适合用作光纤的一次涂层材料的辐射固化树脂组合物，其可以形成具有高断裂强度的低弹性模量和小的光透射损失的固化涂层; 涂料组合物包含（A）每分子平均含量为可聚合不饱和基团的聚合物，分子链中的氨基甲酸酯键，数均分子量为3,000至30,000，（B）多官能单体具有两个或多个可聚合不饱和基团，（C）具有一个可聚合不饱和基团的单体和（D）辐射活性引发剂。涂层的割线模量小于0.15kg / mm2，拉伸强度大于0.15kg / mm2。

8. 发明授权

US06309747B1 Liquid curable resin composition for optical fibers 失效
标题翻译：光纤用液固树脂组合物
公开(公告)号：US06309747B1
公开(公告)日：2001-10-30
申请号：US09149003
申请日：1998-09-08
申请人： Mitsuhito Suwa , Zen Komiya , Yuji Takasugi , Takashi Ukachi
发明人： Mitsuhito Suwa , Zen Komiya , Yuji Takasugi , Takashi Ukachi
IPC分类号： G02B600
CPC分类号： C09D4/06 , C03C25/106 , C03C25/28 , Y10T428/2933 , Y10T428/2938 , C08F290/046 , C08F290/126
摘要： A liquid curable resin composition for optical fibers comprising a polymer (a) having a number average molecular weight of 5,000 or more and containing at least two types of recurring ethylenic units, of which one type has a substituent group containing an ethylenically unsaturated group and the second type is substituted by a group —COOR3 (wherein R3 is a hydrogen atom or a hydrocarbon group having 1-30 carbon atoms), an aryl group, a cyano group, an alkyl group having 1-10 carbon atoms or by one or more halogen atoms.
摘要翻译：一种光纤用液态固化性树脂组合物，其含有数均分子量为5000以上且含有至少2种重复烯属单元的聚合物（a），其中一种具有含烯属不饱和基团的取代基，第二类被-COOR 3（其中R3是氢原子或具有1-30个碳原子的烃基），芳基，氰基，具有1-10个碳原子的烷基或一个或多个卤原子。

9. 发明授权

US06191187B1 Optical glass fiber coating compositions 失效
标题翻译：光学玻璃纤维涂料组合物
公开(公告)号：US06191187B1
公开(公告)日：2001-02-20
申请号：US08838848
申请日：1997-04-11
申请人： Tetsuya Yamamura , Masakatsu Ukon , Zen Komiya , Takashi Ukachi
发明人： Tetsuya Yamamura , Masakatsu Ukon , Zen Komiya , Takashi Ukachi
IPC分类号： C08F248
CPC分类号： C03C25/1065 , C09D4/06 , Y10T428/2938 , Y10T428/2942 , Y10T428/2947 , C08F290/067
摘要： An optical glass fiber coating composition comprising: (A) a urethane (meth)acrylate polymer, (B) a (meth)acrylate compound represented by the following formula (1), go wherein R1 is a hydrogen or a methyl group (C) a reaction diluent, and (D) a polymerization initiator. The composition has superior storage stability over a long period of time and, at a cured state, exhibits excellent UV resistance, heat resistance, yellowing resistance, and oil resistance.
摘要翻译：一种光学玻璃纤维涂料组合物，其包含：（A）氨基甲酸酯（甲基）丙烯酸酯聚合物，（B）由下式（1）表示的（甲基）丙烯酸酯化合物，其中R 1为氢或甲基（C）反应稀释剂和（D）聚合引发剂。该组合物在长时间内具有优异的储存稳定性，并且在固化状态下表现出优异的耐紫外线性，耐热性，耐黄变性和耐油性。

10. 发明授权

US6136880A Radiation-curable liquid resin composition for coating optical fibers 失效
标题翻译：用于涂覆光纤的可辐射固化液体树脂组合物
公开(公告)号：US6136880A
公开(公告)日：2000-10-24
申请号：US64173
申请日：1998-04-22
申请人： Paul Eugene Snowwhite , Timothy Edward Bishop , David Michael Szum , Zen Komiya , Miyuki Ishikawa , Takashi Ukachi
发明人： Paul Eugene Snowwhite , Timothy Edward Bishop , David Michael Szum , Zen Komiya , Miyuki Ishikawa , Takashi Ukachi
IPC分类号： C03C25/10 , C08F2/46 , C08G18/67
CPC分类号： C08G18/672 , C03C25/106 , Y10T428/2938 , Y10T428/2942 , Y10T428/2947
摘要： A radiation-curable composition for optical fiber coatings comprising about 10 wt. % to about 90 wt. % of at least one radiation-curable oligomer (A), about 10 wt. % to about 90 wt. % of at least one radiation-curable monomer diluent (B), and an effective amount of at least one photoinitiator (C) represented by formula (1): ##STR1## wherein Ar.sup.1 to Ar.sup.3 are aromatic groups which may have one or more substitution groups.
摘要翻译：一种用于光纤涂层的可辐射固化组合物，其包含约10wt。％至约90wt。％的至少一种可辐射固化的低聚物（A），约10wt。％至约90wt。至少一种可辐射固化的单体稀释剂（B）的％，和有效量的由式（1）表示的至少一种光引发剂（C）：其中Ar 1至Ar 3是可具有一个或多个取代基的芳族基团。

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