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1. 发明授权

US5913004A Optical glass fiber coating composition 失效
标题翻译：光学玻璃纤维涂料组合物
公开(公告)号：US5913004A
公开(公告)日：1999-06-15
申请号：US840169
申请日：1997-04-14
申请人： Hideaki Takase , Mitsuhito Suwa , Zen Komiya , Takashi Ukachi
发明人： Hideaki Takase , Mitsuhito Suwa , Zen Komiya , Takashi Ukachi
IPC分类号： C03C25/10 , C08F290/06 , C08G18/10 , C08G18/67 , C09D175/16 , G02B6/02 , G02B6/16
CPC分类号： C09D175/16 , C03C25/106 , C08F290/067 , C08G18/10 , C08G18/672
摘要： Provided is an optical glass fiber coating composition which when coated on an optical glass fiber and suitably cured provides a coating having the combination of properties (i) through (iv):(i) a stable tensile modulus that is low at room temperature and over a broad range of temperatures below room temperature,(ii) an adhesion to the optical glass fiber sufficient to prevent structural defects and microbending in the optical glass fiber,(iii) the capability of being removed by stripping from the optical glass fiber substantially no residue left on the optical glass fiber, and(iv) which satisfies each of the following inequalities (I) and (II),X.ltoreq.0.2 kg/mm.sup.2 (I)X/Y.gtoreq.1/10 (II) wherein X is the tensile modulus (kg/mm.sup.2) measured at 23.degree. C. and Y is the tensile modulus (kg/mm.sup.2) measured at -40.degree. C.,This coating composition comprises:(A) a urethane (meth)acrylate formed from,(a) a diol compound containing at least one structure represented by one of the following formulas (1) and (2), ##STR1## (b) a compound containing two isocyanate groups, and (c) a compound containing a (meth)acrylate group and a hydroxy group;(B) a second (meth)acrylate-containing compound of which the homopolymer has a glass transition temperature of at most about 0.degree. C.; and(C) a polymerization initiator.
摘要翻译：提供了一种光学玻璃纤维涂料组合物，其在光学玻璃纤维上涂覆并适当固化时提供了具有性能（i）至（iv）的组合的涂层：（i）在室温和过高时稳定的拉伸模量低于室温的宽范围的温度，（ii）足以防止光学玻璃纤维中的结构缺陷和微弯曲的光学玻璃纤维的粘附，（iii）通过从光学玻璃纤维剥离而基本上没有残留物的去除能力留下在光学玻璃纤维上，和（iv）满足以下不等式（I）和（II）中的每一个，X <= 0.2kg / mm 2（I）X / Y> / = 1/10（II）其中 X为在23℃下测定的拉伸弹性模量（kg / mm2），Y为在-40℃下测定的拉伸弹性模量（kg / mm2）。该涂料组合物包含：（A）形成的氨基甲酸酯（甲基）由（a）含有由下述式（1）表示的至少一种结构的二醇化合物a nd（2），（b）含有2个异氰酸酯基的化合物，（c）含有（甲基）丙烯酸酯基和羟基的化合物; （B）第二（甲基）丙烯酸酯化合物，其均聚物的玻璃化转变温度为至多约0℃; 和（C）聚合引发剂。

2. 发明授权

US06710097B2 Photocurable resin composition and optical parts 失效
标题翻译：光固化树脂组合物和光学部件
公开(公告)号：US06710097B2
公开(公告)日：2004-03-23
申请号：US09998929
申请日：2001-12-03
申请人： Hideaki Takase , Jirou Ueda , Takayoshi Tanabe , Takashi Ukachi
发明人： Hideaki Takase , Jirou Ueda , Takayoshi Tanabe , Takashi Ukachi
IPC分类号： C08F246
CPC分类号： C08F283/006 , C08F283/00 , C08G18/672 , C08G18/48
摘要： A photocurable resin composition comprising: (A) a urethane (meth)acrylate produced by reacting at least a polyether polyol with a number average molecular weight of 500 or more having an alkyleneoxy structure in the molecule, an organic polyisocyanate compound, and a (meth)acrylate containing a hydroxyl group; (B) a monofunctional (meth)acrylate shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 represents —(CH2CH2O)p—, —(CH(CH3)CH2O)q—, or —CH2CH(OH)CH2O—, Y1, Y2, and Y3 individually represent a hydrogen atom, bromine atom, alkyl group having 1-10 carbon atoms, phenyl group, or —C(CH3)2C6H5—, and p and q represent integers from 0 to 10; and (C) a photoinitiator; its use and optical parts prepared from the photocurable resin composition.
摘要翻译：一种光固化性树脂组合物，其含有：（A）通过至少使分子中具有亚烷基氧基结构的数均分子量为500以上的聚醚多元醇，有机多异氰酸酯化合物和（甲基）丙烯酸酯，）丙烯酸酯;（B）由下式（1）表示的单官能（甲基）丙烯酸酯，其中R 1表示氢原子或甲基，R 2表示 - （CH 2 CH 2 O）， - （CH（CH 3）CH 2 O）q-或-CH 2 CH（OH）CH 2 O-，Y 1，Y 2和Y 3各自表示氢原子，溴原子， 10个碳原子，苯基或-C（CH 3）2 C 6 H 5 - ，p和q表示0至10的整数; 和（C）光引发剂;其用途和由光固化树脂组合物制备的光学部件。

3. 发明授权

US06440519B1 Photocurable adhesive for optical disk 失效
标题翻译：用于光盘的可光固化粘合剂
公开(公告)号：US06440519B1
公开(公告)日：2002-08-27
申请号：US09160546
申请日：1998-09-25
申请人： Hideaki Takase , Ryoji Furuta , Toshihiko Takahashi , Takashi Ukachi , Yuichi Takehana
发明人： Hideaki Takase , Ryoji Furuta , Toshihiko Takahashi , Takashi Ukachi , Yuichi Takehana
IPC分类号： B32B302
CPC分类号： G11B7/256 , C08G18/672 , C08G18/6785 , C09J175/16 , G03F7/027 , G03F7/0751 , G11B7/2531 , G11B7/2532 , G11B7/2533 , G11B7/2534 , G11B7/26 , C08G18/42 , C08G18/44 , C08G18/48
摘要： A photocurable resin composition which comprises (A) a urethane (meth)acrylate oligomer obtained by the reaction of (a) at least one polyol compound preferably selected from the group consisting of polyester polyols and polycarbonate polyols, (b) a polyisocyanate compound, and (c) a hydroxyl group-containing (meth)acrylate compound; (B) a (meth)acrylolylphosphate; (C) a multifunctional (meth)acrylate compound; and (D) a photopolymerization initiator and, optionally, (E) an organosilyl-containing mercapto compound. The composition exhibits a fast cure speed, and the cured products obtained from the composition exhibit superior adhesion under high temperature-high humidity conditions and metal corrosion properties.
摘要翻译：一种光固化树脂组合物，其包含（A）通过（a）至少一种优选选自聚酯多元醇和聚碳酸酯多元醇的多元醇化合物反应得到的氨基甲酸酯（甲基）丙烯酸酯低聚物，（b）多异氰酸酯化合物和（c）含羟基的（甲基）丙烯酸酯化合物; （B）（甲基）丙烯酰磷酸酯; （C）多官能（甲基）丙烯酸酯化合物; 和（D）光聚合引发剂和（E）含有机甲硅烷基的巯基化合物。组合物表现出快速固化速度，并且由组合物获得的固化产物在高温高湿条件下表现出优异的粘附性和金属腐蚀性能。

4. 发明授权

US6013714A Resin composition and fibrous material forming mold 失效
标题翻译：树脂组合物和纤维材料成型模具
公开(公告)号：US6013714A
公开(公告)日：2000-01-11
申请号：US934126
申请日：1997-09-19
申请人： Yuichi Haruta , Hideaki Takase , Tsuyoshi Watanabe , Takashi Ukachi
发明人： Yuichi Haruta , Hideaki Takase , Tsuyoshi Watanabe , Takashi Ukachi
IPC分类号： G03F7/004 , B29C33/38 , B29C33/40 , B29C67/00 , C08F2/48 , C08F22/10 , C08K3/00 , C08L63/00 , D21J3/00
CPC分类号： B29C67/0066 , B29C33/3842 , C08F2/48 , C08F22/105 , B29K2105/16
摘要： Process for the manufacture of a mold for making products from fibrous materials by performing a combination of steps of(1) applying a thin layer of resin on a supporting stage(2) selectively irradiating the thin layer of resin as to cure a selected part of said resin(3) applying a further thin layer of resin, and repeating steps (2) and (3) as to obtain a three dimensional shape of a plurality of cured layers, optionally combined with either one of the steps of washing and post-curing the three dimensional shape, as to obtain the mold, wherein the resin ocmpositiona is formulated from constituents comprises at least one photoreaction monomer at least one photoinitiator at least one filler.
摘要翻译：一种用于制造由纤维材料制造产品的模具的方法，该模具通过以下步骤组合：（1）在支撑台（2）上施加薄层树脂，选择性地照射树脂薄层，以固化所选择的部分所述树脂（3）施加另外的薄层树脂，并且重复步骤（2）和（3）以得到多个固化层的三维形状，任选地与洗涤和后处理的任一步骤组合，固化三维形状以获得模具，其中树脂组合物由组分配制包含至少一种光反应单体至少一种光引发剂至少一种填料。

5. 发明申请

US20100137490A1 RESIN COMPOSITION, CURED PRODUCT AND OPTICAL PARTS 审中-公开
标题翻译：树脂组合物，固化产品和光学部件
公开(公告)号：US20100137490A1
公开(公告)日：2010-06-03
申请号：US12694850
申请日：2010-01-27
申请人： Mitsuru Ueda , Shinji Ando , Jin-gang Liu , Yuzi Shibasaki , Yasuhiro Nakamura , Shuichi Sugawara , Miwa Ariyuki , Yuichi Eriyama , Keisuke Kuriyama , Hideaki Takase
发明人： Mitsuru Ueda , Shinji Ando , Jin-gang Liu , Yuzi Shibasaki , Yasuhiro Nakamura , Shuichi Sugawara , Miwa Ariyuki , Yuichi Eriyama , Keisuke Kuriyama , Hideaki Takase
IPC分类号： C08K3/22 , C08L79/08 , C08G73/10
CPC分类号： C08L79/08 , C08G73/1064 , C08J5/18 , C08J2379/08 , C08K3/22 , Y10T428/1023
摘要： It is provided for a resin composition including (A) at least one polyamic acid having the structure represented by the following formula (1): wherein R1 is independently an alkyl group having 1 to 3 carbon atoms or a cyano group; a is independently an integer of 0 to 4; R is a tetravalent organic group; n is an integer of 1 to 4; and m is an integer of 1 to 100,000, and (E) an organic solvent.
摘要翻译：提供一种树脂组合物，其包含（A）至少一种具有由下式（1）表示的结构的聚酰胺酸：其中R 1独立地为具有1至3个碳原子的烷基或氰基; a独立地为0〜4的整数; R是四价有机基团; n为1〜4的整数， m为1〜100的整数，（E）有机溶剂。

6. 发明申请

US20070223868A1 Photosensitive Resin Composition for Optical Waveguide Formation and Optical Waveguide 有权
标题翻译：用于光波导形成和光波导的光敏树脂组合物
公开(公告)号：US20070223868A1
公开(公告)日：2007-09-27
申请号：US10593815
申请日：2005-02-23
申请人： Tomohiro Utaka , Hideaki Takase , Yuuichi Eriyama
发明人： Tomohiro Utaka , Hideaki Takase , Yuuichi Eriyama
IPC分类号： G02B6/02
CPC分类号： G02B6/1221 , C08G59/08 , C08G59/68 , G02B6/138
摘要： A radiation-sensitive resin composition for forming optical waveguides, which comprises (A) a novolac type epoxy resin and (B) a photo-acid generator. The composition is used as materials for a core portion 5 of an optical waveguide 1, and the like. In the composition, component (A) is represented by the following general formula (1). (In the formula, R1 is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, or an aralkyl group; and n is an integer from 0 to 10.) The composition is excellent in patterning properties and the like in curing process, and is also excellent in heat resistance, transmission characteristics, and long-term reliability after the optical waveguide has been formed.
摘要翻译：一种用于形成光波导的辐射敏感性树脂组合物，其包含（A）酚醛清漆型环氧树脂和（B）光酸产生剂。该组合物用作光波导1的芯部分5的材料等。在组合物中，组分（A）由以下通式（1）表示。（式中，R 1为氢原子，碳原子数为1〜12的烷基或芳烷基，n为0〜10的整数。）组成优异在固化过程中的图案化特性等，并且在形成光波导之后的耐热性，透射特性和长期可靠性也优异。

7. 发明申请

US20070189671A1 Method for manufacturing optical waveguide chip 审中-公开
标题翻译：光波导芯片制造方法
公开(公告)号：US20070189671A1
公开(公告)日：2007-08-16
申请号：US10591913
申请日：2005-02-23
申请人： Kentarou Tamaki , Hideaki Takase , Jun Huangfu , Yuuichi Eriyama
发明人： Kentarou Tamaki , Hideaki Takase , Jun Huangfu , Yuuichi Eriyama
IPC分类号： G02B6/30
CPC分类号： G02B6/30 , G02B6/138
摘要： An optical waveguide chip having an optical waveguide which can keep good transmission characteristics stably over a long period of time without separations or cracks even in severe use conditions, and an optical fiber guide portion formed without cracks firmly with a shape and a size corresponding to those of an optical fiber is provided. An optical waveguide chip 1 has a support 2, an optical waveguide 3 having a core portion 7, clad layers 6 and 8, an optical fiber guide portion 4 for positioning an optical fiber to be connected with the optical waveguide 3, and a cover member (glass plate) 5. The optical waveguide 3 is made of a radiation-sensitive polysiloxane composition. The optical fiber guide portion 4 is made of the same or a different radiation-sensitive polysiloxane composition as/from the material of the optical waveguide 3. The optical waveguide 3 and the optical fiber guide portion 4 are formed by separate processes.
摘要翻译：一种具有光波导的光波导芯片，即使在严格的使用条件下也能够长时间稳定地保持良好的透射特性而没有分离或裂纹，并且光纤引导部分形成无裂纹，形状和尺寸对应于那些提供了光纤。光波导芯片1具有支撑体2，具有芯部7的光波导3，包层6,8，用于定位与光波导3连接的光纤的光纤引导部4，以及盖部件（玻璃板）5。光波导3由辐射敏感性聚硅氧烷组合物制成。光纤引导部分4由与光波导3的材料相同或不同的辐射敏感性聚硅氧烷组合物制成。光波导3和光纤引导部4通过分开的工序形成。

8. 发明授权

US07084187B2 Curable liquid resin composition 有权
标题翻译：可固化液体树脂组合物
公开(公告)号：US07084187B2
公开(公告)日：2006-08-01
申请号：US10488472
申请日：2002-09-26
申请人： Hideaki Takase , Yoshikazu Yamaguchi , Takayoshi Tanabe
发明人： Hideaki Takase , Yoshikazu Yamaguchi , Takayoshi Tanabe
IPC分类号： C08J3/28
CPC分类号： C09D4/00 , C08F230/08
摘要： To provide a radiation-sensitive curable liquid resin composition having excellent applicability and capable of producing a film excelling in hardness, scratch resistance, adhesion, transparency, and appearance of the surface of the film.A curable liquid resin composition comprising: (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium to a specific organic compound which comprises a polymerizable unsaturated group and a group shown by —X—C(═Y)—NH— (wherein X is NH, O, or S, and Y is O or S), and preferably a silanol group, (B) a compound having two or more polymerizable unsaturated groups in the molecule, (C) a specific alkylene glycol organic solvent, and preferably (D) a polymerization initiator.
摘要翻译：本发明提供一种具有优异适用性且能够制备出优异的薄膜表面的硬度，耐擦伤性，粘附性，透明性和外观的薄膜的辐射敏感性固化性液体树脂组合物。一种可固化液体树脂组合物，其包含：（A）通过将选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物键合到特定的包含可聚合不饱和基团和由-XC（-Y）-NH-（其中X是NH，O或S，Y是O或S）表示的基团的有机化合物，优选硅烷醇基，（B）在分子中具有两个以上聚合性不饱和基团的化合物，（C）特定的亚烷基二醇有机溶剂，优选（D）聚合引发剂。

9. 发明申请

US20060008222A1 Photosensitive resin composition for optical waveguide formation and optical wave guide 有权
标题翻译：用于光波导形成和光波导的光敏树脂组合物
公开(公告)号：US20060008222A1
公开(公告)日：2006-01-12
申请号：US10527547
申请日：2003-09-30
申请人： Hideaki Takase , Yuuichi Eriyama
发明人： Hideaki Takase , Yuuichi Eriyama
IPC分类号： G02B6/10
CPC分类号： C08F222/1006 , G02B6/1221 , G02B6/138 , G02B2006/12069
摘要： A photosensitive resin composition for optical waveguide formation, comprising: (A) a di(meth)acrylate having the structure represented by the following general formula (1): (wherein R1 is —(OCH2CH2)m—, —(OCH(CH3)CH2)m—, or —OCH2CH(OH)CH2—; X is —C(CH3)2—, —CH2—, —O—, or —SO2—; Y is a hydrogen atom or a halogen atom; m is an integer of 0 to 4); (B) a mono(meth)acrylate having the structure represented by the following general formula (2): (wherein R2 is —(OCH2CH2)p—, —(OCH(CH3)CH2)p—, or —OCH2CH(OH)CH2—; Y is a hydrogen atom, a halogen atom, Ph-C(CH3)2—, Ph-, or an alkyl group having 1 to 20 carbon atoms; p is an integer of 0 to 4; Ph is a phenyl group); and (C) a photoradical polymerization initiator. The composition has excellent patterning ability, refractive index, heat resistance, and transmission characteristic.
摘要翻译：一种光波导形成用感光性树脂组合物，其包含：（A）具有以下通式（1）所示结构的二（甲基）丙烯酸酯：（其中R 1为 - （OCH

10. 发明授权

US08563214B2 Radiation sensitive resin composition and method of forming an interlayer insulating film 有权
标题翻译：辐射敏感性树脂组合物和形成层间绝缘膜的方法
公开(公告)号：US08563214B2
公开(公告)日：2013-10-22
申请号：US13502211
申请日：2010-10-14
申请人： Katsuhiro Kikuchi , Kentaro Usui , Masakazu Shibasaki , Takashi Ochi , Tatsuro Kato , Kenichi Hamada , Masashi Arai , Megumi Murata , Hideaki Takase
发明人： Katsuhiro Kikuchi , Kentaro Usui , Masakazu Shibasaki , Takashi Ochi , Tatsuro Kato , Kenichi Hamada , Masashi Arai , Megumi Murata , Hideaki Takase
IPC分类号： G03F7/023
CPC分类号： G03F7/0233 , G03F7/0226 , G03F7/40
摘要： The present invention relates to a radiation sensitive resin composition comprising [A] an alkali-soluble resin, [B] a 1,2-quinonediazide compound and [C] a radical trapping agent.The radiation sensitive resin composition can provide an interlayer insulating film which satisfies general requirements for an interlayer insulating film such as high light transmittance and has excellent heat-resistant dimensional stability, heat discoloration resistance and adhesion to a substrate along with the improvement of process efficiency for improving product yield at a high resolution and has excellent storage stability.
摘要翻译：本发明涉及一种辐射敏感性树脂组合物，其包含[A]碱溶性树脂，[B] 1,2-醌二叠氮化合物和[C]基团捕获剂。辐射敏感性树脂组合物可以提供层间绝缘膜，其满足诸如高透光率的层间绝缘膜的一般要求，并且具有优异的耐热尺寸稳定性，耐热变色性和对基材的粘附性，同时提高了工艺效率以高分辨率提高产品收率，并具有优良的储存稳定性。

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