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1. 发明授权

US06417392B1 Method for production of alkylamino(Meth)acrylate and apparatus therefor 失效
标题翻译：制备烷基氨基（甲基）丙烯酸酯的方法及其设备
公开(公告)号：US06417392B1
公开(公告)日：2002-07-09
申请号：US09164796
申请日：1998-10-01
申请人： Hideaki Nagano , Tadayoshi Kawashima , Tetsuya Kajihara , Kaoru Iwasaki , Sumio Nakashima
发明人： Hideaki Nagano , Tadayoshi Kawashima , Tetsuya Kajihara , Kaoru Iwasaki , Sumio Nakashima
IPC分类号： C07C6952
CPC分类号： B01D3/009 , C07C213/06 , Y02P20/127 , C07C219/20
摘要： In the operation of producing an alkylamino(meth)acrylate by the reaction of transesterification of an alkyl(meth)acrylate with an alkylamino alcohol, the alkyl alcohol by-produced during the transesterification is distilled in the form of an azeotropic mixture with the alkyl(meth)acrylate, the resultant distillate is purified with an ion-exchange resin and handled, on the other hand, the reaction solution is distilled to allow separation of the catalyst wherein is provided a method and apparatus for effecting, in the production of the alkylamino(meth)acrylate, the distillation under such a condition as represses the amount of in crease of the Michael adduct below 2%.
摘要翻译：在通过（甲基）丙烯酸烷基酯与烷基氨基醇的酯交换反应制备烷基氨基（甲基）丙烯酸酯的操作中，在酯交换期间副产生的烷基醇与烷基（甲基）丙烯酸酯，所得馏出物用离子交换树脂纯化，另一方面，蒸馏反应溶液以允许分离催化剂，其中提供了在制备烷基氨基中实现的方法和装置（甲基）丙烯酸酯，在抑制迈克尔加合物的折痕量低于2％的条件下进行蒸馏。

2. 发明授权

US06465681B2 Production process for hydroxyalkyl (meth)acrylate 有权
标题翻译：（甲基）丙烯酸羟烷基酯的制备方法
公开(公告)号：US06465681B2
公开(公告)日：2002-10-15
申请号：US10021061
申请日：2001-12-19
申请人： Masahiro Uemura , Tokumasa Ishida , Yukihiro Yoneda , Tetsuya Kajihara , Yasuhiro Shingai , Tadayoshi Kawashima
发明人： Masahiro Uemura , Tokumasa Ishida , Yukihiro Yoneda , Tetsuya Kajihara , Yasuhiro Shingai , Tadayoshi Kawashima
IPC分类号： C07C6726
CPC分类号： C07C67/26 , C07C69/54
摘要： The present invention provides: a production process for a hydroxyalkyl(meth)acrylate, which can raise productivity together with avoiding danger of explosion, and further can suppress side-formation of impurities such as a diester or a monoester wherein the impurities have a bad influence on product quality. When the time from the start of adding an alkylene oxide (AO) till the end of supplying the entirety of the AO is defined as T (hour), the amount of more than 50% of the entirety of the AO is supplied before T/2 (hour) has passed since the start of adding the AO. In addition, when the total amount of an AO as supplied and the time from the start of adding the AO till the end of supplying the entirety of the AO are defined as W (mol) and T (hour) respectively, the supply of the AO is started at a supplying speed V0 (mol/hour) that is faster than the average supplying speed V (=W/T) (mol/hour), and thereafter the supplying speed of the AO is decreased at least once, and then the supply of the entirety of the AO is completed for T (hour) from the start of adding the AO.
摘要翻译：本发明提供：（甲基）丙烯酸羟烷基酯的制造方法，其能够提高生产率，同时避免爆炸的危险，并且还可以抑制杂质如杂质影响不良的杂质的副产物对产品质量。当从添加烯化氧（AO）开始直到提供AO全部结束时的时间定义为T（小时）时，超过全部AO的50％的量在T / 从加入AO开始，已经过了2（小时）。此外，当供应的AO的总量和从AO的添加开始到提供AO的全部的时间分别被定义为W（mol）和T（小时）时， AO以比平均供给速度V（= W / T）（mol /小时）快）的供给速度V0（mol /小时）开始，此后AO的供给速度至少减少一次，然后从添加AO开始，T（小时）完成AO的整体供应。

3. 发明授权

US06960670B2 Method for production of maleic anhydride 失效
标题翻译：马来酸酐生产方法
公开(公告)号：US06960670B2
公开(公告)日：2005-11-01
申请号：US10174669
申请日：2002-06-19
申请人： Tadayoshi Kawashima , Yoshitake Ishii , Kei Hamamoto , Souichi Yamada , Tetsuya Kajihara
发明人： Tadayoshi Kawashima , Yoshitake Ishii , Kei Hamamoto , Souichi Yamada , Tetsuya Kajihara
IPC分类号： C07C51/46 , C07C51/56 , C07D307/60
CPC分类号： C07C51/46 , C07C51/56 , C07C57/145
摘要： This invention discloses a method for producing maleic anhydride comprising an azeotropic distillation step to dehydrate a crude maleic acid-containing aqueous solution, which method is characterized by as an azeotropic solvent (1) using an organic solvent exhibiting a maximum dissolving concentration of the organic solvent in water in the range of 0.1-5% by weight at a temperature of 20° C. According to this invention, it is made possible to prevent the occurrence of a blocking substance, allow a continuous operation for a long time, and remove by-produced acid components by a process of distillation for azeotropic dehydration.
摘要翻译：本发明公开了一种马来酸酐的制造方法，其特征在于，使用含有所述有机溶剂的最大溶解浓度的有机溶剂作为共沸溶剂（1）进行脱水的共沸蒸馏工序，在20℃的温度范围为0.1-5重量％的水中。根据本发明，可以防止发生阻塞物质，长时间连续操作，并且通过通过蒸馏共沸脱水方法生产的酸组分。

4. 发明授权

US06552218B2 Process for producing hydroxyalkyl (meth)acrylate 失效
标题翻译：（甲基）丙烯酸羟烷基酯的制备方法
公开(公告)号：US06552218B2
公开(公告)日：2003-04-22
申请号：US09944087
申请日：2001-09-04
申请人： Tetsuya Kajihara , Tokumasa Ishida , Yasuhiro Shingai
发明人： Tetsuya Kajihara , Tokumasa Ishida , Yasuhiro Shingai
IPC分类号： C07C6726
CPC分类号： C07C67/26 , C07C69/54
摘要： The present invention provides a process for producing a hydroxyalkyl (meth)acrylate which enables to control sufficiently the formation of a diester at the time of a reaction and/or at the time of distillation. In the process for producing the hydroxyalkyl (meth)acrylate which comprises the step of carrying out a reaction between (meth)acrylic acid and an alkylene oxide in the existence of a catalyst, (1) the reaction between (meth)acrylic acid and the alkylene oxide, or (2) distillation of the resultant hydroxyalkyl (meth)acrylate is performed in the coexistence of a liquid having the relative dielectric constant of not less than 20 at 25° C.
摘要翻译：本发明提供了一种制备羟基烷基（甲基）丙烯酸酯的方法，其能够充分控制在反应时和/或蒸馏时二酯的形成。在制备（甲基）丙烯酸羟烷基酯的方法中，其包括在催化剂存在下进行（甲基）丙烯酸和烯化氧反应的步骤，（1）（甲基）丙烯酸与环氧烷之间的反应，或（2）所得物羟基烷基（甲基）丙烯酸酯在25℃下相对介电常数不小于20的液体共存时进行。

5. 发明授权

US06660881B2 Process for producing (meth)acrylic ester 有权
公开(公告)号：US06660881B2
公开(公告)日：2003-12-09
申请号：US09928574
申请日：2001-08-12
申请人： Hajime Matsumoto , Tetsuya Kajihara , Yasuhiro Shingai , Masatoshi Ueoka , Yukihiro Yoneda , Masahiro Uemura , Sei Nakahara , Fumio Munechika
发明人： Hajime Matsumoto , Tetsuya Kajihara , Yasuhiro Shingai , Masatoshi Ueoka , Yukihiro Yoneda , Masahiro Uemura , Sei Nakahara , Fumio Munechika
IPC分类号： C07C6954
CPC分类号： C07C67/08 , C07C67/26 , C07C69/54
摘要： The present invention provides a process for producing a (meth)acrylic ester which enables to obtain a (meth)acrylic ester in an excellent reaction yield. The process for producing a (meth)acrylic ester uses an alcohol and an acid as raw materials and an ion-exchange resin as a catalyst, and the process is characterized by comprising a dehydration step and an esterification step, wherein the esterification reaction step follows the dehydration step in which water impregnated in the ion-exchange resin is removed by using as a dehydrating solvent at least one member selected from the group consisting of the alcohol, the acid, and the resulting ester.

6. 发明授权

US06610879B2 Reaction method by using heterogeneous catalyst and reaction apparatus therefor 有权
公开(公告)号：US06610879B2
公开(公告)日：2003-08-26
申请号：US09901011
申请日：2001-07-10
申请人： Yukihiro Yoneda , Tetsuya Kajihara , Yasuhiro Shingai , Hajime Matsumoto , Tokumasa Ishida
发明人： Yukihiro Yoneda , Tetsuya Kajihara , Yasuhiro Shingai , Hajime Matsumoto , Tokumasa Ishida
IPC分类号： C07C6952
CPC分类号： C07C67/08 , B01J8/005 , B01J8/008 , B01J8/20 , B01J2208/00867 , C07C67/26 , C07C69/54
摘要： When carrying out a liquid-phase reaction by using a heterogeneous catalyst, the separation of the heterogeneous catalyst and the reaction liquid is carried out certainly and effectively. A reaction method involves carrying out a reaction in liquid phase by using a heterogeneous catalyst particle 30 in a reactor 10, and comprises the steps of: (a) allowing a reaction liquid 40 supplied into the reactor 10 from such as a supplying inlet 12 to react in the presence of the heterogeneous catalyst particle 30, and (b) passing the resultant reaction liquid 40 containing the heterogeneous catalyst particle 30 through a line screen 20 having an opening width where the heterogeneous catalyst particle 30 is not allowed to pass substantially, and then extracting the reaction liquid 40 separated from the heterogeneous catalyst particle 30 from the reactor 10 by way of such as an extracting outlet 14.

7. 发明授权

US06414182B1 Production process for hydroxyalkyl ester 有权
标题翻译：羟烷基酯的生产工艺
公开(公告)号：US06414182B1
公开(公告)日：2002-07-02
申请号：US09620546
申请日：2000-07-22
申请人： Yasuhiro Shingai , Tokumasa Ishida , Fumio Shibusawa , Tetsuya Kajihara , Yukihiro Yoneda , Hajime Matsumoto , Masatoshi Ueoka
发明人： Yasuhiro Shingai , Tokumasa Ishida , Fumio Shibusawa , Tetsuya Kajihara , Yukihiro Yoneda , Hajime Matsumoto , Masatoshi Ueoka
IPC分类号： C07C6728
CPC分类号： C07C67/26 , C07C69/54
摘要： The present invention provide a production process for a hydroxyalkyl ester which comprises the step of carrying out a reaction between a carboxylic acid and an alkylene oxide in the presence of a catalyst, wherein the production process sufficiently enhances the conversion or selectivity in the reaction. The production process is characterized in that the reaction is carried out in a reaction liquid under conditions where a relationship a
摘要翻译：本发明提供一种羟烷基酯的制备方法，其包括在催化剂存在下，在羧酸和烯化氧之间进行反应的步骤，其中所述制备方法足以提高反应中的转化率或选择性。其制造方法的特征在于，反应在反应液中，在反应液中保持a

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