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1. 发明授权

US5726227A Polymer moulding compositions stabilised with phosphorous acid esters 失效
标题翻译：用亚磷酸酯稳定的聚合物模塑组合物
公开(公告)号：US5726227A
公开(公告)日：1998-03-10
申请号：US754233
申请日：1996-11-20
申请人： Herbert Magerstedt , Ernst Grigat
发明人： Herbert Magerstedt , Ernst Grigat
IPC分类号： C08K3/00 , C08K5/00 , C08K5/52 , C08K5/524 , C08K5/529 , C08K7/00 , C08K7/02 , C08L101/00 , C08K5/15
CPC分类号： C08K5/529
摘要： Thermoplastic moulding compositions containing A) polymers selected from the group comprising polyolefines, styrene polymers, polyamides, polyalkyl methacrylates, polyphenylene sulphides, ABS graft polymers, and thermoplastic polyurethanes, and B) esters of phosphorous acid which contain at least one oxetane group and at least one radical of a dihydric or polyhydric phenol per molecule, and optionally C) fillers and reinforcing materials, D) flame retardant additives, E) elastomeric modifiers.
摘要翻译：含有A）选自包含聚烯烃，苯乙烯聚合物，聚酰胺，聚烷基甲基丙烯酸酯，聚苯硫醚，ABS接枝聚合物和热塑性聚氨酯的聚合物的热塑性模塑组合物，以及B）含有至少一个氧杂环丁烷基团的亚磷酸酯和至少每个分子的二羟基或多元酚的一个基团，以及任选的C）填料和增强材料，D）阻燃添加剂，E）弹性体改性剂。

2. 发明授权

US4031067A Polytriazines and a process for their production 失效
标题翻译：聚三嗪类及其生产工艺
公开(公告)号：US4031067A
公开(公告)日：1977-06-21
申请号：US707552
申请日：1976-07-22
申请人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
发明人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
IPC分类号： C08G73/00 , C08G73/06 , C08G75/00 , C08G18/00 , C08G18/71
CPC分类号： C08G73/065
摘要： Mixtures of aliphatic, cycloaliphatic or aromatic polyfunctional N-cyanosulfon amides and aromatic polyfunctional cyanic acid ester are converted at 30.degree. to 150.degree. C into fusible prepolymers or prepolymers soluble in organic solvents (polymeric N-organo-isourea ethers). Said prepolymers are highly stable in storage and react at 150.degree. - 350.degree. C to high molecular weight polymers of of triazine structure which are insoluble in solvents and infusible. The prepolymers may be used for the production of coatings or shaped articles or laminates.
摘要翻译：脂肪族，脂环族或芳香族多官能N-氰基磺酰胺和芳香族多官能氰酸酯的混合物在30℃至150℃下转化成可溶于有机溶剂（聚合N-有机 - 异脲醚）的可熔预聚物或预聚物。所述预聚物在储存中高度稳定，在150-350℃下与不溶于溶剂和不溶性的三嗪结构的高分子量聚合物反应。预聚物可用于生产涂料或成型制品或层压材料。

3. 发明授权

US4028393A Process for the production of polyfunctional cyanic acid esters 失效
标题翻译：制备多官能氰酸酯的方法
公开(公告)号：US4028393A
公开(公告)日：1977-06-07
申请号：US658814
申请日：1976-02-17
申请人： Gunther Rottloff , Rudolf Sundermann , Ernst Grigat , Rolf Putter
发明人： Gunther Rottloff , Rudolf Sundermann , Ernst Grigat , Rolf Putter
IPC分类号： C07C323/20 , C07C20060101 , C07C67/00 , C07C253/00 , C07C261/02 , C07C313/00 , C07C315/04 , C07C317/22 , C08G73/06 , C07C122/00
CPC分类号： C07C261/02 , C07C2103/94
摘要： Highly pure aromatic polyfunctional cyanic acid esters having a high stability in storage and being extraordinarily suitable for use as starting compound for the production of plastics by cyclopoly-tri-merization are obtained by a special process.A di- or polytrialkyl ammonium phenolate of the formula: ##STR1## in which Ar represents an optionally substituted aromatic radical,R.sub.1, r.sub.2 and R.sub.3 are the same or different and each represents a linear or branched alkyl radical, andn is a number from 2 to 6,Is reacted at a temperature in the range of from -40.degree. to +65.degree. C in the presence of a trialkyl amine and an organic solvent with an excess of cyanogen halide.The excess of cyanogen halide is up to 80% by weight, based on the total weight of the phenolate and the trialkyl amine.
摘要翻译：通过特殊的方法可获得高度稳定的储存和非常适合用作通过环状三聚化生产塑料的起始化合物的高纯度芳香族多官能氰酸酯。

4. 发明授权

US4282367A Process for the separation of polyurethane foam hydrolysates into polyol and diamine 失效
标题翻译：将聚氨酯泡沫水解物分离成多元醇和二胺的方法
公开(公告)号：US4282367A
公开(公告)日：1981-08-04
申请号：US105059
申请日：1979-12-19
申请人： Georg Niederdellmann , Norbert Roemer , Ernst Grigat
发明人： Georg Niederdellmann , Norbert Roemer , Ernst Grigat
IPC分类号： C08G18/00 , C08G18/82 , C08J11/16 , C08G18/48 , C08G18/14
CPC分类号： C08J11/16 , C08J2375/04 , Y02W30/705 , Y10S521/914
摘要： The instant invention is directed to a process for the separation of polyurethane hydrolysates into polyamines and polyols which can be used again for the production of polyurethanes, comprising introducing gaseous hydrogen chloride into the hydrolysate mixture which has optionally been diluted with an inert solvent, and removing the precipitated amine salt by filtration, characterized in that(a) gaseous hydrogen chloride is optionally first introduced into the hydrolysate in a quantity of from 0.02 to 0.07 mol per amine equivalent, the reaction mixture is filtered and the filter residue is discarded, then(b) from 0.20 to 0.47 mol of gaseous hydrogen chloride per mol of amine equivalents still present is introduced into the filtrate and the precipitated amine salt is filtered off, then(c) stage (b) is repeated one or more times until the amine group content in the filtrate is below 1% by weight, based on the solvent-free filtrate, and finally(d) precipitation of the amine is completed by the introduction of from 0.5 to 1.0 mol of gaseous hydrogen chloride, based on the amine equivalents remaining in the filtrate.
摘要翻译：本发明涉及将聚氨酯水解物分离成多胺和多元醇的方法，其可以再次用于生产聚氨酯，包括将气态氯化氢引入到任选用惰性溶剂稀释的水解产物混合物中，并除去通过过滤沉淀的胺盐，其特征在于，（a）气态氯化氢任选地首先以每个胺当量为0.02至0.07mol的量引入水解产物中，将反应混合物过滤并弃去过滤残余物，然后（ b）将0.20至0.47摩尔的气态氯化氢/摩尔仍存在的胺当量引入滤液中，滤出沉淀的胺盐，然后（c）重复步骤（b）一次或多次，直至胺基基于无溶剂的滤液，滤液中的含量低于1重量％，最后（d）胺的沉淀完全通过根据残留在滤液中的胺当量，从0.5至1.0mol的气态氯化氢引入。

5. 发明授权

US4066577A High molecular weight polytriazines of soluble polymeric N-cyano-isourea ethers 失效
标题翻译：高分子量聚苯乙烯可溶性聚合N-氰基异荣醚
公开(公告)号：US4066577A
公开(公告)日：1978-01-03
申请号：US707543
申请日：1976-07-22
申请人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
发明人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
IPC分类号： C08G73/00 , C08G73/06 , C08G73/08
CPC分类号： C08G73/0655
摘要： High molecular weight temperature-resistant polymers of polytriazine structure obtained by heating cyanamides of the formula Ir -- (nh-cn).sub.nin which R represents an aliphatic, cycloaliphatic, heterocyclic or aromatic radical, optionally interrupted by oxygen and n is a number from 2 to 5, with polyfunctional, aromatic cyanic acid esters into a fusible or in organic solvents soluble polymeric N-cyano-isourea ether and completing the reaction at elevated temperatures and optionally in the presence of a catalyst to form said polymer of polytriazine structure.

6. 发明授权

US4051212A Process for the continuous degradation of plastics 失效
标题翻译：塑料连续降解过程
公开(公告)号：US4051212A
公开(公告)日：1977-09-27
申请号：US608853
申请日：1975-08-29
申请人： Ernst Grigat , Hartmut Hetzel
发明人： Ernst Grigat , Hartmut Hetzel
IPC分类号： B01J19/20 , B09B3/00 , B29B11/00 , B29B17/00 , C08F6/00 , C08G85/00 , C08J11/00 , C08J11/14 , C07C87/14 , B29H19/00
CPC分类号： B29C47/766 , C08J11/14 , B29C47/0009 , Y02W30/704 , Y10S264/911 , Y10S264/916
摘要： The instant invention relates to a continuous process for the hydrolytic degradation of plastics wherein a hydrolyzable material is introduced with water into a screw machine, and is subjected therein to a temperature of 100 to 300.degree. C, and a pressure of 5 to 100 bars for 2 to 100 minutes. The invention also relates to an apparatus useful in conducting the process.

7. 发明授权

US4049630A Process for preparation of s-triazine prepolymers 失效
标题翻译：制备s-三嗪预聚物的方法
公开(公告)号：US4049630A
公开(公告)日：1977-09-20
申请号：US631560
申请日：1975-11-13
申请人： Rudolf Sundermann , Rolf Putter , Ernst Grigat
发明人： Rudolf Sundermann , Rolf Putter , Ernst Grigat
IPC分类号： C08G73/00 , C07D251/26 , C07D251/34 , C08G18/83 , C08G63/91 , C08G73/06
CPC分类号： C08G73/065 , C07D251/26 , C07D251/34 , C08G18/833 , C08G63/916
摘要： Process for the preparation of s-triazine prepolymers which comprisesA. condensing a hydroxy compound which has 2 or more alcoholic hydroxyl groups;B. condensing the resulting condensation product with an aromatic hydroxy compound; andC. thereafter reacting the free hydroxyl groups of the condensation product obtained from (b) with cyanogen halide and in the presence of a base.
摘要翻译：制备s-三嗪预聚物的方法，其包括A.冷凝具有2个或更多个醇溶性羟基的羟基化合物; B.用芳族羟基化合物浓缩结晶凝结产物; 和C.反应自（B）与氰基卤化物和碱的存在产生的冷凝产物的自由羟基组合。

8. 发明授权

US06307003B1 Compostable adhesive 失效
标题翻译：可堆肥胶
公开(公告)号：US06307003B1
公开(公告)日：2001-10-23
申请号：US09171383
申请日：1999-03-15
申请人： Ernst Grigat , Karsten-Josef Idel , Uwe Westeppe , Wolfgang Schulz-Schlitte , Winfried Pommeranz , Jürgen Lörcks , Harald Schmidt
发明人： Ernst Grigat , Karsten-Josef Idel , Uwe Westeppe , Wolfgang Schulz-Schlitte , Winfried Pommeranz , Jürgen Lörcks , Harald Schmidt
IPC分类号： C08G6400
CPC分类号： C08G18/42 , C08G2230/00 , C09J167/00 , C09J167/02 , C09J167/04 , C09J169/005 , C09J175/06 , C09J177/12
摘要： The present invention relates to a compostable adhesive, to a method of producing the same, and to the use of the adhesive for the adhesive bonding of materials.
摘要翻译：本发明涉及可堆肥粘合剂，其制备方法，以及粘合剂用于粘合材料的用途。

9. 发明授权

US5455311A Thermoplastic block copolyesters capable of being composted for use as packaging materials 失效
标题翻译：能够堆肥的热塑性嵌段共聚酯可用作包装材料
公开(公告)号：US5455311A
公开(公告)日：1995-10-03
申请号：US287073
申请日：1994-08-08
申请人： Ernst Grigat , Ralf Dujardin , Ralf Timmermann , Hans-Georg Rast
发明人： Ernst Grigat , Ralf Dujardin , Ralf Timmermann , Hans-Georg Rast
IPC分类号： C08G18/34 , C08G18/42 , C08G63/00 , C08G63/02 , C08G63/64 , C08G69/44 , C08J5/18 , C08G81/00
CPC分类号： C08G69/44 , C08G18/34 , C08G18/4263 , C08G63/64
摘要： The object of the present invention is the production of thermoplastically workable copolymers capable of being composted, characterized in that they consist of partially crystalline soft segments formed from aliphatic esters and also of amorphous hard segments and that the proportion of soft segments amounts to 70% to 95% by weight.
摘要翻译：本发明的目的是生产能够堆肥的热塑性可加工共聚物，其特征在于它们由部分结晶的由脂肪族酯形成的软链段以及无定形硬链段组成，并且软链段的比例达到70％至 95重量％。

10. 发明授权

US5223548A Method of foaming thermoplastic polycarbonate 失效
标题翻译：热塑性聚碳酸酯的发泡方法
公开(公告)号：US5223548A
公开(公告)日：1993-06-29
申请号：US989391
申请日：1992-12-11
申请人： Ernst Grigat , Wolfgang Ebert , Burkhard Kohler , Wolfgang Beer , Ralf Dujardin , Klaus Horn
发明人： Ernst Grigat , Wolfgang Ebert , Burkhard Kohler , Wolfgang Beer , Ralf Dujardin , Klaus Horn
IPC分类号： C08J9/06 , C08J9/00 , C08L69/00
CPC分类号： C08J9/0028 , C08J9/0061 , C08L69/00 , C08J2369/00 , C08J2405/00
摘要： A method of foaming thermoplastic aromatic polycarbonates is disclosed. Accordingly, a polycarbonate resin is mixed with 0.01 to 10%, the percent being relative to the total weight of polycarbonate resin and polysaccharide, of a particular polysaccharide and the mixture then processed thermoplastically without the application of negative pressure in an extruder, at temperatures of 180.degree. C. to 320.degree. C., or in an injection molding machine, at temperatures of 190.degree. C. to 330.degree. C., to obtain foamed molded articles.
摘要翻译：公开了一种发泡热塑性芳族聚碳酸酯的方法。因此，聚碳酸酯树脂与特定多糖的相对于聚碳酸酯树脂和多糖的总重量的百分比为0.01〜10％，然后将混合物热塑性地加工而不在挤出机中施加负压，温度为 180℃至320℃，或在注塑机中，在190℃至330℃的温度下，得到发泡模塑制品。

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