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1. 发明授权

US4282367A Process for the separation of polyurethane foam hydrolysates into polyol and diamine 失效
标题翻译：将聚氨酯泡沫水解物分离成多元醇和二胺的方法
公开(公告)号：US4282367A
公开(公告)日：1981-08-04
申请号：US105059
申请日：1979-12-19
申请人： Georg Niederdellmann , Norbert Roemer , Ernst Grigat
发明人： Georg Niederdellmann , Norbert Roemer , Ernst Grigat
IPC分类号： C08G18/00 , C08G18/82 , C08J11/16 , C08G18/48 , C08G18/14
CPC分类号： C08J11/16 , C08J2375/04 , Y02W30/705 , Y10S521/914
摘要： The instant invention is directed to a process for the separation of polyurethane hydrolysates into polyamines and polyols which can be used again for the production of polyurethanes, comprising introducing gaseous hydrogen chloride into the hydrolysate mixture which has optionally been diluted with an inert solvent, and removing the precipitated amine salt by filtration, characterized in that(a) gaseous hydrogen chloride is optionally first introduced into the hydrolysate in a quantity of from 0.02 to 0.07 mol per amine equivalent, the reaction mixture is filtered and the filter residue is discarded, then(b) from 0.20 to 0.47 mol of gaseous hydrogen chloride per mol of amine equivalents still present is introduced into the filtrate and the precipitated amine salt is filtered off, then(c) stage (b) is repeated one or more times until the amine group content in the filtrate is below 1% by weight, based on the solvent-free filtrate, and finally(d) precipitation of the amine is completed by the introduction of from 0.5 to 1.0 mol of gaseous hydrogen chloride, based on the amine equivalents remaining in the filtrate.
摘要翻译：本发明涉及将聚氨酯水解物分离成多胺和多元醇的方法，其可以再次用于生产聚氨酯，包括将气态氯化氢引入到任选用惰性溶剂稀释的水解产物混合物中，并除去通过过滤沉淀的胺盐，其特征在于，（a）气态氯化氢任选地首先以每个胺当量为0.02至0.07mol的量引入水解产物中，将反应混合物过滤并弃去过滤残余物，然后（ b）将0.20至0.47摩尔的气态氯化氢/摩尔仍存在的胺当量引入滤液中，滤出沉淀的胺盐，然后（c）重复步骤（b）一次或多次，直至胺基基于无溶剂的滤液，滤液中的含量低于1重量％，最后（d）胺的沉淀完全通过根据残留在滤液中的胺当量，从0.5至1.0mol的气态氯化氢引入。

2. 发明授权

US4399236A Process for separating polyurethane hydrolyzates into polyether and diamine 失效
标题翻译：将聚氨酯水解产物分离成聚醚和二胺的方法
公开(公告)号：US4399236A
公开(公告)日：1983-08-16
申请号：US299418
申请日：1981-09-04
申请人： Georg Niederdellmann , Norbert Roemer , Jurgen Schenk , Hartmut Hetzel , Ernst Grigat
发明人： Georg Niederdellmann , Norbert Roemer , Jurgen Schenk , Hartmut Hetzel , Ernst Grigat
IPC分类号： C08G18/00 , C08G18/82 , C08J11/00 , C08J11/10 , C08J11/04 , C08G18/48
CPC分类号： C08J11/10 , C08J2375/04 , Y02W30/702
摘要： The present invention is directed to a process for separating polyurethane hydrolyzates, preferably polyurethane foam hydrolyzates, into substantially amine-free foamable polyethers and diamines, comprising (a) (i) briefly expanding a hot polyurethane hydrolyzate obtained in a continuous screw extruder to normal pressure or in vacuo and, without using readily volatile components (ii) spraying said hydrolyzate directly into a tubular coil evaporator which is heated to 180.degree.-300.degree. C. and at the end of which a pressure of from 0.1 to 20 mbar is applied and (iii) separating a hydrolyzate containing less than 1% by weight of NH.sub.2 in a following cyclone from most of the diamine evaporated and all the solvent used, the diamine being separated from the solvent used in a following distillation column, optionally without any further heat input; (b) precipitating any diamine still present quantitatively in the form of its hydrochloride by introducing excess hydrogen chloride into the hydrolyzate, optionally diluted with inert solvents; and (c) the regenerated polyether obtained after removal by filtration of the precipitated amine salt being freed under reduced pressure from inert solvent and excess hydrogen chloride.
摘要翻译：本发明涉及将聚氨酯水解物（优选聚氨酯泡沫水解产物）分离成基本上不含胺的可发泡聚醚和二胺的方法，其包括（a）（i）将在连续螺杆挤出机中获得的热聚氨酯水解产物短暂膨胀至常压或在真空中，并且不使用易挥发性组分（ii）将所述水解产物直接喷射到加热至180-300℃的管状线圈蒸发器中，并且其末端施加0.1至20mbar的压力，（iii）在以下旋风分离器中从大部分蒸发的二胺和所有使用的溶剂中分离含有小于1重量％的NH 2的水解产物，二胺与随后的蒸馏塔中使用的溶剂分离，任选没有任何进一步的热输入（b）通过将过量的氯化氢引入水解产物中，任选地用惰性溶剂稀释，沉淀出以其盐酸盐形式定量存在的任何二胺; 和（c）通过过滤除去沉淀的胺盐后得到的再生聚醚，在惰性溶剂和过量的氯化氢中减压除去。

3. 发明授权

US4511680A Process for the continuous high temperature glycolytic cleavage of polyurethane plastics waste in screw machines 失效
标题翻译：在螺杆机械中连续高温糖酵解切割聚氨酯塑料废料的工艺
公开(公告)号：US4511680A
公开(公告)日：1985-04-16
申请号：US525846
申请日：1983-08-24
申请人： Georg Niederdellmann , Ernst Grigat
发明人： Georg Niederdellmann , Ernst Grigat
IPC分类号： C08J11/00 , B29B11/00 , B29B17/00 , C08J11/04 , C08J11/24 , B29C29/00 , B09B3/00 , C08L75/00
CPC分类号： C08J11/24 , B29B17/00 , B29K2075/00 , C08J2375/04 , Y02W30/62 , Y02W30/706
摘要： A process for the continuous glycolytic cleavage of polyurethane plastics waste in multi-shaft screw machines by the addition of optionally preheated diols, at a degradation temperature of 250.degree. C., while maintaining a pressure at least such that the polyurethane-diol mixture is in the liquid phase, by the discharge of the glycolysate mixture after short residence times of from 2 to 30 minutes in the reaction screw, and by rapid cooling of the glycolysate mixture.
摘要翻译：通过在250℃的降解温度下加入任选预热的二醇，在多轴螺杆机器中连续糖酵解切割聚氨酯塑料废料的方法，同时保持至少使得聚氨酯 - 二醇混合物处于通过在反应螺杆中停留2至30分钟的短停留时间之后通过糖酵解混合物的排出，并通过快速冷却糖精混合物来进行液相。

4. 发明授权

US4031067A Polytriazines and a process for their production 失效
标题翻译：聚三嗪类及其生产工艺
公开(公告)号：US4031067A
公开(公告)日：1977-06-21
申请号：US707552
申请日：1976-07-22
申请人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
发明人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
IPC分类号： C08G73/00 , C08G73/06 , C08G75/00 , C08G18/00 , C08G18/71
CPC分类号： C08G73/065
摘要： Mixtures of aliphatic, cycloaliphatic or aromatic polyfunctional N-cyanosulfon amides and aromatic polyfunctional cyanic acid ester are converted at 30.degree. to 150.degree. C into fusible prepolymers or prepolymers soluble in organic solvents (polymeric N-organo-isourea ethers). Said prepolymers are highly stable in storage and react at 150.degree. - 350.degree. C to high molecular weight polymers of of triazine structure which are insoluble in solvents and infusible. The prepolymers may be used for the production of coatings or shaped articles or laminates.
摘要翻译：脂肪族，脂环族或芳香族多官能N-氰基磺酰胺和芳香族多官能氰酸酯的混合物在30℃至150℃下转化成可溶于有机溶剂（聚合N-有机 - 异脲醚）的可熔预聚物或预聚物。所述预聚物在储存中高度稳定，在150-350℃下与不溶于溶剂和不溶性的三嗪结构的高分子量聚合物反应。预聚物可用于生产涂料或成型制品或层压材料。

5. 发明授权

US4028393A Process for the production of polyfunctional cyanic acid esters 失效
标题翻译：制备多官能氰酸酯的方法
公开(公告)号：US4028393A
公开(公告)日：1977-06-07
申请号：US658814
申请日：1976-02-17
申请人： Gunther Rottloff , Rudolf Sundermann , Ernst Grigat , Rolf Putter
发明人： Gunther Rottloff , Rudolf Sundermann , Ernst Grigat , Rolf Putter
IPC分类号： C07C323/20 , C07C20060101 , C07C67/00 , C07C253/00 , C07C261/02 , C07C313/00 , C07C315/04 , C07C317/22 , C08G73/06 , C07C122/00
CPC分类号： C07C261/02 , C07C2103/94
摘要： Highly pure aromatic polyfunctional cyanic acid esters having a high stability in storage and being extraordinarily suitable for use as starting compound for the production of plastics by cyclopoly-tri-merization are obtained by a special process.A di- or polytrialkyl ammonium phenolate of the formula: ##STR1## in which Ar represents an optionally substituted aromatic radical,R.sub.1, r.sub.2 and R.sub.3 are the same or different and each represents a linear or branched alkyl radical, andn is a number from 2 to 6,Is reacted at a temperature in the range of from -40.degree. to +65.degree. C in the presence of a trialkyl amine and an organic solvent with an excess of cyanogen halide.The excess of cyanogen halide is up to 80% by weight, based on the total weight of the phenolate and the trialkyl amine.
摘要翻译：通过特殊的方法可获得高度稳定的储存和非常适合用作通过环状三聚化生产塑料的起始化合物的高纯度芳香族多官能氰酸酯。

6. 发明授权

US4066577A High molecular weight polytriazines of soluble polymeric N-cyano-isourea ethers 失效
标题翻译：高分子量聚苯乙烯可溶性聚合N-氰基异荣醚
公开(公告)号：US4066577A
公开(公告)日：1978-01-03
申请号：US707543
申请日：1976-07-22
申请人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
发明人： Rudolf Sundermann , Gunther Rottloff , Ernst Grigat
IPC分类号： C08G73/00 , C08G73/06 , C08G73/08
CPC分类号： C08G73/0655
摘要： High molecular weight temperature-resistant polymers of polytriazine structure obtained by heating cyanamides of the formula Ir -- (nh-cn).sub.nin which R represents an aliphatic, cycloaliphatic, heterocyclic or aromatic radical, optionally interrupted by oxygen and n is a number from 2 to 5, with polyfunctional, aromatic cyanic acid esters into a fusible or in organic solvents soluble polymeric N-cyano-isourea ether and completing the reaction at elevated temperatures and optionally in the presence of a catalyst to form said polymer of polytriazine structure.

7. 发明授权

US4051212A Process for the continuous degradation of plastics 失效
标题翻译：塑料连续降解过程
公开(公告)号：US4051212A
公开(公告)日：1977-09-27
申请号：US608853
申请日：1975-08-29
申请人： Ernst Grigat , Hartmut Hetzel
发明人： Ernst Grigat , Hartmut Hetzel
IPC分类号： B01J19/20 , B09B3/00 , B29B11/00 , B29B17/00 , C08F6/00 , C08G85/00 , C08J11/00 , C08J11/14 , C07C87/14 , B29H19/00
CPC分类号： B29C47/766 , C08J11/14 , B29C47/0009 , Y02W30/704 , Y10S264/911 , Y10S264/916
摘要： The instant invention relates to a continuous process for the hydrolytic degradation of plastics wherein a hydrolyzable material is introduced with water into a screw machine, and is subjected therein to a temperature of 100 to 300.degree. C, and a pressure of 5 to 100 bars for 2 to 100 minutes. The invention also relates to an apparatus useful in conducting the process.

8. 发明授权

US4049630A Process for preparation of s-triazine prepolymers 失效
标题翻译：制备s-三嗪预聚物的方法
公开(公告)号：US4049630A
公开(公告)日：1977-09-20
申请号：US631560
申请日：1975-11-13
申请人： Rudolf Sundermann , Rolf Putter , Ernst Grigat
发明人： Rudolf Sundermann , Rolf Putter , Ernst Grigat
IPC分类号： C08G73/00 , C07D251/26 , C07D251/34 , C08G18/83 , C08G63/91 , C08G73/06
CPC分类号： C08G73/065 , C07D251/26 , C07D251/34 , C08G18/833 , C08G63/916
摘要： Process for the preparation of s-triazine prepolymers which comprisesA. condensing a hydroxy compound which has 2 or more alcoholic hydroxyl groups;B. condensing the resulting condensation product with an aromatic hydroxy compound; andC. thereafter reacting the free hydroxyl groups of the condensation product obtained from (b) with cyanogen halide and in the presence of a base.
摘要翻译：制备s-三嗪预聚物的方法，其包括A.冷凝具有2个或更多个醇溶性羟基的羟基化合物; B.用芳族羟基化合物浓缩结晶凝结产物; 和C.反应自（B）与氰基卤化物和碱的存在产生的冷凝产物的自由羟基组合。

9. 发明授权

US06307003B1 Compostable adhesive 失效
标题翻译：可堆肥胶
公开(公告)号：US06307003B1
公开(公告)日：2001-10-23
申请号：US09171383
申请日：1999-03-15
申请人： Ernst Grigat , Karsten-Josef Idel , Uwe Westeppe , Wolfgang Schulz-Schlitte , Winfried Pommeranz , Jürgen Lörcks , Harald Schmidt
发明人： Ernst Grigat , Karsten-Josef Idel , Uwe Westeppe , Wolfgang Schulz-Schlitte , Winfried Pommeranz , Jürgen Lörcks , Harald Schmidt
IPC分类号： C08G6400
CPC分类号： C08G18/42 , C08G2230/00 , C09J167/00 , C09J167/02 , C09J167/04 , C09J169/005 , C09J175/06 , C09J177/12
摘要： The present invention relates to a compostable adhesive, to a method of producing the same, and to the use of the adhesive for the adhesive bonding of materials.
摘要翻译：本发明涉及可堆肥粘合剂，其制备方法，以及粘合剂用于粘合材料的用途。

10. 发明授权

US5455311A Thermoplastic block copolyesters capable of being composted for use as packaging materials 失效
标题翻译：能够堆肥的热塑性嵌段共聚酯可用作包装材料
公开(公告)号：US5455311A
公开(公告)日：1995-10-03
申请号：US287073
申请日：1994-08-08
申请人： Ernst Grigat , Ralf Dujardin , Ralf Timmermann , Hans-Georg Rast
发明人： Ernst Grigat , Ralf Dujardin , Ralf Timmermann , Hans-Georg Rast
IPC分类号： C08G18/34 , C08G18/42 , C08G63/00 , C08G63/02 , C08G63/64 , C08G69/44 , C08J5/18 , C08G81/00
CPC分类号： C08G69/44 , C08G18/34 , C08G18/4263 , C08G63/64
摘要： The object of the present invention is the production of thermoplastically workable copolymers capable of being composted, characterized in that they consist of partially crystalline soft segments formed from aliphatic esters and also of amorphous hard segments and that the proportion of soft segments amounts to 70% to 95% by weight.
摘要翻译：本发明的目的是生产能够堆肥的热塑性可加工共聚物，其特征在于它们由部分结晶的由脂肪族酯形成的软链段以及无定形硬链段组成，并且软链段的比例达到70％至 95重量％。

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