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1. 发明授权

US5076904A Electrochemical measuring cell for determining ammonia or hydrazine in a measuring sample 失效
标题翻译：用于测定样品中氨基酸或水合物的电化学测量单元
公开(公告)号：US5076904A
公开(公告)日：1991-12-31
申请号：US507755
申请日：1990-04-12
申请人： Herbert Kiesele , Uwe Kuhn , Stephan Haupt
发明人： Herbert Kiesele , Uwe Kuhn , Stephan Haupt
IPC分类号： G01N27/404 , C25B11/08 , G01N27/416 , G01N27/49
CPC分类号： G01N27/4045
摘要： The invention is directed to an electrochemical measuring cell for determining ammonia or hydrazine in a gaseous or liquid measuring sample. The measuring cell has at least one measuring electrode and at least one counter electrode which are disposed in an electrolyte chamber filled with a soluble electrolyte. The electrolyte chamber is closed off in the direction facing toward the measuring sample by a permeable membrane. The measuring cell provides a selective ammonia measurement having the following advantages: a short response time, a linear response and a low tendency to drift. The electrodes of the measuring cell are so configured that the oxidation of the ammonia as a measurement reaction has no influence on the sensitivity of the measuring cell. For this purpose, at least the measuring electrode is provided with a coating containing cobalt oxide which is in direct contact with the electrolyte.
摘要翻译：本发明涉及用于测定气态或液体测量样品中的氨或肼的电化学测量池。测量单元具有至少一个测量电极和至少一个对电极，它们设置在填充有可溶性电解质的电解质室中。电解质室通过渗透膜在朝向测量样品的方向上封闭。测量池提供选择性氨测量，其具有以下优点：响应时间短，线性响应和低漂移倾向。测量单元的电极被配置为使得作为测量反应的氨的氧化对测量单元的灵敏度没有影响。为此，至少测量电极设置有与电解质直接接触的含有氧化钴的涂层。

2. 发明授权

US4961834A Electrochemical measuring cell for amperometrically determining ammonia and derivatives thereof 失效
标题翻译：用于电化学测定氨及其衍生物的电化学测量电池
公开(公告)号：US4961834A
公开(公告)日：1990-10-09
申请号：US448269
申请日：1989-12-11
申请人： Uwe Kuhn , Christiane Roocks , Herbert Kiesele
发明人： Uwe Kuhn , Christiane Roocks , Herbert Kiesele
IPC分类号： G01N27/404 , G01N27/416 , G01N27/49 , G01N33/00
CPC分类号： G01N27/4045 , G01N33/0054
摘要： The invention is directed to an electrochemical measuring cell for determining ammonia and its derivatives in a gaseous or liquid measuring sample. The measuring cell has at least one anode and at least one cathode which are disposed in an electrolyte chamber filled with a soluble electrolyte. The electrolyte chamber is closed off in the direction facing toward the measuring sample by a permeable membrane. The measuring cell provides a more selective ammonia sensor having the following advantages: a short response time, a linear response and exhibits the lowest possible tendency toward drift. The electrolyte of the measuring cell is so configured that the reaction products of the measuring reaction do not affect subsequent measurements. For this purpose the measuring cell, which operates in an amperometric measuring mode, contains a soluble non-oxidizable reagent in the electrolyte which reacts completely with ammonia to form an oxidizable product which is convertible by its oxidation into non-oxidizable soluble secondary products which are chemically and electrochemically inert.
摘要翻译：本发明涉及一种用于在气体或液体测量样品中测定氨及其衍生物的电化学测量池。测量池具有至少一个阳极和至少一个阴极，它们设置在填充有可溶性电解质的电解质室中。电解质室通过渗透膜在朝向测量样品的方向上封闭。测量池提供了更具选择性的氨传感器，其具有以下优点：响应时间短，线性响应，并且具有尽可能低的漂移倾向。测量池的电解质配置使得测量反应的反应产物不影响随后的测量。为此目的，以电流计测量模式运行的测量池在电解液中含有可与氨反应的可溶性不可氧化试剂，以形成可氧化产物，该产物可通过其氧化转化为不可氧化的可溶性次级产物，化学和电化学惰性。

3. 发明授权

US5344546A Electrical measuring cell for determinging ammonia, amines, hydrazine amines, hydrazine and hydrazine derivatives 失效
标题翻译：用于测定氨，胺，肼和肼衍生物的电化学测量池
公开(公告)号：US5344546A
公开(公告)日：1994-09-06
申请号：US19764
申请日：1993-02-19
申请人： Herbert Kiesele , Stephan Haupt , Uwe Kuhn
发明人： Herbert Kiesele , Stephan Haupt , Uwe Kuhn
IPC分类号： G01N27/49 , G01N33/00 , G01N27/404
CPC分类号： G01N27/4045 , G01N33/0054
摘要： The invention is directed to an electrochemical cell for measuring ammonia, amines, hydrazine and hydrazine derivatives and includes a measuring electrode in an electrolyte. The measuring electrode is provided with a coating made of a transition metal oxide and is improved in that its measuring sensitivity during long-term loading is increased. The cross sensitivity of the measuring cell is reduced especially with respect to NO.sub.2 and SO.sub.2. For this purpose, the oxide constituents of the coating are made of a metal conducting oxide of one element or an oxide mixture of several elements of the platinum metal group. Oxides of ruthenium and iridium have proven especially useful. The invention is also directed to an electrochemical measuring cell for measuring ammonia or hydrazine and includes at least a measuring electrode and a counter electrode in an electrolyte. The measuring cell provides a signal increase having a shorter response time and an improved signal stability. For this purpose, the electrolyte is an aqueous solution of a hygroscopic salt of an alkali metal or alkaline earth metal such as calcium nitrate or lithium nitrate or a mixture of both salts.
摘要翻译：本发明涉及用于测量氨，胺，肼和肼衍生物的电化学电池，并且在电解质中包括测量电极。测量电极设置有由过渡金属氧化物制成的涂层，并且改进了其在长期负载期间的测量灵敏度增加。测量池的交叉灵敏度特别是相对于NO2和SO2而降低。为此，涂层的氧化物组分由一种元素的金属导电氧化物或铂金属基团的若干元素的氧化物混合物制成。钌和铱的氧化物被证明是特别有用的。本发明还涉及一种用于测量氨或肼的电化学测量池，并且在电解质中至少包括测量电极和对电极。测量单元提供具有较短响应时间和改进的信号稳定性的信号增加。为此，电解质是碱金属或碱土金属的吸湿盐如硝酸钙或硝酸锂或这两种盐的混合物的水溶液。

4. 发明授权

US5198092A Electrochemical measuring cell for determining ammonia or hydrazine in a measuring sample 失效
标题翻译：用于测定样品中氨或肼的电化学测量池
公开(公告)号：US5198092A
公开(公告)日：1993-03-30
申请号：US696089
申请日：1991-05-06
申请人： Herbert Kiesele , Uwe Kuhn , Stephan Haupt
发明人： Herbert Kiesele , Uwe Kuhn , Stephan Haupt
IPC分类号： G01N27/49
CPC分类号： G01N27/4045
摘要： The invention is directed to an electrochemical measuring cell for determining ammonia or hydrazine in a gaseous or liquid measuring sample. The measuring cell has at least one measuring electrode and at least one counter electrode which are disposed in an electrolyte chamber filled with a soluble electrolyte containing a cobalt salt dissolved therein. The electrolyte chamber is closed off in the direction facing toward the measuring sample by a permeable membrane. The measuring cell provides a selective ammonia measurement having the following advantages: a short response time, a linear response and a low tendency to drift. The electrodes of the measuring cell are so configured that the oxidation of the ammonia as a measurement reaction has no influence on the sensitivity of the measuring cell. For this purpose, at least the measuring electrode is provided with a coating containing cobalt oxide which is in direct contact with the electrolyte.
摘要翻译：本发明涉及用于测定气态或液体测量样品中的氨或肼的电化学测量池。测量单元具有至少一个测量电极和至少一个对电极，其设置在填充有溶解有钴盐的可溶性电解质的电解质室中。电解质室通过渗透膜在朝向测量样品的方向上封闭。测量池提供选择性氨测量，其具有以下优点：响应时间短，线性响应和低漂移倾向。测量单元的电极被配置为使得作为测量反应的氨的氧化对测量单元的灵敏度没有影响。为此，至少测量电极设置有与电解质直接接触的含有氧化钴的涂层。

5. 发明授权

US5041204A Electrochemical measuring cell for detecting hydrogen cyanide or sulfur dioxide 失效
标题翻译：用于检测氰化氢或二氧化硫的电化学测量池
公开(公告)号：US5041204A
公开(公告)日：1991-08-20
申请号：US543436
申请日：1990-06-26
申请人： Uwe Kuhn , Herbert Kiesele , Stephan Haupt
发明人： Uwe Kuhn , Herbert Kiesele , Stephan Haupt
IPC分类号： G01N27/49
CPC分类号： G01N27/4045
摘要： The invention is directed to an electrochemical measuring cell for detecting hydrogen cyanide or sulfur dioxide by means of at least one measuring electrode and a counter electrode disposed in an electrolyte. The electrolyte is accommodated in a measuring chamber closed off with respect to the ambient by a membrane permeable to the substance to be detected. This measuring cell is improved in that the long-term stability of the measuring signal is increased and a corrosion of the electrodes is prevented. For this purpose, the electrolyte in the electrolyte chamber contains an additive of copper salts for catalyzing the oxidation of the substance to be detected.
摘要翻译：本发明涉及一种用于通过至少一个测量电极和设置在电解质中的对电极来检测氰化氢或二氧化硫的电化学测量池。电解质容纳在相对于环境的封闭的测量室中，所述测量室可被待检测物质透过的膜。该测量单元的改进在于测量信号的长期稳定性增加，并且防止了电极的腐蚀。为此，电解质室中的电解质含有用于催化待检测物质的氧化的铜盐添加剂。

6. 发明授权

US5372696A Electrochemical sensor of modular design 失效
标题翻译：电化学传感器采用模块化设计
公开(公告)号：US5372696A
公开(公告)日：1994-12-13
申请号：US93784
申请日：1993-07-19
申请人： Herbert Kiesele , Uwe Kuhn
发明人： Herbert Kiesele , Uwe Kuhn
IPC分类号： G01D11/24 , G01N27/416 , G01N27/49 , G01N27/26
CPC分类号： G01N27/4045 , G01D11/245 , G01N27/4162
摘要： An electrochemical sensor for fluid media with at least two electrodes, which are in contact with one another via an electrolyte and are accommodated in a housing. Many different sensor variants are attainable with a few, standardized components. The housing (1) includes a plurality of modules (4a, 4b; 4c-4m), which are placed next to one another, are designed as hollow bodies, and are connected to one another, wherein at least two lateral surfaces (9) of each module (4a-4m) are suitable for connection to additional modules (4a-4m), and at least two of the modules (4a, 4b; 4c-4m) accommodate one electrode (2, 3) each, and the hollow space (16) enclosed by the modules (4a, 4b; 4c-4m) is delimited from the environment by the two electrodes (2, 3), on the one hand, and by a partial area (17) each of the inner wall (5) of the modules (4a, 4b; 4c-4m), and is provided for accommodating the electrolyte (18).
摘要翻译：一种用于具有至少两个电极的流体介质的电化学传感器，其经由电解质彼此接触并容纳在壳体中。许多不同的传感器变体可以通过几个标准化的部件来实现。壳体（1）包括彼此相邻放置的多个模块（4a，4b; 4c-4m）被设计为中空体，并且彼此连接，其中至少两个侧表面（9）每个模块（4a-4m）适于连接到附加模块（4a-4m），并且至少两个模块（4a，4b; 4c-4m）分别容纳一个电极（2,3）由模块（4a，4b; 4c-4m）包围的空间（16）通过两个电极（2,3）和一部分区域（17）与环境隔开，每个内壁（4a，4b; 4c-4m）的上表面（5），用于容纳电解质（18）。

7. 发明授权

US5316648A Electrochemical measuring cell for detecting gases and vapors 失效
标题翻译：用于检测气体和蒸汽的电化学测量池
公开(公告)号：US5316648A
公开(公告)日：1994-05-31
申请号：US943678
申请日：1992-09-11
申请人： Uwe Kuhn , Herbert Kiesele , Stephan Haupt
发明人： Uwe Kuhn , Herbert Kiesele , Stephan Haupt
IPC分类号： G01N27/49 , G01N27/26
CPC分类号： G01N27/4045
摘要： An electrochemical measuring cell has a three-electrode system including electrode, counter electrode and reference electrode in an electrolyte. The measuring cell has an additive promoting the electrochemical reaction and is selective and highly sensitive for the detection of hydrogen halides and also provides a stable measuring signal. A measuring cell of this kind has an additive of tetrachloroauric acid in the electrolyte for detecting hydrochloric acid with all electrodes being made of gold. The counter electrode is protected by a cation exchange membrane to provide a further improvement.
摘要翻译：电化学测量单元具有在电解质中包括电极，对电极和参比电极的三电极系统。测量池具有促进电化学反应的添加剂，并且对于检测卤化氢具有选择性和高度敏感性，并且还提供稳定的测量信号。这种测量电池在用于检测所有电极由金制成的盐酸的电解质中具有四氯金酸的添加剂。对电极由阳离子交换膜保护以提供进一步的改进。

8. 发明申请

US20060230813A1 Gas-measuring system with gas sensor and gas generator 有权
标题翻译：带气体传感器和气体发生器的气体测量系统
公开(公告)号：US20060230813A1
公开(公告)日：2006-10-19
申请号：US11348748
申请日：2006-02-07
申请人： Peter Tschuncky , Herbert Kiesele , Uwe Kuhn , Frank Mett , Andreas Hengstenberg , Kerstin Caro
发明人： Peter Tschuncky , Herbert Kiesele , Uwe Kuhn , Frank Mett , Andreas Hengstenberg , Kerstin Caro
IPC分类号： G01N11/00 , G01N33/487 , G01N7/00
CPC分类号： G01N33/0006
摘要： A gas-measuring system contains at least one gas sensor (1) and at least one gas generator (4). The gas sensor (1) has at least one measuring surface (3), at which a target gas concentration can be measured. The gas generator (4) has at least one discharge surface (5), from which a current-proportional quantity of test gas can be discharged. The measuring surface (3) and the discharge surface (5) are designed and the gas sensor (1) and the gas generator (4) can be arranged such that the measuring surface (3) and the discharge surface (5) are in direct contact with the ambient atmosphere and the distance between the two surfaces is shorter than the extension of the smaller of the two surfaces.
摘要翻译：气体测量系统包含至少一个气体传感器（1）和至少一个气体发生器（4）。气体传感器（1）具有至少一个可以测量目标气体浓度的测量表面（3）。气体发生器（4）具有至少一个排放表面（5），可以排出电流比例量的测试气体。测量表面（3）和排出表面（5）被设计，气体传感器（1）和气体发生器（4）可以被布置成使测量表面（3）和排放表面（5）直接与环境气氛接触，两个表面之间的距离比两个表面中较小者的延伸短。

9. 发明授权

US5228974A Electrochemical measuring cell for determining ammonia or hydrazine in a measuring sample 失效
标题翻译：用于测定样品中氨或肼的电化学测量池
公开(公告)号：US5228974A
公开(公告)日：1993-07-20
申请号：US804722
申请日：1991-12-11
申请人： Herbert Kiesele , Uwe Kuhn , Stephan Haupt
发明人： Herbert Kiesele , Uwe Kuhn , Stephan Haupt
IPC分类号： G01N27/49 , G01N33/00
CPC分类号： G01N27/4045 , G01N33/0054
摘要： The invention is directed to an electrochemical measuring cell for measuring ammonia or hydrazine and includes at least a measuring electrode and a counter electrode in an electrolyte. The measuring cell provides a signal increase having a shorter response time and an improved signal stability. For this purpose, the electrolyte is an aqueous solution of a hygroscopic salt of an alkali metal or earth alkali metal such as calcium nitrate or lithium nitrate or a mixture of both salts.
摘要翻译：本发明涉及用于测量氨或肼的电化学测量池，并且在电解质中至少包括测量电极和对电极。测量单元提供具有较短响应时间和改进的信号稳定性的信号增加。为此，电解质是碱金属或碱土金属的吸湿盐如硝酸钙或硝酸锂或这两种盐的混合物的水溶液。

10. 发明授权

US6126407A Pump device for high pressure fuel delivery in fuel injection system of internal combustion engines 失效
标题翻译：用于内燃机燃油喷射系统中高压燃料输送的泵装置
公开(公告)号：US6126407A
公开(公告)日：2000-10-03
申请号：US284773
申请日：1999-05-28
申请人： Josef Guentert , Bernd Streicher , Uwe Kuhn , Juergen Hammer , Thomas Lettner
发明人： Josef Guentert , Bernd Streicher , Uwe Kuhn , Juergen Hammer , Thomas Lettner
IPC分类号： F02M37/06 , F02M39/00 , F02M59/06 , F02M59/44 , F04B23/10 , H05B1/00 , H05B3/02
CPC分类号： F04B23/103 , F02M39/005
摘要： The invention relates to a pump device for high-pressure fuel delivery in fuel injection systems of internal combustion engines, in particular in a common rail injection system, including a radial piston pump (2, 68, 80) with a drive shaft (38, 74, 114) that is supported in a pump housing (14) and is embodied eccentrically or has cam-like projections in the circumference direction, preferably with a number of pistons that are each disposed in a cylinder chamber radially in relation to the drive shaft and can be driven to reciprocate in the cylinder chamber when the drive shaft rotates, and with a check valve on the intake side and the high pressure side, and a low pressure pump (4, 71, 82) connected before the radial piston pump; in order to improve the pump device in such a way that it is more compact and can be produced more cheaply and the danger of the occurrence of leaks is reduced, the low pressure pump (4, 71, 82) is provided on or in the pump housing (14) of the radial piston pump (2, 68, 80), on the end remote from the drive end (10), and can be driven by the drive shaft (38, 74, 114) of the radial piston pump. (FIG. 1b)
摘要翻译： PCT No.PCT / DE98 / 01919 Sec。 371日期1999年5月28日 102（e）日期1999年5月28日PCT提交1998年7月9日PCT公布。公开号WO99 / 09316 日期1999年2月25日本发明涉及一种用于内燃机的燃料喷射系统中的高压燃料输送的泵装置，特别是在共轨喷射系统中，包括径向活塞泵（2,88,80），其具有驱动轴（38,74,114），其被支撑在泵壳体（14）中，并且在圆周方向上偏心地设置或具有凸轮状突起，优选地，多个活塞各自以径向位于气缸室中与驱动轴相关联，并且可以在驱动轴旋转时被驱动以在气缸室中往复运动，并且在进气侧和高压侧具有止回阀，并且在低压泵（4,71,82）之前连接的低压泵径向活塞泵; 为了改善泵装置，使得其更紧凑并且可以更便宜地生产并且泄漏发生的危险降低，低压泵（4,71,82）设置在或径向柱塞泵（2,68,80）的泵壳体（14）在远离驱动端（10）的一端上，并且可以由径向柱塞泵（38,64）的驱动轴（38,74,114）驱动。（图1b）

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