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1. 发明授权

US07645367B2 Gas-measuring system with gas sensor and gas generator 有权
标题翻译：带气体传感器和气体发生器的气体测量系统
公开(公告)号：US07645367B2
公开(公告)日：2010-01-12
申请号：US11348748
申请日：2006-02-07
申请人： Peter Tschuncky , Herbert Kiesele , Uwe Kühn , Frank Mett , Andreas Hengstenberg , Kerstin Caro
发明人： Peter Tschuncky , Herbert Kiesele , Uwe Kühn , Frank Mett , Andreas Hengstenberg , Kerstin Caro
IPC分类号： G01N27/26 , G01N27/404
CPC分类号： G01N33/0006
摘要： A gas-measuring system contains at least one gas sensor (1) and at least one gas generator (4). The gas sensor (1) has at least one measuring surface (3), at which a target gas concentration can be measured. The gas generator (4) has at least one discharge surface (5), from which a current-proportional quantity of test gas can be discharged. The measuring surface (3) and the discharge surface (5) are designed and the gas sensor (1) and the gas generator (4) can be arranged such that the measuring surface (3) and the discharge surface (5) are in direct contact with the ambient atmosphere and the distance between the two surfaces is shorter than the extension of the smaller of the two surfaces.
摘要翻译：气体测量系统包含至少一个气体传感器（1）和至少一个气体发生器（4）。气体传感器（1）具有至少一个可以测量目标气体浓度的测量表面（3）。气体发生器（4）具有至少一个排放表面（5），可以排出电流比例量的测试气体。测量表面（3）和排出表面（5）被设计，气体传感器（1）和气体发生器（4）可以被布置成使测量表面（3）和排放表面（5）直接与环境气氛接触，两个表面之间的距离比两个表面中较小者的延伸短。

2. 发明申请

US20080041730A1 ELECTROCHEMICAL GAS GENERATOR FOR CARBON MONOXIDE 有权
标题翻译：一氧化碳电化学气体发生器
公开(公告)号：US20080041730A1
公开(公告)日：2008-02-21
申请号：US11835603
申请日：2007-08-08
申请人： Kerstin CARO , Peter Tschuncky , Herbert Kiesele
发明人： Kerstin CARO , Peter Tschuncky , Herbert Kiesele
IPC分类号： C25B9/00 , C25B1/00
CPC分类号： G01N33/0006 , C25B1/00
摘要： An electrochemical gas generator is provided including an electrolysis cell (1) with a gas-impermeable housing, which is closed by a gas-permeable membrane (2) for the discharge of the test gas or calibrating gas CO. A chemically inert cathode (5) formed of a noble metal, a mixture of noble metals or a material containing carbon, is in direct contact with an electrolyte (7). An anode (4) formed of a noble metal, a mixture of noble metals or a material containing carbon, is in direct contact with a mesoxalic acid salt, the mesoxalic acid salt being in direct contact with the electrolyte (7). A control unit (6) is provided that also acts as a power source and is connected to the electrodes (4, 5).
摘要翻译：提供一种电化学气体发生器，其包括具有气体不可渗透壳体的电解池（1），其由用于排出测试气体或校准气体CO的透气膜（2）封闭。化学惰性阴极（5 ）由贵金属，贵金属或含碳材料的混合物形成，与电解质（7）直接接触。由贵金属形成的阳极（4），贵金属或含碳材料的混合物与中草酸盐直接接触，所述中草酸盐与电解质（7）直接接触。还提供控制单元（6），其也用作电源并且连接到电极（4,5）。

3. 发明授权

US5855750A Electrochemical measuring cell for detecting oxidizing gases 失效
标题翻译：用于检测氧化性气体的电化学测量池
公开(公告)号：US5855750A
公开(公告)日：1999-01-05
申请号：US796514
申请日：1997-02-06
申请人： Herbert Kiesele
发明人： Herbert Kiesele
IPC分类号： G01N27/49 , G01N27/26
CPC分类号： G01N27/4045
摘要： An electrochemical measuring cell for detecting oxidizing gases, containing an electrode with a redox mediator, which is oxidized by the gas to be detected. A measuring electrode is employed made of an inert material, and a counterelectrode is provided. The dynamics and reproducibility of the measured signal are improved by providing the counterelectrode formed of an anodically oxidizable material and is arranged behind the measuring electrode in the direction of diffusion in a sandwich-like arrangement.
摘要翻译：一种用于检测氧化气体的电化学测量池，其含有由待检测气体氧化的氧化还原介体的电极。使用由惰性材料制成的测量电极，并提供反电极。通过提供由阳极可氧化材料形成的反电极来改善测量信号的动态和再现性，并且以夹层状布置在扩散方向上布置在测量电极后面。

4. 发明授权

US5372696A Electrochemical sensor of modular design 失效
标题翻译：电化学传感器采用模块化设计
公开(公告)号：US5372696A
公开(公告)日：1994-12-13
申请号：US93784
申请日：1993-07-19
申请人： Herbert Kiesele , Uwe Kuhn
发明人： Herbert Kiesele , Uwe Kuhn
IPC分类号： G01D11/24 , G01N27/416 , G01N27/49 , G01N27/26
CPC分类号： G01N27/4045 , G01D11/245 , G01N27/4162
摘要： An electrochemical sensor for fluid media with at least two electrodes, which are in contact with one another via an electrolyte and are accommodated in a housing. Many different sensor variants are attainable with a few, standardized components. The housing (1) includes a plurality of modules (4a, 4b; 4c-4m), which are placed next to one another, are designed as hollow bodies, and are connected to one another, wherein at least two lateral surfaces (9) of each module (4a-4m) are suitable for connection to additional modules (4a-4m), and at least two of the modules (4a, 4b; 4c-4m) accommodate one electrode (2, 3) each, and the hollow space (16) enclosed by the modules (4a, 4b; 4c-4m) is delimited from the environment by the two electrodes (2, 3), on the one hand, and by a partial area (17) each of the inner wall (5) of the modules (4a, 4b; 4c-4m), and is provided for accommodating the electrolyte (18).
摘要翻译：一种用于具有至少两个电极的流体介质的电化学传感器，其经由电解质彼此接触并容纳在壳体中。许多不同的传感器变体可以通过几个标准化的部件来实现。壳体（1）包括彼此相邻放置的多个模块（4a，4b; 4c-4m）被设计为中空体，并且彼此连接，其中至少两个侧表面（9）每个模块（4a-4m）适于连接到附加模块（4a-4m），并且至少两个模块（4a，4b; 4c-4m）分别容纳一个电极（2,3）由模块（4a，4b; 4c-4m）包围的空间（16）通过两个电极（2,3）和一部分区域（17）与环境隔开，每个内壁（4a，4b; 4c-4m）的上表面（5），用于容纳电解质（18）。

5. 发明授权

US5316648A Electrochemical measuring cell for detecting gases and vapors 失效
标题翻译：用于检测气体和蒸汽的电化学测量池
公开(公告)号：US5316648A
公开(公告)日：1994-05-31
申请号：US943678
申请日：1992-09-11
申请人： Uwe Kuhn , Herbert Kiesele , Stephan Haupt
发明人： Uwe Kuhn , Herbert Kiesele , Stephan Haupt
IPC分类号： G01N27/49 , G01N27/26
CPC分类号： G01N27/4045
摘要： An electrochemical measuring cell has a three-electrode system including electrode, counter electrode and reference electrode in an electrolyte. The measuring cell has an additive promoting the electrochemical reaction and is selective and highly sensitive for the detection of hydrogen halides and also provides a stable measuring signal. A measuring cell of this kind has an additive of tetrachloroauric acid in the electrolyte for detecting hydrochloric acid with all electrodes being made of gold. The counter electrode is protected by a cation exchange membrane to provide a further improvement.
摘要翻译：电化学测量单元具有在电解质中包括电极，对电极和参比电极的三电极系统。测量池具有促进电化学反应的添加剂，并且对于检测卤化氢具有选择性和高度敏感性，并且还提供稳定的测量信号。这种测量电池在用于检测所有电极由金制成的盐酸的电解质中具有四氯金酸的添加剂。对电极由阳离子交换膜保护以提供进一步的改进。

6. 发明授权

US5281324A Measuring sensor for detecting gaseous components 失效
标题翻译：用于检测气体组分的测量传感器
公开(公告)号：US5281324A
公开(公告)日：1994-01-25
申请号：US42664
申请日：1993-04-05
申请人： Herbert Kiesele , Jurgen Sohege
发明人： Herbert Kiesele , Jurgen Sohege
IPC分类号： G01N27/49 , G01N27/26
CPC分类号： G01N27/404 , G01N27/4045
摘要： The invention is directed to a measuring sensor for detecting gaseous components which operates in the diffusion limit current region. The measuring sensor includes a support body and has an electrolyte chamber partitioned by a diffusion membrane from the ambient containing the gaseous components. The measuring electrode of the measuring sensor is improved so that a simpler manipulation for covering the electrolyte chamber with a membrane is possible without endangering the mechanical stability of the membrane. During operation, the detection operation is intended to take place completely at that electrode surface which is in direct electrochemical exchange communication with the electrolyte supply. For this purpose, the coating is configured as an adherent layer to the support body so that it forms an impermeable adherence region in the lateral direction between coating and support body. A process for producing the measuring electrode is characterized in that the coating is adheringly applied to a front face of the support body which forms a closed surface. Thereafter, a membrane layer is applied to the coating and a break through for communicating with the electrolyte chamber is formed in the support body by removing a portion of the support body starting from a rear face thereof lying opposite the front face. The break through is formed by removing the portion of the support body through to the coating. In the completed measuring sensor, this permits the electrolyte from the electrolyte chamber to penetrate through the break through to the coating.
摘要翻译：本发明涉及一种用于检测在扩散极限电流区域中工作的气体组分的测量传感器。测量传感器包括支撑体，并且具有由包含气体组分的环境的扩散膜分隔开的电解质室。改进了测量传感器的测量电极，使得用膜覆盖电解质室的更简单的操作是可能的，而不会危及膜的机械稳定性。在操作期间，检测操作旨在完全发生在与电解质供应的直接电化学交换连通的电极表面处。为此，涂层被构造成与支撑体的粘合层，使得其在涂层和支撑体之间的横向上形成不可渗透的粘附区域。用于制造测量电极的方法的特征在于，该涂层被附着地施加到形成封闭表面的支撑体的前表面。此后，将膜层施加到涂层，并且通过从与前表面相对的后表面开始移除支撑体的一部分，在支撑体中形成用于与电解质室连通的突破。通过将支撑体的部分移除到涂层而形成断裂。在完成的测量传感器中，这允许来自电解质室的电解质渗透穿过涂层。

7. 发明授权

US5128018A Electrochemical measuring cell for detecting gas components in a fluid medium 失效
标题翻译：用于检测流体介质中气体组分的电化学测量单元
公开(公告)号：US5128018A
公开(公告)日：1992-07-07
申请号：US628206
申请日：1990-12-14
申请人： Herbert Kiesele
发明人： Herbert Kiesele
IPC分类号： G01N27/49
CPC分类号： G01N27/4045
摘要： The invention relates to an electrochemical measuring cell for detecting selected gaseous components such as hydride gases, sulfur dioxide and nitrogen dioxide by means of at least one measuring electrode and a counter electrode disposed in an electrolyte. The electrodes and the electrolyte are accommodated in a measuring chamber which is closed off to the ambient by a membrane permeable to the substance to be detected. This measuring cell is improved in that the long-term stability of the measuring signal is increased and the measuring sensitivity as well as the selectivity are increased. For this purpose, the electrolyte includes an additive catalyzing the oxidation of the substance to be detected. The additive contained in the electrolyte can be inorganic heteropoly acids or iron salts.
摘要翻译：本发明涉及一种用于通过至少一个测量电极和设置在电解质中的对电极来检测选定气体组分如氢化物气体，二氧化硫和二氧化氮的电化学测量池。电极和电解质容纳在测量室中，该测量室通过可被待检测物质渗透的膜封闭到环境中。改进了该测量单元，因为测量信号的长期稳定性增加，并且测量灵敏度以及选择性增加。为此，电解质包括催化待检测物质氧化的添加剂。包含在电解质中的添加剂可以是无机杂多酸或铁盐。

8. 发明授权

US07704374B2 Electrochemical gas sensor 有权
标题翻译：电化学气体传感器
公开(公告)号：US07704374B2
公开(公告)日：2010-04-27
申请号：US11612726
申请日：2006-12-19
申请人： Sabrina Sommer , Herbert Kiesele , Frank Mett
发明人： Sabrina Sommer , Herbert Kiesele , Frank Mett
IPC分类号： G01N27/26
CPC分类号： G01N27/127
摘要： An electrochemical gas sensor is provided with a carbon-based measuring electrode (3) that it can be used for a large number of electrochemical detection reactions and can be manufactured at a low cost. The measuring electrode (3) contains carbon nanotubes.
摘要翻译：电化学气体传感器设置有碳基测量电极（3），其可用于大量的电化学检测反应并且可以以低成本制造。测量电极（3）含有碳纳米管。

9. 发明申请

US20060237313A1 Electrochemical sensor 有权
标题翻译：电化学传感器
公开(公告)号：US20060237313A1
公开(公告)日：2006-10-26
申请号：US11269184
申请日：2005-11-08
申请人： Herbert Kiesele , Frank Mett , Sabrina Sommer
发明人： Herbert Kiesele , Frank Mett , Sabrina Sommer
IPC分类号： G01N27/26
CPC分类号： G01N27/404
摘要： An electrochemical sensor with at least one measuring electrode (3), at least one auxiliary electrode (7) and at least one reference electrode (5), wherein a protective electrode (6), which ensures at the reference electrode (5) the at least partial shielding of the reference electrode (5) against substances that would lead to a change in the reference potential when reaching the reference electrode (5), is arranged in the vicinity of the reference electrode (5). A highly stable reference potential can be obtained with the present invention.
摘要翻译：一种具有至少一个测量电极（3），至少一个辅助电极（7）和至少一个参考电极（5）的电化学传感器，其中保护电极（6）确保参考电极（5）处于对于参考电极（5）的附近，参考电极（5）的最小部分屏蔽被抵抗在到达参考电极（5）时会导致参考电位变化的物质。本发明可以获得高度稳定的参考电位。

10. 发明授权

US06793786B2 Flow gap gas distribution adapter for an electrochemical gas sensor 有权
标题翻译：用于电化学气体传感器的流隙气体分配适配器
公开(公告)号：US06793786B2
公开(公告)日：2004-09-21
申请号：US10109477
申请日：2002-03-28
申请人： Herbert Kiesele , Uwe Kühn , Rainer Kunz , Frank Mett
发明人： Herbert Kiesele , Uwe Kühn , Rainer Kunz , Frank Mett
IPC分类号： G01N27404
CPC分类号： G01N27/404 , G01N33/0009
摘要： An adapter (1) and electrochemical gas sensor (2) is provided with an electrochemical gas sensor housing (14) accommodating an electrolyte (13), with at least one measuring electrode (12) arranged therein and with a membrane (11), which screens the measuring electrode (12) from a measured gas and is permeable to the measured gas. The measuring sensitivity of an electrochemical gas sensor is increased by the adapter (1) having a gas-impermeable surface (15) extending in parallel to and at a spaced location from the membrane (11). The adapter (1) and the membrane (11) form a flow gap (10) for the measured gas delivered by a pump. The adapter (1) may be plugged onto the electrochemical sensor (2) at its outer edge (1a). The measured gas enters through a central opening (17), expands in the flow gap (10) radially to the outside and leaves same via the ring-shaped gap (16).
摘要翻译：适配器（1）和电化学气体传感器（2）设置有容纳电解质（13）的电化学气体传感器壳体（14），其中布置有至少一个测量电极（12）和膜（11），其中从测量的气体中筛选测量电极（12）并且对测得的气体是可渗透的。电化学气体传感器的测量灵敏度由具有气体不可渗透表面（15）的适配器（1）增加，所述气体不可渗透表面（15）平行延伸并在与膜（11）的间隔开的位置。适配器（1）和膜（11）形成用于由泵输送的测量气体的流动间隙（10）。适配器（1）可以在其外边缘（1a）处被插入到电化学传感器（2）上。测量的气体通过中心开口（17）进入，在流动间隙（10）中径向扩张到外部并经由环形间隙（16）离开。

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