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    • 4. 发明授权
    • Polyoxymethylene moulding compositions with improved heat stability and stability against discoloration
    • 具有改善的热稳定性和抗变色稳定性的聚甲醛模塑组合物
    • US06191222B1
    • 2001-02-20
    • US09130470
    • 1998-08-07
    • Bruno KellerStephanie SchauhoffKlaus DornHartmut AltDietrich Michelchen
    • Bruno KellerStephanie SchauhoffKlaus DornHartmut AltDietrich Michelchen
    • C08L5900
    • C08L59/00C08L2666/04
    • Polyoxymethylene moulding compositions of the invention comprise (i) at least one polyoxymethylene homo- and/or copolymer, (ii) at least one conventional additive and (iii) at least one polymeric plastics material as an additive for improving the heat stability, and are distinguished in that (iii) is a copolymer which is obtainable by polymerization in bulk of a mixture of A) 60-90 parts of one or more (meth)acrylates, B) 10-40 parts of one or more (meth)acrylamides, C) per 100 parts of A)+B), >0.2 to 5 parts of molecular weight regulator and D) per 100 parts of A)+B), up to 2 parts of lipophilic free radical polymerization initiators, and in that the moulding composition comprises (iii) in an amount of 0.01 to 2 parts, based on the sum of (i)+(ii) where all the amounts relate to parts by weight (wt/wt) and A) and B) together must give 100 parts. By the use of relatively highly regulated bulk co- or terpolymerization for stabilizing POM moulding compositions, advantages over the use of emulsion or suspension bead polymerization result in the heat stability, in the stability against discoloration and/or in the residual monomer contents of POM moulding compositions and shaped articles and shaped films produced therefrom.
    • 本发明的聚氧亚甲基成型组合物包含(i)至少一种聚甲醛均聚物和/或共聚物,(ii)至少一种常规添加剂和(iii)至少一种聚合塑料材料,作为改善热稳定性的添加剂,并且 不同之处在于(iii)是通过本体混合的A)60-90份一种或多种(甲基)丙烯酸酯,B)10-40份一种或多种(甲基)丙烯酰胺,C )每100份A)+ B),> 0.2至5份分子量调节剂和D)/ 100份A)+ B),至多2份亲脂性自由基聚合引发剂,并且模塑组合物包含( iii)按照所有量与重量份(wt / wt)相关的(i)+(ii)和A)和B)之和的总和为0.01至2份,B)一起必须给出100份。 使用相对高度调节的体积共聚或三元共聚来稳定POM模塑组合物,优于使用乳液或 悬浮珠聚合导致热稳定性,POM成型组合物和成形制品的残留单体含量的稳定性和/或由其制备的成型制品的稳定性。
    • 9. 发明授权
    • Foamable polyvinyl halogenated resin mass, use of polymerizates thereof
as processing aids and objects formed therefrom
    • 可发泡聚乙烯基卤化树脂物质,其聚合物用作加工助剂和由其形成的物体
    • US6043293A
    • 2000-03-28
    • US174874
    • 1998-10-19
    • Pavel BelikGeorg SchneiderKlaus DornStefan ForsterBernd Frischkemuth
    • Pavel BelikGeorg SchneiderKlaus DornStefan ForsterBernd Frischkemuth
    • C08J9/04C08F2/22C08J9/00C08L27/00C08L27/06C08L33/12
    • C08J9/0061C08L27/06C08J2327/02C08J2433/00C08L33/12
    • There are provided foamable, foamable polyvinyl halide resin masses containing: A) 1 to 25 parts relative to 100 parts of polyvinyl halide, of a polymerizate obtainable through the emulsion polymerization of i) up to 20 to not more than 75 parts of methylmethacrylate, ii) 25 to 80 parts of one or more C.sub.2 -C.sub.18 alkylmethacrylates, iii) 0 to 5 parts of one or more vinyl unsaturated monomers copolymerizable with (i) and/or (ii, wherein the components (i)-(iii) together yield 100 parts and are polymerized with up to a further 100 parts of usual additives for emulsion polymerization, wherein the emulsion polymerizate is single stepped and has a viscosity number of >700 cm.sup.3 /g and wherein copolymers are excluded which contain iv) MMA per se, or less than 20 or more than 75 parts of MMA together with either v) one or more acrylic acid esters, and/or vi) ethyl methacrylate, n-butyl-methacrylate, or ethylhexyl methacrylate. The resin mass further includes: B) 0.1-10 parts based on 100 parts of the polyvinyl halide of one or more foaming materials, C) 0-100 parts based on 100 parts polyvinyl halide of the usual additives. This polyvinyl halide resin mass, after foaming, yields a resin mass which, as well as of good surface properties, has a foam density of
    • 提供了可发泡的,可发泡的聚卤乙烯树脂块,其包含:A)相对于100份聚卤乙烯为1至25份,通过i)至多20至不超过75份甲基丙烯酸甲酯可获得的聚合物,ii )25至80份一种或多种C 2 -C 18烷基甲基丙烯酸酯,iii)0至5份可与(i)和/或(ii)共聚的一种或多种乙烯基不饱和单体,其中组分(i) - (iii)共同产生 100份,再与100份常用的乳液聚合添加剂进行聚合,其中乳液聚合物为单步级,粘度为> 700cm3 / g,其中排除含有iv)MMA本身的共聚物, 或小于20或大于75份的MMA以及v)一种或多种丙烯酸酯,和/或vi)甲基丙烯酸乙酯,正丁基 - 甲基丙烯酸酯或甲基丙烯酸乙基己基酯。 树脂质量还包括:B)基于100份一种或多种发泡材料的聚卤乙烯的0.1-10份,C)基于100份常规添加剂的聚卤乙烯的0-100份。 该聚卤乙烯树脂组合物在发泡后产生具有良好表面性质的泡沫密度<0.7g / cm 3的树脂组合物。