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1. 发明授权

US09630387B2 Process for continuous inline production of coated polymeric substrates or laminates 有权
公开(公告)号：US09630387B2
公开(公告)日：2017-04-25
申请号：US14126693
申请日：2012-06-15
申请人： Waldemar Kanzler , Thomas Hasskerl , Ghirmay Seyoum , Patrick Kliem , Werner Krebs , Dieter Foerster , Manfred Dannehl
发明人： Waldemar Kanzler , Thomas Hasskerl , Ghirmay Seyoum , Patrick Kliem , Werner Krebs , Dieter Foerster , Manfred Dannehl
IPC分类号： B32B7/12 , B32B37/12 , C08F2/48 , C08J7/04
CPC分类号： B32B37/1284 , B32B7/12 , C08F2/48 , C08J7/047 , Y10T428/2495 , Y10T428/31507 , Y10T428/31935
摘要： The present invention relates to a method for the continuous inline production of coated polymeric substrates or laminates and also to an apparatus for implementing this method.

2. 发明授权

US08993093B2 Coated sheet-like plastic material with reduced tendency to colonization by algae, process for the in-line production thereof and use 有权
标题翻译：具有减少藻类定居倾向的涂层片状塑料材料，其在线生产和使用的方法
公开(公告)号：US08993093B2
公开(公告)日：2015-03-31
申请号：US13635452
申请日：2011-03-02
申请人： Thomas Hasskerl , Wolfgang Scharnke , Martin Berkenkopf , Jann Schmidt , Xin Lu , Uwe Schneider
发明人： Thomas Hasskerl , Wolfgang Scharnke , Martin Berkenkopf , Jann Schmidt , Xin Lu , Uwe Schneider
IPC分类号： B32B5/16 , C09D1/00 , B01J21/06 , B01J35/00 , B01J37/02 , C08J7/04 , B01J21/08 , B01J35/02 , B05D7/04
CPC分类号： C09D1/00 , B01J21/063 , B01J21/08 , B01J35/004 , B01J35/023 , B01J37/0215 , B05D7/04 , B05D2451/00 , C02F2303/20 , C08J7/045 , Y10T428/24364 , Y10T428/24372 , Y10T428/24413 , Y10T428/256 , B05D2401/10 , B05D2401/32
摘要： A coated sheet-like plastics material comprising a) as base, a thermoplastic substrate; and b) on the base, a photocatalytically active coating comprising a water-spreading layer which involves either a sol-adhesion-promoter layer, layer b1+2), comprising an adhesion promoter and a colloid sol, or a colloid-sol layer b2) arranged on an adhesion-promoter layer b1) applied on the substrate a), and a photocatalytically active layer b3) arranged on the water-spreading layer b1+2) or b2), where b3) is obtainable through application and drying of a mixture comprising, based on the solids content of the mixture in percent by weight b31) from 1 to 25% of titanium dioxide and b32) from 75 to 99% of silicon dioxide and/or of a metal oxide which is not soluble in water or of an anionically modified silicon dioxide or metal oxide; where the titanium dioxide is particulate with an average primary-particle size smaller than 10 nm. In-line process for producing said material, and also use as roofing material or as glazing material, preferably in areas with moist conditions. The coated sheet-like plastics material of the invention combines water-spreading properties with photocatalytic activity, without any damage to the thermoplastic substrates. The coated sheet-like plastics substrate of the invention is produced in a relatively uncomplicated, inexpensive and fast in-line process and, in use, provides impressive substrate stability and impressive effectiveness of the coating in resisting initial algal growth.
摘要翻译：一种涂覆的片状塑料材料，其包含：a）作为基底，热塑性基材; 和b）在基材上，包含包含粘合促进剂和胶体溶胶的胶体粘附促进剂层b1 + 2的水分散层或胶体 - 溶胶层b2的光催化活性涂层）和布置在水扩散层b1 + 2）上的光催化活性层b3）或b2），其中b3）可通过施加和干燥a 混合物，其包含基于混合物的固体含量，以重量比b31），1至25％的二氧化钛和b32）75至99％的二氧化硅和/或不溶于水的金属氧化物的阴离子改性二氧化硅或金属氧化物; 其中二氧化钛是平均一次粒径小于10nm的颗粒。用于生产所述材料的在线方法，并且还用作屋顶材料或玻璃材料，优选地在具有潮湿条件的区域中。本发明的涂覆片状塑料材料将水分散性与光催化活性相结合，对热塑性基材没有任何损害。本发明的涂覆的片状塑料基材以相对简单，廉价和快速的在线方法生产，并且在使用中提供令人印象深刻的基材稳定性和涂层在抵抗初始藻类生长中令人印象深刻的有效性。

3. 发明申请

US20140106148A1 PROCESS FOR CONTINUOUS INLINE PRODUCTION OF COATED POLYMERIC SUBSTRATES OR LAMINATES 有权
标题翻译：连续生产涂层聚合物基板或层压板的工艺
公开(公告)号：US20140106148A1
公开(公告)日：2014-04-17
申请号：US14126693
申请日：2012-06-15
申请人： Waldemar Kanzler , Thomas Hasskerl , Ghirmay Seyoum , Patrick Kliem , Werner Krebs , Dieter Foerster , Manfred Dannehl
发明人： Waldemar Kanzler , Thomas Hasskerl , Ghirmay Seyoum , Patrick Kliem , Werner Krebs , Dieter Foerster , Manfred Dannehl
IPC分类号： B32B37/12 , B32B7/12
CPC分类号： B32B37/1284 , B32B7/12 , C08F2/48 , C08J7/047 , Y10T428/2495 , Y10T428/31507 , Y10T428/31935
摘要： The present invention relates to a method for the continuous inline production of coated polymeric substrates or laminates and also to an apparatus for implementing this method.
摘要翻译：本发明涉及一种用于连续在线生产涂覆的聚合物基材或层压材料的方法，也涉及用于实施该方法的设备。

4. 发明申请

US20070172673A1 Coating agents and plastic body with an antigraffiti effect and method for the production thereof 审中-公开
标题翻译：涂布剂和具有防刮擦效果的塑料体及其制造方法
公开(公告)号：US20070172673A1
公开(公告)日：2007-07-26
申请号：US10555772
申请日：2004-03-25
申请人： Patrick Becker , Thomas Hasskerl , Rolf Neeb , Ghirmay Seyoum , Reiner Lingelbach
发明人： Patrick Becker , Thomas Hasskerl , Rolf Neeb , Ghirmay Seyoum , Reiner Lingelbach
IPC分类号： B32B9/04 , C09D5/00
CPC分类号： C08G77/24 , C08J7/047 , C08J2483/00 , Y10T428/31663
摘要： The invention relates to coating agents having an antigraffiti effect. Said coating agents can be obtained according to a method consisting in condensing the organic silicon compounds of general formula (I): R1nSIX4-n, wherein R1 represents a group comprising 1-20 carbon atoms, X represents an alkoxy radical having 1-20 carbon atoms or halogen and n represents an even number between 0-3. The different radicals X or R1 can be identical or different and/or the precondensates can be obtained from said components. At least 50 wt. % of the silicon compounds, in relation to the total weight of the used silicon compounds, is represented by the formula R1SiX3, wherein R1 and X have the above-cited meaning, in order to form polysiloxanes until the ratio of signals R1SiO(OH) and signals R1SiO1,5 measured by NMR-spectroscopy ranges from 0.6-4, and by adding compounds of formula (II) (R″)uSi(R′)t(OR)(4-t-u) to said polysiloxane mixture, wherein R represents a group comprising 1-20 carbon atoms having at least 3 fluoro atoms. U is 1 or 2 and t is 0 or 1, R and R′ are identical or different and represent a group comprising 1-20 carbon atoms. The also relates to plastic bodies which have coating which can be obtained by means of the coating agents.
摘要翻译：本发明涉及具有防刮涂作用的包衣剂。所述包衣剂可以根据通式（I）的有机硅化合物缩合的方法获得：R 1，N 2，S 4，N 4，其中R 1表示包含1-20个碳原子的基团，X表示具有1-20个碳原子的烷氧基或卤素，n表示0-3之间的偶数。不同的基团X或R 1可以相同或不同，和/或可以从所述组分获得预缩合物。至少50wt。相对于所使用的硅化合物的总重量，硅化合物的百分比由式R 1 SiX 3 N表示，其中R 1， SUP>和X具有上述含义，为了形成聚硅氧烷，直到信号R 1 SiO（OH）和信号R 1 SiO 2的比例，通过NMR光谱测量的5 范围为0.6-4，并且通过加入式（II）（R“）的化合物（R”）Si（R'）（OR）（4-tu））与所述聚硅氧烷混合物，其中R表示含有至少3个氟原子的1-20个碳原子的基团。 U为1或2，t为0或1，R和R'相同或不同，表示1-20个碳原子的基团。也涉及具有可以通过涂布剂获得的涂层的塑料体。

5. 发明授权

US07704586B2 Plastic molded bodies having two-dimensional and three-dimensional image structures produced through laser subsurface engraving 失效
标题翻译：通过激光地下雕刻制造的具有二维和三维图像结构的塑料成型体
公开(公告)号：US07704586B2
公开(公告)日：2010-04-27
申请号：US11368602
申请日：2006-03-07
申请人： Klaus-Dieter Schübel , Jürgen Kreutz , Wilhelm Wolff , Günther Ittmann , Thomas Hasskerl , Harald Häger , Ralf Richter , Wolfgang Stuber
发明人： Klaus-Dieter Schübel , Jürgen Kreutz , Wilhelm Wolff , Günther Ittmann , Thomas Hasskerl , Harald Häger , Ralf Richter , Wolfgang Stuber
IPC分类号： B32B5/00 , B32B7/00 , B42D15/00
CPC分类号： B44C5/00 , B23K2103/42 , B23K2103/50 , B41M5/24 , B41M5/267 , B44C1/228 , B44F1/06 , Y10T428/24
摘要： The present invention relates to plastic molded bodies having two-dimensional or three-dimensional image structures produced in the interior through laser subsurface engraving. The plastic molded bodies are made of plastic materials which have a content of nanoscale metal oxides having particle sizes from 1 to 500 nm, both the plastic material and also the included metal oxide being transparent to the laser light used for producing the image structures. The plastic materials from which the molded bodies are manufactured particularly contain metal oxides having particle sizes from 5 to 100 nm at a content of 0.0001 to 0.1 weight-percent. Typical metal oxides are nanoscale indium-tin oxide or antimony-tin oxide.
摘要翻译：本发明涉及具有通过激光地下雕刻在内部制造的二维或三维图像结构的塑料模塑体。塑料成型体由塑料材料制成，其具有粒径为1至500nm的纳米级金属氧化物的含量，塑料材料和所包含的金属氧化物对于用于制造图像结构的激光是透明的。制造成型体的塑料材料特别含有0.0001-0.1重量％的粒度为5〜100nm的金属氧化物。典型的金属氧化物是纳米级氧化铟锡或氧化锑锡。

6. 发明授权

US07456239B2 Articles made of PMMA molding compound 有权
标题翻译：由PMMA成型制成的制品
公开(公告)号：US07456239B2
公开(公告)日：2008-11-25
申请号：US10523971
申请日：2003-07-25
申请人： Alexander Theil , Michael Zietek , Heinrich Gaul , Hans-Juergen Kress , Thomas Hasskerl , Rudolf Blass , Werner Hoess
发明人： Alexander Theil , Michael Zietek , Heinrich Gaul , Hans-Juergen Kress , Thomas Hasskerl , Rudolf Blass , Werner Hoess
IPC分类号： C08L33/00
CPC分类号： E04C2/20 , C08K3/22 , C08K5/0008
摘要： The invention relates to a moulding composition and to the mouldings which can be produced therefrom. Due to their good resistance in the hot water cycle test and in the hot-water/isopropanol test, the plastics mouldings have particularly good suitability for the production of sanitary components.
摘要翻译：本发明涉及一种可由其制备的模塑组合物和模制品。由于在热水循环试验和热水/异丙醇试验中具有良好的抵抗性，所以塑料模制品对生产卫生部件具有特别好的适用性。

7. 发明授权

US07235305B2 Self-cleaning synthetic body and method for producing the same 失效
标题翻译：自清洁合成体及其制造方法
公开(公告)号：US07235305B2
公开(公告)日：2007-06-26
申请号：US10508844
申请日：2003-05-20
申请人： Thomas Hasskerl , Rolf Neeb , Ghirmay Seyoum
发明人： Thomas Hasskerl , Rolf Neeb , Ghirmay Seyoum
IPC分类号： B32B25/20
CPC分类号： C08J7/047 , C08J7/04 , C08J2483/00 , Y10T428/256 , Y10T428/265 , Y10T428/31663 , Y10T428/31667
摘要： The invention relates to self-cleaning synthetic bodies, obtained as follows: a) a siloxane coating (a) is applied to a synthetic substrate and cured, b) the polar fraction of the surface energy of the cured siloxane coating on the substrate is increased to a value of at least 10 mN/m and c) a coating (b) containing photocatalytically active TiO2 particles is applied to the synthetic substrate and cured.
摘要翻译：本发明涉及如下获得的自清洁合成物：a）将硅氧烷涂层（a）施加到合成基底上并固化，b）基底上固化的硅氧烷涂层的表面能的极性分数增加达到至少10mN / m的值，并且c）将含有光催化活性的TiO 2颗粒的涂层（b）施加到合成基材上并固化。

8. 发明申请

US20070003756A1 Plastic body with an inorganic coating method for production and use thereof 审中-公开
标题翻译：具有生产和使用无机涂层方法的塑料体
公开(公告)号：US20070003756A1
公开(公告)日：2007-01-04
申请号：US10573075
申请日：2004-07-02
申请人： Patrick Becker , Norbert Brand , Thomas Hasskerl , Rolf Neeb , Ghirmay Seyoum
发明人： Patrick Becker , Norbert Brand , Thomas Hasskerl , Rolf Neeb , Ghirmay Seyoum
IPC分类号： B32B27/06 , B05D3/12 , B05D1/18 , B05D3/02
CPC分类号： B29D11/00865 , B29C37/0032 , B29C39/025 , B29C41/08 , B29K2105/0002 , B29K2995/0005 , B29K2995/0026 , B29K2995/0087 , B29L2007/002 , B29L2009/00 , B29L2011/00 , B29L2011/0016 , B29L2031/3061 , Y10T428/265
摘要： The invention relates to a method for production of a plastic body, made from a plastic obtained by means of a radical polymerisation with single- or multi-sided, inorganic coating containing silicon. The coating of a substrate is firstly achieved with a paint composition, containing inorganic particles in a solvent which can optionally contain additional flow improvers. One or more of such coated substrates can be used for the construction of a polymerisation chamber, in which the coated sides lie within the chamber. After radical polymerisation of a monomer mixture in the presence of a polymerisation initiator, the internal inorganic coating of the substrate transfers into or onto the surfaces of the radically polymerised plastic or of the plastic body. The invention further relates to the corresponding plastic body and the uses thereof.
摘要翻译：本发明涉及一种用于生产塑料体的方法，该塑料体由通过具有含硅单体或多面无机涂层的自由基聚合获得的塑料制成。首先通过涂料组合物实现基材的涂层，所述涂料组合物在溶剂中含有无机颗粒，其可以任选地含有另外的流动改进剂。一个或多个这样的涂覆的基底可用于构建聚合室，其中涂覆的侧面位于室内。在聚合引发剂存在下，单体混合物自由基聚合之后，基材的内部无机涂层转移到自由基聚合的塑料或塑料体的表面中或表面上。本发明还涉及相应的塑料体及其用途。

9. 发明授权

US5880235A Copolymers useful for producing cast glass and thermally dimensionally stable molding materials 失效
标题翻译：可用于生产铸造玻璃和热尺寸稳定的成型材料的共聚物
公开(公告)号：US5880235A
公开(公告)日：1999-03-09
申请号：US586177
申请日：1996-01-17
申请人： Helmut Schwind , Dirk Hauch , Thomas Hasskerl , Klaus Dorn , Mathias Hopp
发明人： Helmut Schwind , Dirk Hauch , Thomas Hasskerl , Klaus Dorn , Mathias Hopp
IPC分类号： C08F2/02 , C08F24/00 , C08F218/00 , C08F224/00
CPC分类号： C08F224/00
摘要： The invention relates to copolymers for producing cast glass or thermally dimensionally stable formed materials.
摘要翻译：本发明涉及用于生产铸造玻璃或热尺寸稳定的成形材料的共聚物。

10. 发明授权

US09399335B2 Adhesive for producing composite bodies, a plastic glass composite or composite glass for architecture and construction 有权
标题翻译：用于生产复合体的粘合剂，用于建筑和结构的塑料玻璃复合材料或复合玻璃
公开(公告)号：US09399335B2
公开(公告)日：2016-07-26
申请号：US14377061
申请日：2013-02-14
申请人： Thomas Hasskerl , Klaus Koralewski , Sabine Schwarz-Barac , Roger Recktenwald , Werner Hoess , Florian Band
发明人： Thomas Hasskerl , Klaus Koralewski , Sabine Schwarz-Barac , Roger Recktenwald , Werner Hoess , Florian Band
IPC分类号： B32B7/12 , C09J4/06 , C09J133/08 , C09J133/10 , B32B17/10 , B32B37/00 , C08F220/18 , C08F220/32
CPC分类号： B32B7/12 , B32B17/10018 , B32B17/10036 , B32B17/10743 , B32B17/10899 , B32B37/00 , B32B2250/05 , B32B2250/40 , B32B2315/08 , C08F2220/1825 , C08F2220/325 , C09J4/06 , C09J133/08 , C09J133/10 , Y02E10/52 , Y10T428/2495 , Y10T428/266 , Y10T428/31645
摘要： Provided is an adhesive composition suitable for producing a laminate. The composition contains specified amounts of (a) polyisobutyl methacrylate, isobutyl methacrylate or a mixture thereof, (b) butyl acrylate, (c) polybutyl acrylate, (d) a (meth)acrylate compound and (e) a silicon compound. These components may be in polymerizable form, in polymerized form or in a combination of polymerizable form and polymerized form. The amounts of components (a) to (e) total 100 wt. % and the amount of (b) and (c) represents 30 to 90 wt. %, based on the sum total of components (a) to (e). The composition may optionally further contain from 0.1 to 6 wt. %, based on the total weight of the adhesive composition, of additives different from components (a) to (e) described above.
摘要翻译：提供了适用于生产层压体的粘合剂组合物。该组合物含有规定量的（a）甲基丙烯酸异丁酯，甲基丙烯酸异丁酯或其混合物，（b）丙烯酸丁酯，（c）丙烯酸丁酯，（d）（甲基）丙烯酸酯化合物和（e）硅化合物。这些组分可以是可聚合形式，聚合形式或可聚合形式和聚合形式的组合。组分（a）至（e）的总量为100重量％％，（b）和（c）的量为30〜90重量％。％，基于组分（a）至（e）的总和。组合物可任选地进一步含有0.1至6重量％％，基于粘合剂组合物的总重量，不同于上述组分（a）至（e）的添加剂。

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