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1. 发明授权

US07256317B2 Process for the preparation of surfactant alcohols and surfactant alcohol ethers, the prepared products and their use 有权
标题翻译：制备表面活性剂醇和表面活性剂醇醚的方法，制备的产品及其用途
公开(公告)号：US07256317B2
公开(公告)日：2007-08-14
申请号：US10765996
申请日：2004-01-29
申请人： Heiko Maas , Michael Roeper , Marc Walter , Ralf Schulz , Juergen Tropsch , Hans-Ulrich Jaeger , Peter Schwab , Michael Schulz
发明人： Heiko Maas , Michael Roeper , Marc Walter , Ralf Schulz , Juergen Tropsch , Hans-Ulrich Jaeger , Peter Schwab , Michael Schulz
IPC分类号： C07C27/12
CPC分类号： C07F9/11 , C07C11/02 , C07C29/16 , C07F9/091 , C07C31/125
摘要： The invention describes a process for the preparation of novel surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having from about 10 to 20 carbon atoms or of mixtures of such olefins to give alkanols, and optional subsequent alkoxylation, which comprisessubjecting a C4-olefin mixture to metathesis, dimerizing the resulting olefins, and then derivatizing them to give surfactant alcohols, and optionally alkoxylating said alcohols.The olefin mixture obtained in the dimerization has a high proportion of branched components and less than 10% by weight of compounds which contain a vinylidene group.invention further describes the use of the surfactant alcohols and surfactant alcohol ethers to give surfactants by glycosylation or polyglycosylation, sulfation or phosphation.
摘要翻译：本发明描述了通过衍生具有约10至20个碳原子的烯烃或这种烯烃的混合物来制备新型表面活性剂醇和表面活性剂醇醚以产生链烷醇的方法，以及任选的随后的烷氧基化，其包括使C

2. 发明授权

US07807615B2 Production of (co)surfactants by reacting polyols with olefins 有权
标题翻译：通过使多元醇与烯烃反应制备（共）表面活性剂
公开(公告)号：US07807615B2
公开(公告)日：2010-10-05
申请号：US11911028
申请日：2006-04-05
申请人： Juergen Stephan , Michael Roeper , Thomas Heidemann , Michael Triller , Juergen Tropsch
发明人： Juergen Stephan , Michael Roeper , Thomas Heidemann , Michael Triller , Juergen Tropsch
IPC分类号： C11D1/66
CPC分类号： C07C41/06 , C07C43/135 , C08G65/329 , C11D1/72 , C11D1/721 , C11D3/3707 , Y02P20/582
摘要： The present invention relates to a process for preparing polyol alkyl ethers by reacting compounds comprising at least three hydroxyl functionalities with olefins in the presence of acidic catalysts at temperatures of from 20 to 250° C. and pressures of from 0.5 to 10 bar, wherein the olefins correspond to the general formula (I) in which R1 is hydrogen and R2 is a linear or branched carbon radical having from 7 to 28 carbon atoms, or R1 and R2 are each linear or branched carbon radicals having from 1 to 27 carbon atoms, the sum of the carbon number of R1 and R2 being at most 28, to polyol alkyl ethers derived from compounds having at least three hydroxyl functionalities, not more than all but one hydroxyl functionality being replaced by a moiety of the general formula (VIII) to the use of these polyol alkyl ethers as surfactants and to laundry detergents and cleaning compositions comprising these polyol alkyl ethers.
摘要翻译：本发明涉及一种制备多元醇烷基醚的方法，该方法是在20至250℃的温度和0.5至10巴的压力下，在酸性催化剂存在下，使包含至少三个羟基官能团的化合物与烯烃反应，烯烃对应于其中R 1为氢且R 2为具有7至28个碳原子的直链或支链碳原子的通式（I），或R 1和R 2为具有1至27个碳原子的直链或支链碳原子， R 1和R 2的碳数最多为28的多元醇烷基醚衍生自具有至少三个羟基官能团的化合物的多元醇烷基醚，不超过一个羟基官能团，除了一个羟基官能团被通式（Ⅷ）的部分替代为使用这些多元醇烷基醚作为表面活性剂和洗衣洗涤剂以及包含这些多元醇烷基醚的清洁组合物。

3. 发明授权

US07060852B2 Method for producing alkyl aryl sulphonates 失效
标题翻译：烷基芳基磺酸盐的制备方法
公开(公告)号：US07060852B2
公开(公告)日：2006-06-13
申请号：US10343835
申请日：2001-08-10
申请人： Heiko Maas , Thomas Narbeshuber , Michael Roeper
发明人： Heiko Maas , Thomas Narbeshuber , Michael Roeper
IPC分类号： C07C309/31
CPC分类号： C07C303/32 , C07C2/08 , C07C2/66 , C07C6/04 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C11/107 , C07C15/107
摘要： The invention relates to a process for the preparation of alkylarylsulfonates by a) reaction of a C4-olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C10-12-olefins, and optional removal of the C10-12-olefins, c) reaction of the C10-12-olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.
摘要翻译：本发明涉及一种通过以下方法制备烷基芳基磺酸盐的方法：a）C 4 - 4α-烯烃混合物在复分解催化剂上的反应，用于制备包含2-戊烯和/或3-己烯的烯烃混合物并且任选地除去2-戊烯和/或3-己烯，b）在二级催化剂中在阶段a）中获得的2-戊烯和/或3-己烯的二聚化，得到含有C 10-12 并且任选地除去C 10-12 - 烯烃，c）在步骤b）中获得的C 10-12α-烯烃混合物的反应，在烷基化催化剂存在下用芳族烃形成烷基芳族化合物，其中在反应之前可以加入另外的直链烯烃，d）在步骤c）中获得的烷基芳族化合物的磺化，并中和得到烷基芳基磺酸盐，其中在磺化之前，可以另外加入直链烷基苯，e）任选地将在sta中获得的烷基芳基磺酸盐 ge d）与直链烷基芳基磺酸盐。

4. 发明授权

US5026920A Obtaining alkanals having a 2-alkyl branch from alkanal mixtures 失效
标题翻译：从链烷醇混合物中获得具有2-烷基支链的链烷烃
公开(公告)号：US5026920A
公开(公告)日：1991-06-25
申请号：US433661
申请日：1989-11-08
申请人： Michael Roeper , Franz Merger , Joerg Liebe , Armin V. Grenacher , Edgar Hahl
发明人： Michael Roeper , Franz Merger , Joerg Liebe , Armin V. Grenacher , Edgar Hahl
IPC分类号： C07C47/02 , C07C45/50 , C07C45/75 , C07C45/82 , C07C45/85
CPC分类号： C07C45/82 , C07C45/50 , C07C45/75 , C07C45/85
摘要： Alkanals having a 2-alkyl branch are obtained from mixtures which contain the alkanals having a 2-alkyl branch in addition to n-alkanals, 3-alkylalkanals and/or further isomers by a process in whicha) the alkanal mixture is reacted with an aqueous formaldehyde solution in the presence of a secondary amine and of a carboxylic acid as a catalyst,b) the aqueous phase containing the catalyst and any unconverted excess formaldehyde is separated off andc) the alkanals having a 2-alkyl branch are isolated by distillation from the condensates of the other alkanals with formaldehyde.
摘要翻译：具有2-烷基支链的烷烃由含有具有2-烷基支链的亚烷基的链烷烃，3-烷基链烷醇和/或其它异构体的混合物通过以下方法获得：其中a）使所述链烷醛混合物与在仲胺和羧酸作为催化剂存在下的甲醛水溶液，b）分离含有催化剂和任何未转化的过量甲醛的水相，并且c）通过蒸馏分离具有2-烷基支链的链烷烃从其他链烷烃与甲醛的缩合物。

5. 发明授权

US5387719A Preparation of aldehydes 失效
标题翻译：醛的制备
公开(公告)号：US5387719A
公开(公告)日：1995-02-07
申请号：US120427
申请日：1993-09-14
申请人： Heinz-Josef Kneuper , Michael Roeper , Rocco Paciello
发明人： Heinz-Josef Kneuper , Michael Roeper , Rocco Paciello
IPC分类号： C07B61/00 , C07C45/50 , C07C47/02 , C07C45/00 , C07C45/78
CPC分类号： B01J31/20 , B01J31/181 , B01J31/4046 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J2540/32 , B01J31/2234 , Y02P20/584
摘要： A process for the preparation of aldehydes by hydroformylation of olefins having more than 7 carbon atoms, comprising hydroformylation by means of a rhodium catalyst dissolved homogeneously in the reaction medium, removal of the rhodium catalyst from the hydroformylation reaction product, and recycling of the rhodium separated off from the hydroformylation product into the hydroformylation step, in which the rhodium catalyst is extracted from the hydroformylation product into the aqueous phase by means of an aqueous solution of a nitrogen-containing complexing agent from the group comprising of sulfonated pyridines, sulfonated quinolines, substituted or unsubstituted, sulfonated or sulfonated substituent-carrying 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2"-terpyridines and porphines, and/or from the group comprising of carboxylated pyridines, carboxylated quinolines, substituted or unsubstituted, carboxylated or carboxylated substituent-carrying 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2"-terpyridines and porphines, and the aqueous, rhodium-containing extract is recycled into the hydroformylation step.
摘要翻译：一种通过使具有多于7个碳原子的烯烃的加氢甲酰化制备醛的方法，包括通过均匀地溶解在反应介质中的铑催化剂进行加氢甲酰化，从加氢甲酰化反应产物中除去铑催化剂，以及回收分离的铑从加氢甲酰化产物进入加氢甲酰化步骤，其中通过含有磺化吡啶，磺化喹啉，取代的含氮络合剂的水溶液将铑催化剂从加氢甲酰化产物中提取到水相中或未取代的磺化或磺化取代基的2,2'-联吡啶，1,10-菲咯啉，2,2'-二喹啉，2,2'，6'，2“ - 三联吡啶和卟吩，和/或羧基化吡啶类，羧基化喹啉，取代或未取代的羧基化或羧基取代基的2,2'-二吡啶基 nes，1,10-菲咯啉，2,2'-二喹啉，2,2'，6'，2“ - 三联吡啶和卟吩，并将含水铑的提取物再循环到加氢甲酰化步骤中。

6. 发明授权

US5349097A Catalytic isomerization of .alpha.-alkenols 失效
标题翻译： α-烯醇的催化异构化
公开(公告)号：US5349097A
公开(公告)日：1994-09-20
申请号：US99236
申请日：1993-07-29
申请人： Alfred Thome , Michael Roeper , Heinz-Josef Kneuper
发明人： Alfred Thome , Michael Roeper , Heinz-Josef Kneuper
IPC分类号： C07C29/56 , C07C33/02 , C07C35/17
CPC分类号： C07C29/56
摘要： A process for the catalytic isomerization of secondary .alpha.-alkenols of formula I ##STR1## in which R.sup.1 is a C.sub.1 -C.sub.20 alkyl group or a C.sub.2 -C.sub.2 alkenyl group and in which R.sup.2 stands for hydrogen, a halogen atom, a C.sub.1 -C.sub.10 alkoxy group, a carbonyl group, or a C.sub.1 -C.sub.20 alkyl group and in which R.sup.1 and R.sup.2 can be joined together to complete a five-membered or six-membered carbocyclic ring, to primary .alpha.-alkenols of formula II ##STR2## or for the isomerization of primary .alpha.-alkenols of formula II to secondary .alpha.-alkenols of formula I, wherein the isomerization is carried out in the presence of organotrioxorhenium(VII) compounds of formula III ##STR3## in which R.sup.3 is a C.sub.1 -C.sub.10 alkyl group, a cyclopentadienyl group substituted by from one to five C.sub.1 -C.sub.4 alkyl groups, an unsubstituted cyclopentadienyl group, a C.sub.6 -C.sub.10 aryl group, or a C.sub.7 -C.sub.11 aralkyl group, or wherein the isomerization is carried out in the presence of organotrioxorhenium(VII) compounds of formula III attached to a polymeric support.
摘要翻译：一种式Ⅰ的仲α-烯醇的催化异构化方法，其中R1是C1-C20烷基或C2-C2链烯基，其中R2代表氢，卤素原子， C 1 -C 10烷氧基，羰基或C 1 -C 20烷基，并且其中R 1和R 2可以连接在一起以完成五元或六元碳环，与式II的α-α-烯醇（II）化合物或式II的仲α-烯醇的异构化转化为式I的仲α-烯醇，其中异构化在式III的有机三氧化铼（VII）化合物（III）的存在下进行，其中其中R 3为C 1 -C 10烷基，被1至5个C 1 -C 4烷基取代的环戊二烯基，未取代的环戊二烯基，C 6 -C 10芳基或C 7 -C 11芳烷基，或其中异构化为在连接到a的式III的有机三氧化钌（VII）化合物的存在下进行聚合物支持。

7. 发明授权

US5264616A Preparation of .omega.-formylalkanecarboxylic esters 失效
标题翻译： ω-甲酰基烷基羧酸酯的制备
公开(公告)号：US5264616A
公开(公告)日：1993-11-23
申请号：US18495
申请日：1993-02-17
申请人： Michael Roeper , Peter M. Lorz , Dieter Koeffer
发明人： Michael Roeper , Peter M. Lorz , Dieter Koeffer
IPC分类号： C07C67/313 , C07C67/347 , C07C69/66 , C07F9/6574 , C07C45/50 , C07C67/38
CPC分类号： C07C67/347
摘要： .omega.-Formyl-C.sub.4 -C.sub.20 -alkanecarboxylic esters are prepared by reacting C.sub.4 -C.sub.20 -alkenecarboxylic esters with carbon monoxide and hydrogen at from 30.degree. to 150.degree. C. and under from 0.01 to 30 bar in the presence of rhodium carbonyl complexes which are modified with polyphosphites.
摘要翻译： ω-甲酰基-C 4 -C 20烷烃羧酸酯是通过使C4-C20-烯烃羧酸酯与一氧化碳和氢气在30-150℃和0.01至30巴下在羰基铑络合物用多亚磷酸酯改性。

8. 发明授权

US5202297A Rhodium hydroformylation catalysts containing bisphosphite ligands 失效
标题翻译：含有二硫键配位体的氢氧化钠催化剂
公开(公告)号：US5202297A
公开(公告)日：1993-04-13
申请号：US747596
申请日：1991-08-20
申请人： Peter M. Lorz , Werner Bertleff , Michael Roeper , Dieter Koeffer
发明人： Peter M. Lorz , Werner Bertleff , Michael Roeper , Dieter Koeffer
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/6574 , C07F15/00
CPC分类号： C07F15/008 , B01J31/185 , C07C45/50 , C07F9/65746 , B01J2231/321 , B01J2531/0266 , B01J2531/822
摘要： Rhodium hydroformylation catalysts containing bisphosphite ligands of the formula I ##STR1## where --X-- is a divalent bisarylene radical or R.sup.1,W is a divalent arylene, bisarylene or alkylene radical, andR.sup.1 and R.sup.2 are identical or different and are substituted or unsubstituted alkylene or ortho-arylene.
摘要翻译：含有式I的二亚磷酸酯配体的铑加氢甲酰化催化剂其中-X-为二价双亚芳基或R 1，W为二价亚芳基，双亚芳基或亚烷基，R 1和R 2相同或不同，为取代或未取代的亚烷基或邻亚芳基。

9. 发明授权

US4950797A Preparation of carbonyl compounds by isomerization of allyl alcohols 失效
标题翻译：通过烯丙醇异构化制备羰基化合物
公开(公告)号：US4950797A
公开(公告)日：1990-08-21
申请号：US201064
申请日：1988-06-01
申请人： Rudolf Kummer , Werner Bertleff , Michael Roeper
发明人： Rudolf Kummer , Werner Bertleff , Michael Roeper
IPC分类号： C07C45/51 , C07C45/78 , C07C45/81 , C07C47/19
CPC分类号： C07C45/783 , C07C45/512 , C07C45/81 , C07C47/19
摘要： A process for the preparation of carbonyl compounds by catalyzed isomerization of allyl alcohols in a tertiary phosphine or phosphite ester in the presence of a rhodium compound at a temperature of from 80.degree. C. to 180.degree. C., a carrier gas being passed through the reaction mixture and the carbonyl compound being separated from the emergent gas mixture by cooling.
摘要翻译：在铑化合物存在下，在80℃〜180℃的温度下，通过在叔膦或亚磷酸酯中催化异构化烯丙醇来制备羰基化合物的方法，载气通过反应混合物和羰基化合物通过冷却与出气混合物分离。

10. 发明授权

US4910328A Preparation of omega-formylalkanecarboxylic esters 失效
标题翻译： ω-甲酰基烷羧酸酯的制备
公开(公告)号：US4910328A
公开(公告)日：1990-03-20
申请号：US206752
申请日：1988-06-15
申请人： Werner Bertleff , Robert Maerkl , Michael Roeper
发明人： Werner Bertleff , Robert Maerkl , Michael Roeper
IPC分类号： C07B61/00 , B01J31/20 , C07C67/313 , C07C69/67
CPC分类号： C07C67/347
摘要： .omega.-Formylalkanecarboxylic esters are prepared by hydroformylation of an alkenecarboxylic ester with carbon monoxide and hydrogen at elevated tempertures and under superatmospheric pressure in the presence of a cobalt carbonyl complex by a process in which an .alpha.,.beta.-unsaturated alkenecarboxylic ester is hydroformylated in the presence of from 0.01 to 1 mol %, calculated as cobalt, of a cobalt carbonyl complex, while maintaining a conversion of from 10 to 70% of .alpha.,.beta.-unsaturated alkenecarboxylic esters.
摘要翻译：通过在钴羰基络合物存在下，在升高的温度和超大气压下，用一氧化碳和氢气将烯羧酸酯加氢甲酰化制备ω-甲酰基烷羧酸酯，其中α，β-不饱和烯烃羧酸酯在存在下加氢甲酰化 0.01至1摩尔％，钴计算为钴羰基络合物，同时保持10至70％的α，β-不饱和烯烃羧酸酯的转化率。

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