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1. 发明授权

US4910328A Preparation of omega-formylalkanecarboxylic esters 失效
标题翻译： ω-甲酰基烷羧酸酯的制备
公开(公告)号：US4910328A
公开(公告)日：1990-03-20
申请号：US206752
申请日：1988-06-15
申请人： Werner Bertleff , Robert Maerkl , Michael Roeper
发明人： Werner Bertleff , Robert Maerkl , Michael Roeper
IPC分类号： C07B61/00 , B01J31/20 , C07C67/313 , C07C69/67
CPC分类号： C07C67/347
摘要： .omega.-Formylalkanecarboxylic esters are prepared by hydroformylation of an alkenecarboxylic ester with carbon monoxide and hydrogen at elevated tempertures and under superatmospheric pressure in the presence of a cobalt carbonyl complex by a process in which an .alpha.,.beta.-unsaturated alkenecarboxylic ester is hydroformylated in the presence of from 0.01 to 1 mol %, calculated as cobalt, of a cobalt carbonyl complex, while maintaining a conversion of from 10 to 70% of .alpha.,.beta.-unsaturated alkenecarboxylic esters.
摘要翻译：通过在钴羰基络合物存在下，在升高的温度和超大气压下，用一氧化碳和氢气将烯羧酸酯加氢甲酰化制备ω-甲酰基烷羧酸酯，其中α，β-不饱和烯烃羧酸酯在存在下加氢甲酰化 0.01至1摩尔％，钴计算为钴羰基络合物，同时保持10至70％的α，β-不饱和烯烃羧酸酯的转化率。

2. 发明授权

US4925972A Preparation of alkyl pentenoates 失效
标题翻译：戊烯酸烷基酯的制备
公开(公告)号：US4925972A
公开(公告)日：1990-05-15
申请号：US378794
申请日：1989-07-12
申请人： Robert Maerkl , Wolfgang Harder
发明人： Robert Maerkl , Wolfgang Harder
IPC分类号： B01J31/20 , B01J31/40 , C07B61/00 , C07C67/38 , C07C69/533
CPC分类号： C07C69/533
摘要： Alkyl pentenoates are prepared by(a) reacting butadiene or a butadiene-containing hydrocarbon mixture with carbon monoxide and an alkanol in the presence of a tertiary aromatic heterocyclic nitrogen base and a cobalt carbonyl catalyst at from 80.degree. to 160.degree. C. under from 100 to 1,000 bar to obtain a reaction mixture which contains alkyl pentenoate, C.sub.6 -diester, tertiary nitrogen base, alkanol, butadiene, hydrocarbon and by-product,(b) substantially removing from the reaction mixture obtained any excess hydrocarbon, nitrogen base, alkanol and alkyl pentenoate by distillation to obtain a residue which contains cobalt carbonyl catalyst,(c) bringing the residue which contains cobalt carbonyl catalyst into contact with a mixture of carbon monoxide and hydrogen at elevated temperature and elevated pressure, and(d) recycling the residue which contains cobalt carbonyl catalyst into alkyl pentenoate synthesis stage (a).
摘要翻译：戊烯酸烷基酯通过以下步骤制备：（a）在叔芳族杂环氮碱和羰基钴催化剂存在下，在80〜160℃下，将丁二烯或含丁二烯的烃混合物与一氧化碳和链烷醇反应，至1,000巴以获得含有戊烯酸烷基酯，C6-二酯，叔氮碱，链烷醇，丁二烯，烃和副产物的反应混合物，（b）从反应混合物中大量除去得到的任何过量的烃，氮碱，链烷醇和通过蒸馏得到含有羰基钴催化剂的残余物，（c）在升高的温度和升高的压力下使包含羰基钴催化剂的残余物与一氧化碳和氢气的混合物接触，和（d）将残余物含有羰基羰基催化剂成为戊烯酸烷基酯合成阶段（a）。

3. 发明授权

US4755625A Preparation of 1,1,2-trialkoxyethanes 失效
标题翻译： 1,1,2-三烷氧基乙醚的制备
公开(公告)号：US4755625A
公开(公告)日：1988-07-05
申请号：US73999
申请日：1987-07-16
申请人： Robert Maerkl , Werner Bertleff , Rudolf Kummer
发明人： Robert Maerkl , Werner Bertleff , Rudolf Kummer
IPC分类号： C07B61/00 , B01J31/00 , B01J31/20 , B01J31/24 , C07C41/00 , C07C41/48 , C07C43/315 , C07C67/00 , C07D317/22 , C07D319/06 , C07D321/06
CPC分类号： C07C41/48
摘要： 1,1,2-trialkoxyethanes I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.8 -alkyl and R.sup.1 and R.sup.2 may furthermore be bonded to one another to form a 5-membered to 7-membered ring, are prepared by reacting a formaldehyde dialkyl acetal II with carbon monoxide and hydrogen, from 0.5 to 1.5 moles of hydrogen being used per mole of carbon monoxide, and with not less than 1 mole of alcohol R.sup.3 OH per mole of formaldehyde dialkyl acetal under superatmospheric pressure and at elevated temperatures in the presence of a catalyst which is formed from a cobalt carbonyl compound and a trivalent organic compound of the formula III ##STR2## where A is phosphorus, arsenic, antimony or bismuth and R.sup.4, R.sup.5 and R.sup.6 are each an organic radical.
摘要翻译：其中R 1，R 2和R 3各自是C 1 -C 8 - 烷基，R 1和R 2可以彼此键合形成5元至7元环，通过使甲醛二烷基缩醛II与一氧化碳和氢反应，每摩尔一氧化碳使用0.5至1.5摩尔氢，并且在超大气压下每摩尔甲醛二烷基缩醛不少于1摩尔醇R3OH，在由羰基钴化合物和式III的三价有机化合物形成的催化剂存在下，在升高的温度下，其中A是磷，砷，锑或铋，并且R 4，R 5和R 6各自是有机的激进。

4. 发明授权

US4861895A Treatment of aqueous solutions obtained in the carbalkoxylation of olefinically unsaturated compounds 失效
标题翻译：处理在烯属不饱和化合物的碳烷基化反应中获得的水溶液
公开(公告)号：US4861895A
公开(公告)日：1989-08-29
申请号：US77630
申请日：1987-07-24
申请人： Werner Bertleff , Robert Maerkl , Peter Magnussen , Gebhard Kuehn , Peter Stops
发明人： Werner Bertleff , Robert Maerkl , Peter Magnussen , Gebhard Kuehn , Peter Stops
IPC分类号： C07C67/38 , C07C67/00 , C07C67/48 , C07C67/54 , C07C67/60 , C07C69/02 , C07C69/34 , C07C69/44 , C07C69/533 , C07D211/70 , C07D213/06
CPC分类号： C07C67/38 , C07C67/60
摘要： Aqueous solutions which are obtained in the carbalkoxylation of olefinically unsaturated compounds and contain heterocyclic aromatic nitrogen bases, their transformation products and lower fatty acids and/or their salts are treated by a process in which (a) the aqueous solution is heated to 150.degree.-300.degree. C. under from 10 to 300 bar and (b) heterocyclic aromatic nitrogen bases which are formed again from the transformation products are then separated off.
摘要翻译：通过以下方法处理在烯属不饱和化合物的碳烷基氧化中含有杂环芳族氮碱，它们的转化产物和低级脂肪酸和/或其盐的水溶液，其中（a）将水溶液加热至150℃， 300℃，10-300巴，（b）从转化产物再次形成的杂环芳基氮碱分离出来。

5. 发明授权

US4894474A Preparation of alkyl pentenoates 失效
标题翻译：戊烯酸烷基酯的制备
公开(公告)号：US4894474A
公开(公告)日：1990-01-16
申请号：US225823
申请日：1988-07-29
申请人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
发明人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
IPC分类号： C07C67/38 , B01J31/20 , C07B61/00 , C07C69/533
CPC分类号： C07C69/533
摘要： Alkyl pentenoates are prepared by reacting butadiene with carbon monoxide and an alkanol in the presence of a cobalt carbonyl complex and a tertiary, aromatic heterocyclic nitrogen base at from 80.degree. to 160.degree. C. under from 100 to 1,000 bar in the presence of from 0.1 to 10% by volume of hydrogen, based on the amount of carbon monoxide used.
摘要翻译：烷基戊烯酸酯是通过使丁二烯与一氧化碳和链烷醇在羰基钴配合物和叔芳族杂环氮碱存在下，在80-160℃，100-1,000巴下，存在0.1当量至10体积％的氢气，基于所用一氧化碳的量。

6. 发明授权

US4777284A Continuous preparation of carbalkoxy-containing aliphatic compounds 失效
标题翻译：连续制备含有烷氧基的脂族化合物
公开(公告)号：US4777284A
公开(公告)日：1988-10-11
申请号：US116877
申请日：1987-11-05
申请人： Robert Maerkl , Werner Bertleff , Gebhard Kuehn , Paul Panitz , Peter Stops , Rudolf Kummer , Guenter Schuch
发明人： Robert Maerkl , Werner Bertleff , Gebhard Kuehn , Paul Panitz , Peter Stops , Rudolf Kummer , Guenter Schuch
IPC分类号： B01J31/20 , B01J31/00 , C07B61/00 , C07C67/30 , C07C67/38 , C07C69/003 , C07C69/34 , C07C69/44 , C07C69/533 , C07C69/593
CPC分类号： C07C67/38
摘要： Carbalkoxy-containing aliphatic compounds are prepared continuously by reacting an olefinically unsaturated aliphatic compound with carbon monoxide and an alkanol in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base at from 80.degree. to 200.degree. C. and under from 100 to 1,200 bar by an improved process in which carbon monoxide is circulated, and a carbon dioxide content of from 0.1 to 2% by volume is maintained in the carbon monoxide fed to the reaction.
摘要翻译：在羰基催化剂和叔氮碱的存在下，在80〜200℃，100〜1200巴下，使烯属不饱和脂肪族化合物与一氧化碳和链烷醇反应制备含有链烷烃基的脂肪族化合物通过一氧化碳循环的改进方法，并且在进料到反应中的一氧化碳中维持二氧化碳含量为0.1-2体积％。

7. 发明授权

US5081313A Process for the preparation of 2,3-dialkoxypropanals 失效
标题翻译：制备2,3-二烷氧基丙酸的方法
公开(公告)号：US5081313A
公开(公告)日：1992-01-14
申请号：US528021
申请日：1990-05-23
申请人： Dieter Koeffer , Robert Maerkl , Werner Bertleff
发明人： Dieter Koeffer , Robert Maerkl , Werner Bertleff
IPC分类号： B01J31/04 , B01J31/20 , B01J31/24 , C07B61/00 , C07C45/49 , C07C45/50 , C07C47/198
CPC分类号： C07C45/49
摘要： The preparation of 2,3-dialkoxypropanals of the general formula I ##STR1## in which R.sup.1 and R.sup.2 denote C.sub.1 -C.sub.8 -alkyl or C.sub.5 - or C.sub.6 -cycloalkyl which may or may not bear substituents which are inert under the conditions of the reaction, wherein a 1,2-dialkoxy ethene of the general formula IIR.sup.1 O--HC.dbd.CH--OR.sup.2 (II)is reacted with carbon monoxide and hydrogen in the presence of a rhodium-containing catalyst.
摘要翻译：制备通式I（I）的2,3-二烷氧基丙醛，其中R 1和R 2表示可在或不具有在条件下为惰性的取代基的C 1 -C 8 - 烷基或C 5 - 或C 6 - 环烷基的反应，其中在含铑催化剂存在下，将通式II的R 1 -O-HC = CH-OR 2（II）的1,2-二烷氧基乙烯与一氧化碳和氢气反应。

8. 发明授权

US4740525A Preparation of ethylene glycol 失效
标题翻译：乙二醇的制备
公开(公告)号：US4740525A
公开(公告)日：1988-04-26
申请号：US900770
申请日：1986-08-26
申请人： Robert Maerkl , Werner Bertleff , Wolfgang Harder , Rudolf Kummer
发明人： Robert Maerkl , Werner Bertleff , Wolfgang Harder , Rudolf Kummer
IPC分类号： C07B61/00 , B01J31/00 , C07C29/158 , C07C27/06 , C07C31/20
CPC分类号： C07C29/158 , Y02P20/52
摘要： Ethylene glycol is prepared from carbon monoxide and hydrogen in homogeneous liquid phase under superatmospheric pressure and at elevated temperature in the presence of a rhodium-containing catalyst and in the presence of an organic solvent, the organic solvent used being a C.sub.2 -C.sub.20 -n-alkanol and the concentration of this alkanol, based on the total amount of the mixture, constantly being maintained at not less than 50% by weight.
摘要翻译：乙二醇由均一液相中的一氧化碳和氢气在超大气压和升高的温度下在含铑催化剂存在下制备，并且在有机溶剂存在下，所用的有机溶剂是C 2 -C 20正 - 链烷醇和该烷醇的浓度，基于混合物的总量，不断保持在不小于50重量％。

9. 发明授权

US4724241A Preparation of ethylene glycol 失效
标题翻译：乙二醇的制备
公开(公告)号：US4724241A
公开(公告)日：1988-02-09
申请号：US42158
申请日：1987-04-24
申请人： Robert Maerkl , Wolfgang Harder
发明人： Robert Maerkl , Wolfgang Harder
IPC分类号： C07B61/00 , B01J23/00 , B01J31/00 , C07C27/00 , C07C27/06 , C07C29/15 , C07C29/158 , C07C31/20 , C07C67/00
CPC分类号： C07C29/158 , Y02P20/52
摘要： Ethylene glycol is prepared from carbon monoxide and hydrogen in a homogeneous liquid phase under superatmospheric pressure and at elevated temperatures in the presence of a rhodium-containing catalyst and in the presence of a porphyrin as organic nitrogen-containing promoter.
摘要翻译：乙二醇由均一液相中的一氧化碳和氢气在超大气压和升高的温度下，在含铑催化剂存在下和在作为有机含氮促进剂的卟啉存在下制备。

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